JPS59208098A - Improvement of adhesive strength of paint film formed by anionic electrodeposition - Google Patents
Improvement of adhesive strength of paint film formed by anionic electrodepositionInfo
- Publication number
- JPS59208098A JPS59208098A JP8379383A JP8379383A JPS59208098A JP S59208098 A JPS59208098 A JP S59208098A JP 8379383 A JP8379383 A JP 8379383A JP 8379383 A JP8379383 A JP 8379383A JP S59208098 A JPS59208098 A JP S59208098A
- Authority
- JP
- Japan
- Prior art keywords
- plating
- electrolysis
- plated
- anionic electrodeposition
- adhesive strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Electrochemical Coating By Surface Reaction (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、金属めっきされた物品の表面にアニオン電着
塗装を施こす際に、その塗膜の密着性を向上させる前処
理方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a pretreatment method for improving the adhesion of a coating film when applying anion electrodeposition coating to the surface of a metal-plated article.
従来から鉄、銅、黄銅、白銅、亜鉛、アルミニウムなど
の金属製物品はむろんのこと、合成樹脂製物品に対して
も、防食性、耐食性ないしは装飾目的を以って、広く金
属めっきが為されて来た。Conventionally, metal plating has been widely applied not only to articles made of metals such as iron, copper, brass, cupronickel, zinc, and aluminum, but also to articles made of synthetic resin for anticorrosion, corrosion resistance, or decorative purposes. I came.
ところが、めっき金属がニッケルＮｉとかニッケル合金
である場合には、硫黄酸化物ＳＯ工金含有雰囲気中、極
めて短時間で黒変を来し、人体に由来する汗や湿気によ
っても、光沢を失ったり変色したりする。めっき金属が
金、銀、ロジウムなどのような貴金属である場合には、
上記のような化学変化や変色はないけれども、その価格
が高価であるために、厚いめっきを施こすことは経済的
に困難で、きわめて薄いめっき層となっている。これが
ために、使用中に屡々めっき層か摩耗し、既述した防食
等のめつき目的が果せないものとなっている。また外観
的には、めっきに使用されている金属の種類に特有な金
属光沢が尊重される場合もあるが、もつと緩和された金
属光沢や、他の色彩が要求されることも少くない。However, if the plating metal is nickel or nickel alloy, it will turn black in an extremely short period of time in an atmosphere containing sulfur oxide SO-plated metal, and may lose its luster due to sweat and moisture from the human body. It may change color. If the plating metal is a precious metal such as gold, silver, rhodium, etc.
Although there is no chemical change or discoloration as described above, due to its high price, it is economically difficult to apply thick plating, resulting in an extremely thin plating layer. For this reason, the plating layer often wears out during use, making it impossible to achieve the purpose of plating, such as anticorrosion, as described above. In addition, in terms of appearance, although the metallic luster characteristic of the type of metal used for plating is respected in some cases, it is often the case that a milder metallic luster or other colors are required.
これがために、金属めっき層の上に透明ないし半透明、
もしくは各種色彩の塗料を塗装することが試みられて来
た。そのような塗装方法として、一般には、浸漬法ない
しスプレー法が用いられる。This makes the metal plating layer transparent or semi-transparent.
Alternatively, attempts have been made to paint it with various colors of paint. As such a coating method, a dipping method or a spray method is generally used.
これら塗装方法でも、塗装さるべきめっきされている物
品の外形が単純である場合には、比較的均一に塗装を施
こすことも不可能ではないが、外形が複雑なものでは、
スプレー法によってさえもいわゆるタレやカブリが発生
し易く、均一な塗膜を得ることけ置部である。その上、
これら方法では通常塗料中の有機溶剤例えばシンナーに
よる環境衛生上の難点があり、また、塗装作業そのもの
から云っても、塗料粘度の調整などに特別な技能が必要
とされ、かつ塗装能率も低い。 ゛しかもめつき
された物品表面への上述した塗装には、根本的とも云う
べき難点がある。それは、めっき層と塗膜との間の密着
性が悪く、塗膜が剥離し易いということである。通常物
品表面に施こされているめっき層の表面は極めて平滑で
あるがために、塗膜と機械的に密着し難いということの
ほか、めっき層金属には、酸化な絶し不働態化のような
経時変化があり、それに起因して塗膜との密着が悪くな
ることが知られている。また、従来のすべての場合が、
めっき工程と塗装工程とは、必然的に独立した別工程と
して構成されているので、油や塵挨などがめつき層表面
を汚染し、それが密着性不良の誘因ともなっている。Even with these coating methods, if the outer shape of the plated item to be coated is simple, it is possible to apply the coating relatively uniformly, but if the outer shape is complex,
Even with the spray method, so-called sagging and fogging tend to occur, and it is difficult to obtain a uniform coating film. On top of that,
These methods usually have problems in terms of environmental hygiene due to organic solvents such as thinners in the paint, and the painting process itself requires special skills such as adjusting the viscosity of the paint, and the painting efficiency is low. Moreover, the above-mentioned coating on the surface of a plated article has some fundamental drawbacks. This means that the adhesion between the plating layer and the coating film is poor, and the coating film is likely to peel off. Since the surface of the plating layer that is normally applied to the surface of the product is extremely smooth, it is difficult to mechanically adhere to the coating film. It is known that there is a change over time, which causes poor adhesion with the paint film. Also, in all conventional cases,
Since the plating process and the painting process are necessarily separate and separate processes, oil, dust, etc. contaminate the surface of the plating layer, which also causes poor adhesion.
本発明は、上述したような観点から為されたものであっ
て、めっきされた物品を、アニオン電着塗装するに先立
って、６価クロムイオン含有水溶液を電解浴（以下、ク
ロムイオン電解浴と略す）として陰極電解することを特
徴とするめつき層への塗膜の密着性向上方法であり、工
程的には、金属めっき工程から、この陰極電解を経て、
アニオン電着塗装工程へと直結させることができるので
ある。The present invention has been made from the above-mentioned viewpoint, and prior to applying anion electrodeposition coating to a plated article, an aqueous solution containing hexavalent chromium ions is applied to an electrolytic bath (hereinafter referred to as a chromium ion electrolytic bath). This is a method for improving the adhesion of a coating film to a plating layer, which is characterized by cathodic electrolysis (abbreviated), and the process is from the metal plating process, through this cathodic electrolysis,
It can be directly connected to the anion electrodeposition coating process.
本発明に適用されるめっきされた物品とは、電解めっき
、無電解めっき、溶融めっきなどすべてのめつき方法に
よってめっきされた物品を含み、めっき金属の種類とし
ては、Ｎｔ ＋ Ａｕ、＋ Ｚｎ ＋ ｃｒなどの単独
のほか、ｓ、 ｃ、 ｌ ５ＴＬＮ４ Ｃｕｒ ＋
Ｎｉ−Ｃｏ、ＳニーＣｏなどの合金も含まれる。めっき
されている物品の素材は金属のほか、導電性を付与され
た合成樹脂および表面に導電性が付与されている合成樹
脂が含まれる。そのような合成樹脂としてけＡＢＳ樹脂
のような複合性樹脂、ポリプロピレンのようなポリオレ
フィン系樹脂、ナイロンのようなポリアミド系樹脂など
を挙けることができる。The plated articles applied to the present invention include articles plated by all plating methods such as electrolytic plating, electroless plating, and hot-dip plating, and the types of plated metals include Nt + Au, + Zn + In addition to single such as cr, s, c, l 5TLN4 Cur +
Also included are alloys such as Ni-Co and Snee-Co. In addition to metals, the materials of plated articles include synthetic resins that have been given conductivity and synthetic resins whose surfaces have been given conductivity. Examples of such synthetic resins include composite resins such as ABS resins, polyolefin resins such as polypropylene, and polyamide resins such as nylon.
本発明に使用する電解浴たる６価クロムイオン含有水溶
液とは、ＣＩ ５〜１００ ｆ／ｉｔを含み、ＰＨＯ〜
１０の水溶液であって、電解触媒として、ＣＩ 、
５０４”−、ＣＯＯ−、Ｆ−、！−、Ｂ；’： など
のアニオンを一種もしくけ二種以上、０．Ｏ１〜ｌｐ／
Ａの範囲で含有するも差支えない。ｃｒ の供給源と
しては、クロム酸またはその塩１例えばクロム酸カリウ
ム、クロム酸アンモニウム、クロム酸ナトリウム、重ク
ロム酸アンモニウム、重クロム酸ナトリウム、重クロム
酸カリウムなどが挙げられる。The aqueous solution containing hexavalent chromium ions, which is the electrolytic bath used in the present invention, contains CI 5 to 100 f/it and PHO to
10 aqueous solution, as an electrocatalyst, CI,
504''-, COO-, F-, !-, B;': Two or more types of anions such as 0.O1 to lp/
It may be contained within the range of A. Sources of cr include chromic acid or its salts 1 such as potassium chromate, ammonium chromate, sodium chromate, ammonium dichromate, sodium dichromate, potassium dichromate, and the like.
このよう、な電解浴によるめっきされた物品を陰極電解
するとは、該物品を常法通りその係着用治具に係着させ
た状態で洛中に浸漬し、訃ろんこのものを陰極として電
解するのである。To cathodely electrolyze an article plated in an electrolytic bath in this way, the article is immersed in water while attached to a fixing jig in the usual way, and electrolyzed using a corpse as a cathode. It is.
電解条件としては、浴温１０〜８０°Ｃ１好ましくは２
０〜６０°Ｃ、ＤＫ Ｏ，２〜１０ Ａ／ｄ扉２で３０
秒〜１０分程度が適当とされる。陽極には通常用いられ
てψるステンレス、カーボン、鉛、鉛−スズ合金が用い
られる。如上数値は本発明者らが実、験的に得た数値で
ある。The electrolytic conditions include a bath temperature of 10 to 80°C, preferably 2°C.
0~60°C, DK O, 2~10 A/d 30 at door 2
A period of about seconds to 10 minutes is considered appropriate. For the anode, commonly used stainless steel, carbon, lead, or lead-tin alloy is used. The above numerical values are actually numerical values obtained experimentally by the present inventors.
上述したところにより、陰極電解を行うと、物品のめつ
き層の表面には、無色迭明な６価りロムヲ含むクロメー
ト皮膜が形成される。このクロメート皮膜が、つき゛に
施こされるアニオン電着塗膜とのバインダの役割を果す
ものと考えられる。As described above, when cathodic electrolysis is performed, a colorless and clear chromate film containing hexavalent ROM is formed on the surface of the plating layer of the article. It is believed that this chromate film acts as a binder with the anionic electrodeposition coating that is subsequently applied.
本発明方法にあっては、このようなりロメート皮膜の上
に水性塗料のアニオン電着塗装が施こされるのである。In the method of the present invention, anionic electrodeposition of a water-based paint is thus applied on the romate film.
そのような水性塗料としては、アクリル樹脂、フェノー
ル−アルデヒド初期縮合物、エーテル化メラミン樹后、
アミン中和アルキッド樹脂などをビヒクルとした市販の
ものがそのま＼使用できる。電着条件は、従来のアニオ
ン電着塗装法の条件ととくに異らない。Such water-based paints include acrylic resins, phenol-aldehyde initial condensates, etherified melamine resins,
Commercially available products with vehicles such as amine-neutralized alkyd resins can be used as is. The electrodeposition conditions are not particularly different from those of conventional anionic electrodeposition coating methods.
電着後は、常法通り塗膜硬化処理、例えば１６０〜２０
０″Ｃが適用され、こ＼に本発明に係るめっき物品表面
への塗装は完結する。After electrodeposition, the coating film is cured as usual, e.g.
0''C is applied, and the coating on the surface of the plated article according to the present invention is completed.
本発明前処理を適用すると、同じ水性塗料の塗膜でも、
めっき層に対する著しい密着性の向上が認められる。こ
の密着性の試験には、つぎに記すＡ −Ｅなる５種の試
験法を採用した。When the pretreatment of the present invention is applied, even with the same water-based paint film,
A significant improvement in adhesion to the plating layer is observed. For this adhesion test, the following five test methods A to E were adopted.
Ａ：テープ剥離・・・・・・ＪＩＳ Ｋ−５４００Ｂ
：アセトン浸漬・・・・・・アセトン（試薬１級）中
に２４時間浸漬後、テープハクリ（クロスカット）。A: Tape peeling...JIS K-5400B
: Acetone immersion... After immersion in acetone (1st class reagent) for 24 hours, tape peeling (cross cut).
Ｃ：エタノール浸漬・・・・・・エタノール（試薬１級
）中に４８時間浸漬後、テープハクリ（クロスカット
）。C: Ethanol immersion: After 48 hours of immersion in ethanol (grade 1 reagent), tape peeling (cross cutting).
Ｄ ： キャステスト・・・・・・ＪＩＳ Ｈ８６１
０による（４８Ａ）。D: Cast test...JIS H861
According to 0 (48A).
Ｅ ：エリクセン・・・・・・ ＪＩＳ Ｂ７７２９
によるエリクセン試験機を用い、６間押出し後テープハ
クリ。E: Eriksen...JIS B7729
After extrusion for 6 hours, peel off the tape using an Erichsen testing machine.
実施例１
黄銅板（７Ｘ １５ Ｘｏ、３ｃｍ）を、常法通り電解
用の係着用治具に係着し、常法通り電解法によって厚さ
５μのＮｉめつきを施し、さらに浴のみを替。Example 1 A brass plate (7 x 15 .
えて、その上に厚さ０．１μのムめつきを施した。Then, a 0.1 μm thick layer was applied thereon.
係着用治具から取外すことなくこのものを陰極とし、１
８−８ステンレスを陽極として、次記のクロムイオン電
解浴中で陰極電解を行った。Use this as a cathode without removing it from the attachment jig, and
Using 8-8 stainless steel as an anode, cathode electrolysis was performed in the following chromium ion electrolytic bath.
クロムイオン電解浴
重クロム酸カリ ・・・・・・・・・・・・・・・・・
・・・・・・・ １２ｏｇ／１２硫酸アンモニウム・・
・・・・・・・・・・・・・・・・・・・ ０゜ｓ ｇ
／ｌＰＨ・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・ ４．３電解条
件
浴温 ・・・・・・−・・・・・・・・・・・・・・
−・・・・・・・・・・・・・・・・・ ４５°Ｃ電流
密度（ＤＫ）・・・・・・・・・・・・・・・・・・・
・・・・・・・・ ３ Ａ ／ ｃｈｎ ２電解時間
・・・・・−・・・・・・・・・・・・・・・・・・・
−・・・・・・・・・ ２分間上記陰極電解が済んだら
直ちにこれを浴から引き上げ、係着具に係着したま＼水
洗槽内です＼ぎ洗いしたのち、引きつソいて同じ係着具
に係着したま＼、アニオン電着塗装を−行った。Chromium ion electrolytic bath Potassium dichromate ・・・・・・・・・・・・・・・・・・
・・・・・・ 12og/12 ammonium sulfate・・
・・・・・・・・・・・・・・・・・・ 0゜s g
/lPH・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・ 4.3 Electrolysis conditions Bath temperature ・・・・・・－・・・・・・・・・・・・・・・
−・・・・・・・・・・・・・・・・・・ 45°C current density (DK)・・・・・・・・・・・・・・・・・・
・・・・・・・・・ 3 A / chn 2 electrolysis time
・・・・・・－・・・・・・・・・・・・・・・・・・
−・・・・・・・・・ Immediately after the cathodic electrolysis described above for 2 minutes is completed, take it out of the bath, keep it attached to the attachment device, and wash it. While attached to the garment, anion electrodeposition coating was applied.
即ち、固形分１２％のアニオン型アクリル系熱硬化性樹
脂電着塗料浴中に懸吊し、これを陽極とし、１８−８ス
テンレスを陰極として、電圧１００■、浴温２５°Ｃで
１分間通電した。That is, it was suspended in an anionic thermosetting acrylic resin electrodeposition paint bath with a solid content of 12%, and this was used as an anode, and 18-8 stainless steel was used as a cathode, and a voltage of 100 μ was applied for 1 minute at a bath temperature of 25°C. The power was turned on.
通電が完了したら、これを塗料浴から引き上げ、ついで
１７０°Ｃ９２０分間の焼付処理を行った。得られた塗
膜の密着性の試験結果は、クロムイオン電解浴電解を行
わない比較例１と共に第１表に併記した通りである。After energization was completed, it was taken out of the paint bath and then baked at 170° C. for 920 minutes. The test results of the adhesion of the obtained coating film are shown in Table 1 together with Comparative Example 1 in which chromium ion electrolytic bath electrolysis was not performed.
実施例２
厚さ１０μにＮｉの電解めっきを施した鉄板（７Ｘ １
５ Ｘ ０．３ｏｎ ）を用い、これを次記クロムイオ
ン電解洛中で実施例１と同様にして陰極電解を行った。Example 2 Iron plate (7X 1
5 x 0.3 on), and cathode electrolysis was carried out in the same manner as in Example 1 in the following chromium ion electrolyte.
クロムイオン電解浴
クロム酸カリウム・・・−・・・・・・・・・・・・・
・ ５０ｙ／１酢酸ナトリウム ・・・・・・・・・・
・・・・・・・・・・・ １ ｙ／ＩＰＨ・・・・・・
・−・・・・・・・・・・・・・・・・・・−・・・・
・・・・・・・・ ８．０電解条件
浴温 ・・・・・・・・・・・・・・・・−・・・・
・・・・・・・・−・・・・・・ ２５°Ｃ電解密度（
ＤＫ）・・・・・−・・・・・・・・・・・・・・−・
・・ ０ 、５ Ａ／ｄｒｎ２電解時間・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・ ５分間通電完了後該電解浴から引上げて、水洗し、
同じ係着具に係着したま＼、下記アニオン電着塗装を行
った。この塗装に用いた塗料および電解条件は実施例１
と同じである。塗装後に行われた焼付は条件も、実施例
１と同じ＜１７０°Ｃｌ２Ｏ分とした。Chromium ion electrolytic bath Potassium chromate・・・・・・・・・・・・・・・・・・
・ 50y/1 sodium acetate ・・・・・・・・・・・
・・・・・・・・・・・・ 1 y/IPH・・・・・・
・－・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・ 8.0 Electrolysis conditions Bath temperature ・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・−・・・・・・ 25°C electrolytic density (
DK)・・・・・・－・・・・・・・・・・・・・・・・・・
...0,5 A/drn2 electrolysis time...
・・・・・・・・・・・・・・・・・・・・・・・・
- After 5 minutes of energization, pull it out of the electrolytic bath and wash it with water.
While it was attached to the same attachment tool, the following anion electrodeposition coating was applied. The paint and electrolytic conditions used for this coating are as shown in Example 1.
is the same as The baking conditions after painting were the same as in Example 1, <170° Cl2O content.
得られた塗膜の密着性試験成績は、クロムイオン電解浴
電解を省略した比較例２と共に第１表、に併載した通り
である。The results of the adhesion test of the obtained coating film are listed in Table 1 together with Comparative Example 2 in which chromium ion electrolytic bath electrolysis was omitted.
実施例３
厚さ５μの光沢ＺｒＬめつきを施した鉄板（７×１５Ｘ
０．３ｃＩｎ）を用ψ、次記クロムイオン電解浴中で実
施例１と同様にして陰極電解を行った。Example 3 Iron plate (7×15×
Cathode electrolysis was carried out in the same manner as in Example 1 in the following chromium ion electrolytic bath using 0.3 cIn).
クロムイオン電解浴
重クロム酸アンモニウム・・・・・・・・・・・・５０
ｇ／（１クロム酸カリウム・−・・・−・・・−・・・
・・・・・・・・・・３５１／１１塩化カリウム ・・
・・・・・−・−・・・・・・・・・・−・・・−・・
・・ ｌｆ！／ｎＰＨ・−・・・・・・・・・・・−・
・・・・−・・・・・・・・・・・・・・・・・・・・
−・ ５．５電解条件
浴温 ・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・６０°Ｃ
電流密度（ＤＫ）・・・・・・・・・・・・・・・・・
・・・・・・・−・・・−・３Ａ／ｄ、ｘ２時間 ・・
・・・・・・・・・・・・・・・・・−・・・・・・・
・・・・・−・・・・・・・−・・・・・・・３分間通
電完了後、実施例１と同じ塗料、電解条件で電着塗装を
行い、ついで同様に１７０°Ｃｌ２Ｏ分の焼実施例
塗膜の密着性試験成績は、クロムイオン電解洛中の電解
を省略したものである比較例３と共に、第１表に記載し
た通りである。Chromium ion electrolytic bath Ammonium dichromate・・・・・・・・・50
g/(1 Potassium chromate・・・・・・・・・・−・・・
・・・・・・・・・351/11 Potassium chloride ・・
・・・・・・−・−・・・・・・・・・・−・・・−・・
・・lf! /nPH・-・・・・・・・・・・・・
・・・－・・・・・・・・・・・・・・・・・・・・・
−・ 5.5 Electrolysis conditions Bath temperature ・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・60°C
Current density (DK)・・・・・・・・・・・・・・・・・・
・・・・・・・・・−・・・−・3A/d, x2 hours ・・
・・・・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・－・・・・・・・・・・・・・・・・・・ After 3 minutes of energization, electrodeposition was applied using the same paint and electrolytic conditions as in Example 1, and then 170° Cl2O was applied in the same manner. The adhesion test results of the coating films of the baked examples are as listed in Table 1, along with Comparative Example 3 in which the electrolysis during chromium ion electrolysis was omitted.
本発明方法によれば、上述の通り通常の金属めっきを施
したのち、同じ治具でクロムイオン電解洛中の陰極電解
が行われ、引上げて係着用治具から取り外すことなく、
電着塗装工程ないしは焼付は工程まで、一連の工程とし
て表面処理が遂行されるので、作業工程は格段に合理化
されるのである。しかも、金属めっき工程と電着塗装工
程間に、めっき金属の不動態化とか、汚染が生ずるとか
の子地がないので、得られた塗膜の密着性にすぐれるの
である。According to the method of the present invention, after normal metal plating is applied as described above, cathode electrolysis during chromium ion electrolysis is performed in the same jig, without being pulled up and removed from the attachment jig.
Since the surface treatment is performed as a series of steps, including the electrodeposition coating process or baking process, the work process is significantly streamlined. Moreover, since there is no passivation or contamination of the plated metal between the metal plating process and the electrodeposition coating process, the resulting coating film has excellent adhesion.
出願人 清水商事株式会社 代理人 弁理土石間壬生弥 （ほか１名）Applicant: Shimizu Shoji Co., Ltd. Agent: Patent attorney Mibuya Doishima (1 other person)
Claims (1)
、６価クロムイオン含有水溶液をＮＭ浴として陰極電解
することを特徴とするアニオン電着塗膜の密着性向上法A method for improving the adhesion of an anionic electrodeposition coating film, which comprises cathodic electrolyzing an aqueous solution containing hexavalent chromium ions as an NM bath prior to anionic electrodeposition coating on a plated article.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8379383A JPS59208098A (en) | 1983-05-12 | 1983-05-12 | Improvement of adhesive strength of paint film formed by anionic electrodeposition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8379383A JPS59208098A (en) | 1983-05-12 | 1983-05-12 | Improvement of adhesive strength of paint film formed by anionic electrodeposition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59208098A true JPS59208098A (en) | 1984-11-26 |
| JPH0130920B2 JPH0130920B2 (en) | 1989-06-22 |
Family
ID=13812522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8379383A Granted JPS59208098A (en) | 1983-05-12 | 1983-05-12 | Improvement of adhesive strength of paint film formed by anionic electrodeposition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59208098A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60211081A (en) * | 1984-04-04 | 1985-10-23 | Nippon Steel Corp | Method and apparatus for electroplated coating |
| JPS61107199U (en) * | 1984-12-18 | 1986-07-07 | ||
| EP1302565A1 (en) * | 2001-10-11 | 2003-04-16 | FRANZ Oberflächentechnik GmbH & Co KG | Coating method for light metal alloy surfaces |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4829379A (en) * | 1971-08-16 | 1973-04-18 | ||
| JPS4925537A (en) * | 1972-06-30 | 1974-03-07 | ||
| JPS4999936A (en) * | 1972-11-28 | 1974-09-20 | ||
| JPS49100147A (en) * | 1972-11-17 | 1974-09-21 | ||
| JPS511541A (en) * | 1974-06-26 | 1976-01-08 | Shinto Paint Co Ltd | TOSOMAESHORIHOHO |
| JPS5275627A (en) * | 1975-12-20 | 1977-06-24 | Nitsutetsu Kaatenooru Kk | Surface treatment of aluminum or its alloy |
| JPS5319981A (en) * | 1976-08-09 | 1978-02-23 | Matsushita Electric Ind Co Ltd | Functional organic material |
| JPS5735697A (en) * | 1980-08-14 | 1982-02-26 | Nippon Steel Corp | Production of chromate film steel plate for vessel of superior weldability and corrosion resistance after painting |
| JPS57123999A (en) * | 1981-01-21 | 1982-08-02 | Nippon Steel Corp | Steel plate for drawn and ironed can |
-
1983
- 1983-05-12 JP JP8379383A patent/JPS59208098A/en active Granted
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4829379A (en) * | 1971-08-16 | 1973-04-18 | ||
| JPS4925537A (en) * | 1972-06-30 | 1974-03-07 | ||
| JPS49100147A (en) * | 1972-11-17 | 1974-09-21 | ||
| JPS4999936A (en) * | 1972-11-28 | 1974-09-20 | ||
| JPS511541A (en) * | 1974-06-26 | 1976-01-08 | Shinto Paint Co Ltd | TOSOMAESHORIHOHO |
| JPS5275627A (en) * | 1975-12-20 | 1977-06-24 | Nitsutetsu Kaatenooru Kk | Surface treatment of aluminum or its alloy |
| JPS5319981A (en) * | 1976-08-09 | 1978-02-23 | Matsushita Electric Ind Co Ltd | Functional organic material |
| JPS5735697A (en) * | 1980-08-14 | 1982-02-26 | Nippon Steel Corp | Production of chromate film steel plate for vessel of superior weldability and corrosion resistance after painting |
| JPS57123999A (en) * | 1981-01-21 | 1982-08-02 | Nippon Steel Corp | Steel plate for drawn and ironed can |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60211081A (en) * | 1984-04-04 | 1985-10-23 | Nippon Steel Corp | Method and apparatus for electroplated coating |
| JPS61107199U (en) * | 1984-12-18 | 1986-07-07 | ||
| EP1302565A1 (en) * | 2001-10-11 | 2003-04-16 | FRANZ Oberflächentechnik GmbH & Co KG | Coating method for light metal alloy surfaces |
| WO2003033777A1 (en) * | 2001-10-11 | 2003-04-24 | Franz Oberflächentechnik Gmbh & Co. Kg | Coating method for light metal alloy surfaces |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0130920B2 (en) | 1989-06-22 |
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