JPS59203636A - Modified fine particulate mineral and preparation thereof - Google Patents
Modified fine particulate mineral and preparation thereofInfo
- Publication number
- JPS59203636A JPS59203636A JP7490983A JP7490983A JPS59203636A JP S59203636 A JPS59203636 A JP S59203636A JP 7490983 A JP7490983 A JP 7490983A JP 7490983 A JP7490983 A JP 7490983A JP S59203636 A JPS59203636 A JP S59203636A
- Authority
- JP
- Japan
- Prior art keywords
- fine
- electromagnetic waves
- particle
- silicic acid
- electromagnetic wave
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 14
- 239000011707 mineral Substances 0.000 title claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 8
- -1 polygorskite Inorganic materials 0.000 claims abstract description 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052622 kaolinite Inorganic materials 0.000 claims abstract description 4
- 229910001919 chlorite Inorganic materials 0.000 claims abstract description 3
- 229910052619 chlorite group Inorganic materials 0.000 claims abstract description 3
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011859 microparticle Substances 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 239000003570 air Substances 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002090 carbon oxide Inorganic materials 0.000 claims 1
- 235000015243 ice cream Nutrition 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000004568 cement Substances 0.000 abstract description 6
- 239000010419 fine particle Substances 0.000 abstract description 6
- 230000003197 catalytic effect Effects 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 4
- 239000000919 ceramic Substances 0.000 abstract description 3
- 239000002893 slag Substances 0.000 abstract description 2
- 229910021647 smectite Inorganic materials 0.000 abstract description 2
- 239000004113 Sepiolite Substances 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229910000271 hectorite Inorganic materials 0.000 abstract 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052903 pyrophyllite Inorganic materials 0.000 abstract 1
- 229910052624 sepiolite Inorganic materials 0.000 abstract 1
- 235000019355 sepiolite Nutrition 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000011882 ultra-fine particle Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000000635 electron micrograph Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000005672 electromagnetic field Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- FBOUIAKEJMZPQG-AWNIVKPZSA-N (1E)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-AWNIVKPZSA-N 0.000 description 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical class C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 210000003323 beak Anatomy 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011400 blast furnace cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 235000020985 whole grains Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
Abstract
Description
【発明の詳細な説明】
本発明は請求範囲に述へた各種鉱物即ちセレ°オライド
・バルゴルスカイト・モンモリロナイト・ヘラクトライ
トを含むスメクタイト・パイロフライト・カオリナイト
又は緑泥岩・凝灰岩及び珪酸を主成分とする。水砕スラ
グ等の微粒子を大気又はその他請求範囲４Ｗ述べた雰囲
気のなかで、種々の波形の電磁波げよるエネルギーを加
えて微粒子鉱物等Ｗ歪を与え形態的変形又に、潜在的活
性即ち表面活性を形成せしめ各種工業上原料としての画
期的特性を得ようとする新規技術に関するー１ 粘土鉱
物類げおける歪については、Ｓ ４０２・Ｓ ｉＡｌの
４面体イオン、Ａ１・Ｍｇの八面体イオン（Ｅ）（Ｈ２
Ｏ）の層間イオンをもち、これ等の結晶構造は細かいｐ
Ｊがみ〃げ富む、こと昏ゴ須藤俊男（岩波書店：粘土鉱
物学）によって明かげされている。DETAILED DESCRIPTION OF THE INVENTION The present invention is based on various minerals mentioned in the claims, namely, smectite, pyrophrite, kaolinite, chlorite, tuff, and silicic acid including celeolide, balgorskite, montmorillonite, and heractolite. do. Microparticles such as granulated slag are exposed to energy from electromagnetic waves of various waveforms in the atmosphere or other atmospheres mentioned in Claim 4W to give distortion to microparticle minerals, etc., resulting in morphological deformation or latent activity, i.e., surface activity. Concerning new technology to obtain innovative properties as various industrial raw materials by forming E) (H2
O) has interlayer ions, and these crystal structures have fine p
This is revealed by Toshio Kogo Sudo (Iwanami Shoten: Clay Mineralogy), also known as J.
又、今日まで機器分析においては赤外線・紫外線その他
の電磁波の吸収現象げよって定性、定量分析に利用して
いる。Furthermore, in instrumental analysis to date, absorption phenomena of infrared rays, ultraviolet rays, and other electromagnetic waves have been utilized for qualitative and quantitative analysis.
本発明の目的とするところは、電磁波による歪によって
得られる新物質でありその新技術であるが、上述の分析
手段からもその確実な効果を実証することが出来るもの
である。The object of the present invention is a new material obtained by distortion caused by electromagnetic waves and a new technology thereof, and its reliable effects can be demonstrated by the above-mentioned analytical means.
実施例としては、モンモリロナイト微粒子を電磁波場内
を通過げしめるとき、微粒子は交番磁場電極間を極めて
高速Ｗ往復し」−イ、ルギーによる歪を受げつ瓦各粒子
は衝突し、遂げは破壊現象が見らハろ。したがって、本
発明の新技術は超微粉砕の目的ぽ利用さハることが出来
る。As an example, when fine particles of montmorillonite are passed through an electromagnetic field, they reciprocate at an extremely high speed between the alternating magnetic field electrodes. Hello! Therefore, the new technology of the present invention can be utilized for the purpose of ultrafine grinding.
ｉ（、ｉｌ］］１７よｉ］ば平均粒経約ＡＯミクロンの
粒子げ１１．０００ホルト１２０→ノ−イクル正弦波形
の交番電磁場シ通過距＊ｔｓｏｏミｖメートル１城露時
間６０秒πおいて１Ｄミク巨ン以下Ｗ得ら」また。i(,il]]17, i], particles with average particle diameter of about AO microns are 11.000 holt 120→no-cycle sinusoidal waveform alternating electromagnetic field, passing distance *tsoo m v m 1 time dew time 60 seconds π and Also, 1D Miku Giant and below W are obtained.
上記の電磁波場域げ大谷石の微粒子を仝様條件げおいて
処理し得らねた活性表面を有する微粒子と椰子穀粒状活
性炭を、各種ガスの吸着性能Ｗついて比較試験した。両
者１００ｇをガラス管内に収め、各種試験ガス２０１通
過速度０３１／分ばて行った。The fine particles of Oya stone subjected to the above electromagnetic wave field were subjected to different conditions, and the fine particles having an active surface that could not be treated were compared with coconut grain-shaped activated carbon in terms of their adsorption performance W for various gases. 100 g of both were placed in a glass tube, and various test gases 201 were passed through at a rate of 031/min.
２ 特許を青水範囲πおいて述へた各種鉱物のうち凝灰
岩微粉末に約５．０００ガウスの磁場の存在πおいて電
力！”３０Ｗ１．０００Ｖ、３００サイクル発生紫例紳
２，５３７Ａ’及び１、８４９ Ａｏぼ曝露した。その
結果、３０，０００倍の電子顕微鏡写真（Ｎは曝露前で
あり、２２，５００倍の電子顕微鏡写真（Ｂｊは曝露后
を示す。2 Among the various minerals described in the patent in the blue water range π, the presence of a magnetic field of about 5,000 Gauss in tuff fine powder π Electric power! "30W 1.000V, 300 cycles of 2,537 A' and 1,849 Ao were exposed. As a result, 30,000x electron micrograph (N is before exposure, 22,500x electron micrograph) Photograph (Bj shows after exposure.
明かに粒子は繊維状の多重状となり、その繊維は管状を
呈し比表面積を計測すると約２６０ヘイホーメートルで
あった。The particles clearly became fibrous and multilayered, the fibers taking on a tubular shape, and the specific surface area measured was about 260 hayometers.
この様な結果は本発明匠述べるところの改質さＪまた微
粒子鉱物である。この改質微粒子鉱物をポルトランドセ
メント・早強セメント・高炉セメント・シリカセメント
・アルミナセメント或は各種の混合セメント・石膏・石
灰などγよる水硬性物質粉末等に１〜１０％、このもし
くに７−〜５係を加えることによって水と混練したモル
タル又は適宜細骨材及び粗嘴材を混練して得られるコン
クリートｔ′ｉ、いづれも７゛リーノング水の生成は極
めて少くよく水利反応を促進することが出来だ。Such a result is a modification of the fine-grained mineral described by the inventor of the present invention. This modified fine particle mineral is added to Portland cement, early-strength cement, blast furnace cement, silica cement, alumina cement, various mixed cements, gypsum, lime, and other hydraulic material powders based on γ, at a concentration of 1 to 10%, or 7%. - Concrete t'i obtained by mixing mortar with water or kneading appropriate fine aggregate and coarse beak material by adding 5 parts, both generate very little water and promote water use reaction well. It's possible.
％π好ましいのは揺変性を発揮することであり、成型品
の精度は極めて良好であった。%π is preferable because it exhibits thixotropy, and the precision of the molded product was extremely good.
特にフミン酸塩の在存におけるモルタル強度試験を株式
会社銭高組青梅試験所において行ったところ下記のよう
な結果を得た。In particular, a mortar strength test in the presence of humic acid salts was conducted at Zenitakagumi Ome Testing Laboratory, and the following results were obtained.
上記の結果は有機物を含む土砂、山砂利を骨材として使
用してイ）充分な強度を得ることが出来ることを示すも
のであり、さらに有機物を含むンイルセメントの強度も
満足すべき結果を得ることを示唆するものであって、且
つ土質改良材として効用を発揮しうるものである。 □
さらば、モルタル、発華現象を防止しクラックの発生を
防止することは上記のデーター及び改質粒子構造からも
有効であることは明かである。The above results show that a) sufficient strength can be obtained by using earth and sand and mountain gravel containing organic matter as aggregates, and furthermore, the strength of organic cement containing organic matter also showed satisfactory results. This suggests that the soil can be obtained, and it can also be effective as a soil conditioner. □ Goodbye mortar, it is clear from the above data and modified particle structure that preventing the blooming phenomenon and preventing the occurrence of cracks is effective.
３ 触媒効果
セビオライト・セオライト・カオリナイト等は触媒活性
をもっことは周知のことであるが、本発明Ｗおいて改質
さゎだセ車−°オライド・七オライド・カオリナイト及
びモンモリロナイトその他の鉱物微粒子の触媒活性は電
子顕微鏡写真〃示すように極めて顕著であることは明か
であり、さらπ固定化酵素の担持体及びバイオセンサー
担持体として有効な構造をもっことを示唆している。3. Catalytic effect It is well known that seviolite, theolite, kaolinite, etc. have catalytic activity. It is clear that the catalytic activity of the microparticles is extremely remarkable as shown in the electron micrograph, further suggesting that they have a structure that is effective as a support for a π-immobilized enzyme and a support for a biosensor.
４ セラミックスへの応用効果
本発明による改質全粒鉱物は活性表面のＯＨ基Ｗよるが
らみあ（・によって、水〃よって練合し成型固結するこ
とが出来る。4 Effects of application to ceramics The modified whole-grain mineral according to the present invention can be kneaded with water and molded and solidified due to the OH group W on the active surface.
こわな５００〜８００″ＣＫ加熱することπよってセラ
ミック化の方向πす〜みｉ、ｏｏｏ”ｃ〜１，２００″
Ｃにおいては寸法精度よくセラミック化する。500~800" CK Heating π Therefore, direction of ceramicization π sumi, ooo"c ~ 1,200''
In C, ceramic is formed with good dimensional accuracy.
又、さらに４？徴あることは自己固結性をもたない鉱物
をあたかも粘結剤を用いたようＷ随伴固結することが出
来た。Also, 4 more? One notable finding is that minerals that do not have self-consolidation properties can be consolidated with W, as if using a binder.
Claims (1)
゛オライド・パルゴルスカイト・モンモリロナイト・ヘ
ラクトライト・を含む７メクタイト・パイロフライト・
カオリナイト又は緑泥岩・凝灰岩及び珪酸を主成分とす
る水砕高炉フラグ上記の各種鉱物のウモの単独又は二つ
以上の鉱物の混合物又は複合体として得られる構造をも
つ鉱物の微粉末粒に紫外縁領域（５１０〜Ａ ０００
Ａ”）或は遠赤外線領域の電磁波を作用させて得られる
改質さＪｌだ微粒子鉱物の製品及び製造法π関する。 ２ 前記の各種鉱物結晶の固有振動数π共振ずろよ５な
周波数の電磁波を与え、結晶構造π顕在又は潜在する歪
を与える方法。 ６ 前記各種鉱物結晶粒子に与える電磁波は磁場の存在
のうちであること、及び電磁波及び磁場は交番電磁波で
あり、磁場も極性は交番交替である。又、その波形は鋸
歯状、正弦波の各種を制限するものではない。 ４ 前記２３の方法は大気・望素・酸素・氷菓・水蒸気
・７ンモニア・−酸化炭素・二酸化炭素の各成分の１つ
又は２つ以上の混合気体であり、その混合比率げ０から
１００％における雰囲気において行（・ゴハろ８[Claims] 1. A mineral containing 1'0% or more of silicic acid, such as 7P
7 mectites, pyrophrite, including olide, palgorskite, montmorillonite, heractolite,
A granulated blast furnace flag containing kaolinite, chlorite, tuff, and silicic acid as its main components. Edge area (510~A 000
A") Or it relates to products and manufacturing methods of modified microparticle minerals obtained by applying electromagnetic waves in the far-infrared region. 2. Electromagnetic waves with frequencies of 5 different from the natural frequency π resonance of the various mineral crystals mentioned above. 6. The electromagnetic waves applied to the various mineral crystal particles are in the presence of a magnetic field, and the electromagnetic waves and the magnetic field are alternating electromagnetic waves, and the magnetic field also has an alternating polarity. In addition, the waveform is not limited to sawtooth and sine waves. 4 The above 23 methods can be applied to each of air, oxygen, oxygen, ice cream, water vapor, ammonia, carbon oxide, and carbon dioxide. It is a mixed gas of one or more components, and is carried out in an atmosphere with a mixing ratio of 0 to 100% (・Goharo 8
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7490983A JPS59203636A (en) | 1983-04-30 | 1983-04-30 | Modified fine particulate mineral and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7490983A JPS59203636A (en) | 1983-04-30 | 1983-04-30 | Modified fine particulate mineral and preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59203636A true JPS59203636A (en) | 1984-11-17 |
Family
ID=13560980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7490983A Pending JPS59203636A (en) | 1983-04-30 | 1983-04-30 | Modified fine particulate mineral and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59203636A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030039390A (en) * | 2001-11-12 | 2003-05-22 | 이성문 | Industrial waste Waste limestone Bioball and Sludge bioball The building materials and sea trivet for road breakwater, road boundary stone and manufacturing method thereof. |
| JP2005512792A (en) * | 2001-12-12 | 2005-05-12 | ドゥ−コープ テクノロジーズ リミテッド | Thermal process using cold RF-irradiated liquid as a basic method for producing nano-sized particles |
-
1983
- 1983-04-30 JP JP7490983A patent/JPS59203636A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030039390A (en) * | 2001-11-12 | 2003-05-22 | 이성문 | Industrial waste Waste limestone Bioball and Sludge bioball The building materials and sea trivet for road breakwater, road boundary stone and manufacturing method thereof. |
| JP2005512792A (en) * | 2001-12-12 | 2005-05-12 | ドゥ−コープ テクノロジーズ リミテッド | Thermal process using cold RF-irradiated liquid as a basic method for producing nano-sized particles |
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