JPS59120493A - Thermal transfer sheet - Google Patents

Thermal transfer sheet

Info

Publication number
JPS59120493A
JPS59120493A JP57229041A JP22904182A JPS59120493A JP S59120493 A JPS59120493 A JP S59120493A JP 57229041 A JP57229041 A JP 57229041A JP 22904182 A JP22904182 A JP 22904182A JP S59120493 A JPS59120493 A JP S59120493A
Authority
JP
Japan
Prior art keywords
heat
recording
melting point
thermal transfer
transfer sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57229041A
Other languages
Japanese (ja)
Inventor
Nobuo Oide
大出 延男
Junichi Honma
本間 純一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp, Nippon Electric Co Ltd filed Critical NEC Corp
Priority to JP57229041A priority Critical patent/JPS59120493A/en
Publication of JPS59120493A publication Critical patent/JPS59120493A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382Contact thermal transfer or sublimation processes
    • B41M5/38278Contact thermal transfer or sublimation processes using ink-containing structures, e.g. porous or microporous layers, alveoles or cellules

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Impression-Transfer Materials And Handling Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PURPOSE:The titled sheet low in cost and capable of multi-color recording and intermediate tone recording with only a single heat-sensitive recording layer, wherein a heat-sensitive recording layer comprised of particulates of plural kinds of heat-fusible inks having different melting points and a high polymer functioning as an adhesive is applied onto a base. CONSTITUTION:The heat-sensitive recording layer 20 comprised of the particulates of plural kinds of heat-fusible inks (each of which is preferably comprised of a low melting point substance such as a wax, a softener such as oleic acid and a coloring material such as a pigment or a dye) 30, 40 diferring in color tone in accordance with melting point and a high polymer (e.g., polyvinyl butyral, having a film-forming property) 50 functioning as an adhesive is applied onto the base 10 to obtain the objective thermal transfer sheet. The melting point of the high polymer 50 is preferably higher than those of the inks 30, 40. When recording, electric power supplied to a thermal head is controlled, and only the low melting point ink 30 is transferred onto a recording paper when a small quantity of electric power is supplied, while both of the inks 30, 40 are transferred when a large quantity of electric power is supplied.

Description

【発明の詳細な説明】 本発明は熱転写シート、特に中間調記録あるいは多色記
録を得ることができるようにした熱転写シートに関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermal transfer sheet, and particularly to a thermal transfer sheet capable of producing halftone recording or multicolor recording.

熱転写記録方式は基材上に熱溶融性インク層を設けた熱
転写シートを用いるもので、熱転写シートのインク層面
に普通紙を密着させ、基材側からサーマルヘッド等によ
って選択的に熱を加えることにより、前記インク層を溶
融してそのインクを普通紙に付着させた後熱転写シート
から普通紙をはく離して、普通紙上に記録を得る方式で
ある。
Thermal transfer recording method uses a thermal transfer sheet with a heat-melting ink layer on the base material. Plain paper is brought into close contact with the ink layer surface of the thermal transfer sheet, and heat is selectively applied from the base material side using a thermal head, etc. In this method, the ink layer is melted and the ink is applied to plain paper, and then the plain paper is peeled off from the thermal transfer sheet to obtain a record on the plain paper.

このような熱転写記録方式では可視記録像が普通紙上に
形成されるので、保存性の良い記録が得られるという利
点があり、プリンタやファクシミリに多く採用されてい
るが、近年カラー記録や、中間調記録への要求が高まり
、これらへの対応がなされつつある。
This type of thermal transfer recording method forms a visible recorded image on plain paper, so it has the advantage of producing records with good storage stability, and is often used in printers and facsimile machines, but in recent years color recording and halftone Demand for records is increasing and efforts are being made to meet these demands.

従来、熱転写記録方式によるカラー記録としては互に色
調の異なる複数の熱転写シートを使用する多色記録と1
枚の熱転写シートで2色の記録が可能な2色記録がある
がそれぞれには、次の様な欠点があった。色調の異なる
複数の熱転写シートを使用しての多色記録方式は1色目
の熱転写シートを用いて普通紙上に1色目の記録を行い
、次に普通紙を元の位置に戻して、2色目の熱転写シー
トを用いて2色目の記録を行い、再度普通紙を元の位置
に戻す、これを順次各色毎に繰り返して多色記録を得る
。この方法では各色の記録位置合せのため普通紙の精密
な位置合せ機構が必要になる。
Conventionally, color recording using the thermal transfer recording method includes multicolor recording using multiple thermal transfer sheets with different tones, and one
There is two-color recording that allows two-color recording with a single thermal transfer sheet, but each of them has the following drawbacks. A multicolor recording method using multiple thermal transfer sheets with different tones uses the first color thermal transfer sheet to record the first color on plain paper, then returns the plain paper to its original position and records the second color. A second color recording is performed using a thermal transfer sheet, the plain paper is returned to its original position, and this process is repeated for each color in order to obtain a multicolor recording. This method requires a precise positioning mechanism for plain paper in order to align the recording positions of each color.

またこれに使用される熱転写シートは中間調記録が不可
能なため、例えば3色の熱転写シートを用いても7色の
記録しか行えないという欠点もある。
Furthermore, since the thermal transfer sheet used for this is incapable of halftone recording, there is also the drawback that, for example, even if a three-color thermal transfer sheet is used, only seven colors can be recorded.

ここで中間調記録、例えば3階調の記録が行えるならば
3枚の熱転写シートでも27色の記録が可能となる。
If half-tone recording, for example three-tone recording, is possible, then 27 colors can be recorded even with three thermal transfer sheets.

次に2色記録可能な熱転写シートを用いた記録方式は第
1図に示すように融点と色調の異なる熱溶融性インク層
たとえば低融点インク層1と高融点インク層2とを基材
上に積層した構造のシートを用い、記録は熱転写シート
に与える熱量例えばサーマルヘッドに与える電力を変え
て、インク層1のみまたは、インク層1と2の熱溶融性
インクを普通紙上に転写させる方式である。従ってこの
方式は2色記録のみで良い場合には前述のような位置合
せ機構を不要とするが、融点の異なる熱溶融性インクを
基材3上に2屑に分けて塗布するため熱転写シートのコ
ストが高(なるという欠点がある。さらに同様な構造を
用いた中間調記録が可能な記録方式は第1図におけるイ
ンク層1と2が同一の色調を持ち着色剤濃度がインク済
1より2より高くして成る熱転写シートを用いた記録方
法で、3階調の記録が得られるが、これも同様にコスト
が高くなるという欠点を持っている。
Next, a recording method using a thermal transfer sheet capable of two-color recording is as shown in Fig. 1, in which heat-melting ink layers having different melting points and tones, such as a low-melting point ink layer 1 and a high-melting point ink layer 2, are formed on a base material. Using sheets with a laminated structure, recording is performed by changing the amount of heat applied to the thermal transfer sheet, such as the electric power applied to the thermal head, to transfer only ink layer 1 or the heat-melting ink of ink layers 1 and 2 onto plain paper. . Therefore, this method does not require the above-mentioned positioning mechanism when only two-color recording is required, but since the heat-melting ink with different melting points is applied on the base material 3 in two parts, it is necessary to use the thermal transfer sheet. The disadvantage is that the cost is high.Furthermore, a recording method that uses a similar structure and is capable of halftone recording is that the ink layers 1 and 2 in FIG. A recording method using a thermal transfer sheet with a higher height can provide three-tone recording, but this also has the disadvantage of high cost.

本発明の目的は従来の記録方式のかかる欠点を除去し、
1層のみの感熱記録層を基材上に設けた構造の熱転写シ
ートを用いたもので、2色記録あるいは中間調記録が可
能な熱転写シートを提供することにある。
The purpose of the present invention is to eliminate such drawbacks of conventional recording methods,
An object of the present invention is to provide a thermal transfer sheet that uses a thermal transfer sheet having a structure in which only one thermal recording layer is provided on a base material, and is capable of two-color recording or halftone recording.

本発明によれば融点が異なる複数種類の熱溶融性インク
の微粒子と高分子からなる感熱記録層が基材上に塗工さ
れて成ることを特徴とする熱転写シートが得られる。
According to the present invention, a thermal transfer sheet is obtained, which is characterized in that a heat-sensitive recording layer made of fine particles of a plurality of types of heat-melting inks having different melting points and a polymer is coated on a base material.

更に本発明によれば、熱溶融インクの微粒子は融点に応
じて色調の異なる少なくとも2種類の微粒子であること
を特徴とする特許請求の範囲第1項記載の熱転写シート
が得られる。
Further, according to the present invention, there is obtained a thermal transfer sheet as set forth in claim 1, wherein the fine particles of the heat-melting ink are at least two types of fine particles having different tones depending on their melting points.

更に又1本発明によれば高分子は熱溶融性インクの融点
より高い融点であることを特徴とする特許請求の範囲第
(1)項もしくは第(2)項記載の熱転写シートが得ら
れる。
Furthermore, according to the present invention, there is obtained a thermal transfer sheet as set forth in claim (1) or (2), characterized in that the polymer has a melting point higher than the melting point of the heat-melting ink.

次に本発明の実施例について図面を参照して詳細に説明
する。
Next, embodiments of the present invention will be described in detail with reference to the drawings.

第2図は本発明の一実施例である熱転写シートを示す。FIG. 2 shows a thermal transfer sheet that is an embodiment of the present invention.

第2図において、基材1oは例えばコンデンサー紙、ポ
リエステルフィルム等のシートである。感熱記録層20
は基材10に塗布され、少なくとも融点および色調(又
は着色剤の濃度)の異なる熱溶融性インクの微粒子30
.40と、これらの微粒子を基材1o上に接着させる高
分子50とから構成されている。2色記録用として用い
る場合には融点が低いある色調を有する熱#照性インク
の微粒子3oと、融点が高く、前記色調とは異なる色調
を有する熱溶融性インクの微粒子40とを含む記録層で
、中間調記録用として用いる場合には色調が同じで互い
にその融点が異なる微粒玉たとえば30と40)とを含
む記録層である。
In FIG. 2, the base material 1o is, for example, a sheet of capacitor paper, polyester film, or the like. Heat sensitive recording layer 20
is applied to the base material 10, and fine particles 30 of hot-melt ink having at least different melting points and color tones (or colorant concentrations) are applied to the base material 10.
.. 40, and a polymer 50 for adhering these fine particles onto the base material 1o. When used for two-color recording, a recording layer containing fine particles 3o of heat-luminescent ink having a certain color tone with a low melting point and fine particles 40 of heat-melting ink having a high melting point and a color tone different from the above-mentioned color tone. When used for halftone recording, the recording layer includes fine beads, such as 30 and 40), which have the same color tone but different melting points.

ここで、熱溶融性インク30と40はワックス等の低融
点物質、柔軟剤1着色剤からなっており、低融点物質と
してはポリエチレン、パラフィンワックス、カルナバワ
ックス等が用いられ、柔軟剤としてはオレイン酸、ヒマ
シ油等が用いられ1着色剤としては通常の印刷用インク
に用いられている顔料、染料が用いられる。さらに高分
子50としてはポリビニルブチラール、エポキシ樹脂等
を用いることができるが、感熱記録層を形成するために
造膜性を有することが必要である。第2図に示した熱転
写シートを用いて記録を行うには感熱記録層20側に普
通紙(図示ぜず)を接触させ、基材10側からサーマル
ヘッド(図示せず)を押しあてサーマルヘッドの発熱体
を選択的に発熱させて行うが、サーマルヘッドに供給す
る電力を制御することによって、熱溶融性インク30と
40のうち、低電力供給時には低融点インク30のみが
普通紙上へ転写され、高電力供給時には熱溶融性インク
の30と40の両方が転写されることによって、2色記
録、あるいは中間調記録ができる。
Here, the heat-melting inks 30 and 40 are made of a low melting point substance such as wax, a softener and a coloring agent, and the low melting point substance used is polyethylene, paraffin wax, carnauba wax, etc., and the softener is olein. Acid, castor oil, etc. are used, and as the coloring agent, pigments and dyes used in ordinary printing inks are used. Further, as the polymer 50, polyvinyl butyral, epoxy resin, etc. can be used, but it is necessary to have film-forming properties in order to form a heat-sensitive recording layer. To perform recording using the thermal transfer sheet shown in FIG. 2, a plain paper (not shown) is brought into contact with the heat-sensitive recording layer 20 side, and a thermal head (not shown) is pressed against the thermal head from the base material 10 side. This is done by selectively generating heat from the heating element, but by controlling the power supplied to the thermal head, out of the heat-melting inks 30 and 40, only the low-melting point ink 30 is transferred onto the plain paper when low power is supplied. When high power is supplied, both heat-fusible inks 30 and 40 are transferred, allowing two-color recording or halftone recording.

ただし2色記録の場合、高電力供給時には熱溶融性イン
ク30と40の両方の色が混色してしまうので、混色し
ても良い色、たとえば融点が高い方のインクは黒である
ことが望ましい。また高分子の融点が低融点インクより
低いか同等の場合、低電力供給では、感熱記録層全部が
普通紙上へ転写されるので、高分子の融点は熱溶融性イ
ンクの融点より高いことが望ましい。
However, in the case of two-color recording, when high power is supplied, the colors of both heat-melting inks 30 and 40 will mix, so it is desirable that the color that can be mixed, for example, the ink with a higher melting point, be black. . In addition, if the melting point of the polymer is lower than or equal to that of the low melting point ink, the entire thermosensitive recording layer will be transferred onto plain paper with low power supply, so it is desirable that the melting point of the polymer is higher than the melting point of the thermofusible ink. .

次に本発明の実施例における2色記録可能な熱転写シー
トの具体例を挙けると、まず熱溶融性インクは低融点イ
ンク(赤色)と高融点インク(黒色)とで、下記の成分
を溶融混合して作成した。
Next, to give a specific example of a two-color recordable thermal transfer sheet according to an embodiment of the present invention, first, the heat-melting ink is a low melting point ink (red) and a high melting point ink (black), and the following components are melted. Created by mixing.

低融点インク(赤色) パラフィンワックス(mp48〜50℃)  85重量
部ズダン■(着色剤)        10重量部スパ
ン20(界面活性剤)     5重量部高融点インク
(黒色) カルナバワックス(m980〜86℃)  75重量部
カーボンブラック(着色剤)     10重量部オレ
イン酸(柔軟剤)      10重量部トウィインク
0(界面活性剤)    5重量部この構成からなるそ
れぞれのインクは別個に90℃の湯中に投入して、良く
攪拌される。この熱溶融性インクはエマルジョンが作成
され、その後冷却しさらに乾燥してそれぞれ赤と黒の粒
径5μm以下の大きさの微粉末に作成される。さらに2
種類のインクの微分末(各々50重量部)は高分子とし
てのポリビニルブチラールの5重量%、エチルアルコー
ル溶液200重量部と混合攪拌される。
Low melting point ink (red) Paraffin wax (mp48~50℃) 85 parts by weight Zdan■ (colorant) 10 parts by weight Span 20 (surfactant) 5 parts by weight High melting point ink (black) Carnauba wax (mp980~86℃) 75 parts by weight Carbon black (coloring agent) 10 parts by weight Oleic acid (softener) 10 parts by weight Towi Ink 0 (surfactant) 5 parts by weight Each ink consisting of this composition was separately put into hot water at 90°C. , stir well. This hot-melt ink is made into an emulsion, which is then cooled and further dried to form fine powders with particle diameters of 5 μm or less for red and black, respectively. 2 more
Differential powders of different inks (50 parts by weight each) are mixed and stirred with 5% by weight of polyvinyl butyral as a polymer and 200 parts by weight of an ethyl alcohol solution.

熱転写シートはこの攪拌された微分末をポリエステルフ
ィルム(12μm厚さ)の基材上に塗布した後、乾燥し
て30μm厚さの感熱記録層が得られる。この熱転写シ
ートは上質紙(図示せず)と重ね合せ感熱ファクシミI
J装置で記録したところ、0.4ワツト/素子の電力で
赤色の記録が得られ、0.53ワツト/素子の電力で黒
の記録が得られた。
The thermal transfer sheet is prepared by applying the stirred differential powder onto a base material of a polyester film (12 μm thick) and then drying it to obtain a 30 μm thick heat-sensitive recording layer. This thermal transfer sheet can be overlaid with high-quality paper (not shown) and printed as a thermal facsimile I.
When recording was performed using the J apparatus, red recording was obtained with a power of 0.4 watts/device, and black recording was obtained with a power of 0.53 watts/device.

次に中間調記録用シートとしては低融点インクのズダン
■を5重量部とし、高融点インクのカーボンブラックの
替りにズダン110重量部を用いてそれぞれ低融点イン
ク30′と高融点インク40’とを作成し、前記同様の
方法で微粉末を作成し、同様の組成で熱転写シートを作
成した。この熱転写シートを用いて感熱ファクシミリ装
置で記録したところ・ 0・4ワツト/素子で記録濃度
の低い赤の記録が得られ、0.52ワツト/素子で記録
濃度の高い赤の記録が得られた。本実施例においては1
層の感熱記録層のみで少なくとも2色記録が可能であり
、さらに同様な構成で色調が互いに異なる複数の熱転写
シートを作りそれを用いて、記録電力を制御し記録紙上
に複数の記録を行うことで混合した多色のカラー記録を
行うこともできる。
Next, as a halftone recording sheet, 5 parts by weight of the low melting point ink ZDAN, and 110 parts by weight of ZDAN in place of the high melting point ink carbon black were used to form the low melting point ink 30' and the high melting point ink 40', respectively. A fine powder was prepared in the same manner as above, and a thermal transfer sheet was prepared with the same composition. When this thermal transfer sheet was used to record with a thermal facsimile machine, a red record with a low recording density was obtained at 0.4 watts/element, and a red record with a high recording density was obtained at 0.52 watts/element. . In this example, 1
At least two-color recording is possible with only the heat-sensitive recording layer of the layer, and furthermore, a plurality of thermal transfer sheets having the same structure but different tones are created and used to control the recording power and perform multiple recordings on the recording paper. It is also possible to record multiple colors by mixing them.

本発明は以上説明したように単一の記録層に融点の異な
る複数種の微粒子を混合することにより多色または中間
調の可視記録が得られる効果がある。
As explained above, the present invention has the effect of obtaining multicolor or halftone visible recording by mixing a plurality of types of fine particles having different melting points in a single recording layer.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来の2色記録可能な熱転写シートの断面図、
第2図は本発明による2色記録可能な熱転写シートの一
実施例を示す断面図である。 1・・・・・・低融点インク層、2・・・・・・高融点
インク層、3.10・・・・・・基材、20・・・・・
・感熱記録層、30・・・川伝融点インクの微粒子、4
0・・・・・・高融点インクの微粒子、50・・・・・
・高分子。 代理人 弁理士  内 原   晋
Figure 1 is a cross-sectional view of a conventional two-color recordable thermal transfer sheet.
FIG. 2 is a sectional view showing an embodiment of a two-color recordable thermal transfer sheet according to the present invention. 1...Low melting point ink layer, 2...High melting point ink layer, 3.10...Base material, 20...
・Thermosensitive recording layer, 30... fine particles of Kawaden melting point ink, 4
0...Fine particles of high melting point ink, 50...
·High molecular. Agent Patent Attorney Susumu Uchihara

Claims (3)

【特許請求の範囲】[Claims] (1)融点が異なる複数種類の熱溶融性インクの微粒子
と接着材である高分子からなる感熱記録層が基材上に塗
工されて成ることを特徴とする熱転写シート。
(1) A thermal transfer sheet comprising a heat-sensitive recording layer made of fine particles of a plurality of types of heat-melting inks having different melting points and a polymer as an adhesive, coated on a base material.
(2)熱溶融性インクの微粒子は融点に応じて色調の異
なる少なくとも2種類の微粒子であることを特徴とする
特許請求の範囲第(1)項記載の熱転写シート。
(2) The thermal transfer sheet according to claim (1), wherein the fine particles of the heat-melting ink are at least two types of fine particles having different tones depending on their melting points.
(3)高分子は熱溶融性インクの融点よりも高い融点で
あることを特徴とする特許請求の範囲第(1)項もしく
は第(2)項記載の熱転写シート。
(3) The thermal transfer sheet according to claim (1) or (2), wherein the polymer has a melting point higher than the melting point of the heat-melting ink.
JP57229041A 1982-12-28 1982-12-28 Thermal transfer sheet Pending JPS59120493A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57229041A JPS59120493A (en) 1982-12-28 1982-12-28 Thermal transfer sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57229041A JPS59120493A (en) 1982-12-28 1982-12-28 Thermal transfer sheet

Publications (1)

Publication Number Publication Date
JPS59120493A true JPS59120493A (en) 1984-07-12

Family

ID=16885812

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57229041A Pending JPS59120493A (en) 1982-12-28 1982-12-28 Thermal transfer sheet

Country Status (1)

Country Link
JP (1) JPS59120493A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6161891A (en) * 1984-09-04 1986-03-29 Fuji Xerox Co Ltd Thermal recording medium
FR2584981A1 (en) * 1985-07-22 1987-01-23 Canon Kk THERMAL TRANSFER MATERIAL AND METHOD FOR PRODUCING THE SAME
FR2585292A1 (en) * 1985-07-29 1987-01-30 Canon Kk THERMAL TRANSFER MATERIAL COMPRISING HOT TRANSFERABLE INK

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6161891A (en) * 1984-09-04 1986-03-29 Fuji Xerox Co Ltd Thermal recording medium
JPH0473389B2 (en) * 1984-09-04 1992-11-20 Fuji Xerox Co Ltd
FR2584981A1 (en) * 1985-07-22 1987-01-23 Canon Kk THERMAL TRANSFER MATERIAL AND METHOD FOR PRODUCING THE SAME
FR2585292A1 (en) * 1985-07-29 1987-01-30 Canon Kk THERMAL TRANSFER MATERIAL COMPRISING HOT TRANSFERABLE INK
US5133820A (en) * 1985-07-29 1992-07-28 Canon Kabushiki Kaisha Thermal transfer material

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