JPS59100176A - Adhesive - Google Patents

Adhesive

Info

Publication number
JPS59100176A
JPS59100176A JP20855582A JP20855582A JPS59100176A JP S59100176 A JPS59100176 A JP S59100176A JP 20855582 A JP20855582 A JP 20855582A JP 20855582 A JP20855582 A JP 20855582A JP S59100176 A JPS59100176 A JP S59100176A
Authority
JP
Japan
Prior art keywords
resin
temp
adhesive
temperature
electronic part
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20855582A
Other languages
Japanese (ja)
Inventor
Yukio Yamaguchi
幸雄 山口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp, Nippon Electric Co Ltd filed Critical NEC Corp
Priority to JP20855582A priority Critical patent/JPS59100176A/en
Publication of JPS59100176A publication Critical patent/JPS59100176A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0201Thermal arrangements, e.g. for cooling, heating or preventing overheating
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/303Surface mounted components, e.g. affixing before soldering, aligning means, spacing means
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives

Abstract

PURPOSE:To provide a thermally (or electrically) conductive adhesive which has good heat resistance and facilitates removal of an adherend without being broken, by blending a specified low-melting metal with a resin. CONSTITUTION:Metallic particles (e.g. solder particles) 11 with a solid phase temp. or eutectic temp. higher than the curing temp. of a resin 12 mentioned below and a liquid phase temp. or eutectic temp. lower than the heat-resisting temp. of the resin, are blended with the resin 12 such as epoxy or polyimide resin to obtain an adhesive 1. In application, a substrate 2 is coated with the adhesive 1 and an electronic part 3 is placed thereon and heated at 150 deg.C or below to cure the epoxy resin 12 (during heating, the metallic particles are not molten), whereby the electronic part 3 is bonded to the substrate 2. To remove the electronic part 3, the part 3 is heated at 250 deg.C or above to melt the metallic particles 11 so that mechanical strength of the adhesive layer is lowered and the electronic part 3 can be easily removed by slight external force.

Description

【発明の詳細な説明】 発明の属する技術分野 本分明−1熱伝導1トオたは導電性を有する接着剤に関
する。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention This invention relates to an adhesive having thermal conductivity or electrical conductivity.

従来技術 一般の接着剤は、枦1脂がσへpよぴ1.’lyF、気
の不112,9体であるととめ・ら導電、pr、、熱伝
ン・L件で・−低い0、(−7かし、導電性、熱伝導性
、/I;%:、:←さt)る場合がある。
Conventional adhesives in general have a ratio of 1 fat to σ to 1. 'lyF, 112, 9 bodies of tome-ra conductivity, pr,, heat conduction, L matter - low 0, (-7 kashi, conductivity, thermal conductivity, /I;% :, :←sat) may occur.

例えば電子部品への放べ) 、l’l−11・−トシン
クの取付は等では熱伝導性が良好な)3 >、’:r剤
がJ/? ’がマ′ある。イイ来、このような接着剤と
12ては、(h1脂中に金、ぐ)1    □等の金属
粒子を混入1,7だものが11:・甲さtlでいる−し
かし、このような従来の接一層剤id4、杉IJ接危物
を除去するためには、佼I脂の面1熱劣化温度以上にl
t。
For example, the heat conductivity is good when attaching a sink to an electronic component) 3>,':R agent is J/? There is 'ma'. Good, this kind of adhesive and 12 are mixed with metal particles such as (gold in h1 fat) 1 □ and 1,7 is 11:・Kosa tl - However, such adhesive In order to remove the conventional bonding agent id4, cedar IJ, surface 1 of the cedar lubricant must be heated to a temperature higher than the thermal deterioration temperature.
t.

熱しなければならたい。1′1!を熱11!r科の良好
な樹脂は、当然に耐熱劣化温度が;HT < 、破詞・
管I:ηを除去するたV)には500〜700℃・t′
ビj埃以十の1し百A11に加熱しなければならないた
め、被接着物が熱破壊さfl。
I want it to be hot. 1'1! Heat 11! Good resins of the R family naturally have a heat resistance deterioration temperature;
Tube I: 500-700℃・t' for V) to remove η
Since the adhesive must be heated to a temperature of 10 to 100 A11, the object to be adhered will be thermally destroyed.

てし1って再使用できなくなるという欠点がある。The disadvantage is that it cannot be reused.

一方、面1熱劣化招度が低い4!7+ :liiは、当
然に耐熱特性が勘、いから使用時の発熱等によって特性
が劣化する等問題が釜い。
On the other hand, 4!7+:lii, which has a low degree of surface 1 thermal deterioration, has many problems such as its heat resistance characteristics being deteriorated by heat generation during use.

発明の目的 本発明の目的は、土述の従非の欠点を[;I(決し、耐
熱特性が良好で、しかも披接冶物を破1みしないで容桔
に除去することが可能な熱伝導性井、たゆ導電性分有す
る接オf剤を提供することにある。
OBJECT OF THE INVENTION The purpose of the present invention is to solve the disadvantages of the above-mentioned problems by creating a heat resistant material which has good heat resistance properties and which can be removed into a container without damaging the metal. The object of the present invention is to provide a conductive material having a conductive property.

発明の構成□   ′:、::″一 本発明の接着剤は、樹脂中に、固相温度または共晶温1
片が前記樹脂の硬化温度より高く、かっ液相温度捷たは
共晶温度が前記樹脂の耐熱温度より低い金属粒子を混入
してなることを特徴とする。
Structure of the invention
The piece is characterized in that it contains metal particles that are higher than the curing temperature of the resin and whose liquidus temperature or eutectic temperature is lower than the heat resistance temperature of the resin.

発明の実施例 次に、本発明について、図面□をG IT(t ’して
詳細に説4明する。
Embodiments of the Invention Next, the present invention will be explained in detail by referring to the drawing □ as GIT(t').

第1図は、本発明の一実施例を示す断面図でああ。−1
&ゎち、+m庁11iB1.1ヤッ位、1□2中に半田
1粒子11が混入されていて、熱伝導性およびf4電性
が良好である。基板2上に、接着剤1を塗布し、電子部
品3を載置して、例えば150℃以下でエポキシ樹脂]
2を硬化すれば接着が完了する。半田粒子11の固相又
は共晶温度は、前記150℃より高いから、エポキシ樹
脂12の硬化中に溶融することはない。また、エポキシ
樹脂12は耐熱温度が高く、従って耐熱特性が良好であ
り、使、用、、、、中に電子部品3の発熱Φrによって
劣化すると□ 、・−,11 とはなく、充分な接着強度を保持(〜でいる。また、□
電子1池品、3:の発熱は、接着剤1を介L7て基板2
に集導、されるかう放警管性が良い。、。
FIG. 1 is a sectional view showing one embodiment of the present invention. -1
&ゎchi, +m office 11iB1.1 yach, 1 solder particle 11 is mixed in 1□2, and the thermal conductivity and f4 electric property are good. Apply adhesive 1 on substrate 2, place electronic component 3 on it, and apply epoxy resin at 150° C. or lower, for example.]
Adhesion is completed by curing 2. Since the solid phase or eutectic temperature of the solder particles 11 is higher than the above-mentioned 150° C., the solder particles 11 do not melt during curing of the epoxy resin 12. In addition, the epoxy resin 12 has a high heat resistance temperature and therefore has good heat resistance characteristics, and if it deteriorates due to the heat generation Φr of the electronic component 3 during use, it will not cause □ , -, 11 and will have sufficient adhesion. Maintains strength (with ~.Also, □
The heat generated by the electronic 1 battery, 3: is transferred to the board 2 via the adhesive 1, L7.
It is good to have a good control and control system. ,.

電子部品3を除去するときは、半田粒子11の液相温度
又は共晶温度より高い25 (I CRla“に加熱す
ることによって半田粒子11を溶融すると、構造的に樹
“脂の機械的強Wが低下する。この結果ビン化ット等に
よる僅かな外力によってt電子部品3を除去することが
できる。半田粒子は溶融して相互に合体し、第2図に示
すように半田合体]3がエポキシ樹脂1□2吊に残□存
する。−上記250u程度の加熱:で1、電、子〒品3
は熱イI9さ五ず、除去した後再使用が可晶4・ある。
When removing the electronic component 3, if the solder particles 11 are melted by heating to 25 (ICRla) higher than the liquidus temperature or eutectic temperature of the solder particles 11, the mechanical strength W of the resin will be reduced structurally. As a result, the electronic component 3 can be removed by a slight external force from a bottle or the like.The solder particles melt and coalesce with each other, and as shown in FIG. Epoxy resin 1□2 remains in suspension.-Heating above about 250U: 1, electric, electronic 3
There are four crystals that can be reused after being removed.

基板上には、未硬化の同様な接着剤によって他の新(7
い電子部品を接着して、電子部品を交換することが可能
である。
On the substrate, other new (7
It is possible to replace electronic components by gluing new electronic components together.

上記エポキシ樹脂に代えてポリイミド47i4脂を使用
し、該ポリイミド樹脂の硬化温度よシ高い固相温度また
は共晶温度を有し、かつ該ポリイミド樹脂の耐熱温度よ
り低い液相温度または共晶温度を木する半田粒子等の金
属粒子を混入しても同様な効果を秦する、 発明の効果 以上のように、本発明においては、樹脂の硬化温度より
高い[I−」相温度または共晶温度を有し、液相温度ま
たは共晶温度は該樹脂の耐熱温度より低い金属粒子を、
上記樹脂中に混入する構成としたから、熱伝導性、導筒
、性を有し耐熱特性が良好で、しかも接着、した部品等
を破壊し、ないで容易に除去できる接着剤を提供できる
。すなわち、電子部品等の取付け、除去を容易かつ経済
的に可能とする効果がある。
Polyimide 47i4 resin is used in place of the above epoxy resin, and has a solidus temperature or eutectic temperature higher than the curing temperature of the polyimide resin, and a liquidus temperature or eutectic temperature lower than the heat resistance temperature of the polyimide resin. Even if metal particles such as wood solder particles are mixed, the same effect can be obtained.As described above, in the present invention, the [I-] phase temperature or eutectic temperature higher than the curing temperature of the resin is metal particles having a liquidus temperature or eutectic temperature lower than the heat-resistant temperature of the resin,
Since the adhesive is mixed in the resin, it is possible to provide an adhesive that has thermal conductivity, conductive properties, good heat resistance properties, and can be easily removed without destroying the bonded parts. That is, it has the effect of making it possible to easily and economically attach and remove electronic parts and the like.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例を示す断面図、第2図は本発
明の接着剤によって接着した電子部品を除去した状態を
□示す断面図である。 図において、1・・・接着剤、2・・・基板ζ 3・・
・電子部品、]1・・・半田粒子、12・・・エポキシ
樹、脂、13・・・半田合体。 代理人弁理士 住 1)俊 宗 :   7.、+& 1国 、−、、第、2図
FIG. 1 is a sectional view showing one embodiment of the present invention, and FIG. 2 is a sectional view □ showing a state in which electronic components bonded with the adhesive of the present invention have been removed. In the figure, 1...adhesive, 2...substrate ζ 3...
-Electronic components,] 1...Solder particles, 12...Epoxy resin, resin, 13...Solder union. Representative Patent Attorney Sumi 1) So Toshi: 7. ,+& 1 country,-, ,Figure 2

Claims (1)

【特許請求の範囲】 !+1  PI IJ中に、同相温度または共晶温拷が
前記樹脂の硬化温度より高く、かっ液相温tr(ブたは
共晶温度がillが樹脂の耐熱温度より低い金か1粒子
を混入してなることを特徴にする九着剤。 (2、特許請求の範囲第1項Hc1載の接着i′11 
[おいて、tffiil記金スベ粒子は半田粒子である
ことを7痔徴とするもの1、 (3) ’I’F T!’I”請求の帥囲第1項寸たけ
第2珀d11.岐の接、資剤に卦いて、i11記樹脂は
エホキシ樹涌呻ゾζはポリイミド樹脂11であることを
特徴とするもの4.
[Claims]! +1 PI In IJ, one particle of gold is mixed in which the in-phase temperature or eutectic temperature is higher than the curing temperature of the resin and the liquid phase temperature tr (but or eutectic temperature is lower than the heat resistance temperature of the resin). (2. Adhesive i'11 according to Claim 1 Hc1)
[In this case, tffiil notes that the metal particles are solder particles. ``I'' Claim: Item 1, Dimensions, Item 2, d11. In terms of materials, the resin i11 is an epoxy resin, and the resin ζ is a polyimide resin 11. ..
JP20855582A 1982-11-30 1982-11-30 Adhesive Pending JPS59100176A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20855582A JPS59100176A (en) 1982-11-30 1982-11-30 Adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20855582A JPS59100176A (en) 1982-11-30 1982-11-30 Adhesive

Publications (1)

Publication Number Publication Date
JPS59100176A true JPS59100176A (en) 1984-06-09

Family

ID=16558116

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20855582A Pending JPS59100176A (en) 1982-11-30 1982-11-30 Adhesive

Country Status (1)

Country Link
JP (1) JPS59100176A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5376403A (en) * 1990-02-09 1994-12-27 Capote; Miguel A. Electrically conductive compositions and methods for the preparation and use thereof
US5853622A (en) * 1990-02-09 1998-12-29 Ormet Corporation Transient liquid phase sintering conductive adhesives

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5376403A (en) * 1990-02-09 1994-12-27 Capote; Miguel A. Electrically conductive compositions and methods for the preparation and use thereof
US5830389A (en) * 1990-02-09 1998-11-03 Toranaga Technologies, Inc. Electrically conductive compositions and methods for the preparation and use thereof
US5853622A (en) * 1990-02-09 1998-12-29 Ormet Corporation Transient liquid phase sintering conductive adhesives

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