JPS5884899A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPS5884899A JPS5884899A JP18486681A JP18486681A JPS5884899A JP S5884899 A JPS5884899 A JP S5884899A JP 18486681 A JP18486681 A JP 18486681A JP 18486681 A JP18486681 A JP 18486681A JP S5884899 A JPS5884899 A JP S5884899A
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- Prior art keywords
- phosphoric acid
- acid group
- polymer
- group
- detergent composition
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- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 本発明は洗剤組成物に関するものである。[Detailed description of the invention] FIELD OF THE INVENTION This invention relates to detergent compositions.
さらに詳細には、界面活性剤にビルダー、岸分として燐
酸基を有する重合体を配合してなる洗剤Ｉｉ１威物放物
するものである・
従来、セッケン、合成洗剤、すすぎ剤、清浄剤郷界面活
成剤の洗浄作用を向上させるために。More specifically, it is a detergent made by blending a surfactant with a builder and a polymer having a phosphoric acid group as a base component. Conventionally, soaps, synthetic detergents, rinse agents, and cleaning agents have been used. To improve the cleaning action of the activator.
ポリリン酸ナトリウムは、水遵水中岬に含オれるカルシ
ウム、マグネシウムイオンを捕促する効果が、絶大で、
界面活性剤の洗浄作用を向上させるためのビルダー数分
として必畳欠くべからざるものとして独占的に使用され
ていたｏしかし、ポリリン酸ナトリウムを配合してなる
洗剤綱或物＃ｉ、河１１１．湖の富栄養化源としての開
動点かある。Sodium polyphosphate has a tremendous effect of capturing calcium and magnesium ions contained in the water.
However, detergents containing sodium polyphosphate have been exclusively used as builder components to improve the cleaning action of surfactants. This may be the turning point for the lake as a source of eutrophication.
近年、このポリリン酸ナトリウムに代わるべきビルダー
として水不溶性フルミノ珪酸塩を用いることか試みられ
ており、かがりの効果が見られ洗剤組成物ポリリン酸ナ
トリウム含量をかなシ滅することができた。しかしなが
ら水溶液中のカルシウム、マグネシウム、重金属イオン
の補傷能力は十分でなく洗浄力を低下させないでポリリ
ン酸ナトリウムの添加量を完全に無くすることは、困難
な状態にあシ、より優れたビルダーの出現か望まれてい
る＠
かかｌ事情に鑑み１本発明者らは水溶液中のカルシウム
、マグネシウム、重金属イオン鎮を補傷する能力に優れ
、且つ、排水中に排出されて河川、湖の富栄養化源とな
らないビルダーを見い出すべく銃童研究した結果、燐酸
基を有する１合体が、カルシウム、マグネシウム郷の捕
便能に優れた富栄養化源とならない洗剤ビルグーとして
有効である仁とを見出し９本発明を確立すゐに至った。In recent years, attempts have been made to use water-insoluble fluminosilicate as a builder to replace sodium polyphosphate, and it has been found to have a darning effect, making it possible to significantly reduce the sodium polyphosphate content of detergent compositions. However, the repairing ability of calcium, magnesium, and heavy metal ions in aqueous solutions is insufficient, and it is difficult to completely eliminate the amount of sodium polyphosphate added without reducing the detergency. In view of the current circumstances, the present inventors have discovered that calcium, magnesium, and heavy metal ions in aqueous solutions have an excellent ability to repair, and that they are discharged into wastewater and contribute to the wealth of rivers and lakes. As a result of conducting research to find a builder that does not act as a source of nutrients, it was discovered that a complex with a phosphoric acid group is effective as a detergent builder that has an excellent ability to absorb calcium and magnesium and does not act as a source of eutrophication. 9 The present invention has been established.
すなわち１本発明は、ビルダーとして燐酸基を有する重
合体を配合してなることを４Ｉ拳とする洗剤組成物を提
供するにあるＯ以下に本発明の詳細な説明する。That is, one aspect of the present invention is to provide a detergent composition containing a polymer having a phosphoric acid group as a builder.The present invention will be described in detail below.
本発明の洗剤組成物は少なくとも昇面活性成分と燐酸差
を有する重合体とを含むものを云うが、他の成分をも含
むことかできる０本発明の洗剤組成物において用いられ
る燐酸基を有する重合体としては重合体鎖中に燐酸基を
有するもので且つ、水溶液中のカルシウム、マグネシウ
ムの１金属イオンを補傷する水不溶性の液状又は、同体
状の重合体か用いられる◎このような重合体としては通
常、幹１合体に、一般式（式中１Ｍは水素原子またはカ
ルシウムもしくはマグネシウムと交換可能な金属塩１例
えば ・ナトリウム、カリウム、Ｘはアミノアルキ
レン基、ポリフルキレンポリ７ミノアルキレン基）で示
される燐酸基の一種は二種以上をペンダントに結合した
燐酸基を有する１合体が用いられる。ｌＩＫ力ルレウム
及びマグネシウムの選択吸着性から
（５ＬＬ１２及びＸＦｉ前記と同じ）をペンダントに結
合した重合体が好オしく用いられる。The detergent composition of the present invention includes at least a surface-active component and a polymer having a phosphoric acid difference, but may also contain other components. As the polymer, a water-insoluble liquid or homogeneous polymer having a phosphoric acid group in the polymer chain and capable of repairing one metal ion of calcium or magnesium in an aqueous solution is used. As for coalescence, the general formula (in the formula, 1M is a hydrogen atom or a metal salt exchangeable with calcium or magnesium, for example, sodium, potassium, and X is an aminoalkylene group, a polyfulkylene poly7minoalkylene group) As the type of phosphoric acid group represented by , a combination having two or more phosphoric acid groups bonded pendantly is used. A polymer in which 5LL12 and XFi (same as above) are bonded pendantly is preferably used because of its selective adsorption properties for lureum and magnesium.
燐酸としては、具体的にはアミノメチレン矯駿基、エチ
レンジアミノメチレン燐酸基、ジエチレントリアミノエ
チレン燐酸基、トリエチレンテトラアミノメチレン燐酸
基、アミノエチレン鱗酸基、エチレンジ７１ノエチレン
燐酸差。Examples of the phosphoric acid include aminomethylene phosphoric acid group, ethylenediaminomethylene phosphoric acid group, diethylenetriaminoethylene phosphoric acid group, triethylenetetraaminomethylene phosphoric acid group, aminoethylene scale acid group, and ethylenedi71noethylene phosphoric acid group.
ジエチレントリアミノエチレン燐酸基、トリエチレンテ
トラアミノエチレン燐＃基、テトラエチレンペンタアミ
ノメチレン燐酸基、ベンタエチレンヘキサア丸ノメチレ
ン矯駿基、テトラエチレンペンタアミノエチレン燐酸基
、ペンタエチレンへ牟すアミノエチレン燐酸基、燐酸基
。Diethylenetriaminoethylene phosphoric acid group, triethylenetetraaminoethylene phosphoric acid group, tetraethylenepentaaminomethylene phosphoric acid group, bentaethylenehexa-round methylene phosphoric acid group, tetraethylenepentaaminoethylene phosphoric acid group, aminoethylene phosphoric acid group that converts to pentaethylene , phosphate group.
亜燐酸基、アミノメチレン亜燐酸基、エチレン亜
ジアミノメチレンヂ燐酸基、ジエチレントリアミノメチ
レン亜燐酸基、トリエチレンテトラアミノメチレン亜鱗
酸基等を挙けることかできる。Examples include a phosphorous acid group, an aminomethylene phosphorous acid group, an ethylene diaminomethylene diphosphorous acid group, a diethylene triamino methylene phosphorous acid group, a triethylene tetraamino methylene phosphorous acid group, and the like.
％に好ましくけ、７ミノメチレン燐酸基、エチレンジア
ミノメチレン燐酸基、ジエチレントリ７ミノメチレン燐
酸基、トリエチレンテトラアミノメチレン燐酸基、アミ
ノメチレン亜燐酸基、エチレンジアミノメチレン亜燐酸
基、ジエチレントリアミノメチレン亜燐酸基、テトラエ
チレンペンタアミノメチレン燐酸基、アミノエチレン燐
酸基が挙けられる。%, preferably 7minomethylene phosphate group, ethylenediaminomethylene phosphate group, diethylene tri7minomethylene phosphate group, triethylenetetraaminomethylene phosphate group, aminomethylene phosphorous group, ethylenediaminomethylene phosphorous group, diethylenetriaminomethylene phosphorous group , tetraethylenepentaaminomethylene phosphate group, and aminoethylene phosphate group.
本燐酸基を有する重合体は公知の製造方法で製造するこ
とができ、一般には、ポリ塩化ビニル、ポリ塩化ビニリ
デン、塩素化ポリエチレン。The present phosphoric acid group-containing polymer can be produced by a known production method, and generally includes polyvinyl chloride, polyvinylidene chloride, and chlorinated polyethylene.
塩素化ポリプロピレン、クロルメチル化したスチレンジ
ビニルベンゼン共重合体、セルロース岬重合体に７ミノ
化合物を反応させた重合体。A polymer made by reacting a 7-mino compound with chlorinated polypropylene, chloromethylated styrene divinylbenzene copolymer, and cellulose misaki polymer.
マタハ、アニリン樹脂、グアニジン樹脂等の重合体勢の
一級もしくは二級の７ミノ基を有する重合体に、アルキ
ル燐酸化剤を反応させることにより製造することができ
るＯ
′本発明に用いられゐ燐酸基を有する重合−中の燐酸基
の含量は、一般に−ｍｏｊ／Ｉ［Ｐ−重合体、好ましく
は、Ｊｍｏｌ／Ｋｆ−重合体以上有する重合体が卆４キ
≠使用されるＯ重合体中の燐酸基の含量が−ｍｏｔ１０
−重合体よシ少量の場合には硬水軟化作用が僅少となシ
ビルダーとして有用でない０本燐酸基を有する重合体は
酸又はその金属塩のいずれの瀧でも使用できるが、その
選択は、用いられゐ洗剤の種類、水溶液の組成、ＰＨＩ
Ｋよって選ｄれるＯ
本燐酸基を有すゐ重合体ビルグーの形状は。The phosphoric acid group used in the present invention can be produced by reacting an alkyl phosphorylating agent with a polymer having a primary or secondary 7-mino group in the polymer state, such as mataha, aniline resin, or guanidine resin. The content of phosphoric acid groups in the polymerization is generally - moj/I The content of groups is -mot10
- Polymers with 0 phosphoric acid groups, which are not useful as water softeners because they have little water softening effect when used in small amounts, can be used with either the acid or its metal salt, but the selection depends on the Type of detergent, composition of aqueous solution, PHI
The shape of the polymer virgoo having a phosphoric acid group is selected by K.
繊維状、布状１球状、破砕状、粉状のいずれもが使用可
能であり、洗剤の種類、用途岬によシ・適宜選択される
Ｏ例えば、衣類の洗たく用に使用する場合は、θ、ｌ〜
！シμｍ、好ましくはθ、Ｓ〜７０μ膳の粒径の本ビル
グーまたは、Ｆ布状の物が洗濯後被洗物からの除去の点
で好ましいＯ本発明の洗剤組成物において、燐酸基を有
する重合体ビルグーの洗浄剤組成物への配合量は。Fibrous, cloth-like, spherical, crushed, and powdered forms can all be used, and are selected depending on the type of detergent and purpose. For example, when used for washing clothes, θ , l~
! In the detergent composition of the present invention, the detergent composition of the present invention preferably has a particle size of 70 μm, preferably θ, S to 70 μm, or a cloth-like material having a phosphoric acid group. What is the amount of polymer virgoo added to the cleaning composition?
使用する水の硬ＵＫよって異なるが、一般に洗剤全組成
物の０．５−Ａ’θ重量悌好ましくは、７〜６０重量係
配合される０本ピルグーの添加量が少ないと、十分なカ
ルシウム、マグネシウム補傷効果が達成されないし、一
方、多量になって奄それに比例した効果か達成されない
ので経済的でないので、上記範囲が用いられる。Although it varies depending on the hardness of the water used, in general, the total detergent composition preferably has a weight ratio of 0.5-A'θ, preferably 7 to 60%.If the amount of 0-pilgoo added is small, sufficient calcium, The above range is used because the magnesium repair effect is not achieved and, on the other hand, the amount is too large to achieve an effect proportional to the amount, which is not economical.
本発明の洗剤組成物において界面活性剤としては炭素数
に一／乙のアルキル基を有するアルキルベンゼンスルホ
ン酸塩、炭素数ｌ〜／ｌのフルキル基を有するフルキル
硫酸塩、炭素数ｌ〜／ｌの高級アルフールに酸化エチレ
ンを７〜ｊモル付加させたエトキシ化物の硫酸化物の塩
。In the detergent composition of the present invention, the surfactants include alkylbenzene sulfonates having an alkyl group of 1/2 carbon atoms, furkyl sulfates having a furkyl group having a carbon number of 1 to 1/l, and A sulfate salt of an ethoxy compound obtained by adding 7 to j moles of ethylene oxide to higher alfur.
炭素数／−〜−一のａ−オレフィンスル木ン酸塩、炭素
数／θ〜−一の飽和又は不飽和脂肪酸塩１等の７ニオン
界面活性剤、ポリオキシエチレンアルキルエーテル、゛
ポリオキレエチレンアルキルフェノールエーテル、ポリ
ゝオキシエチレン脂肪酸エステル、ソルビタン脂肪酸エ
ステルポリオキシエチレンエーテル、蔗糖脂肪酸エステ
ル、に肪酸アルキロール７マイド等の非イオン界面活性
剤、ラウリルジメチルカルボキレメチルアン畳ニウムベ
タイン等のベタイン型ヤアラニン型、イミダシリン型な
どの両性界面活性剤を用いることができるＯ
本発明の洗剤組成物中の界面活性剤は、洗剤組成物中ｊ
〜ｊθ重量憾好ましくは１０ＳＪθ重量憾とされるＯ
本発明の洗剤組成物にはまた。ビＡダー、その他の漂白
剤も添加することができる。ビルダーとしてはトリポリ
リン酸塩、ビロリン酸塩。7-ion surfactants such as a-olefin sulfinates with a carbon number of - to -1, saturated or unsaturated fatty acid salts with a carbon number of θ to -1, polyoxyethylene alkyl ethers, polyoxyethylene Nonionic surfactants such as alkylphenol ether, polyoxyethylene fatty acid ester, sorbitan fatty acid ester polyoxyethylene ether, sucrose fatty acid ester, difatty acid alkylol 7mide, betaine type such as lauryldimethylcarboxyremethylamtatium betaine, etc. Amphoteric surfactants such as Yaalanine type and Imidacillin type can be used.
~jθ weight, preferably 10SJθ weight, preferably O The detergent composition of the present invention also includes. Biaders and other bleaching agents can also be added. Builders include tripolyphosphate and birophosphate.
メタリン酸塩などの縮合リン酸塩、ニトリロ三酢酸塩、
エチレンジアミン四酢酸塩、クエン酸塩、ポリアクリル
酸塩、無水マレイン酸−〇ｌｌビニル共重合体の水溶性
塩郷ケイ酸塩、炭酸塩。Condensed phosphates such as metaphosphates, nitrilotriacetates,
Ethylenediaminetetraacetate, citrate, polyacrylate, water-soluble salt silicate, carbonate of maleic anhydride-〇ll vinyl copolymer.
硫酸塩、硼酸塩等が挙けられるＯその他の漂白剤には、
７０．ＦＢ、過硫酸ソーダが挙げられるＯその他特にガ
ラス、陶器、金属表面の洗浄斉Ｊにはケイ砂、モンモリ
ロナイト、ゼオライトなどの水不溶性無機物質を配合で
きる。さらに必１’に応じて酵素、螢光染料、青味付剤
、香料郷の各種添加物も使用できる。Other bleaching agents include sulfates, borates, etc.
70. Examples include FB and sodium persulfate. In addition, water-insoluble inorganic substances such as silica sand, montmorillonite, and zeolite can be added to cleaning agents, especially for glass, ceramic, and metal surfaces. Furthermore, enzymes, fluorescent dyes, blue tints, and various flavoring additives may also be used as required.
以上詳述したように燐酸基を有する重合体をビルダー成
分として用いることにより、ゼオライト等に比較して顕
著な硬水軟化作用を発現し。As detailed above, by using a polymer having a phosphoric acid group as a builder component, it exhibits a remarkable water softening effect compared to zeolite and the like.
優れた洗浄特性、起泡特性を与えるし、また、排水に排
出されても重合体中の燐酸基の安定性の故に富栄養化剤
としての作用もないという慶境衛生上、経済上、工業上
の種々の利点を発揮する０
以下に本発明方法を実施例によってさらに詳靭に説明す
るが１本発明方法は、その豐旨を越えないＲｈ以下の実
施例によって限定されるものではない◇
実施例／
次の組成を有する洗剤組成物を製造した。It provides excellent cleaning and foaming properties, and even when discharged into wastewater, it does not act as a eutrophic agent due to the stability of the phosphoric acid group in the polymer. The method of the present invention will be explained in more detail with reference to examples below, but the method of the present invention is not limited to the following examples which do not exceed the gist of the method.◇ Example/A detergent composition having the following composition was produced.
上記洗剤組成物Ｏ，Ｓ重量部を加え九〇ａ＠［Ｊ！０Ｗ
ｔｌ／ｌの水溶液ｉｏｏｗＫ、牛脂θ、ｓｐ、活性炭ｏ
、ｓｐ、流動パラフィン／、＜１１．四塩化炭素ダθＯ
ｐから成る液中に、長さ／θθ−×巾５５８１１の木綿
の白布を７分間液中に浸漬してつくった汚染布３枚を入
れ、完全に湿し、さらＶｃ／ｊ−のゴム球を入れてラシ
ダーオーメーター（４Ｉコｒｐｍ）Ｋよシ洗浄し洗剤組
成物の洗浄力を調べた。洗浄温度１時間は３０℃。Add parts by weight of the above detergent compositions O and S to 90a@[J! 0W
tl/l aqueous solution ioowK, beef tallow θ, sp, activated carbon o
, sp, liquid paraffin/, <11. Carbon tetrachloride θO
Three pieces of contaminated cloth made by soaking white cotton cloth (length/θθ-×width 55811) in the solution for 7 minutes were placed in a solution consisting of p, completely moistened, and then a rubber ball of Vc/j- was placed. The cleaning power of the detergent composition was examined by washing with a Rashider Ohmeter (4I rpm). The washing temperature is 30°C for 1 hour.
３０分間である０ついで汚染布は浸水で５分間すすぎを
行ない、その後風乾し、アイロンがけを行なって洗浄布
をつくった。The contaminated cloth was then rinsed in water for 5 minutes, air-dried, and ironed to produce a cleaned cloth.
洗浄力として示した値ハ、次の計算式によって得られ九
値である。The value shown as detergency is obtained by the following calculation formula and is a nine value.
Ｐ工：木綿白布の反射率
Ｒ２：汚染布の反射率
Ｒ３：洗浄布の反射率
その結果洗浄力は６−係であった・また洗浄後の水溶液
中のカルシウム濃度は７岬／ｌであったＯ
比較例／
実施例／で使用したアミノメチレン燐酸基ヲ有スるスチ
レンジビニルベンゼン重合体の代りに同量のＮａ１ｇ（
ｉ／ｆ１２ 、 ＳＳ１０２）１ ・、２７Ｈ２０組成
のゼオライトを使用した以外は、同組成成分の洗剤組成
物を製造し、実施例／と同方法で洗浄力試験を行なった
・
その結果洗浄力は４Ｉ７憾であり、洗浄後の水溶液中の
カルシウム濃［は６コ■／ｌであったＯ
実施例λ〜／ダ
実施例１の組成物において、アミノメチレンｔｌａｌｌ
ｆｔを有スるスチレンジビニルベンゼン重合体を第７表
に示すビルダーにかえた以外は同組成成分の洗剤組成物
を製造し、ＩＩ！施例／と同方法で洗東力試験及び水溶
液の力んシウム濃度を測定した・その結果を第７表に示
した。P-work: Reflectance of white cotton cloth R2: Reflectance of contaminated cloth R3: Reflectance of cleaning cloth As a result, the cleaning power was 6-1. Also, the calcium concentration in the aqueous solution after cleaning was 7 capes/l. The same amount of Na1g (
i/f12, SS102)1 ・A detergent composition with the same composition components was produced, except that zeolite with a 27H20 composition was used, and a detergency test was conducted in the same manner as in Example ・ As a result, the detergency was 4I7 Unfortunately, the concentration of calcium in the aqueous solution after washing was 6/l.
A detergent composition having the same components except that the styrene divinylbenzene polymer having ft was replaced with the builder shown in Table 7 was prepared, and II! The force test and the force concentration of the aqueous solution were measured in the same manner as in Example 1.The results are shown in Table 7.
実施ｌ＋ｌ ／〜／４ｔ、比較例／よシ燐酸基を有する
重合体がビルダーとして有効であることが理解できる〇
実施例７５〜／６
実施例／の組成物において、アミノメチレン燐酸基の含
量が異シるスチレンジビニルベンゼン重合体を使用した
以外は同組成成分のその結果を第−表に示した。Examples 75 to 6 In the composition of Example 1, the content of aminomethylene phosphate groups is Table 1 shows the results for the same composition except that a different styrene divinylbenzene polymer was used.
実施例／Ｓ〜／６よシ、燐酸基を有する重合体の燐酸基
含量Ｆｉコｗ７？／４Ｐ−Ｈ淋以上好ましくはｓ 、ｏ
ｍｏｌ／Ｋｐ −創淋以上有することが望ましいこと
か理解できる０
実施例７７〜．２０
実施例／の組成物において界面活性剤の直鎖ドデシルベ
ンゼンスルホン酸ナトリウムを方法で洗浄力試験及／び
水溶液中のカルシウムＩｌ＆を測定した０その結果を第
３表に示し九〇第３表よシ本発明において周込ている燐
酸基を有する重合体は種々の界面活性剤のビルダーとし
て有効であることがわかる。Examples /S to /6, phosphoric acid group content Fi of the polymer having phosphoric acid groups w7? /4P-H or more preferably s, o
I can understand why it is desirable to have mol/Kp - Sorin or higher.0 Example 77~. 20 In the composition of Example//, the surfactant, linear sodium dodecylbenzene sulfonate, was subjected to a detergency test using the method and calcium Il& in the aqueous solution was measured.0 The results are shown in Table 3.90 Table 3 It has been found that the polymer having a phosphoric acid group incorporated in the present invention is effective as a builder for various surfactants.
実施例−／
次の組成を有する洗剤組成物を製造し九〇上記の洗剤組
成物を実施例／と同様にして。Example - A detergent composition having the following composition was prepared and the above detergent composition was prepared in the same manner as in Example.
Claims (1)
合してなることを４１拳とすゐ洗剤組成物Ｑ￥ しくはマグネシウムと蜜換可能な金属塩。 Ｉけア鳳ノアルキレン基、ポυアル本しンポリアミノア
ルキレシ基）で示される燐酸基を有する重合体であるこ
とを特徴とする特許請求のａｍ第１項配置の洗剤ｍ放物
０（ｊ、洗剤組成物中の燐酸基を有する重合体の割合が
θ、ｊ−１０重量嘔であることを特徴とする特許請求の
範囲＃Ｅ／オたは一項記載の洗剤前記と同じ）で示され
る燐酸基を有する重合体であることを特徴とする特許請
求の範囲第１またはＪｌｌ記峻の洗剤組成物。(1) A detergent composition containing a polymer having a phosphoric acid group as a builder or a metal salt that can be exchanged with magnesium. The detergent having the first term configuration of the patent is a polymer having a phosphoric acid group represented by a polyaminoalkylene group, a polyaminoalkylene group, a polyaminoalkylene group, and a polyaminoalkylene group. j, the proportion of the polymer having phosphoric acid groups in the detergent composition is θ, j-10 wt. A detergent composition according to claim 1 or Jll., characterized in that it is a polymer having a phosphoric acid group as shown below.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18486681A JPS5884899A (en) | 1981-11-17 | 1981-11-17 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18486681A JPS5884899A (en) | 1981-11-17 | 1981-11-17 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5884899A true JPS5884899A (en) | 1983-05-21 |
| JPH0117520B2 JPH0117520B2 (en) | 1989-03-30 |
Family
ID=16160676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18486681A Granted JPS5884899A (en) | 1981-11-17 | 1981-11-17 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5884899A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0520611U (en) * | 1991-05-17 | 1993-03-19 | 有限会社ジユリーズマルヤマ | Rotating structure of jewelry |
| JP2018199767A (en) * | 2017-05-26 | 2018-12-20 | 三菱ケミカル株式会社 | Detergent |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0382023U (en) * | 1989-12-15 | 1991-08-21 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5051984A (en) * | 1973-04-09 | 1975-05-09 | ||
| JPS50101287A (en) * | 1974-01-07 | 1975-08-11 | Hooker Chemicals Plastics Corp | |
| JPS5291007A (en) * | 1976-01-23 | 1977-08-01 | Unilever Nv | Detergent composition and preparation thereof |
| JPS5512164A (en) * | 1978-07-13 | 1980-01-28 | Kao Corp | Antibiotic soap |
| JPS5695994A (en) * | 1979-12-28 | 1981-08-03 | Kao Corp | Shampoo composition |
| JPS56139594A (en) * | 1980-04-03 | 1981-10-31 | Kao Corp | Creamy detergent composition |
-
1981
- 1981-11-17 JP JP18486681A patent/JPS5884899A/en active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5051984A (en) * | 1973-04-09 | 1975-05-09 | ||
| JPS50101287A (en) * | 1974-01-07 | 1975-08-11 | Hooker Chemicals Plastics Corp | |
| JPS5291007A (en) * | 1976-01-23 | 1977-08-01 | Unilever Nv | Detergent composition and preparation thereof |
| JPS5512164A (en) * | 1978-07-13 | 1980-01-28 | Kao Corp | Antibiotic soap |
| JPS5695994A (en) * | 1979-12-28 | 1981-08-03 | Kao Corp | Shampoo composition |
| JPS56139594A (en) * | 1980-04-03 | 1981-10-31 | Kao Corp | Creamy detergent composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0520611U (en) * | 1991-05-17 | 1993-03-19 | 有限会社ジユリーズマルヤマ | Rotating structure of jewelry |
| JP2018199767A (en) * | 2017-05-26 | 2018-12-20 | 三菱ケミカル株式会社 | Detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0117520B2 (en) | 1989-03-30 |
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