JPS5878613A - Carpet - Google Patents

Carpet

Info

Publication number
JPS5878613A
JPS5878613A JP17560181A JP17560181A JPS5878613A JP S5878613 A JPS5878613 A JP S5878613A JP 17560181 A JP17560181 A JP 17560181A JP 17560181 A JP17560181 A JP 17560181A JP S5878613 A JPS5878613 A JP S5878613A
Authority
JP
Japan
Prior art keywords
carpet
latex
drug
resin
adsorbent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17560181A
Other languages
Japanese (ja)
Other versions
JPH0158966B2 (en
Inventor
喜代治 片山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teysan Pharmaceuticals Co Ltd
Original Assignee
Teysan Pharmaceuticals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teysan Pharmaceuticals Co Ltd filed Critical Teysan Pharmaceuticals Co Ltd
Priority to JP17560181A priority Critical patent/JPS5878613A/en
Publication of JPS5878613A publication Critical patent/JPS5878613A/en
Publication of JPH0158966B2 publication Critical patent/JPH0158966B2/ja
Granted legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は防電(性、防虫性をもつカーペラ)K係わる。[Detailed description of the invention] The present invention relates to an electric-proof (carpeller with insect-proof and insect-proof properties) K.

更に詳しくは、カーペットのパイルの安姶性を与え名た
めに裏面に塗布される合、成樹脂ラテックスの弔に防虫
剤や抗菌剤を分散固定させて、カーペツートが敷かれて
いる期間中に、これら薬剤を徐放させ木ことKよ・、っ
て、カーペット、のパイルの占める空間に抗菌効果や防
虫効果をもたらすカーペットに関する。また本発明け、
合成樹脂ラテックス中KiW剤を分散させる際に、あら
かし−薬剤を多孔性の吸着剤に吸着させ、薬剤を含有す
る吸着剤をラテックス中に均一に分散させて、カーペッ
トの裏面に塗布し、熱処理乾燥させてラテックスを硬化
させるととkよって、・カーペットを得るものでを・る
More specifically, when it is applied to the back side of the carpet to give it a softer texture, insect repellents and antibacterial agents are dispersed and fixed in the synthetic resin latex, and during the period when the carpet is laid, Carpets that release these chemicals in a sustained manner and provide antibacterial and insect repellent effects to the space occupied by the carpet piles. Also, the present invention
When dispersing the KiW agent in synthetic resin latex, the chemical is adsorbed to a porous adsorbent, the adsorbent containing the drug is uniformly dispersed in the latex, and then applied to the back side of the carpet. When the latex is cured by heat treatment and drying, a carpet is obtained.

従来技術には、カーペットのパイル糸に、抗°菌剤を含
有せしめたものがあるが、カーペットの裏材に薬剤を徐
放させるように分散含有せしめたものはない。カーペッ
トパイルに薬剤を含浸乃至含有せしめたものは、次の問
題点がある、。
In the prior art, there is a method in which an antibacterial agent is contained in the pile yarn of a carpet, but there is no method in which an antibacterial agent is dispersed in the backing material of a carpet so as to release the agent in a sustained manner. Carpet piles impregnated with or containing chemicals have the following problems.

嬉1に一般家に用のカーペットとしては、幼児が嘗める
危険があることから適さない。また、薬剤を含有するパ
イル、糸は弗素加工などの防汚処理ができな1いから、
汚れ易くて実用面の制約がともなう。
Unfortunately, it is not suitable for use as carpet for general homes because there is a risk that young children may lick it. In addition, piles and threads that contain chemicals cannot be treated with antifouling treatments such as fluorine treatment.
It gets dirty easily and has practical limitations.

本発′明者は、カー・ペットの裏打材に薬剤を″含南ゼ
しめる手段を鏡意、研究した結果、本発明に到達で、!
たもの“である。裏打材に存在する4111は、′功−
ペットのパイル一部分の空間に薬剤固有゛の効果を発°
現させるものの、幼児がパイルに触れ、にシ嘗めたりL
7た場合でも危険社全くない点で優れている。
The inventor of the present invention has arrived at the present invention as a result of extensive research on ways to impregnate the lining material of carpets and pets with chemicals.
4111 present in the backing material is
Develops a drug-specific effect in the space of a part of the pet's pile
However, if the infant touches the pile and licks it,
It is excellent in that there is no danger even if it is 7.

本発明H1゛抗菌剤、防虫剤等の薬剤(混合物を包含す
る)を0.1〜20′重量%含有する横軸を11面にコ
ーティングしてなるカーペットである。殊に上記の薬剤
をよ多孔性吸着剤粉末に1★着された状態で合成樹脂中
に分散されてカーペット裏面に塗設されている特徴があ
る。
Invention H1: A carpet comprising 11 horizontal shafts coated with 0.1 to 20% by weight of agents such as antibacterial agents and insect repellents (including mixtures). In particular, the above-mentioned chemical agent is coated with a highly porous adsorbent powder, dispersed in a synthetic resin, and applied to the back surface of the carpet.

本発明を飲用すると4、カーペットの裏打ち用の樹脂と
しては、SBR樹脂、塩化ビニール樹脂、酢酸ビニール
樹脂、天然ゴム、合成ゴム尋が使用でき、東もよく使用
されているS、BR耐樹脂エマルジョン又は懸濁液が本
発明にj−用できζ。
4. As the resin for carpet lining, SBR resin, vinyl chloride resin, vinyl acetate resin, natural rubber, synthetic rubber fathom can be used, and S and BR resistant resin emulsions are also commonly used. Alternatively, suspensions can be used in the present invention.

次に抗菌剤や防虫剤等の薬剤は室温で気化性を有するも
のが、本発明に適用できるものである。例えば、α−ブ
ロムシンナムアルデヒド。
Next, drugs such as antibacterial agents and insect repellents that are vaporizable at room temperature can be applied to the present invention. For example, α-bromucinnamaldehyde.

クレオンート′、パラジクロールベンゼン、ショウノウ
、2,4.5−1リプロムフエノール、パラクロロメタ
クレゾール、オルソフエ;ニルフェノ−ル、 ハ9 p
−rrロメタキシレノール、ペンジールプロモアセテー
ド等が挙げられる。
creonut', paradichlorobenzene, camphor, 2,4.5-1 lipromphenol, parachlorometacresol, orthophenol, nylphenol, ha9p
-rr lometaxylenol, penzyl promoacetate, and the like.

上記の抗菌剤や防°虫剤d多孔性吸着剤に@鴻固定して
樹脂ラテックスに分散させる。この多孔性吸着剤としで
、活性炭、シリカゲル、活性アルミナ、無水珪酸、ホー
キダ・・ゴド、天然ゼオライト、ツーラスアース、白土
、サイクロデキストリン等々〃二例示でdる。
The above antibacterial agents and insect repellents are fixed on porous adsorbents and dispersed in resin latex. Examples of the porous adsorbent include activated carbon, silica gel, activated alumina, silicic anhydride, Hokida Godo, natural zeolite, Turas earth, clay, cyclodextrin, etc., to name a few.

抗菌剤や防虫剤を多孔性吸着−質に@着させるには、次
の手段をとるとよい。まず薬剤が、液体の場合には、吸
着剤粉末や吸着剤粒子を、この液状薬剤量に浸漬、シ、
脱液後、更に新畔な吸着剤粉末を添加し、よ″く混合す
る。この混合物を1昼夜エージングする。薬剤は吸着性
粉末に対し10重f[チ程度とすそと安定性が論い。
In order to attach antibacterial agents and insect repellents to porous adsorbent materials, the following methods may be used. First, if the drug is a liquid, immerse the adsorbent powder or adsorbent particles in the amount of the liquid drug.
After removing the liquid, add fresh adsorbent powder and mix well. This mixture is aged for one day and night. .

また薬剤が固体の場合には、薬★1を溶媒に溶解して溶
液を造り、との薬剤溶液中に吸着剤粉末′を浸漬すると
七によって、前記と同緩に薬剤を吸着した吸着剤粉末を
準備でた石。
In addition, if the drug is a solid, the drug ★1 is dissolved in a solvent to make a solution, and the adsorbent powder' is immersed in the drug solution. A prepared stone.

−、裏打用の膨脂に薬剤が吸゛着同定された秒着剤、粉
末を分散させろ方法は、裏打用の樹脂は殆どm−懸濁液
又は乳仕液であすることから、檜に混合混゛  練すれ
ばよい。一般にラテックス液は高l11度(70〜80
チ)であるから、分散を均一1!、するには充分撹拌す
る必要がある。
- The method of dispersing the identified second adhesive and powder into the expanded fat for the lining is that most resins for the lining are mixed with m-suspension or emulsion, so the method is to Just mix and knead. Generally, latex liquid has a high temperature of 11 degrees (70 to 80 degrees).
h), so the dispersion is uniform 1! , it is necessary to stir thoroughly.

薬剤−分散ラテックス灯、現在広く使用され−(いる、
カーペット用バックコーティング機!=TてtIi!4
Tiす今。リバースコニティング方式が均一なコーティ
ング階を得るために好ましい。・タフティングカーペッ
トの場合Ktlf、スクリムにタフティングし、た後、
ラテックスのバックコーティングを施す。コーティング
iはパイルの目付により肇わるが、乾燥重量で平均1〜
1.5に9 / m’がよい。コーティング捗け1、必
要があれば、ジュートバッキングを張合わせる。次いで
150℃程度で5〜lO分間乾燥する。
Pharmaceutical-dispersed latex lamps are currently widely used (
Back coating machine for carpet! =TtetIi! 4
Ti now. A reverse conniting method is preferred to obtain a uniform coating level.・In the case of tufted carpet, after tufting the scrim,
Apply a latex back coating. Coating i varies depending on the pile weight, but the average dry weight is 1~
1.5 to 9/m' is good. Coating progress 1. If necessary, attach jute backing. Next, it is dried at about 150° C. for 5 to 10 minutes.

薬剤を級着した吸着性粉末は、合成樹脂ラテックスの乾
燥重量に対1−1て10SJV下、好ましく社、3〜5
1%がよい。薬剤を10チ吸着した粉末が5%混入され
た場合はラテックス固型分に対して0.5チの薬斉1が
混入されることになる。
The adsorbent powder graded with the drug is 1-1 to the dry weight of the synthetic resin latex under 10 SJV, preferably 3-5.
1% is good. If 5% of the powder adsorbing 10 drugs is mixed, 0.5 drugs of drug concentration 1 will be mixed into the latex solid content.

カーペットの裏打層には、抗菌剤及び、(又は)防虫剤
として0.1〜20重2量チ含有するようにする。0.
1チ未清の少ない薬剤量でけ防範効果や防虫効果が得ら
れない。また20′N量チを越える含有量では薬剤が揮
散性を有するものであることから、臭気が激しく、実用
性がない。ラテックスに対し約5〜2,0重量%の薬剤
を分散させる場合には、吸着剤に′同定しても固定しな
くてもよい。
The backing layer of the carpet should contain 0.1 to 20 parts by weight of an antibacterial agent and/or an insect repellent. 0.
If the amount of the drug is too small, no control or insect repellent effect can be obtained. Furthermore, if the content exceeds 20'N, the chemical will be volatile and will give off a strong odor, making it impractical. When the drug is dispersed in an amount of about 5 to 2.0% by weight based on the latex, it may not be immobilized on the adsorbent.

本発明によって、カーペットや他の類(Uの敷物のバッ
キングに薬剤を固定し、この揮・散により抗菌効果や防
虫効果をもつカーペットが得られ、1〜3年間にわたり
効°果が持続されて敷物は衛生的であり、生活環境、居
住性が著り、 <改良できる。
According to the present invention, a chemical is fixed to the backing of carpets and other types of rugs (U), and by volatilization and dispersion of the chemical, carpets with antibacterial and insect repellent effects can be obtained, and the effects can be maintained for 1 to 3 years. Rugs are hygienic and improve the living environment and livability.

ν下実施例を挙げて本発明を東に説明する。The present invention will be explained in detail by giving examples below.

実施例1 ゛ナイロンのタフテイニ/グカーペット′を用いた実施
例を示す。
Example 1 An example using ``Nylon Tufty/Grug Carpet'' is shown.

1.2°25 tJe7’e sフイラメベトナイロン
三色異染糸の3プライした糸を使用して、1インチ0 タフティング密度で、レベルループパ゛イルのカーペッ
トを製造した。目付は1.1 Kg / m’ 、ノ;
イル長は5m、基布はポリグロビレン糸千儀で密度は2
2本X16本/インチのものを使用した。
A level loop pile carpet was made using three plies of 1.2°25tJe7'es filamented nylon tricolor discolored yarn at a 1 inch 0 tufting density. The basis weight is 1.1 Kg/m', no;
The length is 5m, the base fabric is polyglobylene yarn, and the density is 2.
2 pieces x 16 pieces/inch were used.

連続染色機にて常法により染色し、乾燥後、ラテックス
を゛リバースコーターで塗布−した。
It was dyed using a continuous dyeing machine in a conventional manner, and after drying, latex was applied using a reverse coater.

ラテックスには、エアロシール(デグ(ツサ社製のもの
)に1o3tJkl:%のα−、ブロムシンナムアルデ
ヒドを゛吸着固定したものを添加した。
To the latex, Aeroseal (Deg (manufactured by Tsusa)) in which 103tJkl:% of α-bromocinnamaldehyde was adsorbed and fixed was added.

ラテックスの配合は次の通りである。The formulation of the latex is as follows.

カルボキシル変性SBR樹脂ラテックス  10000
部水酸化チルミニラム         300部カル
ボキシメチルセルロース        15部吸着剤
(薬剤含有処理)           20部安定剤
                   3部このラテ
ックス組成物は充分撹拌17て、比t1、 s o 、
粘度1950GCP(センチボイズ)固形8分濃度80
%のf^世なものを得た:此をリバースコーターに11
)、含水重被で1.3Ky/−になるように塗布し、゛
同時に7オシス/平方ヤードの目付のジュート布を恨合
わせて熱風乾燥機にて1部40℃でi分間処理して仕上
けた。このカーペットをAとする。
Carboxyl modified SBR resin latex 10000
Parts: 300 parts of hydroxide, 300 parts of carboxymethylcellulose, 15 parts of adsorbent (treated with chemicals), 20 parts, 3 parts of stabilizer.This latex composition was thoroughly stirred to give a ratio of t1, s o ,
Viscosity 1950GCP (centiboise) Solid 8% Concentration 80
I got % f^ worldly thing: I used this as a reverse coater 11
), applied to a moisture-containing heavy coating of 1.3 Ky/-, and finished by applying jute cloth with a basis weight of 7 oz/square yard at the same time and treating each part in a hot air dryer at 40°C for i minutes. I got it. This carpet is called A.

実施例2 線条化たア、°クリル繊維のs1/Iの太さの紡績糸を
使用して1/ lゲージのタ°フティング機にてタフト
しで、カットパイルカーペットを製造した。哀りリムは
ポ、、す、プロ、ビレ゛ンスリット糸の24本X13本
/−インチの密度のものを使った。
Example 2 A cut pile carpet was produced by tufting a spun yarn of filamentated acryl fiber with a thickness of s1/I using a 1/1 gauge tufting machine. For the rim, I used Po, Su, Pro, Bere Slit thread with a density of 24 x 13 threads/-inch.

ラテックスは市販のポリアクリル酸エステル樹脂系のす
でに配合済のものを使用した。薬剤はパラクロロメタク
レ゛ゾールをアセトンに溶解し天然ゼオライトにe着処
理1、吸着量が15チのものを、アクリル樹脂固ル分に
対して10チ、混合した。
The latex used was a commercially available polyacrylic acid ester resin that had already been mixed. The drug was prepared by dissolving parachloromethacresol in acetone, applying e-adsorption treatment to natural zeolite, and adsorbing 15% of the drug, which was mixed in an amount of 10% based on the solid content of the acrylic resin.

カーペットに対七で乾燥重量でo、sKe/平方米に庁
るように樹脂を塗布し、乾燥したカー、ペットに、スコ
ッチガード、スプレーを行い、両耳をスリットして仕上
けた。このカーペットをBとする。
Resin was applied to the carpet to a dry weight of o, sKe/m2, and the dried car and pet were sprayed with Scotchgard and finished by slitting both ears. This carpet is called B.

実施例3 実−例1及び同2の工程で製造したカーペットA及びカ
ーベラ)Hに対する抗菌試験を下肥の通り実施した。
Example 3 An antibacterial test was carried out on Carpet A and Carbella) H produced in the steps of Examples 1 and 2 using manure.

夫々のカーペツ、トより直径1倒の試料片を切抜き、こ
れをパイル面を下になるようにシャーレの培地面に置い
た。
A sample piece with a diameter of one inch was cut out from each carpet and placed on the culture medium side of a petri dish with the pile side facing down.

真1で曇j1ポテト寒天培地に胞子を白金耳で平行に画
#v塗抹し、カーペット見本の・;4部シ面を培地面・
JLあてて、シャーレのフタをして、・27℃にて培養
し7日後に増殖の程度を判定しノr 0細菌では寒天平
板画線法を用い細菌に肉シナブイヨン244間培饗の1
白金耳を各平板に幣押する。次にカーペット試料片のパ
イル面を培地面にあてて置き、次でフタをして37℃で
培養し、48時間優に増殖の程度を判定した。
Smear the spores in parallel with a platinum loop onto a cloudy potato agar medium using #1, and place the 4th side of the carpet sample on the medium side.
Place the lid on the petri dish and incubate at 27°C. After 7 days, determine the degree of growth.
Stamp a platinum loop onto each plate. Next, the pile side of the carpet sample piece was placed against the medium surface, and then the carpet sample piece was placed with a lid and cultured at 37°C, and the degree of growth was determined over 48 hours.

試験結果を市販のナイロンタフ子ツドカーベツ)Cとと
もに第1表に示す。
The test results are shown in Table 1 together with the commercially available nylon tough carburetor C).

第  1  表 注=(−)発生阻止 (+)増  殖 実施例4 防虫効果についても実施例3と同一の力〜ベトについて
実施1−な。
Table 1 Note = (-) Inhibition of outbreak (+) Proliferation Example 4 The insect repellent effect was the same as in Example 3.

シャーレ(直径95−1高さ25σ)の中心に2m直径
に切りとったカーペット試料片1ヶ置き、此の中に対象
昆虫を入れてフタをし比較した。結果を第2表に示した
A carpet sample piece cut to a diameter of 2 m was placed in the center of a Petri dish (diameter 95-1 height 25σ), the target insect was placed in it, the lid was closed, and comparisons were made. The results are shown in Table 2.

第  2  表 注:効果判定は10疋の昆虫をンヤーレに入れ、5疋が
死亡する迄の日数を示す。
Note to Table 2: Effect evaluation indicates the number of days it takes for 5 insects to die after 10 insects are placed in the nyare.

Claims (1)

【特許請求の範囲】 l)、抗菌剤及び(又は)防虫剤を0.1〜20重量%
含有する樹脂をt面にコーティングしてなるカーペット
。 2)1を温で気、化し得る性質を、もつ抗菌剤又は防虫
剤であることを特徴とする特許請求の範囲第1項記載の
カーペット。 3)抗菌剤又は防虫剤が多孔性゛数層性粉末に吸着され
た状態で樹脂に分散されていることを特徴とする特許請
求の範囲第1項又祉第2項記載のカーペット。
[Claims] l) 0.1 to 20% by weight of an antibacterial agent and/or insect repellent;
Carpet made by coating the t-side with resin. 2) The carpet according to claim 1, which is an antibacterial agent or an insect repellent having the property of being able to oxidize 1 with heat. 3) The carpet according to claim 1 or claim 2, characterized in that an antibacterial agent or an insect repellent is dispersed in the resin while being adsorbed to a porous multilayer powder.
JP17560181A 1981-11-04 1981-11-04 Carpet Granted JPS5878613A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17560181A JPS5878613A (en) 1981-11-04 1981-11-04 Carpet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17560181A JPS5878613A (en) 1981-11-04 1981-11-04 Carpet

Publications (2)

Publication Number Publication Date
JPS5878613A true JPS5878613A (en) 1983-05-12
JPH0158966B2 JPH0158966B2 (en) 1989-12-14

Family

ID=15998937

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17560181A Granted JPS5878613A (en) 1981-11-04 1981-11-04 Carpet

Country Status (1)

Country Link
JP (1) JPS5878613A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58180673A (en) * 1982-04-12 1983-10-22 ジェイエスアール株式会社 Carpet containing available component
JPS59191977U (en) * 1983-06-09 1984-12-20 帝三製薬株式会社 carpet
JPS6091081U (en) * 1983-11-28 1985-06-21 株式会社クラレ insect-proof carpet
JPS60126122A (en) * 1983-12-13 1985-07-05 東武株式会社 Carpet and its production
JPS60156314U (en) * 1984-03-27 1985-10-18 東武株式会社 electric carpet
JP2002028065A (en) * 2000-07-13 2002-01-29 Toli Corp Insect resistance carpet

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57120386U (en) * 1981-01-21 1982-07-26
JPS5838516A (en) * 1981-08-31 1983-03-07 旭化成株式会社 Carpet

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57120386U (en) * 1981-01-21 1982-07-26
JPS5838516A (en) * 1981-08-31 1983-03-07 旭化成株式会社 Carpet

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58180673A (en) * 1982-04-12 1983-10-22 ジェイエスアール株式会社 Carpet containing available component
JPS59191977U (en) * 1983-06-09 1984-12-20 帝三製薬株式会社 carpet
JPS6091081U (en) * 1983-11-28 1985-06-21 株式会社クラレ insect-proof carpet
JPH0243243Y2 (en) * 1983-11-28 1990-11-16
JPS60126122A (en) * 1983-12-13 1985-07-05 東武株式会社 Carpet and its production
JPS6324371B2 (en) * 1983-12-13 1988-05-20 Tobu Kk
JPS60156314U (en) * 1984-03-27 1985-10-18 東武株式会社 electric carpet
JP2002028065A (en) * 2000-07-13 2002-01-29 Toli Corp Insect resistance carpet

Also Published As

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