JPS5857551B2 - Heat dyeing method - Google Patents
Heat dyeing methodInfo
- Publication number
- JPS5857551B2 JPS5857551B2 JP51136516A JP13651676A JPS5857551B2 JP S5857551 B2 JPS5857551 B2 JP S5857551B2 JP 51136516 A JP51136516 A JP 51136516A JP 13651676 A JP13651676 A JP 13651676A JP S5857551 B2 JPS5857551 B2 JP S5857551B2
- Authority
- JP
- Japan
- Prior art keywords
- transfer
- layer
- transferred
- synthetic resin
- transfer layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Coloring (AREA)
Description
【発明の詳細な説明】
本発明はアクリル樹脂板、ポリエステル樹脂板、ポリエ
チレン樹脂板、ポリプロピレン樹脂板等の各種合成樹脂
部分いはＦＲＰ等の各種複合材料の合成樹脂部材に耐候
性のすぐれた繊細緻密な多色模様の染色を行う方法に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention is applicable to various synthetic resin parts such as acrylic resin plates, polyester resin plates, polyethylene resin plates, polypropylene resin plates, etc., or synthetic resin parts of various composite materials such as FRP, which have excellent weather resistance and delicate properties. This invention relates to a method for dyeing a dense multicolor pattern.
従来、各種合成樹脂部分いは各種複合材料の合成樹脂部
分に図柄を施す方法としては、（１）直接印刷法、（２
）ラミネート法、（３）転写絵付法、又は（４）特公昭
４７−５１７３４号公報に示される昇華転写法等が行オ
つれている。Conventionally, methods for applying designs to various synthetic resin parts or synthetic resin parts of various composite materials include (1) direct printing method, (2)
) lamination method, (3) transfer painting method, or (4) sublimation transfer method shown in Japanese Patent Publication No. 47-51734, etc. are becoming increasingly popular.
然しなから、（１）の方法では（イ）大型の特殊印刷機
を必要とし、印刷ロスが多い。However, method (1) requires (a) a large special printing machine, resulting in a lot of printing loss.
（ロ）曲面等への印刷が困難である。(b) Printing on curved surfaces is difficult.
←→多色模様連続階調柄を表現することが困難である。←→It is difficult to express multicolor patterns and continuous tone patterns.
に）表面に印刷インキ塗膜が印刷されているだけである
ので製品に深みがなく、且つ耐摩擦性が弱い等の欠点を
有している。2) Since the surface is only printed with a printing ink coating, the product lacks depth and has drawbacks such as poor abrasion resistance.
又、（２）の方法においては、（イ）ラミネート物量の
接着力不足により剥離が生ずる。Furthermore, in the method (2), (a) peeling occurs due to insufficient adhesive strength of the amount of laminate.
（ロ）素材の持ち味が表現できない等り欠点を有してい
る。(b) It has drawbacks such as not being able to express the characteristics of the material.
又、（３）の方法においては、被転写体の表面に転写層
が接着しているたけである為、（イ）立体感が無い。Furthermore, in the method (3), since the transfer layer is merely adhered to the surface of the object to be transferred, (a) there is no three-dimensional effect.
（０）耐摩擦性が弱い等の欠点を有している。又、（４
）の方法は、（１） 、 （２）及び（３）の欠点を改
良するものとして考えられたものであるが、（イ）多色
模様の形成は容易であるが、その転写工程が単なる昇華
転写紙と被染色体との接触のみによるためパターンずれ
が生じ易い。(0) It has drawbacks such as poor abrasion resistance. Also, (4
Method (a) was designed to improve the drawbacks of (1), (2), and (3), but (a) although it is easy to form a multicolored pattern, the transfer process is simple. Pattern deviations are likely to occur due to only contact between the sublimation transfer paper and the target chromosome.
（ロ）昇華性染料が高価であるため製品の価格も高い。(b) Since sublimation dyes are expensive, the price of the product is also high.
（ハ）転写後において製品の耐候性や堅牢度が乏しい。(c) The product has poor weather resistance and fastness after transfer.
に）使用する昇華転写紙を長期間保存すると図柄層の染
料が昇華してしまう。) If the sublimation transfer paper used is stored for a long period of time, the dye in the pattern layer will sublimate.
等の欠点を有している。本発明は前記（４）の昇華転写
法の有する欠点をさらに改良除去するために研究の結果
、ホットスタンピング方式の利用、即ち非昇華性染料で
印刷されたインキ層を転写層中に含む転写材の該転写層
を被染色体である合成樹脂部材面へ一旦転写した後、こ
れを乾式加熱すれば、従来乾式加熱では不可能とされて
いた非昇華性染料においても染色が可能であることを見
い出し本発明の完成に至ったものである。It has the following disadvantages. In order to further improve and eliminate the drawbacks of the sublimation transfer method described in (4) above, the present invention utilizes a hot stamping method, that is, a transfer material containing an ink layer printed with a non-sublimable dye in the transfer layer. We discovered that by once transferring this transfer layer to the surface of a synthetic resin member that is to be chromosomal and then dry heating it, it is possible to dye even non-sublimable dyes, which was conventionally thought to be impossible with dry heating. This has led to the completion of the present invention.
本発明に使用される転写材は、非昇華性染料で印刷され
たインキ層を転写層中に含むものであれば如何なる層構
成のものでもよく、例えば第１図に示すように、ポリエ
ステルフィルム、セロノ）ン等のシート又はこれと紙等
との複合材よりなる基、体シート１の一面に、該基体シ
ート１と剥離可能な剥離材例えばポリメチルメタアクリ
ル酸樹脂等を印刷塗布して剥離層２を形成し、次いでこ
の一ヒに非昇華性染料を含む着色インキを用いてグラビ
ア印刷等により所望の図柄のインキ層３を形成した後、
更にこの上に加熱加圧により被転写体に接着する接着層
４を設けたもの、或いは第２図に示すように前記インキ
層３及び接着層４の代りに剥離層２の上に非昇華性染料
を含む所望の図柄の着色接着層５を設けたものを使用す
ることができる。The transfer material used in the present invention may have any layer structure as long as the transfer layer includes an ink layer printed with a non-sublimable dye. For example, as shown in FIG. 1, a polyester film, A release material that can be peeled off from the base sheet 1, such as polymethyl methacrylic acid resin, is printed on one side of the base sheet 1 made of a sheet such as seronon, or a composite material of this and paper, etc., and then peeled off. After forming a layer 2, and then forming an ink layer 3 with a desired pattern on this layer by gravure printing or the like using a colored ink containing a non-sublimable dye,
Furthermore, an adhesive layer 4 that adheres to the transferred object by heat and pressure is provided on this, or as shown in FIG. One provided with a colored adhesive layer 5 containing a dye and having a desired pattern can be used.
本発明は、前記のごとき転写材の転写層を第３図に示す
様に被転写体の合成樹脂部材面に設置して転写した後、
乾式加熱により所望の図柄のインキ層３又は着色接着層
５に含まれている非昇華性染料を被転写体の合成樹脂部
材６内へ移行せしめ、第４図に示す如く転写層ａのイン
キ層３の図柄に対応した位置の被転写体の合成樹脂部材
を染色させる。In the present invention, after the transfer layer of the above-mentioned transfer material is placed on the surface of the synthetic resin member of the object to be transferred as shown in FIG.
By dry heating, the non-sublimable dye contained in the ink layer 3 or the colored adhesive layer 5 of the desired pattern is transferred into the synthetic resin member 6 of the transfer target, and the ink layer of the transfer layer a is transferred as shown in FIG. The synthetic resin member of the transferred body at the position corresponding to the pattern 3 is dyed.
尚、転写層を被転写体の合成樹脂部材に転写するに際し
ては加圧又は加熱加圧によりいわゆるバインダー転写を
行う。When transferring the transfer layer to the synthetic resin member of the object to be transferred, so-called binder transfer is performed by applying pressure or heating and pressing.
加熱染色後は、被転写体面に残存する転写層ａを溶剤洗
浄や温水洗浄により溶解除去或いはパフかけ等により研
摩除去すると、第５図に示すように転写材に形成した所
望の図柄のインキ層３の図柄に対応した染色図柄を有す
る染色物が得られる。After heat dyeing, the transfer layer a remaining on the surface of the transfer material is dissolved and removed by solvent cleaning or hot water washing, or is removed by polishing by puffing, etc., and as shown in FIG. 5, the ink layer of the desired design formed on the transfer material is removed. A dyed product having a dyed pattern corresponding to the pattern 3 is obtained.
本発明を適用し得る被転写体としては、各種合成樹脂板
や合成樹脂を塗装或いは含浸させた金属、ガラス、スレ
ート等の複合材料等を用いることができるが、転写後の
乾式加熱に耐えるものを選択使用する必要がある。As the transfer object to which the present invention can be applied, various synthetic resin plates and composite materials such as metal, glass, and slate coated or impregnated with synthetic resin can be used, but materials that can withstand dry heating after transfer can be used. You need to use the selection.
本発明に使用するインキ層又は着色接着層中に含まれる
非昇華性染料としては、従来公知の各種のものを使用で
きるが、適用する合成樹脂部材に応じて適宜選択使用す
るのが望ましい。As the non-sublimable dye contained in the ink layer or colored adhesive layer used in the present invention, various conventionally known non-sublimable dyes can be used, but it is desirable to select and use them as appropriate depending on the synthetic resin member to which they are applied.
例えば、合成樹脂部材がアクリル系樹脂の場合には塩基
性染料、酸性染料等を、又ポリエステル系樹脂の場合に
は非昇華性分散染料、カチオン染料等を、又ポリアミド
系樹脂の場合には酸性染料、非昇華性分散染料、建染染
料等を、又ポリプロピレン系樹脂の場合には油溶性染料
、非昇華性分散染料等を適宜選択して使用するのが好ま
しい。For example, if the synthetic resin member is acrylic resin, use basic dyes, acidic dyes, etc., if it is polyester resin, use non-sublimable disperse dyes, cationic dyes, etc., and if it is polyamide resin, use acidic dyes, etc. It is preferable to use dyes, non-sublimable disperse dyes, vat dyes, etc., and in the case of polypropylene resins, oil-soluble dyes, non-sublimable disperse dyes, etc., appropriately selected.
又、前記した転写後の被染色体及び転写層の乾式加熱条
件としては、１２０〜２４０℃、３０秒〜１０分が適当
である。Further, the appropriate dry heating conditions for the chromosomes and the transfer layer after transfer are 120 to 240° C. and 30 seconds to 10 minutes.
以上説明した如く、本発明は非昇華性染料で印刷された
インキ層を転写層中に含む転写材を利用して被転写体の
合成樹脂部材に、従来では全く考えられていなかった非
昇華性染料を乾式加熱のみによって染色を行うことがで
きる。As explained above, the present invention utilizes a transfer material containing an ink layer printed with a non-sublimable dye in the transfer layer to apply a non-sublimable property to the synthetic resin member of the transfer target, which has been completely unthinkable in the past. Dyeing can be carried out only by dry heating the dye.
したがって、円筒面や球面等の立体表面へ染色する場合
にもパターンすれを起重ことかなく、繊細緻密な多色摸
様連続階調柄の染色が可能であり、昇華４ヒＬ染別に比
し安価な染料を用いて酬候性や堅牢度の１ぐれた染色体
を得ることができ、而も転写材の被転写体への転写速度
が大きいことから大量生産が可能であり、そして又染料
が合成樹脂内部にまで浸透移行し立体感のある染色体を
得ることができるものである。Therefore, even when dyeing a three-dimensional surface such as a cylindrical or spherical surface, it is possible to dye a delicate and detailed continuous tone pattern like a multicolor print without causing any pattern misalignment, compared to sublimation 4-layer dyeing. However, it is possible to obtain chromosomes with superior dye properties and fastness using inexpensive dyes, and mass production is possible due to the high transfer speed of the transfer material to the transfer target. can penetrate and migrate into the interior of the synthetic resin, making it possible to obtain chromosomes with a three-dimensional effect.
以下実施例を記載し、本発明を具体的に説明する。EXAMPLES The present invention will be specifically explained below with reference to Examples.
実施例 １
より成る組成をポリエステルフィルム（
２５μ厚）
に順次クラビア印刷して得られた転写材の接着層面をユ
リア樹脂板上に設置して加熱加圧により転写層を転与し
、而る後１８０°Ｃ１１００分間乾力日熱し、その後ト
リクレンにより転写層を溶解除去した。Example 1 The adhesive layer surface of the transfer material obtained by sequentially printing the composition of Example 1 on a polyester film (25μ thick) was placed on a urea resin plate, and the transfer layer was transferred by heating and pressing. After drying in the sun at 180° C. for 1100 minutes, the transfer layer was dissolved and removed using trichlene.
その結果内部にまで非昇華性浸透し極めて立体感のある
多色模様連続階調柄を有するユリア樹月’ＦＡ反がイ尋
られた。As a result, Yuria Kizuki's FA fabric, which has a continuous gradation multicolor pattern with an extremely three-dimensional effect that penetrates into the interior without sublimation, was discovered.
実施例 ２
（１）剥離層、及び（２）インキ層
実施例１に同じ
より戊る組成をポリエステルフィルム（２５μ厚に順次
グラビア印刷して得られた転写材の接着層面をポリアミ
ド樹脂板（ナイロン−６）上に設置して加熱加圧により
転写層を転写し、而る後１５０°Ｃの温度で５分間乾式
加熱し、その後トリクレンにより転写層を溶解除去した
。Example 2 (1) Release layer, and (2) Ink layer The adhesive layer surface of the transfer material obtained by gravure printing the same composition as in Example 1 onto a polyester film (25μ thick) was applied to a polyamide resin plate (nylon -6), the transfer layer was transferred by heating and pressing, and then dry heating was performed at a temperature of 150° C. for 5 minutes, and then the transfer layer was dissolved and removed using trichlene.
その結果内部にまで非昇華性染料が浸透し極めて立体感
のある多色模様連続階調柄を有するポリアミド樹脂板が
得られた。As a result, a polyamide resin board was obtained in which the non-sublimable dye penetrated into the interior and had a multicolored continuous tone pattern with an extremely three-dimensional effect.
よりなる組成をポリエステルフィルム（２５μ厚）に順
次グラビア印刷して得られた転写材の着色接着層面を表
面に熱硬化アクリル樹脂を焼付塗装したアルミニウム鑵
に設置して加熱加圧により転写層を転写し、而る後２４
０°Ｃの温度で３分間乾式加熱し、その後温水洗浄によ
り転写層を溶解除去した。The colored adhesive layer surface of the transfer material obtained by successively gravure printing a composition of the following on a polyester film (25μ thick) was placed on an aluminum plate with a thermosetting acrylic resin baked on the surface, and the transfer layer was transferred by heating and pressure. Then after 24
Dry heating was performed at a temperature of 0°C for 3 minutes, and then the transfer layer was dissolved and removed by washing with warm water.
その結果、多色模様連続階調柄を有するアクリル樹脂塗
装アルミニウム鑵が得られた。As a result, an acrylic resin-coated aluminum plate having a multicolor continuous tone pattern was obtained.
【図面の簡単な説明】
第１図及び第２図は本発明に使用する転写材の一実施例
を示す断面図である。
第３図は転写層を転写移行して基体、シートを剥離する
状態を示す断面図であり、第４図は転写後の乾式加熱に
より転写層中に含まれる非昇華性染料が被転写体の合成
樹脂部材へ移行する状態を示す断面図であり、第５図は
染色後転写層を除去した被転写体の断面図である。
図中１は基体シート、２は剥離層、３はインキ層、４は
接着層、５は着色接着層、６は合成樹脂部材、１は非染
色部材、ａは転写層、ｂは被転写体。BRIEF DESCRIPTION OF THE DRAWINGS FIGS. 1 and 2 are cross-sectional views showing one embodiment of a transfer material used in the present invention. Fig. 3 is a cross-sectional view showing the state in which the transfer layer is transferred and the substrate and sheet are peeled off, and Fig. 4 is a cross-sectional view showing the state in which the transfer layer is transferred and the substrate and sheet are peeled off. FIG. 5 is a cross-sectional view showing a state in which the material is transferred to a synthetic resin member, and FIG. 5 is a cross-sectional view of the transferred object from which the transfer layer has been removed after dyeing. In the figure, 1 is a base sheet, 2 is a release layer, 3 is an ink layer, 4 is an adhesive layer, 5 is a colored adhesive layer, 6 is a synthetic resin member, 1 is a non-dyed member, a is a transfer layer, and b is a transferred object .
Claims (1)
む転写材を被転写体の合成樹脂部材面に設置し、その転
写層を転写した後、乾式加熱により該転写層内の非昇華
性染料を被転写体の合成樹脂部材内部へ移行せしめ、而
る後被転写体上の残存物を除去処理することを特徴とす
る加熱染色法。1. A transfer material containing an ink layer printed with a non-sublimable dye in the transfer layer is placed on the synthetic resin member surface of the transfer target, and after the transfer layer is transferred, the non-sublimation in the transfer layer is removed by dry heating. A heat dyeing method characterized by transferring a coloring dye into the inside of a synthetic resin member of an object to be transferred, and then removing any residue on the object to be transferred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51136516A JPS5857551B2 (en) | 1976-11-12 | 1976-11-12 | Heat dyeing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51136516A JPS5857551B2 (en) | 1976-11-12 | 1976-11-12 | Heat dyeing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5360970A JPS5360970A (en) | 1978-05-31 |
| JPS5857551B2 true JPS5857551B2 (en) | 1983-12-20 |
Family
ID=15176994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51136516A Expired JPS5857551B2 (en) | 1976-11-12 | 1976-11-12 | Heat dyeing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5857551B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01111165U (en) * | 1988-01-18 | 1989-07-26 | ||
| JP2019173233A (en) * | 2018-03-29 | 2019-10-10 | 株式会社丸保 | Method for transfer-printing polyamide fiber material |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4587155A (en) * | 1982-05-12 | 1986-05-06 | Raymond Iannetta | Method of applying a dye image to a plastic member and the image bearing member thereby formed |
| US4668239A (en) * | 1982-05-12 | 1987-05-26 | K-T, Inc. | Method of applying a dye image to a plastic member |
-
1976
- 1976-11-12 JP JP51136516A patent/JPS5857551B2/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01111165U (en) * | 1988-01-18 | 1989-07-26 | ||
| JP2019173233A (en) * | 2018-03-29 | 2019-10-10 | 株式会社丸保 | Method for transfer-printing polyamide fiber material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5360970A (en) | 1978-05-31 |
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