JPS5849768A - Adhesive composition for surface protection - Google Patents
Adhesive composition for surface protectionInfo
- Publication number
- JPS5849768A JPS5849768A JP14849681A JP14849681A JPS5849768A JP S5849768 A JPS5849768 A JP S5849768A JP 14849681 A JP14849681 A JP 14849681A JP 14849681 A JP14849681 A JP 14849681A JP S5849768 A JPS5849768 A JP S5849768A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive composition
- adhesive
- acrylate
- homopolymer
- surface protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は金属板、化粧板、ガラス−、樹脂板の如き板状
物品Ｏ’ＲＷＪＫ貼り付けられ、これらの物品１１にゴ
ミが付着したり、傷付けられたりする０を防止するため
に用いられる表面録−用帖梼フイルム又は＆−）に使用
される表ｍ保護用接ＩＩ１組成物（以下接着組成物とい
う）Ｋ関するもので、建に詳しくは貼り付は初切におい
て適度な接−性を有し、しかも経日後も殆んど七の接着
力が上昇せず、簡単に＠雌除去できる接着組成物を提供
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention is designed to prevent O'RWJK from attaching plate-like articles such as metal plates, decorative plates, glass, and resin plates, and to prevent dust from adhering to or being damaged by these articles. This article relates to a protective adhesive II composition (hereinafter referred to as an adhesive composition) K used for a protective adhesive film or &-) used for surface protection. The object of the present invention is to provide an adhesive composition that has appropriate adhesion properties, has almost no increase in adhesive strength even after a period of time, and can be easily removed.
表面保護用粘着フィルム（以下粘着フィルムという）は
、ゴミ付着防止、表面損傷防止など所明の目的が達成さ
れると剥離されるものである。A surface protection adhesive film (hereinafter referred to as an adhesive film) is peeled off when a predetermined purpose, such as preventing dust from adhering to the surface or preventing damage to the surface, is achieved.
これまでかかる粘着フィルムには、アクリル系感圧接着
剤組成物、天然ゴム又はポリイソプレンゴム系感圧接着
剤組成物などの接着剤組成物が使用されているが、これ
を板状物品の表面に貼り付けて長明間保存しておくと、
経日で接着力が上昇するために剥離が困感であったり、
剥離しえても板状物品面に多量の糊残りがするといつた
問題がありた。Adhesive compositions such as acrylic pressure-sensitive adhesive compositions, natural rubber or polyisoprene rubber pressure-sensitive adhesive compositions have been used for such adhesive films to date, and adhesive compositions such as acrylic pressure-sensitive adhesive compositions, natural rubber or polyisoprene rubber-based pressure-sensitive adhesive compositions have been used on the surface of plate-shaped articles. If you paste it and save it for a long time,
It may be difficult to peel off because the adhesive strength increases over time, or
Even if the adhesive could be peeled off, there was a problem in that a large amount of adhesive remained on the surface of the plate-shaped article.
かかる開明を解決する手段として、接着剤組成物に界面
活性剤やシラコーン組成物を剥離調整剤として配合する
方法が提案され、一部実施されている。この方法は、接
着剤組成物中に配合した界面活性剤やＶ９プーン組成物
を経時的に接着剤層と板状物品との界面Ｋｉｔみ出させ
て非接着性の薄膜状物を形成させ、経日での接着力の上
昇を防止するものである。As a means to solve this problem, a method of incorporating a surfactant or a silicone composition as a release modifier into an adhesive composition has been proposed and has been partially implemented. In this method, a surfactant or a V9 Poon composition blended in an adhesive composition is allowed to ooze out over time from the interface between an adhesive layer and a plate-like article to form a non-adhesive thin film-like material. This prevents the adhesive strength from increasing over time.
しかしてこの方法では、接着剤層の種類、厚みなどＫよ
りて滲み出し量が異なるために、安定した剥離効果が得
られＫくいという不都合があり、また板状物品に粘着フ
ィルムを貼着した状態で加熱されたりすると、滲み出し
が急激に起って接着力の低下を来たし、板金加工などの
加工時にフィルムが板状物品面より浮いたり、或いはフ
ィルムを剥がしたときに板状物品面に薄膜状物が残留し
、これが後工程の印刷工程などのときに、印刷ムラを起
生させたりするといった不都合がある。However, this method has the disadvantage that it is difficult to obtain a stable peeling effect because the amount of seepage varies depending on the type and thickness of the adhesive layer. If the film is heated in this condition, oozing will occur rapidly and the adhesive force will decrease, and the film may float above the surface of the plate-shaped object during processing such as sheet metal processing, or when the film is peeled off, it may bleed onto the surface of the plate-shaped object. There is a problem that a thin film-like substance remains, which causes printing unevenness during a subsequent printing process.
本発明者達はかかる従来技術？情況に鑑み鋭意研究を重
ねた結果、アクリル系感圧接着剤組成物に、スチレン及
びその誘導体のホモポリマーを配合することＫより、上
記の諸問題を解決できることを見い出し、本発明に至り
たものである。The present inventors have such prior art? As a result of extensive research in view of the circumstances, it was discovered that the above problems could be solved by blending a homopolymer of styrene and its derivatives into an acrylic pressure-sensitive adhesive composition, leading to the present invention. It is.
即ち本発明は、アクリル系感圧接着剤組成物Ｋ。That is, the present invention provides acrylic pressure-sensitive adhesive composition K.
スチレン及びその誘導体のホモポリマーを配合してなる
接着組成物を提供するものであり。The present invention provides an adhesive composition containing a homopolymer of styrene and its derivatives.
本発明の実施に当って用いられるアクリル系感圧接着剤
組成物としては、アルキル基のモ均Ｏ数が１〜１２個の
アクリル酸アルキルエステルと、他の共重合可能な官能
性モノマーとの共重合物が挙げられる。The acrylic pressure-sensitive adhesive composition used in the practice of the present invention is composed of an acrylic acid alkyl ester having an alkyl group having an average O number of 1 to 12, and other copolymerizable functional monomers. Examples include copolymers.
アクリル酸アルキルエステルとしては、メチルアクリレ
ート、エチルアクリレート、プロピルアクリレート、ｎ
−ブチルアクリレート、ヘキンルアクリレート、２−エ
チルブチルアクリレート、イソオクチルアクリレート、
２−エチルへキシルアクリレート、デＶルアクリレート
、ドデνルアクツレートなどを挙げることができ、また
官能性モノマーとしては、（メタ）アクリル酸、イタコ
ン酸、マレイン酸、無水マレイン酸、ヒドロキシエチル
アクリレート、ヒドロキシプロピルアクリレート、アク
リルアミド、ジメチルアクリルアミドなどを挙げること
ができ、これらＯモノマーは０．５〜１５重量％の範囲
で配合される。Examples of acrylic acid alkyl esters include methyl acrylate, ethyl acrylate, propyl acrylate, n
-butyl acrylate, hequinyl acrylate, 2-ethylbutyl acrylate, isooctyl acrylate,
Examples of functional monomers include 2-ethylhexyl acrylate, deV acrylate, and dodeV acrylate, and examples of functional monomers include (meth)acrylic acid, itaconic acid, maleic acid, maleic anhydride, hydroxyethyl acrylate, Hydroxypropyl acrylate, acrylamide, dimethyl acrylamide, etc. can be mentioned, and these O monomers are blended in a range of 0.5 to 15% by weight.
これらのアクリル酸アルキルエステルと官能性モノマー
との共重合物系には、２０重量慢以下の共重合可能なビ
ニルモノマー例えば酢酸ビニル、プロピオン酸ビニル、
アクリミニトリル、メタクリル酸アルキルエステルなど
を共重合させることもできる。In the copolymer system of these acrylic acid alkyl esters and functional monomers, copolymerizable vinyl monomers having a weight of 20% or less, such as vinyl acetate, vinyl propionate,
Acryminitrile, methacrylic acid alkyl ester, etc. can also be copolymerized.
このように組成したアクリル系感圧接着剤組成物には、
スチレン及びその誘導体のホモポリマーが配合され、本
発明の接＊組成物とされる。The acrylic pressure-sensitive adhesive composition composed in this way has the following properties:
A homopolymer of styrene and its derivatives is blended into the adhesive composition of the present invention.
ホモポリマーの配合量は、０．１〜２０重量％の範囲と
するのが好ましく、０．１部１％以下で、は添加の効果
が認められず、２０重量％以上では接着組成物の初刷接
着力が著しく低下するので好ましくないものである。The blending amount of the homopolymer is preferably in the range of 0.1 to 20% by weight; if it is less than 0.1 parts and 1%, no effect of addition will be observed, and if it is more than 20% by weight, the initial content of the adhesive composition will be reduced. This is undesirable because it significantly reduces the adhesion to the brush.
上記のスチレン誘導体としては、４−ｔｅｒｔ−ブチル
スチレン、２・４−ジイソプロピルスチレン、２・５−
ジメチルスチレン、３Φ４−ジエチルスチレン、２−ヒ
ドロキシメチルスチレン、２−メチルスチレン、４−メ
チルスチレン、４−ブチルスチレンなどを挙げることが
できる。The above styrene derivatives include 4-tert-butylstyrene, 2,4-diisopropylstyrene, 2,5-
Examples include dimethylstyrene, 3Φ4-diethylstyrene, 2-hydroxymethylstyrene, 2-methylstyrene, 4-methylstyrene, and 4-butylstyrene.
このようにアクリル系感圧接着剤組成物に、スチレン及
びその誘導体のホモポリマーが配合された接着組成物に
は、必要に応じてポリインシアネート化合物、メラミン
化合物の如き架橋剤、その低粘着付与性樹脂、充填剤な
どの配合剤が添加され、ポリエチレン、ポリプロピレン
、ポリ塩化ビニルの如きプラスチックからなるフィルム
又は紙などの自己支持性フィルム状物（厚さ約１０〜２
００声（２）に塗布乾燥され、表面保護用粘着フィルム
が得られる。In this way, an adhesive composition in which a homopolymer of styrene and its derivatives is blended with an acrylic pressure-sensitive adhesive composition may optionally contain a crosslinking agent such as a polyincyanate compound or a melamine compound, and its low tackifying property. Compounding agents such as resins and fillers are added to form a self-supporting film-like material (with a thickness of about 10 to 2
00 (2) and dried to obtain an adhesive film for surface protection.
本発明の表面保護用接着組成物は、後述する実施例にて
より具体的に実証されるが、経日での接着力の上昇が少
ないものである。The adhesive composition for surface protection of the present invention shows little increase in adhesive strength over time, as will be demonstrated more specifically in the Examples described later.
以下本発明の実施例を示す。文中部とあるのは重量部を
意味する。なお以下の実施例は、本発明の接着組成物を
用いた表面保膜用粘着フィルムで表列した。
一
実施例１
ブデルアクリレート：アクリロニトリル：アクリル酸−
ｔｏｏ：ｉｓ：ｓ （重量比）を常法によりトルエン中
で重合して得たアクリル系共重合物１，００部にボッイ
ソシアネート化合物２部とポリスチレン１部とを配合し
た接着組成物溶液を、表面コロナ放電旭理したポリエチ
レンフイルム（厚さ６０７ｍ）の処理面に、乾燥後の厚
みが５７寓となるようにに塗布して１００℃で３分間乾
燥して、表面保護用粘着フィルムを得た。Examples of the present invention will be shown below. The text middle part means the weight part. In addition, the following examples are listed using adhesive films for surface film retention using the adhesive composition of the present invention.
Example 1 Budel acrylate: Acrylonitrile: Acrylic acid-
An adhesive composition solution containing 1,00 parts of an acrylic copolymer obtained by polymerizing too:is:s (weight ratio) in toluene by a conventional method, 2 parts of a boisocyanate compound and 1 part of polystyrene, It was applied to the treated surface of a polyethylene film (thickness 607 m) subjected to surface corona discharge treatment so that the thickness after drying would be 57 mm, and dried at 100°C for 3 minutes to obtain a surface protective adhesive film. .
実施例２
２−エチルへキシルアクリレート：エチルアクリレート
：メテルメタアクリレート：２−ヒドロキレエチルアク
リレ−）＝４０：６０：５：５ （重量比）を常法によ
り重合して得たアクリル系共重合物１００ＩＫ、ポリイ
ソシアネート化合物２部とポリスプレン１０部とを配合
した接着組成物溶液を、ボッエチレンフィルム（実施例
１と同じ）の処理面に乾燥後の厚みが５声惰となるよう
に塗布して、１００℃で３分間乾燥して、表面保護用粘
着フィルムを得た。Example 2 Acrylic copolymer obtained by polymerizing 2-ethylhexyl acrylate: ethyl acrylate: methacrylate: 2-hydroxylethyl acrylate = 40:60:5:5 (weight ratio) by a conventional method. An adhesive composition solution containing polymer 100IK, 2 parts of a polyisocyanate compound, and 10 parts of polysprene was applied to the treated surface of a Botethylene film (same as in Example 1) so that the thickness after drying would be 5 parts. Then, it was dried at 100° C. for 3 minutes to obtain an adhesive film for surface protection.
実施例３
２−エチルへ＋Ｖルアクリレート：１クリロニトリル：
アクリル酸−７０：２５：５（ｆｉ量比）を常法により
重合して得たアクリル系共重合物１００部に、ポリイソ
シアネート化合物２部とポリスチレン２０ｓとを配合し
た接着組成物溶液を、ポリエチレンフィルム（実施例１
と同じ）の処理面Ｋ。Example 3 To 2-ethyl+V acrylate: 1 Acrylonitrile:
An adhesive composition solution containing 100 parts of an acrylic copolymer obtained by polymerizing acrylic acid -70:25:5 (fi ratio) by a conventional method, 2 parts of a polyisocyanate compound and 20s of polystyrene was added to polyethylene. Film (Example 1
(same as ) processing surface K.
乾燥後の厚みが６／惰となるように塗布して、１００℃
で３分間乾燥して１表面保護用粘着フィルムを得た。Apply so that the thickness after drying is 6 / 100℃ and heat at 100℃.
The film was dried for 3 minutes to obtain an adhesive film for surface protection.
実施例４
実施例３において、ポリスチレンの代りに、ポリ４−メ
チルスチレンを用いたほかは、実施例３と同様の操作に
より、表面保護用粘着フィルムを得た。Example 4 A surface protection adhesive film was obtained in the same manner as in Example 3, except that poly4-methylstyrene was used instead of polystyrene.
第１表は実施例１〜４の試験結果を示すものである。８
１表中の比較例１〜３は実施例１〜３に夫々対応してお
り、ポリスチレンを配合していないものを示している。Table 1 shows the test results of Examples 1-4. 8
Comparative Examples 1 to 3 in Table 1 correspond to Examples 1 to 3, respectively, and do not contain polystyrene.
第１表中の試験方法
初切接櫂カニＳσ８３０４ス戸ンレス板Ｋｆｙプル（Ｚ
Ｏｓｔｍ幅）を貼り付け゛ｒｉＡ験体を作り、３０分間
放置後に１８０度引き剥がし接着力（引張速度３００ｍ
／ｍｉｎ、２０℃Ｘ６０９１６Ｒ，Ｈ，）を測定した。Test method in Table 1 First cutting paddle Crab Sσ8304 Sealess board Kfy pull (Z
Make a riA test specimen by pasting the 300m width) and peeling it off at 180 degrees after leaving it for 30 minutes.
/min, 20°C x 60916R,H,) was measured.
経日後Ｏ接着カニ上記の試験体を７０℃Ｘ６５４Ｒ，Ｈ
。After a few days, the above test specimen was heated to 70°C x 654R, H.
.
中に１６ｇ時間保存し、取り出して２０℃Ｘ６５％丸■
、の条件下で１８０度引き剥がし接着力（引張速度３０
０５ｍ／ｍ１ｎ）を測定した。Store 16g in the container for an hour, take it out and store it at 20°C x 65%.
, 180 degree peeling adhesive strength (pulling speed 30
05m/m1n) was measured.
促進テスト後の接着カニ試験体をフェザ−オーメーター
中に５０時間保存し、取り出して２０℃×６５％Ｒ，ｉ
ｆ、の条件下で１８０度引き剥がし接着力を測定した。After the accelerated test, the adhesive crab specimen was stored in a Feather-O-meter for 50 hours, taken out, and heated at 20°C x 65% R, i.
The 180 degree peel adhesive strength was measured under the conditions of f.
本発明は上記実施例からも明らかな通り、経日後の接着
力の上昇も僅かで、クエデーオーメーターによる促進テ
ス）Ｋよる接着力の上昇も比較例に比して小さい事実が
顕著である
特許出願人
日東電気工礁株式会社As is clear from the above examples, in the present invention, the increase in adhesive strength after a period of time is small, and the fact that the increase in adhesive strength due to accelerated testing using a quede-ohmeter (K) is also smaller than in comparative examples. Patent applicant Nitto Electric Reef Co., Ltd.
Claims (1)
導体のホモポリマーを配合してなることを特徴とする表
面保１用接着組成物。 乃ホモポリマーの配合量が０．１〜２０重量％である特
許請求Ｏ範囲第１項記載の表面保護出接＊ｍ成物。[Scope of Claims] An adhesive composition for surface preservation, comprising a acrylic pressure-sensitive adhesive composition blended with a homopolymer of styrene and its derivatives. 2. The surface-protecting welding composition according to claim 1, wherein the homopolymer is blended in an amount of 0.1 to 20% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14849681A JPS6036235B2 (en) | 1981-09-19 | 1981-09-19 | Adhesive composition for surface protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14849681A JPS6036235B2 (en) | 1981-09-19 | 1981-09-19 | Adhesive composition for surface protection |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5849768A true JPS5849768A (en) | 1983-03-24 |
| JPS6036235B2 JPS6036235B2 (en) | 1985-08-19 |
Family
ID=15454047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14849681A Expired JPS6036235B2 (en) | 1981-09-19 | 1981-09-19 | Adhesive composition for surface protection |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6036235B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0175593A2 (en) * | 1984-09-21 | 1986-03-26 | Exxon Research And Engineering Company | Petroleum resins and their production |
| JPS638045A (en) * | 1986-06-25 | 1988-01-13 | Toyoda Gosei Co Ltd | Installation structure of molding |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6397546U (en) * | 1986-12-17 | 1988-06-24 |
-
1981
- 1981-09-19 JP JP14849681A patent/JPS6036235B2/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0175593A2 (en) * | 1984-09-21 | 1986-03-26 | Exxon Research And Engineering Company | Petroleum resins and their production |
| JPS638045A (en) * | 1986-06-25 | 1988-01-13 | Toyoda Gosei Co Ltd | Installation structure of molding |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6036235B2 (en) | 1985-08-19 |
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