JPS58183941A - Activator used in deodorization, adsorption and drying, and preparation thereof - Google Patents
Activator used in deodorization, adsorption and drying, and preparation thereofInfo
- Publication number
- JPS58183941A JPS58183941A JP57067566A JP6756682A JPS58183941A JP S58183941 A JPS58183941 A JP S58183941A JP 57067566 A JP57067566 A JP 57067566A JP 6756682 A JP6756682 A JP 6756682A JP S58183941 A JPS58183941 A JP S58183941A
- Authority
- JP
- Japan
- Prior art keywords
- substance
- carbon
- inorg
- activator
- pine resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【発明の詳細な説明】
本発明は活性炭素微粒子と活性無機物を一合させてなる
脱臭吸着乾燥用活性剤とその製造方法に係り、特に従来
の活性剤に不足していた脱燐、脱カドミウム、脱鉛、脱
銅等種々の脱臭、吸着、乾燥作用において優れた能力を
有した活性剤を簡易な方法で安価かつ大量に製造するこ
とを可能とした脱臭吸着乾燥用活性剤とその製造方法に
関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an activator for deodorizing, adsorbing and drying made by combining activated carbon fine particles and active inorganic substances, and a method for producing the same. An activator for deodorization, adsorption, and drying that makes it possible to produce an activator that has excellent abilities in various deodorizing, adsorption, and drying functions such as deleading, decoppering, etc., in a simple manner, at low cost, and in large quantities, and a method for producing the same. Regarding.
現在、活性剤の主流をなしているのは活性炭あるいはシ
リカゲル、アルミナゲル等無機物質の活性ゲルである１
、 ところが、活性炭は吸着剤としそ防毒面、カスまた
は液体の脱臭精製、溶液の脱色、触媒などに使用され、
またシリカゲル等は包装用乾燥剤や−膜設湿剤のほか、
各種ガスの回収、除去に利用されているが、両者ともい
ずれもその用途がせまいため、実際にはこれらを組み合
わせ使用する必要も多々あり、かつ、両者を組合せ使用
しても脱燐、脱カドミウム、脱鉛、脱銅などはなし得な
いものとなっていて、幅広い脱臭、吸着、乾燥能力を有
した活性剤の開発が強く望まれている。Currently, the mainstream activators are activated carbon or activated gels made of inorganic substances such as silica gel and alumina gel1. However, activated carbon is used as an adsorbent and anti-fouling surface, for deodorizing and purifying scum or liquids, decolorizing solutions, Used in catalysts, etc.
In addition, silica gel is used as a packaging desiccant and a membrane dampening agent.
They are used to recover and remove various gases, but since both have limited uses, it is often necessary to use them in combination. However, deleading, copper removal, etc. cannot be achieved, and there is a strong desire to develop an activator that has a wide range of deodorizing, adsorption, and drying abilities.
また、活性炭は、木炭を原料とし、その木炭の中に残存
している石灰分等の夾雑物を除去するための酸洗処理な
ど化学的処理を施して木炭の吸着表面積を広くする工程
ののち、物理的機能を高くするため高温水蒸気を吹き付
ける工程を経て脱臭吸着能力のある活性炭を製造するも
のが多く、シリカゲルは珪石を苛性ソーダで溶解した水
ガラス（硅酸ナトリウムの水溶液）を無機酸で分解して
、ゼリー状に凝固する含水硅酸を十分水・洗したのち加
熱乾燥し、適当に賦活して製造される等、活性炭及び活
性無機物はその製造工程が複雑で原料もなものとなり、
ましてや、両者を一緒に製造することは困難であった。Activated carbon is produced by using charcoal as a raw material and applying chemical treatments such as pickling to remove impurities such as lime remaining in the charcoal to increase the adsorption surface area of the charcoal. Activated carbon, which has deodorizing and adsorption ability, is often manufactured through a process of spraying high-temperature steam to enhance its physical functionality.Silica gel is made by decomposing water glass (aqueous solution of sodium silicate), which is made by dissolving silica stone in caustic soda, with an inorganic acid. The manufacturing process for activated carbon and activated inorganic substances is complicated, and the raw materials are also expensive.
Furthermore, it was difficult to manufacture both together.
そこで、本発明は上記問題点に鑑み、従来の活性炭や活
性無機物の能力を併わせもつと共に、さらに−の活性剤
で前記説燐等種々の脱臭、吸着、乾燥作用を奏して幅広
い用途に使用することができると共に、このような活性
剤を一連の単一の工程で簡易かつ大量に供給でき、よっ
て上記のような高性能の活性剤を安価に製造しうること
を可能とする脱臭吸着乾燥用活性剤とその製造方法の提
供を目的としてなされたものであって、その要旨とする
ところは、
（１）炭素微粒子を吸着した微細孔を備えてなる任意の
無機物質と、前記炭素微粒子とに適宜活性を賦与せしめ
て形成した脱臭吸着乾燥用活性剤。In view of the above-mentioned problems, the present invention combines the capabilities of conventional activated carbon and activated inorganic substances, and also uses an activator to exhibit various deodorizing, adsorption, and drying effects such as the above-mentioned phosphorus, and can be used in a wide range of applications. A deodorizing adsorption drying method that enables the activator to be easily supplied in large quantities through a series of single steps, thereby making it possible to produce the above-mentioned high-performance activator at low cost. The purpose of this work is to provide an activator and a method for producing the same, and its gist is as follows: (1) Any inorganic substance comprising fine pores that have adsorbed carbon fine particles, and the carbon fine particles. An activator for deodorizing, adsorbing and drying formed by imparting appropriate activity to.
（２）前記脱臭吸着乾燥用活性剤を製造するに際し、所
定温度以上に加熱された結晶水を含む無機物質が放出す
る高温の水蒸気と松脂系有機的炭化物質が発生する一酸
化度素に触媒を作用させることによって該−酸化炭素を
還元させ炭素の微粒子とし、談炭素微粒子を結晶水を放
出して生じる無機物質の微細孔内に吸着せしめた後、自
ら放出した高温の水蒸気中に長時間共存させることによ
って、前記無機物質及び炭素微粒子を賦活させる脱臭吸
着乾燥用活性剤の製造方法にある。(2) When producing the deodorizing adsorption drying activator, high-temperature water vapor released by inorganic substances containing crystal water heated above a predetermined temperature and pine resin-based organic carbonized substances catalyze the generated hydrogen monoxide. The carbon oxide is reduced to fine carbon particles by the action of water, and the carbon fine particles are adsorbed into the fine pores of the inorganic material created by releasing crystal water, and then placed in the high-temperature water vapor released by itself for a long time. The present invention provides a method for producing an activator for deodorizing, adsorbing, and drying, which activates the inorganic substance and carbon fine particles by coexisting them with each other.
なお、ここで松脂系有機的炭化物質とは松葉から＆）脂
を＊Ｗする際混入する松葉等を含んだ吠麹のいわゆる粗
製松脂のことを指称するものであり、また松脂とはこの
粗製松脂に混入した松葉等′を除去する等の加工をした
いわゆる精製松脂のことを指称するものである。Note that the pine resin-based organic carbonized substance here refers to the so-called crude pine resin of Hokoji that contains pine needles, etc. that are mixed in when making &) fat from pine needles, and pine resin refers to this crude pine resin. This refers to so-called purified pine resin that has been processed to remove pine needles, etc. mixed in with pine resin.
以下上記した本発明の要Ｗをさらに明確にするため、本
発明の一実施例について説明する。In order to further clarify the essential W of the present invention described above, one embodiment of the present invention will be described below.
本発明による脱臭吸着乾燥用活性剤（以下単に活性剤と
いう）は、その用途に応じた各種形状に成型された結晶
水を含む無機物質の、該結晶水を放出させて生じた微細
孔内に、松脂系有機的炭化物質（以下単に松脂炭化物と
いう）や松脂から生ずる炭素微粒子を吸着させると共に
、該結晶水による高温水蒸気で活性を賦与したものとな
っており、次のようにして製造される。The deodorizing adsorption/drying activator (hereinafter simply referred to as activator) according to the present invention is applied to micropores formed by releasing crystal water of an inorganic substance containing crystal water molded into various shapes depending on its use. It adsorbs pine resin-based organic carbonized substances (hereinafter simply referred to as pine resin carbide) and carbon fine particles generated from pine resin, and is activated by high-temperature steam from the crystal water, and is produced as follows. .
（１）原素材の混合工程
安価な珪石、カリ長石、ソーダ長石、アルミナ、雲母、
蛙目粘土（水簸精製する前の原土）、水ガラスヲ混合し
て、トロンメルで２００メソシュ以上まで−り上げる。(1) Mixing process of raw materials Inexpensive silica, potassium feldspar, soda feldspar, alumina, mica,
Mix the clay (raw soil before elutriation) and water glass and raise it with a trommel to a volume of over 200 mesochs.
これに松脂炭化物を加えて土煉機で煉り、可塑性のある
原素材とし、次の成型工程での成型を容易とする。Carbide of pine resin is added to this and it is ground in a clay mill to create a plastic raw material that can be easily molded in the next molding process.
また、原素材は上記のような安価で、かつ天然に多量に
存在するものであるので、安価に大量な製造を可能とす
る。In addition, since the raw materials are inexpensive and naturally present in large amounts as mentioned above, it is possible to manufacture them in large quantities at low cost.
＜ｉｏ 成型工程
活性剤はその使用する場所と対象により粉末、粒状、板
状、塊状、異型等種々の形状とすることを要求される。<io Molding process The active agent is required to be in various shapes such as powder, granule, plate, lump, irregular shape, etc. depending on the place and object in which it is used.
したがって、上記の如く可塑性をもたせた原素材とする
ことにより、その要求に応じることを可能とし、原素材
を任意の成型プレスで新装の形状に成型し乾燥する。こ
の成型プレスは、陶磁器成型用プレス、耐火煉瓦成型用
プレス等すべての窯業用プレスはもちろん各種プレスを
使用することができる。Therefore, by providing a raw material with plasticity as described above, it is possible to meet this demand, and the raw material is molded into a new shape using an arbitrary molding press and dried. As this molding press, not only all ceramic presses such as ceramic molding presses and firebrick molding presses, but also various presses can be used.
このように、原素材段階で成型随意という、従来にない
製造方法であり、使用時にあらためて成型する必要がな
く製造工程を短縮化、簡素化できる。In this way, this is an unprecedented manufacturing method in which molding is optional at the raw material stage, and there is no need to mold the product again when it is used, making it possible to shorten and simplify the manufacturing process.
（ｉｌｉ） 焼成による活性化工程
まず、密閉空間となっている所定の立体容器内に前記の
成型された原素材を所定量（例えば２０ｋｑ ）を、松
脂の塊と触媒と共に封装する。(ili) Activation step by firing First, a predetermined amount (for example, 20 kq) of the molded raw material is sealed together with a lump of rosin and a catalyst in a predetermined three-dimensional container that is a closed space.
ついで、このように封装した容器を例えば全長すつ、こ
れを２列並列させて６段に積み重ねて合計６０函を積載
し、この台車を１時間毎に送車させ、１日２４台を該ト
ンネル窯内で焼成する。Next, the containers sealed in this way are stacked, for example, in two rows parallel to each other in six tiers, for a total of 60 boxes, and the trolley is sent every hour to deliver 24 boxes per day. Fired in a tunnel kiln.
したがって、１日の焼成トン数は２０トン（なお焼成に
よる欠減は約８０％）となる等、きわめて大量に原素材
の焼成を可能とできるものである。Therefore, the tonnage to be fired per day is 20 tons (the loss due to firing is approximately 80%), making it possible to fire raw materials in extremely large quantities.
また、該焼成に使用する焼成窯は、例えば低火度壁タイ
ル製造用トンネル窯とする。これは、焼成室本体内の温
度が９００°Ｃに定着されているもので、該焼成室内の
温度を８６０６Ｃ〜９００°Ｃとすることができる。The firing kiln used for the firing is, for example, a tunnel kiln for manufacturing low-heat wall tiles. In this case, the temperature inside the firing chamber body is fixed at 900°C, and the temperature inside the firing chamber can be set at 8606°C to 900°C.
したがって、原素材が加熱されることにより、無機物質
に含まれる結晶水が８６０°〜９００°Ｃの簡温水蒸気
として放出され、無機物質に微細孔が形成される。Therefore, by heating the raw material, crystal water contained in the inorganic substance is released as simple steam at a temperature of 860° to 900°C, and micropores are formed in the inorganic substance.
このよう：こ、この方法において結晶水を含む無機物質
を使用し、木炭、活性炭、シリカゲル、アルミナゲル等
を使用しないのは、これらは一度焼成工程を経ているた
め、高温水蒸気を得ることができないからである。Like this: In this method, we use inorganic substances that contain water of crystallization, and we do not use charcoal, activated carbon, silica gel, alumina gel, etc., because they have already gone through the firing process, so high-temperature steam cannot be obtained. It is from.
この高温水蒸気は無機物質と後記炭素微粒子に活性を賦
与するものであると共に、炭素微粒子の生成を促進させ
るものである。This high-temperature steam not only imparts activity to the inorganic substance and the carbon particles described below, but also promotes the formation of the carbon particles.
すなわち、過酸化水素が水と酸素に分解するときに発生
する酸素は発生期の酸素とよばれ、普通の酸素より強い
反応力をもつのと同様に、結晶水を含む無機物質か加熱
されて、結晶水を高温の水蒸気として放出するとき、放
出直後の水蒸気は、普通の水蒸気とは異った強い反応力
をもつものではないか−と思われる。In other words, the oxygen generated when hydrogen peroxide decomposes into water and oxygen is called nascent oxygen, and it has a stronger reaction force than ordinary oxygen. When water of crystallization is released as high-temperature water vapor, it is thought that the water vapor immediately after release has a strong reaction force different from that of ordinary water vapor.
これを裏づけるものに、陶磁器焼成の際しばしは生ずる
１酔う」と呼ばれる現象がある。これは匣鉢内に高温水
蒸気がこもると、陶磁器の地肌が薄黒くまだらに焼土が
る現象をいい、■このまだらな薄黒い地肌は、強い還元
焼成や強い酸化焼成で再度焼直しても決して消滅しない
こと、■この強い反応を免れる方法として、「蒸気ぬき
」と称する排気孔を匣鉢に穿つ方法があり、これがきわ
めて有効なこと、■８５０°Ｃ以下で焼く素焼きの段階
で決して起こらぬ現象であること、以上の８点から帰納
すれば、この［酔う−１という現象は高温の水蒸気に因
るものと考えられ、特に水分が低温で抜けてゆくときの
普通の水蒸気ではなく、８５０°Ｃ以上の高温で発生す
る結晶水の水蒸気の作用によるものと認められるから、
発生期の高温水蒸気の反応力は強いと判断せざるを得な
い。This is supported by a phenomenon called ``drunk'' that often occurs when ceramics are fired. This is a phenomenon in which when high-temperature steam accumulates inside a sagger, the surface of the ceramic becomes dark and mottled. ■This mottled, dark surface remains even if it is refired through strong reduction firing or strong oxidation firing. It never disappears. ■ As a way to avoid this strong reaction, there is a method called "steam release" that is made by drilling an exhaust hole in the sagger, and this is extremely effective. ■ It never occurs during the bisque firing stage, which is fired at temperatures below 850°C. Inferring from the above eight points, it is thought that this phenomenon of ``drunk-1'' is caused by high-temperature water vapor, and is not caused by normal water vapor, which occurs when moisture is released at low temperatures. It is recognized that this is due to the action of water vapor of crystallized water generated at high temperatures of 850°C or higher.
It must be concluded that the reaction force of high-temperature steam during the generation stage is strong.
したがって、前記無機物質より生ずる高温水蒸気もこの
ような強い反応力をもつため、該無機物質及び後記の如
く発生する炭素微粒子に活性を賦与することができ、従
来の活性炭のように、高温水蒸気を吹き付けて物理的性
能を高める操作を単独になす必要がない。Therefore, since the high-temperature steam generated from the inorganic substance also has such a strong reaction force, it is possible to impart activity to the inorganic substance and the carbon particles generated as described below. There is no need to perform a separate operation to improve physical performance by spraying.
一方、前記松脂炭化物からは該焼成工程により−酸化炭
素を生ずるが、さらに多量の一酸化炭素を空間内に充満
させるために、触媒と共に松脂の塊を封装するのである
。On the other hand, carbon oxide is produced from the pine resin carbide during the firing process, and in order to fill the space with an even larger amount of carbon monoxide, a lump of pine resin is sealed together with a catalyst.
高温の一酸化炭素は、低湿の物に接触したり、低温の雰
囲気中に排出されたとき瞬間的に煤となるか、高温状態
では固体の炭素とならない。High-temperature carbon monoxide instantly turns into soot when it comes into contact with a low-humidity object or is discharged into a low-temperature atmosphere, or it does not turn into solid carbon at high temperatures.
しかしながら、発生期の高温水蒸気と混合気体となった
ときは、たとえ温度に変化がなくでも触媒等の作用も加
わって、高温の密閉空間内で、２ＣＯ→ＣＯ！十〇
のような反応を起して炭素微粒子となる。However, when it becomes a mixed gas with high-temperature water vapor during the generation stage, even if there is no change in temperature, the effects of catalysts etc. are added, and in a high-temperature closed space, 2CO→CO! The reaction shown in 10 occurs to form carbon fine particles.
なお、本発明者の研究によれば、焼成によって造られｔ
コシリカゲルと松脂及び触媒と共に密閉空間内）こ共存
させ、本製造方法と同様の工程によって焼成してみると
、松脂が一酸化炭素を発生させても、シリカゲルは高温
水蒸気を発生し得ないから、−酸化炭素は炭素微粒子と
ならす、したがって、シリカゲルには炭素微粒子は少し
も吸着しなこのように、−酸化炭素を炭素の微粒子にす
るには、結晶水の高温水蒸気が不可欠である。そして、
この炭素微粒子は、結晶水を放出してできた無機物質の
分子の間隙である微細孔に吸着する。According to the research of the present inventor, t
When coexisting silica gel, pine resin, and a catalyst in a closed space, and firing it using the same process as this production method, even if pine resin generates carbon monoxide, silica gel cannot generate high-temperature steam. - Carbon oxide becomes carbon fine particles. Therefore, silica gel does not adsorb any carbon particles. In this way, - High temperature steam of crystal water is essential to convert carbon oxide into carbon fine particles. and,
These carbon particles are adsorbed into the micropores, which are the gaps between the molecules of the inorganic substance, which are created by releasing crystal water.
そのとき、前述のとおり、空間内の高温水蒸気の作用を
受けて、吸着した炭素微粒子は活性を賦与されるのであ
る。At that time, as mentioned above, the adsorbed carbon particles are activated by the action of high-temperature steam in the space.
以上のような工程を経て、活性無機物と活性炭素微粒子
とが均質に混在した活性剤を製造できるのである。Through the steps described above, an activator containing a homogeneous mixture of active inorganic substances and activated carbon particles can be produced.
この活性剤および製造方法によれば、次のようなすぐれ
た効果が得られる。According to this activator and manufacturing method, the following excellent effects can be obtained.
（１）結晶水を放出し多孔質状となっている無機物質の
微細孔壁に炭素の微粒子が吸着し、骸無機物質及び炭素
微粒子を自ら発生した高温の水°蒸気によって活性を賦
与したものであるから、活性炭及び活性無機物と同様の
性能を併わせもつうえ、両者の相乗作用により、顕著な
幅広０能力をもつ。(1) Carbon particles are adsorbed on the micropore walls of an inorganic substance that releases crystal water and becomes porous, and the inorganic substance and carbon particles are activated by self-generated high-temperature water and steam. Therefore, it not only has the same performance as activated carbon and activated inorganic materials, but also has a remarkable wide range of zero ability due to the synergistic effect of the two.
例えば本発明者がカドミウム、鉛、銅、１１素、燐につ
いて行なった下水処理場排水壷こお（する吸着能力試験
によれば、次のようなすぐれｔコ吸着能力を示している
。For example, according to an adsorption ability test conducted by the present inventor on cadmium, lead, copper, element 11, and phosphorus in a sewage treatment plant drainage pot, the following excellent adsorption ability was shown.
試験１ 一１１分析結果 一２６分析方法 下水試験方法（１９７４年）による。Test 1 111 analysis results 126 analysis methods According to Sewage Test Methods (1974).
試１
一１１分析結果
１４日後＋ ７．７ １ ｏ、ｓｇ２、分析
方法
下水試験方法（１９７４年）による。Trial 1-11 Analysis result 14 days later + 7.7 1 o, sg2, analysis method According to Sewage Test Method (1974).
試 験厘 １、分析結果 一２１分析方法 下水試験方法（１９７４年）による。Examination staff 1. Analysis results 121 analysis method According to Sewage Test Methods (1974).
このように、脱夷、乾燥作用はもとよ外吸着作用におい
ても、脱カドミウム、脱鉛、脱銅、脱窒素、脱燐等に著
効できわめて幅広い用途に使用が可能となる。In this way, it is highly effective not only in deoxidation and drying actions but also in external adsorption actions such as decadmium, delead, decopper, denitrification, dephosphorization, etc., and can be used in an extremely wide range of applications.
（２）原料となる無機物質や松脂は安価でかつ容易に大
量のものを入手できるので、活性剤を安価、大量に供給
できることはもちろん、無機物質に結晶水を含むものを
使用すれば、焼成工程でそれから容易に高温水蒸気が発
生され、この自ら放出した高温水蒸気によって、無機物
質及び炭素微粒子に活性を賦与できると共に松脂炭化物
等から生ずる一酸化炭素を炭素微粒子に効率よく変換で
き、さらに高温水蒸気を放出した無機物質の微細孔に炭
素微粒子が付着される等きわめて簡易な一連の工程で活
性無機物質内に活性微粒子を均質に混在しうるものであ
る。(2) Inorganic materials and pine resin that serve as raw materials are inexpensive and can be easily obtained in large quantities, so it is possible to supply activators cheaply and in large quantities, and if inorganic materials containing crystal water are used, firing During the process, high-temperature steam is easily generated, and this self-released high-temperature steam can activate inorganic substances and carbon particles, and can efficiently convert carbon monoxide generated from rosin carbide into carbon particles. Through a series of extremely simple steps, such as adhering carbon particles to the fine pores of the inorganic substance that has released the active particles, active particles can be mixed homogeneously within the active inorganic substance.
その際、従来の陶磁器用焼成窯をそのまま利用でき、か
つ該陶磁器の焼成と同時にも行なえる等大量生産がきわ
めて容易で、設備も従来のものをそのまま使用できて至
便である。At this time, mass production is extremely easy, as the conventional firing kiln for ceramics can be used as is, and the firing can be carried out simultaneously with the firing of the ceramics, and the conventional equipment can be used as is, which is very convenient.
（８）さらに、原素材段階で無機物質と松脂炭化物を混
合して可塑性をもたせているので、予め成型してから焼
成することができ、用途に応じた形状を随意かつ簡単に
成型しえて、製造及び施工になお、本発明による活性剤
は上記実施例のような製造方法によってのみ製造しうる
ものではなく、同様の構造となし得るならばどのような
製造方法を用いてもよいことは申すまでない。(8) Furthermore, since the inorganic substance and rosin carbide are mixed at the raw material stage to give it plasticity, it can be molded in advance and then fired, allowing it to be molded into any shape according to the purpose, easily. It should be noted that the activator according to the present invention can be manufactured not only by the manufacturing method described in the above embodiments, but also by any manufacturing method that can produce a similar structure. Not until.
また、無機物質として使用する原材料も上記のものに限
定されるものではなく、上記方法によらない場合は任意
の無機物質の一檀あるいは複数種の混合物であればどの
ようなものでもよく、また結晶水を含むものに限るもの
でもなく、かつ、炭素微粒子を生ずる原料として必ずし
も松脂を使用する必要はなく、さらには上記製造方法に
よる場合にあっても、それに使用する焼成窯、台車、立
体容器等の具体的な形状も上記に限定されるものではな
い。In addition, the raw materials used as the inorganic substance are not limited to those mentioned above, and if the above method is not used, any inorganic substance or a mixture of multiple types may be used. It is not limited to those containing crystallization water, and it is not necessarily necessary to use pine resin as a raw material for producing carbon fine particles.Furthermore, even if the above manufacturing method is used, the firing kiln, trolley, three-dimensional container used for it, etc. The specific shapes such as the above are not limited to the above.
すなわち、これらは本発明の上記した目的と作用、効果
の達成される範囲内においてそれぞれ任意に定められて
よく、これらの変更はいずれも本発明の要旨をなんら変
更するものではない。That is, these changes may be arbitrarily determined within the range in which the above-described objects, functions, and effects of the present invention are achieved, and none of these changes changes the gist of the present invention.
上述の説明によって明白となるように、本発明によれば
、活性炭や活性無機物の両者の性能を併わせもつのみな
らず、さらに優れた脱臭、吸着、乾燥作用をもつ活性剤
を提供でき、かつ、これを一連の簡易な工程で安価かつ
大量に供給しうる製造方法とできる等従来生じていた既
述の問題点がきわめて簡易かつ効果的に改良されるので
、本発明によってもたらされる実益はすこぶる大きいと
申さざるを得ない。As will become clear from the above description, the present invention not only has the performance of both activated carbon and activated inorganic materials, but also provides an activator that has superior deodorizing, adsorption, and drying properties. The above-mentioned problems that have arisen in the past can be improved very simply and effectively, such as by making it possible to produce this in a series of simple steps at low cost and in large quantities, so the practical benefits brought about by the present invention are enormous. I have to say it's big.
第１頁の続き ■出 願 人 田口敦司 多治見市平和町５丁目３番地 ０出 願 人 出崎望 岐阜県土岐郡笠原町３０３１番地 ０出 願 人 鍵谷誠 愛知県丹羽郡扶桑町大字高雄字 北中島４３番地の３ ■出 願 人 高橋和島 岐阜県土岐郡笠原町平園区４０２４ 番地の２７３Continuation of page 1 ■Person Atsushi Taguchi 5-3 Heiwacho, Tajimi City 0 wishes Nozomi Dezaki 3031 Kasahara-cho, Toki-gun, Gifu Prefecture 0 wishes person Makoto Kagitani Aza Takao, Fuso-machi, Niwa-gun, Aichi Prefecture Kitanakajima 43-3 ■Applicant: Wajima Takahashi 4024 Hiraen-ku, Kasahara-machi, Toki-gun, Gifu Prefecture Address 273
Claims (2)
無機物質と、前記炭素微粒子とに適宜活性を賦与せしめ
て形成したことを特徴とする脱臭吸着、乾燥用活性剤。(1) An activator for deodorizing, adsorption, and drying, which is formed by imparting an appropriate activity to an arbitrary inorganic substance having fine pores that adsorb carbon fine particles and the carbon fine particles.
とを混合した原素材を所望形状に成型し、これを松脂及
び触媒と共に密閉空間内に封装して焼成し脱臭吸着乾燥
用活性剤を製造するに際し、所定温度以上に加熱された
無機物質が放出する高温の水蒸気と松脂系有機的炭化物
質が発生する一酸化炭素に触媒を作用させることによっ
て該−酸化炭素を還元させ炭素の微粒子とし、該炭素微
粒子を結晶水を放出して生じる無機物質の微細孔内に前
記炭素微粒子を吸着せしめた後、自ら放申した高温の水
蒸気中に長時間共存させることによって、前記無機物質
及び炭素微粒子に活性を賦与することを特徴とする脱臭
吸着乾燥用活性剤の製造方法。(2) A raw material made by mixing an inorganic substance containing water of crystallization and a pine resin organic carbonized substance is molded into a desired shape, sealed in a closed space with pine resin and a catalyst, and fired to activate the deodorizing adsorption drying process. When producing the agent, a catalyst is applied to high-temperature water vapor released by an inorganic substance heated above a certain temperature and carbon monoxide generated by a pine resin-based organic carbonized substance, thereby reducing the carbon oxide and converting it into carbon. The inorganic material and A method for producing an activator for deodorizing, adsorption and drying, which comprises imparting activity to carbon fine particles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57067566A JPS58183941A (en) | 1982-04-22 | 1982-04-22 | Activator used in deodorization, adsorption and drying, and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57067566A JPS58183941A (en) | 1982-04-22 | 1982-04-22 | Activator used in deodorization, adsorption and drying, and preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58183941A true JPS58183941A (en) | 1983-10-27 |
Family
ID=13348630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57067566A Pending JPS58183941A (en) | 1982-04-22 | 1982-04-22 | Activator used in deodorization, adsorption and drying, and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58183941A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4855276A (en) * | 1987-09-02 | 1989-08-08 | Purafil, Inc. | Solid filtration medium incorporating alumina and carbon |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4888087A (en) * | 1972-02-25 | 1973-11-19 |
-
1982
- 1982-04-22 JP JP57067566A patent/JPS58183941A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4888087A (en) * | 1972-02-25 | 1973-11-19 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4855276A (en) * | 1987-09-02 | 1989-08-08 | Purafil, Inc. | Solid filtration medium incorporating alumina and carbon |
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