JPS58183285A - Transfer foil for golf ball - Google Patents
Transfer foil for golf ballInfo
- Publication number
- JPS58183285A JPS58183285A JP6681682A JP6681682A JPS58183285A JP S58183285 A JPS58183285 A JP S58183285A JP 6681682 A JP6681682 A JP 6681682A JP 6681682 A JP6681682 A JP 6681682A JP S58183285 A JPS58183285 A JP S58183285A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- weight
- ink
- transfer foil
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/12—Transfer pictures or the like, e.g. decalcomanias
Landscapes
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【発明の詳細な説明】 写箔に関するものである。[Detailed description of the invention] It is related to photo foil.
従来ゴルフポールへの絵付方法としては、タコ印刷法等
による直接部−ｕ法や、任意の箔の全面上にベタのイン
キ層を形成したべタ刷り箔を用いてその裏面から加熱さ
れた刻印で押圧し任意の模様を転写する方法や、特開昭
５３−６５１５７号公報に開示されているように，任意
のフィルム上に任意の模様の転写インキ層を形成した転
写箔を用いて印刷する熱転写印刷法が知られている。Conventional methods for painting golf poles include the direct part-u method using tacho printing, etc., and stamping using a solid printing foil with a solid ink layer formed on the entire surface of the foil and heating it from the back side. As disclosed in JP-A No. 53-65157, printing is carried out using a transfer foil on which a transfer ink layer of an arbitrary pattern is formed on an arbitrary film. Thermal transfer printing methods are known.
しかしながら、ゴルフポールに多色模様を施す場合、タ
コ印刷法では一色毎にインキを硬化させる必要があるた
め能率が極めて悪く，又ペタ制り箔を用いる方法では多
色用の特殊なスタンプ装置を必要とし且つペタ刷り箔に
印刷されたインキの大半が使用されることなく廃棄され
るため、コスト高になる等の欠点を有している。更に、
特開昭５３−６３１３７号公報に開示されているような
転写箔も次のような欠点を有している。However, when applying multicolor patterns to golf poles, the tacho printing method requires curing the ink for each color, which is extremely inefficient, and the method using peta stamping foil requires special stamp equipment for multicolor printing. Most of the ink required and printed on the peta printing foil is discarded without being used, so it has drawbacks such as high cost. Furthermore,
The transfer foil disclosed in Japanese Unexamined Patent Publication No. 53-63137 also has the following drawbacks.
即ち、フィルム上に任意模様を形成する際、スクリーン
印刷法を用いた場合インキの乾燥が遅いため、ブロッキ
ング等の問題を起こし易く、印刷方法自体も能率が低い
ため、転写箔がコスト高となり、又グラビア印１１法を
用いた場合、インキ層の輪郭がシャープにならず、いわ
ゆる「泳ぎ」現象も見られ、転写箔として充分満足でき
るものではない。In other words, when screen printing is used to form arbitrary patterns on a film, the ink dries slowly, which tends to cause problems such as blocking, and the printing method itself is inefficient, making transfer foil expensive. Furthermore, when the gravure printing method 11 is used, the outline of the ink layer is not sharp and a so-called "swimming" phenomenon is observed, so that it is not fully satisfactory as a transfer foil.
更に又、これら従来の転写箔の多くは転写性を良くする
ため、フィルム上に離型ワニスを塗り、この上に任意模
様を印刷した後、接着ワニスを塗ｌ るヵ１、離型
ヮ＝ユ又、１着ヮ＝７゜いずゎヵ、一方？使用する構成
となっているので、かかる構成の転写箔では離型ワニス
がトップコートとインキ層との接着を阻害したり、離型
ワニス、接着ワニスのバリ発生があったり、接着ワニス
が黄変したりする欠点を有しており、材料の選択が極め
て難がシ、＜、又工数、材料が増えるためコスト高とな
る欠点を有している。しかもかかる転写箔を用いて転写
した場合、被転写物であるゴルフボール表面に塗布した
塗料の硬化が進んだ時の転写性が極めて悪く、又ディン
プル（Ｄｌｍｐｌｅ）部に転写するとき、転写箔の裏面
から加圧するためのシリコンバッドの材質形状の選定が
難しく、更にゴルフボールへのインキ層の定着を充分に
するため高温、長時間圧着した場合、ゴルフボールの外
皮の歪み等が発生するなどの欠点を有している。Furthermore, in order to improve the transferability of many of these conventional transfer foils, a release varnish is applied onto the film, a desired pattern is printed on this, and then an adhesive varnish is applied. Yumata, 1st place = 7゜Izuwaka, on the other hand? Transfer foils with such a configuration may cause the release varnish to inhibit adhesion between the top coat and the ink layer, cause burrs to form in the release varnish or adhesive varnish, or cause yellowing of the adhesive varnish. It has the disadvantages that it is extremely difficult to select materials, and that it increases the number of man-hours and materials, resulting in high costs. Moreover, when such a transfer foil is used for transfer, the transfer performance is extremely poor when the paint applied to the surface of the golf ball, which is the object to be transferred, has progressed to hardening. It was difficult to select the material and shape of the silicone pad for applying pressure from the back side, and in order to ensure that the ink layer adhered to the golf ball sufficiently, if pressure was applied at high temperatures for a long period of time, the outer skin of the golf ball would become distorted. It has drawbacks.
本発明者等は、上記従来法の欠点を改良すべく鋭意研究
の結果、一度のホットスタンピング工程で多色の精巧な
絵柄が転写でき、且つ過酷な使用条件に耐えるよう物性
面を充分に考慮した転写箔の開発に成功し、特願昭５５
−１４５５０７号として出願している。すなわちこの発
明はポリプロピレンフィルム上に、・離型ワニス又は接
着剤を使用することなくインキ層を形成したもので、特
に離型性及び転写性を具備し且つ必要な物性を充分に具
備したインキ組成物を用いることを特徴とするもので硝
化綿、アルキッド樹脂を主樹脂とし、着色剤として顔料
又は染料を、添加剤としてポリエチレン粉末、可塑剤及
び界面活性剤を有機溶剤に溶解又は分散させて成るイン
キにより、ポリプロピレンフィルム上に所望のインキ層
を形成して成るゴルフボール用転写箔である。As a result of intensive research to improve the shortcomings of the conventional method described above, the inventors of the present invention have developed a method that can transfer elaborate designs in multiple colors in a single hot stamping process, and has sufficiently considered physical properties to withstand harsh usage conditions. Succeeded in developing transfer foil and received a patent application in 1982.
It has been filed as No.-145507. That is, this invention forms an ink layer on a polypropylene film without using a release varnish or an adhesive, and in particular an ink composition that has release properties and transferability and has sufficient necessary physical properties. The main resin is nitrified cotton or alkyd resin, and the colorant is a pigment or dye, and the additives are polyethylene powder, a plasticizer, and a surfactant dissolved or dispersed in an organic solvent. This transfer foil for golf balls is made by forming a desired ink layer on a polypropylene film using ink.
この転写箔は前記した従来法の欠点は解消しているが、
生産性の面で以下のような問題点を有するものであった
。すなわち転写時に、１８０℃という高温条件を要する
ため広面積に転写を行う場合にフィルムに収縮じわが入
りやすくインキ画像に変形が生じたり、又転写後ゴルフ
ポール表面にクリヤートップコートを施す際にそのトッ
プコート用溶剤に転写されたインキ層が浸され、流れて
インキ画像の鮮明さが失われる欠点を有していた。Although this transfer foil eliminates the drawbacks of the conventional method mentioned above,
This method had the following problems in terms of productivity. In other words, when transferring, a high temperature condition of 180°C is required, so when transferring to a large area, the film tends to have shrinkage wrinkles, causing deformation of the ink image, and when applying a clear top coat to the surface of the golf pole after transfer. This had the disadvantage that the ink layer transferred to the top coat solvent was immersed and ran, resulting in loss of clarity of the ink image.
本発明は、従来法及び特願昭５５−１４５５０７号のこ
れら欠点を解消するものである。すなわち本発明はポリ
アミド樹脂、ノ・−ドレジン、アクリル樹脂、ポリエス
テル樹脂及びウレタン樹脂より選ばれた樹脂と硝化綿と
を主樹脂とし、着色剤として顔料又は染料を、添加剤と
してポリエチレン粉末、体質顔料、可塑剤及び界面活性
剤を有機溶剤に溶解又は分散させて成るインキにより、
ポリプロピレンフィルム上に所望のインキ層を形成して
成るゴルフボール用転写箔である。The present invention eliminates these drawbacks of the conventional method and Japanese Patent Application No. 145507/1982. That is, the present invention uses a resin selected from polyamide resin, no-resin, acrylic resin, polyester resin, and urethane resin as the main resin and nitrified cotton, a pigment or dye as a coloring agent, and polyethylene powder and extender pigment as additives. , an ink made by dissolving or dispersing a plasticizer and a surfactant in an organic solvent,
This is a transfer foil for golf balls, which is made by forming a desired ink layer on a polypropylene film.
尚、本発明の別法として、前記したポリアミド樹脂、ハ
ードレジン、アクリル樹脂、ポリエステル樹脂及びウレ
タン樹脂より選ばれた樹脂と硝化綿とを主樹脂とする代
わりに、硝化綿を含まないビニル樹脂又はアクリル樹脂
を主樹脂として作成した転写箔も同様のものとして使用
することができる。In addition, as an alternative method of the present invention, instead of using a resin selected from the aforementioned polyamide resin, hard resin, acrylic resin, polyester resin, and urethane resin and nitrified cotton as the main resin, a vinyl resin that does not contain nitrified cotton or A transfer foil made of acrylic resin as the main resin can also be used in a similar manner.
ここで本発明で用いるインキ層の担体であるフィルムは
、単にインキ層を担持するのみにとどまら−ｆ、ゴルフ
ボールのディンプル部という特異な部位に対してもイン
キ層を完全に転写させるための特性と後述する特殊なイ
ンキ組成物によって形成されるインキ層を転写時に完全
に離型させるための特性を具備しなければならない。Here, the film that is the carrier of the ink layer used in the present invention does not only support the ink layer, but also has characteristics that allow the ink layer to be completely transferred to a unique site such as the dimple portion of the golf ball. The ink layer formed by the special ink composition described later must have characteristics that allow the ink layer to be completely released during transfer.
上記の条件に適合するフィルムとして、ポリエチレンフ
ィルム、ポリプロピレンフィルム、ポリエステルフィル
ム、ポリアミドフィルム、塩化ビニルフィルム、セロフ
ァンフィルムについて各々試験を行なった結果によれば
、ポリプロピレンフィルムが最も良い結果を示した。こ
の結果はこの分野に於いてポリエステルフィルム、セロ
ファンフィルムが実際上一般的に用いられている事実か
らして非常に興味深いことである。According to the results of tests conducted on polyethylene film, polypropylene film, polyester film, polyamide film, vinyl chloride film, and cellophane film as films that meet the above conditions, polypropylene film showed the best results. This result is very interesting in view of the fact that polyester films and cellophane films are actually commonly used in this field.
本発明で用いるインキはポリアミド樹脂、ハードレジン
、アクリル樹脂、ポリエステル樹脂、及びウレタン樹脂
より選ばれた樹脂と硝化綿とを主たる樹脂成分として、
又はビニル樹脂若しくはアクリル樹脂を主たる樹脂成分
として含み、加熱加、、 ＥＥ＆Ｃ，ｉ’）・４７
＊Ｎ’に′＊Ｙ７ｂＱＫ・１０−０、 れらの主た
る樹脂成分が軟化し、タック性が生じて被転写体である
ゴルフボールの表面に接着する作用がある。The ink used in the present invention has a resin selected from polyamide resin, hard resin, acrylic resin, polyester resin, and urethane resin and nitrified cotton as the main resin components,
Or, containing vinyl resin or acrylic resin as the main resin component and heating, EE&C,i')・47
*N' is '*Y7bQK·10-0. These main resin components are softened and have tackiness, which causes them to adhere to the surface of the golf ball, which is the object to be transferred.
展色剤即ち着色剤としての顔料は、被転写体であるゴル
フボールが屋外で使用されることから耐光性が要求され
るので高グレードの顔料を用いるが、前記耐光性を満足
するものであれば染料を用いることもできろ。The pigment used as a coloring agent, that is, a coloring agent, is required to have light resistance since the golf ball, which is the object to be transferred, is used outdoors, so a high grade pigment is used. You could also use dye.
添加剤としてのポリエチレン粉末は、インキ層のブロッ
キング防止と耐摩擦性を向上させる目的で添加され、ま
た可塑剤は主たる樹脂が比較的硬い樹脂であり、被転写
体であるゴルフポールに転写さハたインキ層が打球時の
強い衝撃によりクランクを起こし易いため、クラックの
防止を目的とし添加される。The polyethylene powder as an additive is added to prevent blocking of the ink layer and improve the abrasion resistance, and the plasticizer is used because the main resin is a relatively hard resin, and the plasticizer is used to prevent the ink layer from being transferred to the golf pole. Because the ink layer tends to crack due to strong impact when hitting the ball, it is added to prevent cracks.
更に又、界面活性剤は顔料、ポリエチレン粉末等の非溶
解性物質を有機溶剤中に均一に分散させるための分散剤
として添加され、又体質顔料は、ポリプロピレンフィル
ム上にインキ画像を形成する際のインキの版からの切れ
を良くするために添加される。Furthermore, surfactants are added as dispersants to uniformly disperse insoluble substances such as pigments and polyethylene powders in organic solvents, and extender pigments are used when forming ink images on polypropylene films. Added to improve ink cutting from the plate.
本発明のゴルフポール用転写箔は、以上のような構成で
あるため、従来の転写箔に較べて、ディンプル部を含む
被転写体への転写性能に優れているばかりでなく、転写
されたインキ層の耐光性、耐摩擦性、耐クラツク性等の
物性にも優れているので、強い曝光と衝撃を受けるゴル
フポールのための転写箔として誠に好適なものである。Because the transfer foil for golf poles of the present invention has the above-described structure, it not only has superior transfer performance to a transferred object including dimpled portions compared to conventional transfer foils, but also has superior transfer performance to transferred ink. Since the layer has excellent physical properties such as light resistance, abrasion resistance, and crack resistance, it is truly suitable as a transfer foil for golf poles that are exposed to strong light and impact.
しかも、特願昭５５−１４５５０７号に開示された転写
箔と較べ１６０℃程度の低温転写が可能で、転写の際の
フィルムのしわの発生がなく、又、転写後、ゴルフボー
ル表面にトップコ：トを施してもインクのブリードが無
く、より精密な転写が可能となる等、本発明の実用上の
効果は多大である。Moreover, compared to the transfer foil disclosed in Japanese Patent Application No. 55-145507, it is possible to transfer at a lower temperature of about 160°C, and there is no wrinkles in the film during transfer. The practical effects of the present invention are great, such as there being no ink bleed even when printing is applied, and more precise transfer is possible.
以下本発明を実施例により更に詳細に説明する。The present invention will be explained in more detail below with reference to Examples.
実施例１
〔転写箔の作成〕
下記の１１１乃至（引のインキ組成物を用いて２０μの
二軸延伸ポリプロピレンフィルム上に、グラビア印刷法
によって模様を印刷して転写箔を作成した。Example 1 [Preparation of transfer foil] A transfer foil was prepared by printing a pattern on a 20 μm biaxially stretched polypropylene film by gravure printing using the following ink compositions 111 to 11.
（１１インキ（１）
硝化綿１０重量部、ポリアミド樹脂４．５重量部、カー
ボンブラック１０重量部、シリカ微粉末３重量部、可塑
剤（フタル酸系）５重量部、ポリエチレン粉末１重量部
以下の微量、界面活性剤（ノニオン系）１重量部以下の
微量、混合溶剤（トルエン／イノプロピルアルコール／
酢酸エチル＝６／１／１）６７重量部
（２）インキ（２）
硝化綿７重量部、ウレタン樹脂６重量部、カーボンブラ
ック１０重量部、可塑剤（フタル酸系）３重量部、ポリ
エチレン粉末１重量部以下の微量、界面活性剤（ノニオ
ン系）１重量部以下の微量、混合溶剤（イソプロピルア
ルコール／トルエン／メチルエチルケトン＝３／４／３
）７７重量部（３）インキ（３）
硝化綿１０重量部、エステルガム５重量部、カン系）共
に１重量部以下の微量、混合溶剤（酢酸エチル／トルエ
フ＝５０１５０）７２重量部（４）インキ（４）
硝化ＮＡ１０重量部、ポリエステル樹脂３重量部、ポリ
アゾ系顔料（Ｃｊ、Ｎｏｐｉｇｍｅｎｔ Ｒｅｄ １４
４ ） １２重量部、ポリエチレン粉末１重量部以下の
微量、可塑剤（フタル酸系）３重量部、界面活性剤（ノ
ニオン系）ｉｔ量部以、下の微量、混合溶剤（インプロ
ビルアルコール／トルエン／メチルエチルケトン＝５／
４１５ ）７２重量部
（５）インキ（５）
塩酢ビのコポリマー１５重量部、ポリアゾ系類ｐｒ（同
上）９重量部、ポリエチレン粉末１重量部、沈降性硫酸
バリウム５重量部、可塑剤（同上）、界面活性剤（同上
）共に１重量部以下の微量、混合溶剤（メチルエチルケ
トン／トルエン＝５ｏ１５０）７０重量部
（６）インキ（６）
７・ 硝化綿１０重量部、エステルガム５重量部、
染、 料（Ｃ１１，ＮｏＤｉｓｐｅｒｓｅ Ｂｌｕｅ
１９ ） ７重量部、可塑剤（同上）５重量部、ポリ
エチレン粉末、界面活性剤（同上）共に１重量部以下の
微量、混合溶剤（酢酸エチル／トルエン＝５０１５０）
７５重量部
（７）インキ（７）
硝化綿１０重量部、アクリル樹脂３］ｉ量部、カーボン
ブランク（顔料）１０重量部、ポリエチレン粉末１重量
部以下の微量、可塑剤（フタル酸系）３重量部、界面活
性剤（ノニオン系）１重量部以下の微量、混合溶剤（ト
ルエン／イソグロビルアルコール／酢酸エチル＝６１５
／１ ）７４重量部（８）インキ（８）
アクリル樹脂１０重量部、ポリアゾ系顔料（同上）１１
重量部、可塑剤（同上）３重量部、ポリエチレン粉末、
界面活性剤（同上）共に１重量部以下の微量、混合溶剤
（酢酸エチル／トルエン＝５０７５０）７．４重量部
実施例２
バラタな主材料とする外皮のゴルフボールに白色ウレタ
ン塗料（二液反応加熱乾燥型ゴルフボール用ウレタン塗
料）を塗装し、３′６℃で２０時間乾燥硬化させた後、
これに１６０′ｃｖｃ加熱したシリコンゴム（厚さ３Ｗ
Ｍで表面の曲率半径４ＯＷの円筒状凹面使用）によりイ
ンキ（１）ヲ用いて作成した転写箔を１秒間圧着するこ
とにより転写した。(11 Ink (1) 10 parts by weight of nitrified cotton, 4.5 parts by weight of polyamide resin, 10 parts by weight of carbon black, 3 parts by weight of fine silica powder, 5 parts by weight of plasticizer (phthalic acid), 1 part by weight or less of polyethylene powder trace amount of surfactant (nonionic), trace amount of 1 part by weight or less, mixed solvent (toluene/inopropyl alcohol/
Ethyl acetate = 6/1/1) 67 parts by weight (2) Ink (2) 7 parts by weight of nitrified cotton, 6 parts by weight of urethane resin, 10 parts by weight of carbon black, 3 parts by weight of plasticizer (phthalic acid), polyethylene powder Trace amount of 1 part by weight or less, surfactant (nonionic) trace amount of 1 part by weight or less, mixed solvent (isopropyl alcohol/toluene/methyl ethyl ketone = 3/4/3
) 77 parts by weight (3) Ink (3) 10 parts by weight of nitrified cotton, 5 parts by weight of ester gum, trace amounts of less than 1 part by weight for both can-based), 72 parts by weight of mixed solvent (ethyl acetate/Toluev = 50150) (4) Ink (4) 10 parts by weight of nitrified NA, 3 parts by weight of polyester resin, polyazo pigment (Cj, Nopigment Red 14)
4) 12 parts by weight, a trace amount of 1 part by weight or less of polyethylene powder, 3 parts by weight of a plasticizer (phthalic acid type), a trace amount of 1 part or less of a surfactant (nonionic type), a mixed solvent (Improvil alcohol/toluene) /Methyl ethyl ketone = 5/
415) 72 parts by weight (5) Ink (5) 15 parts by weight of salt-vinyl acetate copolymer, 9 parts by weight of polyazo type pr (same as above), 1 part by weight of polyethylene powder, 5 parts by weight of precipitated barium sulfate, plasticizer (same as above) ), surfactant (same as above) in a trace amount of 1 part by weight or less, mixed solvent (methyl ethyl ketone/toluene = 5o150) 70 parts by weight (6) Ink (6) 7. Nitrified cotton 10 parts by weight, ester gum 5 parts by weight,
Dye (C11, NoDisperse Blue)
19) 7 parts by weight, 5 parts by weight of plasticizer (same as above), trace amounts of less than 1 part by weight of both polyethylene powder and surfactant (same as above), mixed solvent (ethyl acetate/toluene = 50150)
75 parts by weight (7) Ink (7) 10 parts by weight of nitrified cotton, 3 parts by weight of acrylic resin, 10 parts by weight of carbon blank (pigment), a trace amount of 1 part by weight or less of polyethylene powder, 3 parts by weight of plasticizer (phthalic acid) parts by weight, trace amounts of 1 part by weight or less of surfactants (nonionic), mixed solvents (toluene/isoglobil alcohol/ethyl acetate = 615
/1) 74 parts by weight (8) Ink (8) 10 parts by weight of acrylic resin, polyazo pigment (same as above) 11
parts by weight, 3 parts by weight of plasticizer (same as above), polyethylene powder,
A trace amount of less than 1 part by weight of both the surfactant (same as above) and 7.4 parts by weight of a mixed solvent (ethyl acetate/toluene = 50750) Example 2 White urethane paint (two-component reaction After applying heat-drying urethane paint for golf balls and drying and curing at 3'6℃ for 20 hours,
Silicone rubber (thickness 3W) heated to 160' cvc
A transfer foil prepared using ink (1) was transferred by pressing for 1 second using a cylindrical concave surface with a radius of curvature of 4OW.
次に透明ウレタン塗料（二液反応加熱乾燥型ゴルフボー
ル用ウレタン塗料）を塗装し、５６℃で４８時間乾燥硬
化させ、絵付されたゴルフボールを得た。Next, a transparent urethane paint (a two-component heat-dried golf ball urethane paint) was applied and dried and cured at 56° C. for 48 hours to obtain a decorated golf ball.
前記絵付されたゴルフポールに対して次の試験を行った
。The following tests were conducted on the painted golf pole.
まず転写箔の転写性を確認するため、印刷された絵柄即
ちインキ層が完全にゴルフボールに転写されたかどうか
を肉眼観察により判定した。またゴルフボールに転写さ
れた絵柄が美しく転写されたかどうかを肉眼観察により
判定した。そして最後に絵柄の物性を調べるため、衝撃
試験と摩耗試験を行なった。衝撃試験はゴルフポールな
４５ｍ／秒の速度で鉄板に衝突させることを５０回くり
返すことにより行い、この後の絵柄の剥離等の損傷度合
を肉眼観察によって判定し、耐衝撃性とした。また摩耗
試験は衝撃試験を行った後のゴルフボール表面に、水と
砂とを強く吹きつける処理な５分間行い、この後の絵柄
の剥離、摩滅等の損傷度合を肉眼観察によって判定し、
耐摩耗性とした。First, in order to confirm the transferability of the transfer foil, it was determined by visual observation whether the printed pattern, ie, the ink layer, was completely transferred to the golf ball. Furthermore, it was determined by visual observation whether the pattern transferred to the golf ball was beautifully transferred. Finally, an impact test and abrasion test were conducted to examine the physical properties of the design. The impact test was conducted by repeatedly colliding with a steel plate at a speed of 45 m/sec, similar to a golf pole, 50 times, and the degree of damage such as peeling of the pattern was determined by visual observation, and the impact resistance was determined. In addition, the abrasion test was performed by strongly spraying water and sand on the golf ball surface after the impact test for 5 minutes, and the degree of damage such as peeling and abrasion of the pattern was then determined by visual observation.
Abrasion resistant.
その結果このものは、転写性は良好であり、かつ転写さ
れた絵の外観も良好で、かつ耐衝撃性、耐摩耗性共に良
好であった。As a result, this product had good transferability, good appearance of the transferred picture, and good impact resistance and abrasion resistance.
実施例６
アイオノマー樹脂を主材料とする外皮のゴルフボールを
使用した他は、実施例２と同様に実施した。結果は実施
例２と同様であった。Example 6 A test was carried out in the same manner as in Example 2, except that a golf ball whose outer shell was mainly made of ionomer resin was used. The results were similar to Example 2.
実施例４
インキ（２）を用いて作成した転写箔を使用した他は、
実施例３と同様に実施し、結果も同様であった。Example 4 Except for using a transfer foil created using ink (2),
It was carried out in the same manner as in Example 3, and the results were also the same.
実施例５
インキ（３）と（４）を用いて作成した転写箔を使用し
た他は実施例２と同様如実施し、結果も同様であった。Example 5 The same procedure as in Example 2 was carried out except that transfer foils prepared using inks (3) and (4) were used, and the results were also the same.
実施例６
インキ（５）を用いて作成した転写箔を使用した他は、
実施ｆｌＩ ５と同−Ｖｃ実施し、結果も同様であつた
。Example 6 Except for using a transfer foil made using ink (5),
The same -Vc experiment as in experiment flI 5 was carried out, and the results were also the same.
実施例フ
インキ（６）を用いて作成した転写箔を使用した他は実
施例２と同様に実施し、結果も同様であった。Example 2 was carried out in the same manner as in Example 2, except that a transfer foil prepared using Example Fink (6) was used, and the results were also the same.
実施例８
インキ（７）を用いて作成した転写箔を使用した他は実
施例３と同様に実施し、結果も同様であった。Example 8 The same procedure as in Example 3 was carried out except that a transfer foil prepared using ink (7) was used, and the results were also the same.
実施例（９）
インキ（７）と（８）を用いて作成した転写箔を使用し
た他は実施例２と同様に実施し、結果も同様であった。Example (9) Example 2 was carried out in the same manner as in Example 2, except that transfer foils prepared using inks (7) and (8) were used, and the results were also the same.
特許出願人凸版印刷株式会社Patent applicant Toppan Printing Co., Ltd.
Claims (1)
ポリエステル樹脂、及びウレタン［脂より選ばれた樹脂
と硝化綿とを主樹脂とし、着色剤として顔料又は染坪を
、添加剤としてポリエチレン粉末、体質顔料、可塑剤及
び畳面活性剤を有機溶剤に溶解又は分散させて成るイン
キにより、ポリプロピレンフィルム上に所望のインキ層
を形成して収るゴルフボール用転写箔。 （２）ビニル樹脂を主樹脂とし、着色剤として顔料又は
染料を、添加剤としてポリエチレン粉末、体質顔料、可
塑剤及び界面活性剤を有機溶剤に溶解又は分散させて成
るインキにより、ポリプロピレンフィルム上に所望のイ
ンキ層を形成して成るゴルフボール用転写箔。 （３）アクリル樹脂を主樹脂とし着色剤として顔料又は
染料を、添加剤としてポリエチレン粉末１休質顔料、可
塑剤及び界面活性剤を有機溶剤に溶解又は分散させて成
るインキにより、ポリプロピレンフィルム上に所望のイ
ンキ層を形成して成るゴルフボール用転写箔。[Claims] +11 polyamide resin, hard resin, acrylic resin,
The main resins are polyester resin and urethane [resin selected from resin and nitrified cotton, pigment or dye weight is used as a coloring agent, and polyethylene powder, extender pigment, plasticizer, and tatami surface activator are used as an organic solvent as additives. A transfer foil for golf balls that forms a desired ink layer on a polypropylene film using dissolved or dispersed ink. (2) An ink made of vinyl resin as the main resin, pigments or dyes as colorants, and polyethylene powder, extender pigments, plasticizers, and surfactants as additives dissolved or dispersed in an organic solvent is used to coat polypropylene films. A transfer foil for golf balls formed with a desired ink layer. (3) An ink consisting of an acrylic resin as the main resin, a pigment or dye as a coloring agent, and polyethylene powder, 1 dormant pigment, a plasticizer, and a surfactant as additives dissolved or dispersed in an organic solvent is used to coat a polypropylene film. A transfer foil for golf balls formed with a desired ink layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6681682A JPS58183285A (en) | 1982-04-21 | 1982-04-21 | Transfer foil for golf ball |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6681682A JPS58183285A (en) | 1982-04-21 | 1982-04-21 | Transfer foil for golf ball |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58183285A true JPS58183285A (en) | 1983-10-26 |
| JPH0132792B2 JPH0132792B2 (en) | 1989-07-10 |
Family
ID=13326754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6681682A Granted JPS58183285A (en) | 1982-04-21 | 1982-04-21 | Transfer foil for golf ball |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58183285A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60141584A (en) * | 1983-12-29 | 1985-07-26 | Sumitomo Rubber Ind Ltd | Printing method for golf ball |
| JPH02560A (en) * | 1988-11-18 | 1990-01-05 | Hideo Hamada | Transfer printing sheet |
| US6179730B1 (en) | 1995-09-18 | 2001-01-30 | Spalding Sports Worldwide Inc. | Game ball with logo formed from UV ink |
| US6217985B1 (en) * | 1997-08-27 | 2001-04-17 | Kabushiki Kaisha Showa Ink Kogyosho | Transfer printing film and golf ball marked by the same |
| US6865988B1 (en) | 1999-09-07 | 2005-03-15 | Sumitomo Rubber Industries Limited | Transfer foil for golf balls |
| US7048651B2 (en) | 1998-10-06 | 2006-05-23 | Callaway Golf Company | Golf Ball |
| CN103725131A (en) * | 2013-12-30 | 2014-04-16 | 东莞光群雷射科技有限公司 | Gold stamping coating and preparation process thereof |
| JP2021522398A (en) * | 2018-06-18 | 2021-08-30 | ザ マイケル アンド キャサリン スティーブンスン ファミリー リミテッド パートナーシップ | How to make inks, transcripts, transcripts and how to use transcripts for decoration of plastic products |
-
1982
- 1982-04-21 JP JP6681682A patent/JPS58183285A/en active Granted
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60141584A (en) * | 1983-12-29 | 1985-07-26 | Sumitomo Rubber Ind Ltd | Printing method for golf ball |
| JPH0322825B2 (en) * | 1983-12-29 | 1991-03-27 | Sumitomo Rubber Ind | |
| JPH02560A (en) * | 1988-11-18 | 1990-01-05 | Hideo Hamada | Transfer printing sheet |
| JPH0552800B2 (en) * | 1988-11-18 | 1993-08-06 | Hideo Hamada | |
| US6179730B1 (en) | 1995-09-18 | 2001-01-30 | Spalding Sports Worldwide Inc. | Game ball with logo formed from UV ink |
| US6217985B1 (en) * | 1997-08-27 | 2001-04-17 | Kabushiki Kaisha Showa Ink Kogyosho | Transfer printing film and golf ball marked by the same |
| US7048651B2 (en) | 1998-10-06 | 2006-05-23 | Callaway Golf Company | Golf Ball |
| US6865988B1 (en) | 1999-09-07 | 2005-03-15 | Sumitomo Rubber Industries Limited | Transfer foil for golf balls |
| CN103725131A (en) * | 2013-12-30 | 2014-04-16 | 东莞光群雷射科技有限公司 | Gold stamping coating and preparation process thereof |
| JP2021522398A (en) * | 2018-06-18 | 2021-08-30 | ザ マイケル アンド キャサリン スティーブンスン ファミリー リミテッド パートナーシップ | How to make inks, transcripts, transcripts and how to use transcripts for decoration of plastic products |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0132792B2 (en) | 1989-07-10 |
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