JPS58179583A - Production of clad material - Google Patents

Production of clad material

Info

Publication number
JPS58179583A
JPS58179583A JP6182182A JP6182182A JPS58179583A JP S58179583 A JPS58179583 A JP S58179583A JP 6182182 A JP6182182 A JP 6182182A JP 6182182 A JP6182182 A JP 6182182A JP S58179583 A JPS58179583 A JP S58179583A
Authority
JP
Japan
Prior art keywords
base material
materials
diffusion welding
stainless steel
steel pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6182182A
Other languages
Japanese (ja)
Inventor
Akira Kato
昭 加藤
Yukio Usuzaka
臼坂 征雄
Yasuhiro Fukaya
深谷 保博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP6182182A priority Critical patent/JPS58179583A/en
Publication of JPS58179583A publication Critical patent/JPS58179583A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/02Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a press ; Diffusion bonding

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

PURPOSE:To improve yield by fitting a covering tubular material onto a base material, grasping both materials flatly so as to bring the same in tight contact with each other without any clearance and sealing both ends then subjecting the materials to diffusion welding thereby preventing the inflow of air and performing diffusion welding in an ordinary heating furnace. CONSTITUTION:A stainless steel pipe 21 is fitted as a covering tubular material on a round barlike copper base material 20, and both are grasped under pressure with press dies 22, 23 whereby the base material and the covering material are plastically deformed to a flat shape. Such end plates 25 which prevent the inflow of air are welded to both ends of the cladding blank metal 24 formed flatly in tight and close contact with each other to seal both ends. The blank material is put into a heating furnace 26 for the purpose of joining, and a required weight 27 for applying the face pressure necessary for joining is placed thereon during heat, whereby the copper base material 20 and the stainless steel pipe 21 are diffusion-welded. The diffusion welding is accomplished in the same way as mentioned above by deforming both materials plastically to a flat shape with a pair of rolls having the calibers of a flat section, and sealing both ends then heating the materials and rolling the same again.

Description

【発明の詳細な説明】 本発明は、母材の周囲にこの母材と異なる材質の被覆材
を接合した偏平な合わせ材の製造方法Kr1ljL、、
特に耐食性の導電棒材の製造に応用して好適な方法であ
る。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides a method for manufacturing a flat laminated material in which a covering material made of a material different from that of the base material is joined around the base material.
This method is particularly suitable for application to the production of corrosion-resistant conductive rods.

メッキや食塩の電解等を工業的に行なう場合に使用する
電極棒としては導電性のみならず長期間の使用によって
も電解液による腐食が少ない耐食性に優れたものが必要
とされる。この九め、銅等の導電性材料にチタン中ステ
ンレス鋼等の耐食性材料を被覆し、さらKその一端を耐
食性材料で閉塞した断面偏平な導電棒材が使用されてい
る。この導電棒材では内側の導電性材料に通電すること
から被覆材表面への抵抗が小さい方が望ましく、単に両
金属を接触させるだけでなく拡散接合することが望まし
い。
Electrodes used in industrial plating, salt electrolysis, etc. are required to have not only electrical conductivity but also excellent corrosion resistance with little corrosion due to electrolyte even after long-term use. Finally, a conductive rod material with a flat cross section is used, in which a conductive material such as copper is coated with a corrosion-resistant material such as titanium or stainless steel, and one end of the conductive material is closed with a corrosion-resistant material. In this conductive bar, since electricity is applied to the inner conductive material, it is desirable that the resistance to the surface of the covering material be small, and it is desirable not only to simply bring the two metals into contact, but also to perform diffusion bonding.

そこで、従来、導電棒材を製造する方法として真空拡散
溶接法と熱間圧延拡散溶接法とが採用されている。
Therefore, conventionally, vacuum diffusion welding and hot rolling diffusion welding have been adopted as methods for manufacturing conductive bars.

前者の真空拡散溶接法による製造法は、第1図にその工
11を示すように、丸棒状【なす銅母材1にこれより大
径のステンレス鋼管2を嵌合し、これらを相対向する一
対のプレス金113゜4で挟圧して偏平KlI性変形さ
せ、得られ九合わせ素材を真空拡散溶接装置の密閉室5
内の相対向する一対の加圧体6,7間に位置させヒータ
8で加熱しながら加圧するとともに密閉塞s内を真空又
は非酸化性雰囲気にして鋼母材1とステンレス鋼管2と
t−接合する。こののち電解液等の浸入を防止するため
一端に端板9を溶接することで導電棒材が作られていた
The former manufacturing method using the vacuum diffusion welding method involves fitting a stainless steel pipe 2 with a larger diameter into a round bar-shaped copper base material 1, and then facing each other. The material is pressed between a pair of press metals 113゜4 to deform it into a flat KlI shape, and the resulting nine-jointed material is placed in the sealed chamber 5 of the vacuum diffusion welding device.
The steel base material 1, the stainless steel pipe 2, and the t- Join. Thereafter, a conductive bar was produced by welding an end plate 9 to one end to prevent infiltration of electrolyte and the like.

この方法によれば極めて高品質1に#!品が得られるが
、電価で大規模な真空拡散溶接設備が必要となるという
欠点がある。
This method achieves extremely high quality #1! However, the disadvantage is that large-scale vacuum diffusion welding equipment is required due to the electric cost.

一方、後者の島関圧蝿拡散#*法では、第2図にその工
m’を示すように、丸棒状をなす銅母材1にこれより大
径のステンレス鋼管2を嵌合し、これを酸化を防止しつ
つ加熱f10内で加熱し、適温となつ九とζろで織出し
、偏平断面のカリバーを有する相対向する一対のロール
11゜12間に送って圧延によって塑性変形させるとと
−に鋼母材lとステンレス鋼管2とを接合する。このの
ち上述の場合と同様に端板9を溶接して導電棒材が作ら
れて込る。
On the other hand, in the latter island pressure fly diffusion #* method, as shown in Fig. 2, the process m' is shown by fitting a stainless steel pipe 2 with a larger diameter into a round bar-shaped copper base material 1. The material is heated in a heating f10 while preventing oxidation, and then brought to an appropriate temperature and woven using a Natsu9 and Zeta roller, and then sent between a pair of opposing rolls 11° and 12 having flat cross-section calibers to be plastically deformed by rolling. - Join the steel base material l and the stainless steel pipe 2. Thereafter, the end plate 9 is welded to form a conductive bar in the same manner as in the case described above.

この方法では、加熱炉10から取出して熱間圧延成形を
行なうため成形中の酸化を防止できず、未圧延部分に開
放端から空気が浸入し酸化が起こって非接合部が生じや
すい。特に、加熱炉lOから取出してから圧延が行なわ
れる迄の時間が長ければ非接合部の生じる割合4大きく
歩留りも悪化する。
In this method, oxidation cannot be prevented during forming because the material is removed from the heating furnace 10 and hot rolled, and air enters the unrolled portion from the open end, causing oxidation and resulting in non-bonded portions. In particular, if the time from removal from the heating furnace IO to rolling is long, the proportion of non-bonded portions will increase (4) and the yield will deteriorate.

本発明はかかる従来の欠点を解消し、大規模な設備を必
要とせずしかも良質な製品を得ることができる釡わせ材
の製造方法の提供を目的とする。かかる目的を達成する
本発明の構成は、母材にこの母材より大径の被覆管材を
嵌合し、これらを挾圧して偏平[111性変形させ前記
母材の外周面と前記被覆管材の内局面とを密着させ九の
ち、両端部を空気の流入を防止するようシールし、さら
に拡散溶接して前記母材と前記被覆管材とを接合するこ
とを特徴とする。
It is an object of the present invention to provide a method for producing a kettle material that eliminates the above-mentioned conventional drawbacks, does not require large-scale equipment, and can produce high-quality products. The structure of the present invention to achieve such an object is to fit a cladding tube material having a diameter larger than that of the base material into a base material, and to compress and deform the cladding tube material into a flattened material so that the outer circumferential surface of the base material and the cladding tube material are The base material and the cladding tube material are bonded to each other in close contact with each other, after which both ends are sealed to prevent air from entering, and diffusion welding is performed to join the base material and the cladding material.

以下、本発明による合わせ材の製造方法を導電棒材に応
用し九実紬ガについてPlaK説明する。
Hereinafter, PlaK will be explained about Kuji Tsumugi by applying the method of manufacturing a laminated material according to the present invention to a conductive bar material.

第3図はプレス成形を用いる場合の−*m例Kかかる工
程図であり、まず丸棒状をなす鋼母材20に被覆管材と
してこれよシ大径のステンレス鋼管21t−妖合し、こ
れらを相対向する一対のプレス金1122.23で挾圧
して偏平に塑性変形させるが、このとき鋼母材20の外
周面とステンレス鋼管21の内周面とが密着し内部に空
気が残存しないようKする。次に、こうして隙間なく書
着し偏平に成形された合わせ素材24の両端に空気#>
流入を防止するよう端板25をそれぞれ溶接してシール
する。こののち接合のため加熱炉26内に入れ、接合に
必要な面圧を付与するため所要の重錘27を載せて加熱
することで鋼母材20とステンレス鋼管21とを拡散溶
接する。この拡散11II接においては従来、真空雰囲
気とするか、あるいは非酸化性雰囲気として接合面の酸
化を防止しなければならなかったが、銅母材20とステ
ンレス銅管21とを隙間なく書着させその両端部をシー
ル溶接しであるので接合面への空気の浸入が防止され酸
化が進行せず大気中で拡散#I接することができるので
ある。こうして、完全に拡散溶接がなされた合わせ材と
しての導電棒材28が得られたならば、これを必要に応
じて切断することで、片側封じ合わせ材、2本*す、両
端開放合わせ材などの耐食性導電棒が得られる。
Fig. 3 is a process diagram for example K when press forming is used. First, a stainless steel pipe 21t of a larger diameter than this is coated on a steel base material 20 in the shape of a round bar as a covering pipe material. A pair of press metals 1122.23 facing each other are used to clamp and plastically deform the steel base metal 20 into a flat shape. do. Next, air is applied to both ends of the laminated material 24, which is thus written without any gaps and formed into a flat shape.
The end plates 25 are each welded and sealed to prevent inflow. Thereafter, the steel base material 20 and the stainless steel pipe 21 are placed in a heating furnace 26 for bonding, and heated with a required weight 27 placed thereon to apply surface pressure necessary for bonding, thereby diffusion welding the steel base material 20 and the stainless steel pipe 21. Conventionally, in this diffusion 11II bonding, it was necessary to use a vacuum atmosphere or a non-oxidizing atmosphere to prevent oxidation of the bonding surface, but the copper base material 20 and the stainless steel copper tube 21 were bonded without any gaps. Since both ends are sealed and welded, air is prevented from entering the joint surface, and oxidation does not proceed, allowing diffusion #I contact in the atmosphere. In this way, once the conductive bar material 28 is obtained as a laminate material that has been completely diffusion welded, it can be cut as necessary to produce a one-side sealed material, a two-piece material, a laminate material with both ends open, etc. A corrosion-resistant conductive rod is obtained.

第4図はロール成形を用いる場合の一実總例Kかかる工
程図であり、丸棒状をなす鋼母材2゜K被覆管材として
これより大径のステンレス鋼管21を嵌合し、これらを
偏平断面とするカリバーを有する相対向する一対のロー
ル29.30間に送ってロール成形によって偏平Kll
性変形させるとともに鋼母材2oとステンレス鋼管21
とを隙間なく密着させる。こうして隙間なく密着し偏平
に成形され九合わせ素材24の両端に空気の流入を防止
するようプラグ31を挿入しシール溶接して帯封する。
Fig. 4 is a process diagram showing a complete example of roll forming, in which a stainless steel pipe 21 of a larger diameter is fitted as a round bar-shaped steel base material of 2°K as a cladding pipe material, and these are flattened. A flat Kll is sent between a pair of opposing rolls 29.
While deforming the steel base material 2o and the stainless steel pipe 21
Make sure they are in close contact with each other without any gaps. In this way, the plugs 31 are inserted into both ends of the nine-joint material 24, which is tightly fitted without any gaps and formed into a flat shape, to prevent air from flowing in, and are sealed by welding.

こののち、加熱炉九内に入れ加熱し友のち具びロール2
9.30間に送ってロール圧延することで拡散溶接を行
なう。この場合、銅母材2oとステンレス鋼管21とを
隙間なく密着させる九めの第1回目のロール圧延では、
第2im目のロール圧延の偏平化の余j@It−残し次
ものとしておく。このように、事実施例の場合も銅母材
2oとステンレス鋼管21とを隙間な(密着させその両
端部をシール溶接しであるので接合面への空気の浸入が
防止され酸化が進行せず、大気中で拡散溶接することが
できるのである。こうして、完全に拡散溶接がなされ良
合わせ材としての導電棒材28が得られたならば、上述
の場合と同様これを必要に応じて切断すれば良い。
After this, put it in the heating furnace and heat it.
9. Diffusion welding is performed by sending and rolling for 30 minutes. In this case, in the first nine roll rolling to bring the copper base material 2o and the stainless steel pipe 21 into close contact with each other without any gaps,
The remainder of the flattening of the 2nd im roll is left as follows. In this way, the copper base material 2o and the stainless steel pipe 21 are brought into close contact with each other without a gap, and both ends are seal-welded, which prevents air from entering the joint surface and prevents oxidation from proceeding. In this way, diffusion welding can be carried out in the atmosphere.Once the conductive bar material 28 has been completely diffusion welded and serves as a good joining material, it can be cut as necessary as in the case described above. Good.

尚、上記各実施例では隙間なく密着させたのち端板ある
いはプラグを溶接するもので説明したが、いずれの方法
でも良く、また、ロール成形する場合にも加熱炉内で所
要の圧力を付与して拡散溶接しても良く、逆にプレス成
形する場合にも加熱炉で加熱したのちロール成形によっ
て拡散溶接するようKしても良い。また、母材としては
丸棒に限らず中空棒等を使用できる。
In each of the above embodiments, the end plates or plugs are welded after being brought into close contact with each other without any gaps, but any method may be used, and even when roll forming, the required pressure is applied in a heating furnace. Alternatively, in the case of press forming, diffusion welding may be performed by heating in a heating furnace and then performing diffusion welding by roll forming. Further, the base material is not limited to a round bar, but a hollow bar or the like can be used.

また、種々の金属材を用いる合わせ材の製造に応用でき
る。
Moreover, it can be applied to the production of laminated materials using various metal materials.

以上、実施例とともに具体的に説明したように1本発明
方法によれば、母材と被覆管材とを偏平に塑性変形する
際に画材を密着させ接合面に空気の残存を極少とし、そ
の両it−シールするので接合工程において空気の浸入
が防止され接合面の酸化が進行しないので大気中にあっ
ても良好な拡散接合が可能である。また、この種の合わ
せ材では使用に際してその一端を封じて使用することが
多いので、接合前に両端をシールすることは工程の順序
全変更するだけですみ工程が増すこと本ない。したがっ
て、高価な設備を必要とせず、一般の加熱炉を用い容易
に拡散溶接1行なう仁とができ、歩留りが高く品質の優
れた合わせ材を製造することができる。
As explained above in detail with the embodiments, according to the method of the present invention, when the base material and the cladding material are plastically deformed into flat shapes, the art material is brought into close contact with the joint surface, minimizing air remaining on the joint surface, and both Since it is sealed, air is prevented from entering during the bonding process, and oxidation of the bonding surface does not progress, so good diffusion bonding is possible even in the atmosphere. In addition, since this type of laminated material is often used with one end sealed, sealing both ends before joining requires only a complete change in the order of the steps and does not increase the number of steps. Therefore, diffusion welding can be easily performed using a general heating furnace without requiring expensive equipment, and a bonded material with a high yield and excellent quality can be manufactured.

【図面の簡単な説明】[Brief explanation of the drawing]

81図および第2図は従来の合わせ材の製造方法の工程
図で、第1図はプレス成形による真空拡散S接法を、第
2図はロール成形による熱間圧延拡散溶接法を示す。j
I3図およびIIIL4図は本発明の合わせ材の製造方
法の一実論f4Kかかる工程図で、第3ailはプレス
成形による場合、1114図はロール成形による場合を
示す。 図 画 中、 20は銅母材、 21はステンレス鋼管、 22.23はプレス金蓋、 24は合わせ素材、 25は端板、 26は加熱炉、 27は重錘、 28は導電棒材、 29.30はロール、 31はプラグである。 特許出願人 三菱重工業株式会社 復代理人 弁盾士光石士部 (他1名) 第1図 0 ズ 第2図 第4図
FIG. 81 and FIG. 2 are process diagrams of a conventional method for manufacturing a laminated material. FIG. 1 shows a vacuum diffusion S welding method using press forming, and FIG. 2 shows a hot rolling diffusion welding method using roll forming. j
Figures I3 and IIIL4 are process diagrams showing a practical theory f4K of the method for manufacturing the laminated material of the present invention, in which the third rail shows the case of press molding, and the one of Figure 1114 shows the case of roll molding. In the drawing, 20 is a copper base material, 21 is a stainless steel pipe, 22.23 is a press metal lid, 24 is a mating material, 25 is an end plate, 26 is a heating furnace, 27 is a weight, 28 is a conductive bar material, 29 .30 is a roll, 31 is a plug. Patent Applicant Mitsubishi Heavy Industries, Ltd. Sub-Attorney Attorney Shibe Mitsuishi (and 1 other person) Figure 1 0 Figure 2 Figure 4

Claims (1)

【特許請求の範囲】[Claims] 母材にこの母材より大径の被覆管材を嵌合し、これらを
挟圧して偏平に塑性変形させ前記母材の外周面と前記被
覆管材の内周面とを密着させ九のち、両端部を空気の流
入を防止するようシールし、さらに拡散溶接して前記母
材と前記被覆管材とを接合することt−特徴とする合わ
せ材の製造方法。
A cladding tube material having a diameter larger than that of the base material is fitted onto the base material, and these are compressed and plastically deformed into flat shapes so that the outer circumferential surface of the base material and the inner circumferential surface of the cladding tube material are brought into close contact with each other. A method for producing a laminated material, characterized in that the base material and the cladding material are joined by sealing the base material to prevent air from entering, and further by diffusion welding.
JP6182182A 1982-04-15 1982-04-15 Production of clad material Pending JPS58179583A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6182182A JPS58179583A (en) 1982-04-15 1982-04-15 Production of clad material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6182182A JPS58179583A (en) 1982-04-15 1982-04-15 Production of clad material

Publications (1)

Publication Number Publication Date
JPS58179583A true JPS58179583A (en) 1983-10-20

Family

ID=13182125

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6182182A Pending JPS58179583A (en) 1982-04-15 1982-04-15 Production of clad material

Country Status (1)

Country Link
JP (1) JPS58179583A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6277191A (en) * 1985-10-01 1987-04-09 Kuroki Kogyosho:Kk Production of bar like stock made of clad metal
US5366569A (en) * 1992-03-31 1994-11-22 Sket Schwermaschinenbau Magdeburg Gmbh Method for producing a corrosion-resistant composite wire
CN113223755A (en) * 2021-04-13 2021-08-06 南京理工大学 High-strength and high-corrosion-resistance copper-stainless steel composite wire and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6277191A (en) * 1985-10-01 1987-04-09 Kuroki Kogyosho:Kk Production of bar like stock made of clad metal
US5366569A (en) * 1992-03-31 1994-11-22 Sket Schwermaschinenbau Magdeburg Gmbh Method for producing a corrosion-resistant composite wire
CN113223755A (en) * 2021-04-13 2021-08-06 南京理工大学 High-strength and high-corrosion-resistance copper-stainless steel composite wire and preparation method thereof

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