JPS58151941A - Casting mold for continuous casting - Google Patents

Casting mold for continuous casting

Info

Publication number
JPS58151941A
JPS58151941A JP3544182A JP3544182A JPS58151941A JP S58151941 A JPS58151941 A JP S58151941A JP 3544182 A JP3544182 A JP 3544182A JP 3544182 A JP3544182 A JP 3544182A JP S58151941 A JPS58151941 A JP S58151941A
Authority
JP
Japan
Prior art keywords
mold
layer
alloy
alloys
intermediate layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3544182A
Other languages
Japanese (ja)
Inventor
Akira Kubota
昭 久保田
Katsuhiro Hori
堀 勝廣
Masato Takada
正人 高田
Takahiro Nishioka
西岡 隆弘
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mishima Kosan Co Ltd
Original Assignee
Mishima Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mishima Kosan Co Ltd filed Critical Mishima Kosan Co Ltd
Priority to JP3544182A priority Critical patent/JPS58151941A/en
Publication of JPS58151941A publication Critical patent/JPS58151941A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/059Mould materials or platings

Abstract

PURPOSE:To provide a titled casting mold which improves the quality of ingots and prolongs the own life, by covering the body of the copper or copper alloy mold with an intermediate layer of molybdenum or the like having high strength at high temp. and a surface layer of chromium having high abrasion resistance. CONSTITUTION:An intermediate layer 3 consisting of Mo, Mo alloys, W, W alloys, Ta, Ta alloys, Nb, Nb alloys or the like having high strength at high temp. and good heat conductivity in order to improve resistance to thermal fatigue is provided through an Ni or Ni alloy undercoating material 2 in order to improve adhesion on the inside surface of a casting mold body 1 made of Cu or a Cu alloy of a high-speed continuous casting device, and further a surface layer 4 consisting of Cr or an Ni-Cr alloy in order to withstand abrasion and to prevent the sticking of molten steel is provided thereon. The thickness of the layer 3 is made successively smaller from the upper to lower parts of the mold, and the layer 4 is made into the form opposite to said layer or the layer 4 is curled into the end face of the mold, whereby the life of the mold is prolonged further.

Description

【発明の詳細な説明】 本願発明は得られる鋳片の品質を向上させると共に鉤型
自体の寿命を高める連続鋳造用鋳型に−するものである
DETAILED DESCRIPTION OF THE INVENTION The present invention is directed to a continuous casting mold that improves the quality of the obtained slab and extends the life of the hook die itself.

近年連続鋳造法の高速化が進むに従い、連続鋳造用鋳型
の表面温度が高くなり、従来用いられていた表面Jと二
、ケル若しくはニッケル合金層を施したものでは表面が
損傷されるばかりではなく銅若しくは銅合金製鋳型本体
自体が熱の為に強度が低下し使用に耐えられなくなる事
態が生じていた。
In recent years, as continuous casting methods have become faster, the surface temperature of continuous casting molds has become higher, and the conventionally used surfaces with a layer of surface J, 2, KEL or nickel alloy do not only damage the surface. The strength of the copper or copper alloy mold body itself deteriorates due to heat, resulting in a situation where it becomes unusable.

本願発明は上記欠点を解消する連m#造用IIk型に係
り、その要旨は銅若しくは銅合金製麹型本体の内表面上
に、二、ケル若しくは二、ケル合金製アンダーコート材
を介してモリブデン、モリブデン合金、タングステン、
タングステン合金、タンタル、タンタル合金、ニオブ、
ニオブ合金のいずれか一種から成る中間層を設け、更に
その上にりロム若しくはニッケルークロム合金から成る
表面層を設けたことを特徴とする連続鋳造用鋳型である
The present invention relates to a IIk type for continuous m# production which eliminates the above-mentioned drawbacks, and the gist thereof is to coat the inner surface of the mold body made of copper or copper alloy with an undercoat material made of Ni-Kel or Ni-Kel alloy. Molybdenum, molybdenum alloy, tungsten,
Tungsten alloy, tantalum, tantalum alloy, niobium,
This continuous casting mold is characterized in that it has an intermediate layer made of any one of niobium alloys, and a surface layer made of chromium or nickel-chromium alloy.

なお連続鋳造用鋳型はそのメニスカス部付近は烏潟にさ
らされる為に主として耐熱疲労性が要求され、下半部は
凝固シェルに対する耐摩耗が主として要求されるのでそ
の要求に合わせて耐熱性に富む申開層の肉厚を上部メニ
スカス部に於いては厚くする場合もある。
In addition, since the area around the meniscus of a continuous casting mold is exposed to the Karasugata, heat fatigue resistance is mainly required, and the lower half is mainly required to have wear resistance against the solidified shell, so it must be highly heat resistant to meet these requirements. In some cases, the thickness of the Shenkai layer is increased at the upper meniscus.

又本願鋳型の申開層として用いる材料は一般に低湿に於
いては脆く又高温では酸化され易く、特にモリブデンは
その酸化物が容易に揮化するので申開層の剥離防止、酸
化防止及び−型本体の熱収縮変形防止の為壱〇表面層を
上下1両側端面に巻込み中間層が露出しない様にしてお
くと一層効果的である。
In addition, the material used as the opening layer of the mold of the present invention is generally brittle at low humidity and easily oxidized at high temperatures.In particular, the oxide of molybdenum easily volatilizes, so it is necessary to prevent peeling of the opening layer, prevent oxidation, and mold. In order to prevent heat shrinkage and deformation of the main body, it is more effective to wrap the surface layer around both end faces of the upper and lower parts so that the intermediate layer is not exposed.

本−発明に於ける申開層の設は方としては特に限定され
るものではないが通常は溶射によるもの以下本願発明鋳
型を図面を参酌し乍ら詳述すれば、11!1図に示す様
に鏑若しくは鏑合金製鋳型本体(11の内表面上に中間
層(3)がその密着性を高める為にアンダーコート材(
2)を介して設けられており、その上に更に表面層(4
)が般けられている。中間層(3)としては高温強度が
大で熱伝導率が良好な材料が好ましくモリブデン、モリ
ブデン合金(M・−Zr。
The method of forming the opening layer in the present invention is not particularly limited, but is usually done by thermal spraying.The mold of the present invention will be described in detail below with reference to the drawings, as shown in Figure 11!1. The intermediate layer (3) is coated with an undercoat material (3) on the inner surface of the Kabura or Kabura alloy mold body (11) to improve its adhesion.
2), and a surface layer (4) is further provided thereon.
) is popular. The intermediate layer (3) is preferably made of a material that has high high-temperature strength and good thermal conductivity, such as molybdenum or molybdenum alloy (M.-Zr).

MO−Zr−Ti)、タングステン、タングステン合金
(W−The、 、 W−MO)、ニオブ、ニオブ合金
(Nb−V。
MO-Zr-Ti), tungsten, tungsten alloys (W-The, , W-MO), niobium, niobium alloys (Nb-V.

Nb −Mo 、 Nb −T a )タンタル、タン
タル合金(Tm−W。
Nb-Mo, Nb-Ta) tantalum, tantalum alloy (Tm-W.

Ta−W−Hf )等があ抄、アンダーコート材(2)
は該中間層(3)と鋳型本体(1)との密着性を考慮し
てニッケル若しくは二、ケル合金とする。
Ta-W-Hf) etc., undercoat material (2)
is made of nickel or di-Kel alloy in consideration of the adhesion between the intermediate layer (3) and the mold body (1).

又表面層(4は耐摩耗性、溶鋼の表面付着防止等の点か
らクロム若しくは二、ケル−クロム合金とする。
In addition, the surface layer (4) is made of chromium or a ker-chromium alloy from the viewpoint of wear resistance and prevention of molten steel from adhering to the surface.

第2図に示すものは中間層(31が上部から下部Iこな
るにつれ順次薄くな秒表面層+41は逆に厚くなる形態
のものであり、連続鋳造用鋳型がその使用に際して受け
る条件即ち鋳型上部は熱による損傷が大きく、鋳型下部
は凝固シェルによるヒラカキ傷及びそれGζ伴なう剥離
等による損傷が大きいという事に対拠させる為のもので
ある。
The one shown in Fig. 2 has an intermediate layer (31) that becomes thinner as it goes from the upper part to the lower part, and a second surface layer (41) that becomes thicker. This is to counter the fact that the damage caused by heat is large, and the lower part of the mold is caused large damage by cracking scratches caused by the solidified shell and peeling that accompanies Gζ.

又第5図〜第5図に示すのは、前述の中間層(3)の欠
点を補う為に表面層(4)を鋳型の上下、両伺端面に巻
込んだ形態のものであり、又第6図は熱変形防止の為に
中間層(3)とアンダーコート材(2)をも両鉤曇ζ巻
込んだ形態のものを示す。
Moreover, what is shown in FIGS. 5 and 5 is a structure in which a surface layer (4) is wrapped around the upper and lower ends of the mold, and both ends of the mold, in order to compensate for the defects of the intermediate layer (3) mentioned above. FIG. 6 shows a structure in which an intermediate layer (3) and an undercoat material (2) are also rolled up in both halves to prevent thermal deformation.

本願鋳型はアンダーコート材(2)→中間層(3]→表
函層(4)と施した後1通常熱処理を施して各層間の密
着性を向上せしめて用いられる。
The mold of the present invention is used after forming the undercoat material (2) -> the intermediate layer (3) -> the surface layer (4), and then subjecting it to a heat treatment to improve the adhesion between each layer.

以上述べて来た様に本願発明によれば、中間層として用
いている高融点金属又はその合金はそのいずれも熱伝導
性が良好なものである為にそれがAfflに於いて変形
抵抗が大である高温強度を雑持しながらも銅若しくは銅
合金製鋳型を通じての冷却は十分に行なわれるので仁の
中1IIIIIに熱が貯積され結果として鋳型本体の温
度が^くなり、鋳型本体にダメージを与えるという事は
なく、最外表面層たるニッケルークロム合金層と相俟っ
て変形がなくかつ摩耗が少ない高寿命の連続鋳造用鋳型
を構成する為に長期に渡り均一で品質の良い製品を得る
事が出来るものである。
As described above, according to the present invention, the high melting point metal or its alloy used as the intermediate layer has good thermal conductivity, so it has high deformation resistance in Affl. While maintaining high-temperature strength, the cooling through the copper or copper alloy mold is sufficient, so heat is accumulated in the mold, resulting in an increase in the temperature of the mold body and damage to the mold body. Together with the outermost nickel-chromium alloy layer, this creates a long-life continuous casting mold with no deformation and little wear, resulting in a product that is uniform and of high quality over a long period of time. It is possible to obtain.

又申開層の厚さを鋳型上部から下部になるに従い順次肉
薄、表面層は逆にした形態のものでは実際操業に於ける
鋳型の損傷に完全にマツチしているので上記効果が更に
向上し#に型の寿命が大幅に延長され%更にクロム若し
くはニッケルークロム合金から成る表面層を鋳型の上下
両端面及び両側端面に巻込んだ形態のものにあっては中
間層を酸化から守ると共に中間層の剥離、#を型本体の
熱収縮変形を防止するという効果をも期待できるもので
ある。
In addition, if the thickness of the opening layer is gradually reduced from the top of the mold to the bottom, and the surface layer is reversed, the above effect is further improved because it perfectly matches the damage to the mold during actual operation. #The life of the mold is greatly extended.%Furthermore, if a surface layer made of chromium or nickel-chromium alloy is wrapped around both the upper and lower end surfaces of the mold and both end surfaces of the mold, it protects the intermediate layer from oxidation and protects the intermediate layer from oxidation. It can also be expected to have the effect of preventing layer peeling and heat shrinkage deformation of the mold body.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本願発明鋳型の一例を示す斜視図、第2図は同
他の例を示す斜視図、flk3図は同更に他の例を示す
斜視図、第4〜及び第5図は第3図A−A線及びB−B
@に於けるIIIT面図、第6図は中a111及びアン
ダーコート材がII F!に巻込まれt、・形態の#型
の説明図。 図中、 +11 :銅合金製鋳型本体 (2):アンダーコート材 (3):中間層 (4;:表面層 特許出願人  三島光産株式会社 代  理  人    有  吉  数  晴第1図 
    第2図 第4F!!J     第5図 第6図
Fig. 1 is a perspective view showing an example of the mold of the present invention, Fig. 2 is a perspective view showing another example of the same, Fig. 3 is a perspective view showing another example of the same, Figs. Figure A-A line and B-B
IIIT surface view in @, Figure 6 shows middle a111 and undercoat material are IIF! An explanatory diagram of the # type of the t-form. In the figure, +11: Copper alloy mold body (2): Undercoat material (3): Intermediate layer (4;: Surface layer Patent applicant: Mishima Kosan Co., Ltd. Representative: Kazuharu Ariyoshi Figure 1
Figure 2 4F! ! J Figure 5 Figure 6

Claims (1)

【特許請求の範囲】 墓、 銅若しくは調合金製IIIIM1本体の内表面上
に、ニッケル若しくは二、ケル合金製アンダーコート材
を介してモリブデン、モリブデン合金、タングステン、
タングステン合金、タンタル、タンタル合金、ニオブ、
ニオブ合金のいずれか一株から成る中間層を設け、更に
その上にクロム若しくはニッケルークロム合金から成る
表面層を設けたξとを特徴とする連続鋳造用鋳型。 1 中間層が鋳型上部から下部になるに従い順次肉薄と
なり、表面層は逆にfIIJI型上部から下部になるに
従い順次肉厚となることを特徴とする特許請求の範囲第
1項記載の連続鋳造用鋳型。 畠 表面層が鋳型の上下*sit+及び両ajMl向に
於いて中間層を覆設する如き形態に巻込筒れていること
を特徴とする特許画才の範囲第1項若しくは第2項記載
の連続鋳造用鋳型。
[Claims] Molybdenum, molybdenum alloy, tungsten,
Tungsten alloy, tantalum, tantalum alloy, niobium,
A mold for continuous casting, characterized in that an intermediate layer made of any one of niobium alloys is provided, and a surface layer made of chromium or a nickel-chromium alloy is further provided thereon. 1. Continuous casting according to claim 1, characterized in that the intermediate layer becomes progressively thinner from the top to the bottom of the mold, and the surface layer, conversely, becomes progressively thicker from the top to the bottom of the fIIJI mold. template. Hatake: The continuum described in item 1 or 2 of the scope of the patent artist, characterized in that the surface layer is rolled in such a form as to cover the intermediate layer in the upper and lower *sit+ and both ajMl directions of the mold. Casting mold.
JP3544182A 1982-03-05 1982-03-05 Casting mold for continuous casting Pending JPS58151941A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3544182A JPS58151941A (en) 1982-03-05 1982-03-05 Casting mold for continuous casting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3544182A JPS58151941A (en) 1982-03-05 1982-03-05 Casting mold for continuous casting

Publications (1)

Publication Number Publication Date
JPS58151941A true JPS58151941A (en) 1983-09-09

Family

ID=12441923

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3544182A Pending JPS58151941A (en) 1982-03-05 1982-03-05 Casting mold for continuous casting

Country Status (1)

Country Link
JP (1) JPS58151941A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60145247A (en) * 1983-12-29 1985-07-31 Kawasaki Steel Corp Mold for continuous casting and its production
JPS60221151A (en) * 1984-04-18 1985-11-05 Kawasaki Steel Corp Continuous casting mold and formation of thermally sprayed film on inside surface of mold
CN105798544A (en) * 2014-12-31 2016-07-27 北京有色金属研究总院 Tungsten-copper composite material and preparation method thereof
CN106563778A (en) * 2015-10-12 2017-04-19 宝钢特钢有限公司 Clad layer used for hot-top crystallizer
CN108193115A (en) * 2017-12-14 2018-06-22 昆山胜典机电科技进出口有限公司 A kind of preparation method of molybdenum alloy, molybdenum alloy and its application

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60145247A (en) * 1983-12-29 1985-07-31 Kawasaki Steel Corp Mold for continuous casting and its production
JPS6351787B2 (en) * 1983-12-29 1988-10-17 Kawasaki Seitetsu Kk
JPS60221151A (en) * 1984-04-18 1985-11-05 Kawasaki Steel Corp Continuous casting mold and formation of thermally sprayed film on inside surface of mold
JPH0337454B2 (en) * 1984-04-18 1991-06-05 Kawasaki Steel Co
CN105798544A (en) * 2014-12-31 2016-07-27 北京有色金属研究总院 Tungsten-copper composite material and preparation method thereof
CN106563778A (en) * 2015-10-12 2017-04-19 宝钢特钢有限公司 Clad layer used for hot-top crystallizer
CN108193115A (en) * 2017-12-14 2018-06-22 昆山胜典机电科技进出口有限公司 A kind of preparation method of molybdenum alloy, molybdenum alloy and its application
CN108193115B (en) * 2017-12-14 2019-09-24 昆山胜典机电科技进出口有限公司 A kind of preparation method of molybdenum alloy, molybdenum alloy and its application

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