JPS58141389A - Decorating method - Google Patents
Decorating methodInfo
- Publication number
- JPS58141389A JPS58141389A JP2307582A JP2307582A JPS58141389A JP S58141389 A JPS58141389 A JP S58141389A JP 2307582 A JP2307582 A JP 2307582A JP 2307582 A JP2307582 A JP 2307582A JP S58141389 A JPS58141389 A JP S58141389A
- Authority
- JP
- Japan
- Prior art keywords
- decorated
- film
- organometallic compound
- metal film
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Chemically Coating (AREA)
- Physical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
こＯ発明は、ガラス、金属などの被加飾物にメタリック
調の加飾を施ζす方法に関すす。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for applying metallic decoration to objects to be decorated such as glass and metal.
従来、ガラスビン中金属審Ｓなど０表面にメタリック調
の加飾を麿とす方法として、次のような手段が採用され
ている。すなわち、被加飾物表面にまずアル電エウ五な
どを真空蒸着し、この上にアクリル樹−系着色透明塗料
を塗布する４のである。しかし、この方法によって得ら
れ九加飾表面は硬変が低くく、極めて傷つきやすいと−
う欠点があり、被加飾物の商品価値が低いという問題が
あった。このため、表面塗料に装置の向上が期待できる
架橋＊＊＊料を用いることが考えられたが、いずれｋし
ても有機塗料であるため、充分満足できる表部硬度及び
諸物性を得ることができなかった。Conventionally, the following method has been adopted as a method for adding metallic decoration to the surface of glass bottles, such as those of metal grade S. That is, the surface of the object to be decorated is first vacuum-deposited with aluminum or the like, and then an acrylic resin-based colored transparent paint is applied thereon. However, the decorated surface obtained by this method has low cirrhosis and is extremely susceptible to scratches.
However, there was a problem in that the commercial value of the decorated object was low. For this reason, it was considered to use a cross-linked material for the surface coating, which is expected to improve the equipment, but since it is an organic coating no matter what, it is difficult to obtain sufficiently satisfactory surface hardness and various physical properties. could not.
このｌｌ＠は上記事情に鑑みてなされたもので、ガラス
中金属などＯ被加飾物に硬変が極めて高く、したがって
傷つｔｉにくく、シかも外−が集麗なメタリッタ調０加
飾を施ヒすことのできる加飾方法を提供することを一的
とし、被加飾物表面に光沢金属膜を形成し％これを加熱
し九〇ち、ただちに有機金属化合物＊＊ｔｉｍ布し、有
機金属化合物を酸イヒし、光沢金属膜上に金属酸化物膜
を形成することを特徴とすゐ４０である。This ll@ was made in view of the above circumstances, and since hardening is extremely high in objects to be decorated such as metals in glass, metallitter-like decoration is applied that is hard to scratch and has a beautiful outer surface. The primary objective is to provide a decoration method that can be heated, and a shiny metal film is formed on the surface of the object to be decorated, heated, and immediately coated with an organometallic compound. I40 is characterized by forming a metal oxide film on the shiny metal film by immersing the metal in an acid.
以下、図面を参照してヒＯ尭明を詳細に説明する。Hereinafter, HiOyamei will be explained in detail with reference to the drawings.
第１１１１および第２ｍはζＯ尭嘴の加飾方法０−ガを
工１順に示した％Ｏ″ｅ６る。図中符号１はガラス、金
属、耐熱性プラスチックなどで所１１０形状に成形され
た被加飾物である。この被加飾物ＩＦｉ、通常の清浄化
処理が施されて、その表面が清浄化されている。この表
面の所定の加飾面１ａにはアル建ニウム、鋼、クロムな
どよりなる光沢金属膜２が形成される。この光沢金属膜
２の形成は、イオンブレーティング法によって行なわれ
、一般によく用いられる真空蒸着法は用いられない。こ
れは、次工程の加熱ａｍ、真空蒸着法による金属膜の密
着性が低いため、光沢金属膜２が移動し、光沢が低下す
るためである。No. 1111 and No. 2m are %O''e6 showing the decoration method 0-ga of ζO beak in order of process 1. In the figure, code 1 is a cover molded in the shape 110 of glass, metal, heat-resistant plastic, etc. It is a decorated object.This object to be decorated IFi has been subjected to a normal cleaning treatment to clean its surface.A predetermined decorated surface 1a of this surface is coated with aluminum, steel, chromium, etc. A shiny metal film 2 is formed.The formation of this shiny metal film 2 is carried out by the ion blating method, and the commonly used vacuum evaporation method is not used. This is because the adhesion of the metal film by the method is low, so the shiny metal film 2 moves and the gloss decreases.
このようＫして光沢金属１１２が形成された被加飾物１
は、ついで加熱処理される。この加熱は、通常の電気抵
抗炉などに被加飾物ｌを導入することによって行われる
が、光沢金属膜２の酸化劣化を防止するため非酸化性雰
囲気で実施することが好ましい。加熱温度は、次工程で
塗布される有機金属化合物の分解温度以上であって、か
つ被加飾物ｌの変形態ｆ（降伏１１以下であシ、通常は
２５０〜５００℃である。この加熱処理で被加飾物１は
所定のｍ度で充分加熱される。Decorated object 1 with shiny metal 112 formed in this way
is then heat treated. This heating is performed by introducing the object to be decorated into a normal electric resistance furnace or the like, but it is preferably performed in a non-oxidizing atmosphere to prevent oxidative deterioration of the shiny metal film 2. The heating temperature is higher than or equal to the decomposition temperature of the organometallic compound to be applied in the next step, and the deformation f (yield 11 or less) of the object to be decorated (yield 11 or lower) is usually 250 to 500°C.This heat treatment The object to be decorated 1 is sufficiently heated to a predetermined temperature of m degrees.
このようにして、充分加熱された被加飾物１゜光沢金属
膜２上には、ただちに有機金属化合物溶液３が塗布され
る。（ＩＥ２図）ここで用いられる有機金属化合物とし
ては、アセチルアセトンアル建ニウム、アセチルアセト
／りＣＩＡ、アセチルアセトン第２：Ｉパルト、アセチ
ルアセトン第２鉄。In this manner, the organometallic compound solution 3 is immediately applied onto the shiny metal film 2 of the object to be decorated 1° which has been sufficiently heated. (Figure IE2) The organometallic compounds used here include aluminum acetylacetone, acetylacetone/re-CIA, acetylacetone 2:I part, and ferric acetylacetone.
アセチルアセトンニッケルなどＯアセチルアセトン金属
塩、オクチル酸コバルト、オクチル酸マンガン、オクチ
ル酸鉛、オクチル酸亜鉛などのオクチル酸金属塩などが
用いられ、これらは有機溶剤によって適宜希釈され、有
機金属化合物溶液３とされる。この溶Ｉ［３は浸漬、噴
ｌ１１印刷、ハケ塗りなどＯ通常ｏＩｋ布手段に１って
光沢金属膜２上に塗布される。このようにして塗布され
た有機金属化合物溶液３は、被加飾物ｌが有機金属化合
物の分解温度以上に充分加熱されて−るので、急速に酸
化され、金属酸化物に変化し、光沢金属膜２上に金属酸
化物膜４が形成基れ％目的の加飾層器が得られる。Metal salts of acetylacetone such as nickel acetylacetone, metal salts of octylate such as cobalt octylate, manganese octylate, lead octylate, and zinc octylate are used, and these are appropriately diluted with an organic solvent to form an organometallic compound solution 3. Ru. This solution I3 is applied onto the bright metal film 2 by means of dipping, spray printing, brushing, etc., usually by means of an oIk cloth. The organometallic compound solution 3 applied in this manner is rapidly oxidized and transformed into a metal oxide as the object to be decorated 1 is sufficiently heated above the decomposition temperature of the organometallic compound, forming a shiny metal film. A metal oxide film 4 is formed on the base 2 to obtain a decorative layer.
このようにして得られ九金属酸化物膜４は、有機金属化
合物中の金属に起因する特有の色彩−を有し、かつ透明
であるので、下層の光沢金属膜４０金属光沢を表面に映
し出し、その結果非常に員麿なメタリック真の加飾層５
が形成、される、１覧上記属４略金属酸化物であるので
硬く、５したがって表面硬度が極めて高＜ ′ＩｋＤ
ｂ傷つきにくいものとなり、加飾層５も傷つきに、＜、
諭４のとなｈ商品価値の高いものとなる。The nine-metal oxide film 4 obtained in this way has a unique color caused by the metal in the organometallic compound and is transparent, so that the metallic luster of the underlying glossy metal film 40 is reflected on the surface. As a result, a very elegant metallic decoration layer 5
is formed, is a metal oxide in the above-mentioned group 4, and is therefore hard, and 5 therefore has an extremely high surface hardness <'IkD
b It becomes scratch resistant, and the decorative layer 5 also does not get scratched.
It will have a high commercial value.
そして、金属酸化物膜４が形成マれ九被加飾物１は、必
要に応じて被加飾物ｌ、の変形１膨（降伏ＩＬｆ）以下
のａ＆で加熱され、光沢金属１１２と金属酸化物膜４と
の密着性が向上させられる。。Then, the metal oxide film 4 is formed, and the object 1 to be decorated is heated at a temperature of less than 1 deformation expansion (yield ILf) of the object 1, if necessary, to form a shiny metal 112 and a metal oxide film. 4 is improved. .
なお、上記金属酸化物膜４０形成−かいて、−に被加飾
物１を加熱してから有轡金廊作会物１１１１ ４３を塗
布したのは、これらの工程を逆転する生加熱中に有機金
属化合一が昇華し九シ、あるいは酸素不足のため有機金
属化合物中の炭素が完全に酸化されず、光沢金属膜２上
に煤煙となって！！１９％外観を悪くすることがあるか
らである。ｔた、以上の実施例では被加飾物１の加飾面
全体に加飾層５を形成する場合にりいてａ＠Ｌ＊がこれ
に限らず、所望の図柄や文字などをこの加飾層５で、被
加飾物ｌ上に形成することができる。The reason why the metal oxide film 40 was formed by heating the object 1 to be decorated and then applying the coating material 1111 43 was because the organic material was added during raw heating to reverse these steps. The metal compound sublimates, or the carbon in the organometallic compound is not completely oxidized due to lack of oxygen, forming soot on the shiny metal film 2! ! This is because it may worsen the appearance by 19%. In addition, in the above embodiments, when forming the decorative layer 5 on the entire decorative surface of the object 1, a@L* is not limited to this, and desired designs, characters, etc. can be formed on this decorative layer. 5, it can be formed on the object l to be decorated.
以上説明したように、この発明の加飾方法祉、被加飾物
の加飾面に光沢金属膜を形成してから加゛熱し、ついで
ただちに光沢金属膜上に有機金属化合物溶液を塗布し、
有機金属化合物を酸化して光沢金属膜上に金属酸化物膜
を形成するものである。As explained above, the decoration method of the present invention includes forming a shiny metal film on the decorated surface of the object to be decorated, heating it, and then immediately applying an organometallic compound solution on the shiny metal film.
A metal oxide film is formed on a shiny metal film by oxidizing an organometallic compound.
し九がって、この加飾方法によれば、硬度が十分く高く
、シたがって極めて傷つきＫ＜＜、Ｌか４外観が集魔な
メタリックｌ！１１の加飾層を形成することができ、よ
って商品価値の高い加飾物を得石ことができる。Therefore, according to this decoration method, the hardness is sufficiently high, and therefore it is extremely scratch-resistant, and the appearance of L or 4 is attractive. 11 decorative layers can be formed, and therefore a decorated product with high commercial value can be obtained.
第１図および１１１１２１１はこの発明の加飾方法の一
例を工１１１［Ｋ示した概略断面図である。
ｌ・・・・・・被加飾物、２・−一・光沢金属膜、３・
・・・・・有機金属化合物溶液、４７−・金属酸化物膜
、５・・・・・・加飾層。1 and 1111211 are schematic cross-sectional views showing an example of the decorating method of the present invention. l... Decorated object, 2.-1. Shiny metal film, 3.
... Organometallic compound solution, 47-. Metal oxide film, 5 ... Decoration layer.
Claims (1)
加飾物を加熱し２０ち光だちに上記光沢金属膜上に有機
金属化合物溶液を塗布し、有−金属化合物を酸化して上
記光沢金属膜上に金属酸化物膜を形成させることを特徴
とする加飾方法。A shiny metal film is formed on the decorated surface of the object to be decorated, and then the object to be decorated is heated and an organometallic compound solution is applied onto the shiny metal film immediately after 20 minutes to oxidize the organic metal compound. A decorating method characterized by forming a metal oxide film on the shiny metal film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2307582A JPS58141389A (en) | 1982-02-16 | 1982-02-16 | Decorating method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2307582A JPS58141389A (en) | 1982-02-16 | 1982-02-16 | Decorating method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58141389A true JPS58141389A (en) | 1983-08-22 |
| JPH0159355B2 JPH0159355B2 (en) | 1989-12-15 |
Family
ID=12100277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2307582A Granted JPS58141389A (en) | 1982-02-16 | 1982-02-16 | Decorating method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58141389A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62182279A (en) * | 1986-02-05 | 1987-08-10 | Futaki Itsuo | Formation of inorganic film and solution therefor |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04334148A (en) * | 1991-05-09 | 1992-11-20 | Nec Corp | Telephone system |
| JPH0690309A (en) * | 1992-04-30 | 1994-03-29 | Murata Mach Ltd | Pc link for cellular telephone set |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4931767A (en) * | 1972-07-25 | 1974-03-22 |
-
1982
- 1982-02-16 JP JP2307582A patent/JPS58141389A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4931767A (en) * | 1972-07-25 | 1974-03-22 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62182279A (en) * | 1986-02-05 | 1987-08-10 | Futaki Itsuo | Formation of inorganic film and solution therefor |
| JPH0555600B2 (en) * | 1986-02-05 | 1993-08-17 | Suzuki Yasuo |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0159355B2 (en) | 1989-12-15 |
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