JPS5748961A - Preparation of 2,4-diaminobenzenesulfonic acid - Google Patents

Preparation of 2,4-diaminobenzenesulfonic acid

Info

Publication number
JPS5748961A
JPS5748961A JP12377080A JP12377080A JPS5748961A JP S5748961 A JPS5748961 A JP S5748961A JP 12377080 A JP12377080 A JP 12377080A JP 12377080 A JP12377080 A JP 12377080A JP S5748961 A JPS5748961 A JP S5748961A
Authority
JP
Japan
Prior art keywords
diaminobenzene
sulfonation
mass
solution
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12377080A
Other languages
Japanese (ja)
Other versions
JPS632256B2 (en
Inventor
Katsuaki Okawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP12377080A priority Critical patent/JPS5748961A/en
Publication of JPS5748961A publication Critical patent/JPS5748961A/en
Publication of JPS632256B2 publication Critical patent/JPS632256B2/ja
Granted legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the titled compound in high purity, by adding water to a sulfonation mass of metal-diaminobenzene, sagging the solution at 120W150°C, followed by subjecting disulfonic acid prepared as a by-product to demonosulfonation.
CONSTITUTION: In direct sulfonation of meta-diaminobenzene, water is added to a sulfonation mass, and disulfonic acid is desulfonated by heating the solution at 120W150°C, so that disulfonic acid is converted into the desired compound. The amount of water added to the reaction mass is an amount to give a sulfuric acid concentration in the reaction mass of 60W90wt%, preferably 70W85wt%. A solution of diaminobenzene in sulfuric acid in an amount 5 times as heavy as or more than that of diaminobenzene is used as the sulfonation mass. 65wt% fuming sulfuric acid is used as the sulfonating agent.
COPYRIGHT: (C)1982,JPO&Japio
JP12377080A 1980-09-05 1980-09-05 Preparation of 2,4-diaminobenzenesulfonic acid Granted JPS5748961A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12377080A JPS5748961A (en) 1980-09-05 1980-09-05 Preparation of 2,4-diaminobenzenesulfonic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12377080A JPS5748961A (en) 1980-09-05 1980-09-05 Preparation of 2,4-diaminobenzenesulfonic acid

Publications (2)

Publication Number Publication Date
JPS5748961A true JPS5748961A (en) 1982-03-20
JPS632256B2 JPS632256B2 (en) 1988-01-18

Family

ID=14868843

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12377080A Granted JPS5748961A (en) 1980-09-05 1980-09-05 Preparation of 2,4-diaminobenzenesulfonic acid

Country Status (1)

Country Link
JP (1) JPS5748961A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1400507A1 (en) * 2002-09-17 2004-03-24 Bayer Chemicals AG Process for the preparation of isolated 3,4-diaminobenzenesulfonic acid
CN102516137A (en) * 2011-12-08 2012-06-27 江苏远征化工有限公司 Production method of 2,
CN103553982A (en) * 2013-08-22 2014-02-05 上海鸿源鑫创材料科技有限公司 Preparation technology of 2,4-diaminobenzenesulfonic acid
CN108675946A (en) * 2018-06-21 2018-10-19 中北大学 A method of preparing 2,4- diamino benzene sulfonic acids

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5126395A (en) * 1990-03-08 1992-06-30 Basf Aktiengesellschaft Preparation of stable water-in-oil emulsions of hydrolyzed polymers of n-vinylamides
JPH08329634A (en) * 1995-05-31 1996-12-13 Nec Corp Magnetic head
CN100386312C (en) * 2006-07-18 2008-05-07 上海世景国际贸易有限公司 Process for synthesizing 2,4-diamino benzene sulfonic acid and its salt

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1400507A1 (en) * 2002-09-17 2004-03-24 Bayer Chemicals AG Process for the preparation of isolated 3,4-diaminobenzenesulfonic acid
US6787666B2 (en) 2002-09-17 2004-09-07 Bayer Chemicals Ag Process for the preparation of isolated 3,4-diaminobenzenesulphonic acid
CN102516137A (en) * 2011-12-08 2012-06-27 江苏远征化工有限公司 Production method of 2,
CN103553982A (en) * 2013-08-22 2014-02-05 上海鸿源鑫创材料科技有限公司 Preparation technology of 2,4-diaminobenzenesulfonic acid
CN108675946A (en) * 2018-06-21 2018-10-19 中北大学 A method of preparing 2,4- diamino benzene sulfonic acids

Also Published As

Publication number Publication date
JPS632256B2 (en) 1988-01-18

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