JPS5738742A - Preparation of 1,4-dihydroanthraquinone - Google Patents

Preparation of 1,4-dihydroanthraquinone

Info

Publication number
JPS5738742A
JPS5738742A JP11408080A JP11408080A JPS5738742A JP S5738742 A JPS5738742 A JP S5738742A JP 11408080 A JP11408080 A JP 11408080A JP 11408080 A JP11408080 A JP 11408080A JP S5738742 A JPS5738742 A JP S5738742A
Authority
JP
Japan
Prior art keywords
acid
pref
catalyst
solvent
sulfonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11408080A
Other languages
Japanese (ja)
Other versions
JPS6237618B2 (en
Inventor
Kazuya Nagaoka
Koji Kusabe
Keishirou Hata
Mikio Kaseda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawasaki Kasei Chemicals Ltd
Original Assignee
Kawasaki Kasei Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Kasei Chemicals Ltd filed Critical Kawasaki Kasei Chemicals Ltd
Priority to JP11408080A priority Critical patent/JPS5738742A/en
Publication of JPS5738742A publication Critical patent/JPS5738742A/en
Publication of JPS6237618B2 publication Critical patent/JPS6237618B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prepare the titled substance useful as a raw material of pesticides, etc., economically, in an industrial scale, by oxidizing 1,4,4a,9a-tetrahydroanthraquinone, etc. with molecular oxygen in a solvent using an organic acid such as aromatic sulfonic acid in place of a base as a catalyst.
CONSTITUTION: The titled compound is prepared by oxidizing 1,4,4a,9a-tetrahydroanthraquinone or 1,4-dihydroanthraquinone with molecular oxygen, in a polar organic solvent pref. acetic acid or ethanol, in the presence of an organic acid having a pK value of about ≤1 as a catalyst, pref. at 20W100°C. The catalyst is pref. an aromatic sulfonic acid such as benzenesulfonic acid, etc., or an aliphatic sulfonic acid such as methanesulfonic acid, etc. The amount of the catalyst is 0.01W 5%, pref. 0.02W2% of the solvent.
COPYRIGHT: (C)1982,JPO&Japio
JP11408080A 1980-08-21 1980-08-21 Preparation of 1,4-dihydroanthraquinone Granted JPS5738742A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11408080A JPS5738742A (en) 1980-08-21 1980-08-21 Preparation of 1,4-dihydroanthraquinone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11408080A JPS5738742A (en) 1980-08-21 1980-08-21 Preparation of 1,4-dihydroanthraquinone

Publications (2)

Publication Number Publication Date
JPS5738742A true JPS5738742A (en) 1982-03-03
JPS6237618B2 JPS6237618B2 (en) 1987-08-13

Family

ID=14628552

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11408080A Granted JPS5738742A (en) 1980-08-21 1980-08-21 Preparation of 1,4-dihydroanthraquinone

Country Status (1)

Country Link
JP (1) JPS5738742A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01121462A (en) * 1987-11-02 1989-05-15 Hory Corp Formwork for constructing water channel wall
US4981982A (en) * 1987-09-09 1991-01-01 Yoshio Yokoyama Condensation catalyst and catalytical condensation process for organic carboxylic anhydrides
JP2015528823A (en) * 2012-08-13 2015-10-01 アディファルム・エアドゥ Pharmaceutical formulations containing 3-formylrifamycin SV and 3- (4-cinnamyl-1-piperazinyl) amino derivatives of 3-formylrifamycin S and methods for their production

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4981982A (en) * 1987-09-09 1991-01-01 Yoshio Yokoyama Condensation catalyst and catalytical condensation process for organic carboxylic anhydrides
JPH01121462A (en) * 1987-11-02 1989-05-15 Hory Corp Formwork for constructing water channel wall
JP2015528823A (en) * 2012-08-13 2015-10-01 アディファルム・エアドゥ Pharmaceutical formulations containing 3-formylrifamycin SV and 3- (4-cinnamyl-1-piperazinyl) amino derivatives of 3-formylrifamycin S and methods for their production

Also Published As

Publication number Publication date
JPS6237618B2 (en) 1987-08-13

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