JPS57176932A - Preparation of carbonic acid ester - Google Patents
Preparation of carbonic acid esterInfo
- Publication number
- JPS57176932A JPS57176932A JP56061358A JP6135881A JPS57176932A JP S57176932 A JPS57176932 A JP S57176932A JP 56061358 A JP56061358 A JP 56061358A JP 6135881 A JP6135881 A JP 6135881A JP S57176932 A JPS57176932 A JP S57176932A
- Authority
- JP
- Japan
- Prior art keywords
- carbonate
- alkyl
- carbonic acid
- aryl
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare a carbonic acid ester, easily, by the ester exchange of an alkyl carbonate with an aromatic hydroxyl compound using a catalyst containing a non-corrosive and inexpensive lead compound or a phosphine and a chelating agent.
CONSTITUTION: An aryl carbonate and/or alkyl aryl carbonate (e.g. methyl phenyl carbonate) is prepared by the ester-exchange of an alkyl carbonate (e.g. dimethyl carbonate (with an aromatic hydroxyl compound (e.g. phenol) in the presence of a catalyst comprising a lead compound such as Pb(OAc)2, Pb(OAc)4, Pb(OH)2, PbCl2, PbO, PbCO3, etc. (Ac is acetyl). The reaction is preferably carried out in the presence of one or more additives selected from phosphines of formula R1R2R3P (R1WR3 are alkyl or aryl), chelating agents, and alkali halides.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56061358A JPS57176932A (en) | 1981-04-24 | 1981-04-24 | Preparation of carbonic acid ester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56061358A JPS57176932A (en) | 1981-04-24 | 1981-04-24 | Preparation of carbonic acid ester |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57176932A true JPS57176932A (en) | 1982-10-30 |
JPS643181B2 JPS643181B2 (en) | 1989-01-19 |
Family
ID=13168850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56061358A Granted JPS57176932A (en) | 1981-04-24 | 1981-04-24 | Preparation of carbonic acid ester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57176932A (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2608812A1 (en) * | 1986-12-23 | 1988-06-24 | Organo Synthese Ste Fse | PROCESS FOR THE PREPARATION OF ORGANIC CARBONATES BY TRANSESTERIFICATION |
US5354923A (en) * | 1990-11-16 | 1994-10-11 | Bayer Aktiengesellschaft | Process for the preparation of aromatic carbonic diesters |
EP1995233A2 (en) | 2007-05-25 | 2008-11-26 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
EP2036880A2 (en) | 2007-09-14 | 2009-03-18 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
EP2062868A2 (en) | 2007-11-20 | 2009-05-27 | Bayer MaterialScience AG | Process for purifying diaryl carbonates |
US7622601B2 (en) | 2004-10-14 | 2009-11-24 | Asahi Kasei Chemicals Corporation | Process for production of high-purity diaryl carbonate |
US7629485B2 (en) | 2004-12-21 | 2009-12-08 | Asahi Kasei Chemicals Corporation | Process for producing aromatic carbonate |
DE102008029514A1 (en) | 2008-06-21 | 2009-12-24 | Bayer Materialscience Ag | Process for the preparation of diaryl carbonates from dialkyl carbonates |
US7777067B2 (en) | 2004-07-13 | 2010-08-17 | Asahi Kasei Chemicals Corporation | Industrial process for production of an aromatic carbonate |
US7812189B2 (en) | 2004-08-25 | 2010-10-12 | Asahi Kasei Chemicals Corporation | Industrial process for production of high-purity diphenyl carbonate |
EP2239249A1 (en) | 2009-04-08 | 2010-10-13 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
US7919644B2 (en) | 2004-06-17 | 2011-04-05 | Asahi Kasei Chemicals Corporation | Process for producing an aromatic carbonate |
EP2322261A2 (en) | 2009-11-14 | 2011-05-18 | Bayer MaterialScience AG | Method for cleaning dialkyl carbonates |
US8138367B2 (en) | 2004-12-24 | 2012-03-20 | Asahi Kasei Chemicals Corporation | Process for production of aromatic carbonate |
DE102010042937A1 (en) | 2010-10-08 | 2012-04-12 | Bayer Materialscience Aktiengesellschaft | Process for the preparation of diaryl carbonates from dialkyl carbonates |
EP2650278A1 (en) | 2012-04-11 | 2013-10-16 | Bayer MaterialScience AG | Method for manufacturing diaryl carbonates from dialkyl carbonates |
WO2014095776A1 (en) | 2012-12-18 | 2014-06-26 | Bayer Materialscience Ag | Method for producing diaryl carbonate |
US9284254B2 (en) | 2012-09-20 | 2016-03-15 | Sabic Global Technologies B.V. | Process for the continuous manufacture of aryl alkyl carbonate and/or diaryl carbonate using vapor recompression |
-
1981
- 1981-04-24 JP JP56061358A patent/JPS57176932A/en active Granted
Cited By (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0274953A1 (en) * | 1986-12-23 | 1988-07-20 | Societe Francaise D'organo-Synthese | Process for the preparation of organic carbonates by transesterification |
FR2608812A1 (en) * | 1986-12-23 | 1988-06-24 | Organo Synthese Ste Fse | PROCESS FOR THE PREPARATION OF ORGANIC CARBONATES BY TRANSESTERIFICATION |
US5354923A (en) * | 1990-11-16 | 1994-10-11 | Bayer Aktiengesellschaft | Process for the preparation of aromatic carbonic diesters |
US7919644B2 (en) | 2004-06-17 | 2011-04-05 | Asahi Kasei Chemicals Corporation | Process for producing an aromatic carbonate |
US7777067B2 (en) | 2004-07-13 | 2010-08-17 | Asahi Kasei Chemicals Corporation | Industrial process for production of an aromatic carbonate |
US7812189B2 (en) | 2004-08-25 | 2010-10-12 | Asahi Kasei Chemicals Corporation | Industrial process for production of high-purity diphenyl carbonate |
US8044226B2 (en) | 2004-10-14 | 2011-10-25 | Asahi Kasei Chemicals Corporation | Process for production of high-purity diaryl carbonate |
US8044167B2 (en) | 2004-10-14 | 2011-10-25 | Asahi Kasei Chemicals Corporation | Process for production of high-purity diaryl carbonate |
US7622601B2 (en) | 2004-10-14 | 2009-11-24 | Asahi Kasei Chemicals Corporation | Process for production of high-purity diaryl carbonate |
US7629485B2 (en) | 2004-12-21 | 2009-12-08 | Asahi Kasei Chemicals Corporation | Process for producing aromatic carbonate |
US8138367B2 (en) | 2004-12-24 | 2012-03-20 | Asahi Kasei Chemicals Corporation | Process for production of aromatic carbonate |
EP1995233A2 (en) | 2007-05-25 | 2008-11-26 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
US8003817B2 (en) | 2007-05-25 | 2011-08-23 | Bayer Materialscience Ag | Process for the preparation of diaryl carbonates or arylalkyl carbonates from dialkyl carbonates |
DE102007044033A1 (en) | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Process for the preparation of diaryl or alkylaryl carbonates from dialkyl carbonates |
EP2036880A2 (en) | 2007-09-14 | 2009-03-18 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
DE102007055266A1 (en) | 2007-11-20 | 2009-05-28 | Bayer Materialscience Ag | Process for the purification of diaryl carbonates |
EP2062868A2 (en) | 2007-11-20 | 2009-05-27 | Bayer MaterialScience AG | Process for purifying diaryl carbonates |
DE102008029514A1 (en) | 2008-06-21 | 2009-12-24 | Bayer Materialscience Ag | Process for the preparation of diaryl carbonates from dialkyl carbonates |
US9040732B2 (en) | 2008-06-21 | 2015-05-26 | Bayer Materialscience Ag | Process for preparing diaryl carbonates from dialkyl carbonates |
US8952189B2 (en) | 2009-04-08 | 2015-02-10 | Bayer Materialscience Ag | Process for preparing diaryl carbonates or alkyl aryl carbonates from dialkyl carbonates |
DE102009016853A1 (en) | 2009-04-08 | 2010-10-14 | Bayer Materialscience Ag | Process for the preparation of diaryl or alkylaryl carbonates from dialkyl carbonates |
EP2239249A1 (en) | 2009-04-08 | 2010-10-13 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
DE102009053370A1 (en) | 2009-11-14 | 2011-05-19 | Bayer Materialscience Ag | Process for the purification of dialkyl carbonates |
EP2322261A2 (en) | 2009-11-14 | 2011-05-18 | Bayer MaterialScience AG | Method for cleaning dialkyl carbonates |
DE102010042937A1 (en) | 2010-10-08 | 2012-04-12 | Bayer Materialscience Aktiengesellschaft | Process for the preparation of diaryl carbonates from dialkyl carbonates |
US8304509B2 (en) | 2010-10-08 | 2012-11-06 | Bayer Intellectual Property Gmbh | Process for preparing diaryl carbonates from dialkyl carbonates |
EP2457891A1 (en) | 2010-10-08 | 2012-05-30 | Bayer MaterialScience AG | Method for manufacturing diaryl carbonates from dialkyl carbonates |
EP2650278A1 (en) | 2012-04-11 | 2013-10-16 | Bayer MaterialScience AG | Method for manufacturing diaryl carbonates from dialkyl carbonates |
US9284254B2 (en) | 2012-09-20 | 2016-03-15 | Sabic Global Technologies B.V. | Process for the continuous manufacture of aryl alkyl carbonate and/or diaryl carbonate using vapor recompression |
WO2014095776A1 (en) | 2012-12-18 | 2014-06-26 | Bayer Materialscience Ag | Method for producing diaryl carbonate |
US9765012B2 (en) | 2012-12-18 | 2017-09-19 | Covestro Deutschland Ag | Method for producing diaryl carbonate |
Also Published As
Publication number | Publication date |
---|---|
JPS643181B2 (en) | 1989-01-19 |
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