JPS57163360A - Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation - Google Patents

Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation

Info

Publication number
JPS57163360A
JPS57163360A JP56047785A JP4778581A JPS57163360A JP S57163360 A JPS57163360 A JP S57163360A JP 56047785 A JP56047785 A JP 56047785A JP 4778581 A JP4778581 A JP 4778581A JP S57163360 A JPS57163360 A JP S57163360A
Authority
JP
Japan
Prior art keywords
formula
bis
alkoxycarbonylmethyl
compound shown
aminosulphenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP56047785A
Other languages
Japanese (ja)
Other versions
JPS617416B2 (en
Inventor
Koji Soeda
Nobuyoshi Asai
Akira Tanaka
Takeshi Goto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Otsuka Chemical Co Ltd
Otsuka Kagaku Yakuhin KK
Original Assignee
Otsuka Chemical Co Ltd
Otsuka Kagaku Yakuhin KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Otsuka Chemical Co Ltd, Otsuka Kagaku Yakuhin KK filed Critical Otsuka Chemical Co Ltd
Priority to JP56047785A priority Critical patent/JPS57163360A/en
Priority to PH27023A priority patent/PH19220A/en
Priority to CA000399286A priority patent/CA1188706A/en
Priority to US06/361,931 priority patent/US4421693A/en
Priority to DE3211087A priority patent/DE3211087C2/en
Priority to AR288882A priority patent/AR230833A1/en
Priority to ZA822092A priority patent/ZA822092B/en
Priority to ES510885A priority patent/ES510885A0/en
Priority to NZ20982782A priority patent/NZ209827A/en
Priority to IT48109/82A priority patent/IT1147830B/en
Priority to GR67741A priority patent/GR75920B/el
Priority to BE0/207691A priority patent/BE892670A/en
Priority to NL8201290A priority patent/NL8201290A/en
Priority to MX192032A priority patent/MX160562A/en
Priority to OA57648A priority patent/OA07053A/en
Priority to SU823414098A priority patent/SU1243621A3/en
Priority to GB8209194A priority patent/GB2096994B/en
Priority to SE8202001A priority patent/SE456578B/en
Priority to CH1915/82A priority patent/CH653016A5/en
Priority to BR8201783A priority patent/BR8201783A/en
Priority to NZ200163A priority patent/NZ200163A/en
Priority to IL65384A priority patent/IL65384A/en
Priority to FR8205475A priority patent/FR2502616B1/en
Priority to TR21303A priority patent/TR21303A/en
Priority to IN354/CAL/82A priority patent/IN156106B/en
Priority to DD82238568A priority patent/DD204251A5/en
Priority to DD82246179A priority patent/DD208803A5/en
Priority to HU97282A priority patent/HU193263B/en
Priority to KR8201384A priority patent/KR880002299B1/en
Priority to AU82143/82A priority patent/AU545481B2/en
Priority to MA19629A priority patent/MA19424A1/en
Publication of JPS57163360A publication Critical patent/JPS57163360A/en
Priority to ES521601A priority patent/ES521601A0/en
Priority to IN357/MAS/84A priority patent/IN160648B/en
Priority to CA000453645A priority patent/CA1187089A/en
Publication of JPS617416B2 publication Critical patent/JPS617416B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/86—Benzo [b] furans; Hydrogenated benzo [b] furans with an oxygen atom directly attached in position 7

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Furan Compounds (AREA)

Abstract

NEW MATERIAL:A bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative shown by the formulaI(R is 1W6C alkyl, 3W6C cycloalkyl).
EXAMPLE: Bis(methoxycarbonylmethyl)aminosulphenyl chloride.
USE: An intermediate raw material for various kinds of reactions. Especially useful as an intermediate for preparing an insecticide. For example, a compound shown by the formulaIis reacted with a compound shown by the formula II to give a compound shown by the formula III useful as an insecticide.
PROCESS: An iminodiacetic ester shown by the formula IV is reacted with sulfur monochloride shown by the formula S2Cl2 or sulfur dichloride shown by the formula SCl2, to give a compound shown by the formulaI. The reaction is preferably carried out in the presence of a basic compound (e.g., TEA), the reaction temperature is usually -20W50°C, preferably 10W30°C, and the reaction proceeds quantitatively for 1W2hr.
COPYRIGHT: (C)1982,JPO&Japio
JP56047785A 1981-03-30 1981-03-30 Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation Granted JPS57163360A (en)

Priority Applications (34)

Application Number Priority Date Filing Date Title
JP56047785A JPS57163360A (en) 1981-03-30 1981-03-30 Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation
PH27023A PH19220A (en) 1981-03-30 1982-03-19 Aminosulfenyl chloride derivatives and process for preparing the same
CA000399286A CA1188706A (en) 1981-03-30 1982-03-24 Aminosulfenyl chloride derivatives, process for preparing the same
US06/361,931 US4421693A (en) 1981-03-30 1982-03-25 Aminosulfenyl chloride derivatives
DE3211087A DE3211087C2 (en) 1981-03-30 1982-03-25 Aminosulfenylchloridderivate, process for their preparation and their use
AR288882A AR230833A1 (en) 1981-03-30 1982-03-26 AMINOSULFENYLOLORIDE DERIVATIVES, PROCEDURE FOR THEIR PREPARATION AND PROCEDURE FOR THE PREPARATION OF USEFUL CARBAMATE DERIVATIVES AS INSECTICIDES, ACARICIDES AND NEMATOCIDES COMPOUNDS FROM THESE DERIVATIVES
ZA822092A ZA822092B (en) 1981-03-30 1982-03-26 Aminosulfenyl chloride derivatives,process for preparing the same,and process for preparing carbamate derivatives useful as insecticidal,miticidal or nematocidal compounds
ES510885A ES510885A0 (en) 1981-03-30 1982-03-27 PROCEDURE FOR PREPARING AMINOSULPHENYL CHLORIDE DERIVATIVES, USEFUL FOR INSECTICIDES
SE8202001A SE456578B (en) 1981-03-30 1982-03-29 AMINOSULPHENYL CHLORIDE DERIVATIVES, PROCEDURES FOR PREPARING THEREOF, AND PROCEDURES FOR PREPARING CARBAMAT DERIVATIVES USED AS INSECTICIDA, MITICIDA OR NEMATOCIDA COMPOUNDS
IT48109/82A IT1147830B (en) 1981-03-30 1982-03-29 AMINOSOLPHENYLCHLORIDE DERIVATIVES, PROCEDURE TO PREPARE THEM AS WELL AS TO PREPARE FROM THEIR CARBAMATE DERIVATIVES USEFUL AS PESTICIDES
GR67741A GR75920B (en) 1981-03-30 1982-03-29
BE0/207691A BE892670A (en) 1981-03-30 1982-03-29 AMINOSULFENYL CHLORIDE DERIVATIVES, PROCESS FOR THEIR PREPARATION AND PROCESS FOR THE PREPARATION OF CARBAMATE DERIVATIVES USEFUL AS INSECTICIDE, MITICIDE OR NEMATOCIDE COMPOUNDS
NL8201290A NL8201290A (en) 1981-03-30 1982-03-29 AMINOSULPHENYL CHLORIDE DERIVATIVES, METHOD FOR PREPARING THE SAME AND METHOD FOR PREPARING CARBAMATE DERIVATIVES, SUITABLE AS INSECTICIDES, MITICIDES OR NEMATOCIDES.
MX192032A MX160562A (en) 1981-03-30 1982-03-29 A PROCESS TO PREPARE ANINOSULPHENYL CHLORIDE DERIVATIVES
OA57648A OA07053A (en) 1981-03-30 1982-03-29 Aminosulphenyl chloride derivatives, process for their preparation, process for their preparation of carbamate derivatives useful as insecticides, miticides or nematocides.
SU823414098A SU1243621A3 (en) 1981-03-30 1982-03-29 Method of producing derivatives of aminosulfenylchloride
GB8209194A GB2096994B (en) 1981-03-30 1982-03-29 Aminosulfenyl chloride derivatives and process for preparing carbamate derivatives useful as ins
NZ20982782A NZ209827A (en) 1981-03-30 1982-03-29 Process for the preparation of 2,3-dihydro-2,2-dimethylbenzofuran-7-yl n-(n,n-disubstituted aminosulphenyl)-n-methyl carbamate derivatives
CH1915/82A CH653016A5 (en) 1981-03-30 1982-03-29 DERIVATIVES OF AMINOSULFENYL CHLORIDE, PROCESS FOR THE PREPARATION THEREOF AND USE OF SUCH DERIVATIVES FOR THE PREPARATION OF CARBAMATES.
BR8201783A BR8201783A (en) 1981-03-30 1982-03-29 AMINO-SULPHENYL CHLORIDE DERIVATIVE AND PROCESS FOR ITS PREPARATION PROCESS FOR PREPARATION OF CARBAMATE DERIVATIVE
NZ200163A NZ200163A (en) 1981-03-30 1982-03-29 Aminosulphenyl chloride derivatives and methods for their preparation
TR21303A TR21303A (en) 1981-03-30 1982-03-30 AMINOSULFENYL CHLORINE * R T * REVS, THE PROCEDURE FOR PREPARING THEM, AND THE PROCEDURE FOR PREPARING CARBOMATE T * REVS, SUITABLE FOR USE AS AN INTECTIVE, MYTHICID OR NEMATOCIDE COMPOUNDS.
KR8201384A KR880002299B1 (en) 1981-03-30 1982-03-30 Process for the preparation of aminosulfenyl chloride derivatives and carbamate derivatives
IL65384A IL65384A (en) 1981-03-30 1982-03-30 Aminosulfenyl chloride derivatives,their preparation and their use as intermediates for preparing carbamate derivatives
IN354/CAL/82A IN156106B (en) 1981-03-30 1982-03-30
DD82238568A DD204251A5 (en) 1981-03-30 1982-03-30 PROCESS FOR THE PREPARATION OF AMINOULOSE YL CHLORIDE DERIVATIVES
DD82246179A DD208803A5 (en) 1981-03-30 1982-03-30 METHOD OF PREPARING A 2,3-DIHYDRO-2,2-DIMETHYLBENZOFURAN-7-YL-N- (N, N-DISUBSTITUTED AMINOSULPHENYL) -N-METHYL CARBAMATE
HU97282A HU193263B (en) 1981-03-30 1982-03-30 Process for preparing amino-sulphenyl-chloride derivatives
FR8205475A FR2502616B1 (en) 1981-03-30 1982-03-30 AMINOSULFENYL CHLORIDES, PROCESS FOR THEIR PREPARATION AND THEIR USE IN THE PREPARATION OF CARBAMATES HAVING INSECTICIDE, MITICIDE OR NEMATOCIDE PROPERTIES
AU82143/82A AU545481B2 (en) 1981-03-30 1982-03-30 Aminosulfenyl chlorides and preparation of 7-benzofuryl- n-(aminosulfenyl)carbamates
MA19629A MA19424A1 (en) 1981-03-30 1982-03-30 SULFENYL CHLORIDES, PROCESS FOR THEIR PREPARATION AND THAT OF CARBAMATES AS ACARICIDE OR NEMATICIDE INSECTICIDE COMPOUNDS
ES521601A ES521601A0 (en) 1981-03-30 1983-03-31 METHOD OF OBTAINING N-METHYLCARBAMMATIC DERIVATIVES USEFUL FOR INSECTICIDES.
IN357/MAS/84A IN160648B (en) 1981-03-30 1984-03-17
CA000453645A CA1187089A (en) 1981-03-30 1984-05-04 Process for preparing carbamate derivatives useful as insecticidal, miticidal or nematocidal compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56047785A JPS57163360A (en) 1981-03-30 1981-03-30 Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation

Publications (2)

Publication Number Publication Date
JPS57163360A true JPS57163360A (en) 1982-10-07
JPS617416B2 JPS617416B2 (en) 1986-03-06

Family

ID=12785023

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56047785A Granted JPS57163360A (en) 1981-03-30 1981-03-30 Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation

Country Status (4)

Country Link
JP (1) JPS57163360A (en)
BE (1) BE892670A (en)
BR (1) BR8201783A (en)
ZA (1) ZA822092B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0087137A2 (en) * 1982-02-22 1983-08-31 FMC Corporation Trialkylamine/sulfur dioxide catalyzed sulfenylation of carbamates

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0087137A2 (en) * 1982-02-22 1983-08-31 FMC Corporation Trialkylamine/sulfur dioxide catalyzed sulfenylation of carbamates
EP0087137A3 (en) * 1982-02-22 1984-12-12 FMC Corporation Trialkylamine/sulfur dioxide catalyzed sulfenylation of carbamates

Also Published As

Publication number Publication date
BR8201783A (en) 1983-03-01
ZA822092B (en) 1983-05-25
BE892670A (en) 1982-07-16
JPS617416B2 (en) 1986-03-06

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