JPS57163360A - Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation - Google Patents
Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparationInfo
- Publication number
- JPS57163360A JPS57163360A JP56047785A JP4778581A JPS57163360A JP S57163360 A JPS57163360 A JP S57163360A JP 56047785 A JP56047785 A JP 56047785A JP 4778581 A JP4778581 A JP 4778581A JP S57163360 A JPS57163360 A JP S57163360A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- bis
- alkoxycarbonylmethyl
- compound shown
- aminosulphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/86—Benzo [b] furans; Hydrogenated benzo [b] furans with an oxygen atom directly attached in position 7
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Furan Compounds (AREA)
Abstract
NEW MATERIAL:A bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative shown by the formulaI(R is 1W6C alkyl, 3W6C cycloalkyl).
EXAMPLE: Bis(methoxycarbonylmethyl)aminosulphenyl chloride.
USE: An intermediate raw material for various kinds of reactions. Especially useful as an intermediate for preparing an insecticide. For example, a compound shown by the formulaIis reacted with a compound shown by the formula II to give a compound shown by the formula III useful as an insecticide.
PROCESS: An iminodiacetic ester shown by the formula IV is reacted with sulfur monochloride shown by the formula S2Cl2 or sulfur dichloride shown by the formula SCl2, to give a compound shown by the formulaI. The reaction is preferably carried out in the presence of a basic compound (e.g., TEA), the reaction temperature is usually -20W50°C, preferably 10W30°C, and the reaction proceeds quantitatively for 1W2hr.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (34)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56047785A JPS57163360A (en) | 1981-03-30 | 1981-03-30 | Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation |
PH27023A PH19220A (en) | 1981-03-30 | 1982-03-19 | Aminosulfenyl chloride derivatives and process for preparing the same |
CA000399286A CA1188706A (en) | 1981-03-30 | 1982-03-24 | Aminosulfenyl chloride derivatives, process for preparing the same |
US06/361,931 US4421693A (en) | 1981-03-30 | 1982-03-25 | Aminosulfenyl chloride derivatives |
DE3211087A DE3211087C2 (en) | 1981-03-30 | 1982-03-25 | Aminosulfenylchloridderivate, process for their preparation and their use |
AR288882A AR230833A1 (en) | 1981-03-30 | 1982-03-26 | AMINOSULFENYLOLORIDE DERIVATIVES, PROCEDURE FOR THEIR PREPARATION AND PROCEDURE FOR THE PREPARATION OF USEFUL CARBAMATE DERIVATIVES AS INSECTICIDES, ACARICIDES AND NEMATOCIDES COMPOUNDS FROM THESE DERIVATIVES |
ZA822092A ZA822092B (en) | 1981-03-30 | 1982-03-26 | Aminosulfenyl chloride derivatives,process for preparing the same,and process for preparing carbamate derivatives useful as insecticidal,miticidal or nematocidal compounds |
ES510885A ES510885A0 (en) | 1981-03-30 | 1982-03-27 | PROCEDURE FOR PREPARING AMINOSULPHENYL CHLORIDE DERIVATIVES, USEFUL FOR INSECTICIDES |
SE8202001A SE456578B (en) | 1981-03-30 | 1982-03-29 | AMINOSULPHENYL CHLORIDE DERIVATIVES, PROCEDURES FOR PREPARING THEREOF, AND PROCEDURES FOR PREPARING CARBAMAT DERIVATIVES USED AS INSECTICIDA, MITICIDA OR NEMATOCIDA COMPOUNDS |
IT48109/82A IT1147830B (en) | 1981-03-30 | 1982-03-29 | AMINOSOLPHENYLCHLORIDE DERIVATIVES, PROCEDURE TO PREPARE THEM AS WELL AS TO PREPARE FROM THEIR CARBAMATE DERIVATIVES USEFUL AS PESTICIDES |
GR67741A GR75920B (en) | 1981-03-30 | 1982-03-29 | |
BE0/207691A BE892670A (en) | 1981-03-30 | 1982-03-29 | AMINOSULFENYL CHLORIDE DERIVATIVES, PROCESS FOR THEIR PREPARATION AND PROCESS FOR THE PREPARATION OF CARBAMATE DERIVATIVES USEFUL AS INSECTICIDE, MITICIDE OR NEMATOCIDE COMPOUNDS |
NL8201290A NL8201290A (en) | 1981-03-30 | 1982-03-29 | AMINOSULPHENYL CHLORIDE DERIVATIVES, METHOD FOR PREPARING THE SAME AND METHOD FOR PREPARING CARBAMATE DERIVATIVES, SUITABLE AS INSECTICIDES, MITICIDES OR NEMATOCIDES. |
MX192032A MX160562A (en) | 1981-03-30 | 1982-03-29 | A PROCESS TO PREPARE ANINOSULPHENYL CHLORIDE DERIVATIVES |
OA57648A OA07053A (en) | 1981-03-30 | 1982-03-29 | Aminosulphenyl chloride derivatives, process for their preparation, process for their preparation of carbamate derivatives useful as insecticides, miticides or nematocides. |
SU823414098A SU1243621A3 (en) | 1981-03-30 | 1982-03-29 | Method of producing derivatives of aminosulfenylchloride |
GB8209194A GB2096994B (en) | 1981-03-30 | 1982-03-29 | Aminosulfenyl chloride derivatives and process for preparing carbamate derivatives useful as ins |
NZ20982782A NZ209827A (en) | 1981-03-30 | 1982-03-29 | Process for the preparation of 2,3-dihydro-2,2-dimethylbenzofuran-7-yl n-(n,n-disubstituted aminosulphenyl)-n-methyl carbamate derivatives |
CH1915/82A CH653016A5 (en) | 1981-03-30 | 1982-03-29 | DERIVATIVES OF AMINOSULFENYL CHLORIDE, PROCESS FOR THE PREPARATION THEREOF AND USE OF SUCH DERIVATIVES FOR THE PREPARATION OF CARBAMATES. |
BR8201783A BR8201783A (en) | 1981-03-30 | 1982-03-29 | AMINO-SULPHENYL CHLORIDE DERIVATIVE AND PROCESS FOR ITS PREPARATION PROCESS FOR PREPARATION OF CARBAMATE DERIVATIVE |
NZ200163A NZ200163A (en) | 1981-03-30 | 1982-03-29 | Aminosulphenyl chloride derivatives and methods for their preparation |
TR21303A TR21303A (en) | 1981-03-30 | 1982-03-30 | AMINOSULFENYL CHLORINE * R T * REVS, THE PROCEDURE FOR PREPARING THEM, AND THE PROCEDURE FOR PREPARING CARBOMATE T * REVS, SUITABLE FOR USE AS AN INTECTIVE, MYTHICID OR NEMATOCIDE COMPOUNDS. |
KR8201384A KR880002299B1 (en) | 1981-03-30 | 1982-03-30 | Process for the preparation of aminosulfenyl chloride derivatives and carbamate derivatives |
IL65384A IL65384A (en) | 1981-03-30 | 1982-03-30 | Aminosulfenyl chloride derivatives,their preparation and their use as intermediates for preparing carbamate derivatives |
IN354/CAL/82A IN156106B (en) | 1981-03-30 | 1982-03-30 | |
DD82238568A DD204251A5 (en) | 1981-03-30 | 1982-03-30 | PROCESS FOR THE PREPARATION OF AMINOULOSE YL CHLORIDE DERIVATIVES |
DD82246179A DD208803A5 (en) | 1981-03-30 | 1982-03-30 | METHOD OF PREPARING A 2,3-DIHYDRO-2,2-DIMETHYLBENZOFURAN-7-YL-N- (N, N-DISUBSTITUTED AMINOSULPHENYL) -N-METHYL CARBAMATE |
HU97282A HU193263B (en) | 1981-03-30 | 1982-03-30 | Process for preparing amino-sulphenyl-chloride derivatives |
FR8205475A FR2502616B1 (en) | 1981-03-30 | 1982-03-30 | AMINOSULFENYL CHLORIDES, PROCESS FOR THEIR PREPARATION AND THEIR USE IN THE PREPARATION OF CARBAMATES HAVING INSECTICIDE, MITICIDE OR NEMATOCIDE PROPERTIES |
AU82143/82A AU545481B2 (en) | 1981-03-30 | 1982-03-30 | Aminosulfenyl chlorides and preparation of 7-benzofuryl- n-(aminosulfenyl)carbamates |
MA19629A MA19424A1 (en) | 1981-03-30 | 1982-03-30 | SULFENYL CHLORIDES, PROCESS FOR THEIR PREPARATION AND THAT OF CARBAMATES AS ACARICIDE OR NEMATICIDE INSECTICIDE COMPOUNDS |
ES521601A ES521601A0 (en) | 1981-03-30 | 1983-03-31 | METHOD OF OBTAINING N-METHYLCARBAMMATIC DERIVATIVES USEFUL FOR INSECTICIDES. |
IN357/MAS/84A IN160648B (en) | 1981-03-30 | 1984-03-17 | |
CA000453645A CA1187089A (en) | 1981-03-30 | 1984-05-04 | Process for preparing carbamate derivatives useful as insecticidal, miticidal or nematocidal compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56047785A JPS57163360A (en) | 1981-03-30 | 1981-03-30 | Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57163360A true JPS57163360A (en) | 1982-10-07 |
JPS617416B2 JPS617416B2 (en) | 1986-03-06 |
Family
ID=12785023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56047785A Granted JPS57163360A (en) | 1981-03-30 | 1981-03-30 | Bis(alkoxycarbonylmethyl)aminosulphenyl chloride derivative and its preparation |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS57163360A (en) |
BE (1) | BE892670A (en) |
BR (1) | BR8201783A (en) |
ZA (1) | ZA822092B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0087137A2 (en) * | 1982-02-22 | 1983-08-31 | FMC Corporation | Trialkylamine/sulfur dioxide catalyzed sulfenylation of carbamates |
-
1981
- 1981-03-30 JP JP56047785A patent/JPS57163360A/en active Granted
-
1982
- 1982-03-26 ZA ZA822092A patent/ZA822092B/en unknown
- 1982-03-29 BR BR8201783A patent/BR8201783A/en not_active IP Right Cessation
- 1982-03-29 BE BE0/207691A patent/BE892670A/en not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0087137A2 (en) * | 1982-02-22 | 1983-08-31 | FMC Corporation | Trialkylamine/sulfur dioxide catalyzed sulfenylation of carbamates |
EP0087137A3 (en) * | 1982-02-22 | 1984-12-12 | FMC Corporation | Trialkylamine/sulfur dioxide catalyzed sulfenylation of carbamates |
Also Published As
Publication number | Publication date |
---|---|
BR8201783A (en) | 1983-03-01 |
ZA822092B (en) | 1983-05-25 |
BE892670A (en) | 1982-07-16 |
JPS617416B2 (en) | 1986-03-06 |
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