JPS57106631A - Preparation of alkylene glycol - Google Patents
Preparation of alkylene glycolInfo
- Publication number
- JPS57106631A JPS57106631A JP55181277A JP18127780A JPS57106631A JP S57106631 A JPS57106631 A JP S57106631A JP 55181277 A JP55181277 A JP 55181277A JP 18127780 A JP18127780 A JP 18127780A JP S57106631 A JPS57106631 A JP S57106631A
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- catalyst
- steps
- distillation
- recycling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as a raw material of polyester, etc., from alkylene oxide through alkylene carbonate, in high purity and yield, and economically in an industrial scale, by using proper catalyst and process.
CONSTITUTION: A monoalkylene glycol can be prepared by the following steps. (i) Reaction of an alkylene oxide with CO2 in the presence of the reaction intermediate (alkylene carbonate) and a carbonating catalyst (alkali metal halide). (ii) Separation of the produced liquid containing the intermediate into gas and liquid (10). (iii) Distillation of the liquid phase to separated the intermediate in the distillate, recovery (20) of the catalyst from the ?bottom in the form of the intermediate solution, and recycling of the recovered catalyst to the reactor 1. (iv) Recovery (58) of the unliquefied intermediate by cooling with an absorbing in the absorbing liquid. (v) Hydrolysis (28) of the intermediate mixture liquid obtained from the steps iii and iv with water in the presence of a fixed bed hydrolysis catalyst (activated alumina) to obtain a liquid containing the titled compound. (vi) Separation of the liquid into gas and liquid. (vii) Dehumidification (55) of the gaseous phase (CO2) of the steps ii and vi, and recycling to the reactor 1. (viii) Distillation and dehydration of the liquid produced in the step vi. (ix) Fractional distillation (44) of the hydedrated product.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55181277A JPS6059218B2 (en) | 1980-12-23 | 1980-12-23 | Method for producing alkylene glycol |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55181277A JPS6059218B2 (en) | 1980-12-23 | 1980-12-23 | Method for producing alkylene glycol |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57106631A true JPS57106631A (en) | 1982-07-02 |
JPS6059218B2 JPS6059218B2 (en) | 1985-12-24 |
Family
ID=16097874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55181277A Expired JPS6059218B2 (en) | 1980-12-23 | 1980-12-23 | Method for producing alkylene glycol |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6059218B2 (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6245584A (en) * | 1985-08-16 | 1987-02-27 | ヘキスト・アクチエンゲゼルシヤフト | Production of 2-oxo-1, 3-dioxolane |
JPH0232045A (en) * | 1988-07-22 | 1990-02-01 | Toagosei Chem Ind Co Ltd | Production of alkylene carbonate |
US5260495A (en) * | 1991-08-23 | 1993-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Monoalkylene glycol production using highly selective monoalkylene glycol catalysts |
EP0628553A1 (en) * | 1993-06-07 | 1994-12-14 | Bayer Ag | Reactor and continuously performed with it process for preparation of ethylene glycol carbonate or propylene glycol carbonate |
EP0628554A1 (en) * | 1993-06-07 | 1994-12-14 | Bayer Ag | Process for the preparation of propylene glycol carbonate |
EP0776890A2 (en) | 1995-11-30 | 1997-06-04 | Mitsubishi Chemical Corporation | Ethylene glycol process |
JP2006104095A (en) * | 2004-10-04 | 2006-04-20 | Asahi Kasei Chemicals Corp | Continuous manufacturing method of alkylene carbonate |
JP2006104093A (en) * | 2004-10-01 | 2006-04-20 | Asahi Kasei Chemicals Corp | Manufacturing method of alkylene carbonate |
JP2006104096A (en) * | 2004-10-04 | 2006-04-20 | Asahi Kasei Chemicals Corp | Purification method of ethylene carbonate |
US7453015B2 (en) | 2005-08-02 | 2008-11-18 | Shell Oil Company | Process for the preparation of alkylene glycols |
US7462748B2 (en) | 2006-09-07 | 2008-12-09 | Shell Oil Company | Process for the preparation of alkylene glycol |
US7465840B2 (en) | 2006-09-07 | 2008-12-16 | Shell Oil Company | Process for the preparation of alkylene glycol |
US7488835B2 (en) | 2005-08-02 | 2009-02-10 | Shell Oil Company | Process for the preparation of alkylene carbonates |
US7501531B2 (en) | 2006-08-03 | 2009-03-10 | Shell Oil Company | Process for the preparation of alkylene carbonate |
US7504545B2 (en) | 2006-09-15 | 2009-03-17 | Shell Oil Company | Process for the preparation of alkylene glycols |
JP2009513535A (en) * | 2003-06-30 | 2009-04-02 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Propylene carbonate production method |
US7674919B2 (en) | 2006-09-15 | 2010-03-09 | Shell Oil Company | Process for the preparation of alkylene carbonate |
WO2011065528A1 (en) * | 2009-11-30 | 2011-06-03 | 三菱化学株式会社 | Processes for producing ethylene carbonate and ethylene glycol |
US8569548B2 (en) | 2007-07-20 | 2013-10-29 | Shell Oil Company | Process for the preparation of alkylene glycols |
JP2013249244A (en) * | 2012-06-04 | 2013-12-12 | Osaka Gas Co Ltd | Method for refining carbon dioxide |
-
1980
- 1980-12-23 JP JP55181277A patent/JPS6059218B2/en not_active Expired
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6245584A (en) * | 1985-08-16 | 1987-02-27 | ヘキスト・アクチエンゲゼルシヤフト | Production of 2-oxo-1, 3-dioxolane |
JPH0232045A (en) * | 1988-07-22 | 1990-02-01 | Toagosei Chem Ind Co Ltd | Production of alkylene carbonate |
US5260495A (en) * | 1991-08-23 | 1993-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Monoalkylene glycol production using highly selective monoalkylene glycol catalysts |
EP0628554A1 (en) * | 1993-06-07 | 1994-12-14 | Bayer Ag | Process for the preparation of propylene glycol carbonate |
EP0628553A1 (en) * | 1993-06-07 | 1994-12-14 | Bayer Ag | Reactor and continuously performed with it process for preparation of ethylene glycol carbonate or propylene glycol carbonate |
EP0776890A2 (en) | 1995-11-30 | 1997-06-04 | Mitsubishi Chemical Corporation | Ethylene glycol process |
EP0776890A3 (en) * | 1995-11-30 | 1997-08-13 | Mitsubishi Chem Corp | Ethylene glycol process |
CN1068865C (en) * | 1995-11-30 | 2001-07-25 | 三菱化学株式会社 | Ethylene glycol process |
JP4657206B2 (en) * | 2003-06-30 | 2011-03-23 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Propylene carbonate production method |
JP2009513535A (en) * | 2003-06-30 | 2009-04-02 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Propylene carbonate production method |
JP2006104093A (en) * | 2004-10-01 | 2006-04-20 | Asahi Kasei Chemicals Corp | Manufacturing method of alkylene carbonate |
JP4624055B2 (en) * | 2004-10-01 | 2011-02-02 | 旭化成ケミカルズ株式会社 | Method for producing alkylene carbonate |
JP2006104096A (en) * | 2004-10-04 | 2006-04-20 | Asahi Kasei Chemicals Corp | Purification method of ethylene carbonate |
JP2006104095A (en) * | 2004-10-04 | 2006-04-20 | Asahi Kasei Chemicals Corp | Continuous manufacturing method of alkylene carbonate |
US7453015B2 (en) | 2005-08-02 | 2008-11-18 | Shell Oil Company | Process for the preparation of alkylene glycols |
US7488835B2 (en) | 2005-08-02 | 2009-02-10 | Shell Oil Company | Process for the preparation of alkylene carbonates |
US7501531B2 (en) | 2006-08-03 | 2009-03-10 | Shell Oil Company | Process for the preparation of alkylene carbonate |
US7462748B2 (en) | 2006-09-07 | 2008-12-09 | Shell Oil Company | Process for the preparation of alkylene glycol |
US7465840B2 (en) | 2006-09-07 | 2008-12-16 | Shell Oil Company | Process for the preparation of alkylene glycol |
US7674919B2 (en) | 2006-09-15 | 2010-03-09 | Shell Oil Company | Process for the preparation of alkylene carbonate |
US7504545B2 (en) | 2006-09-15 | 2009-03-17 | Shell Oil Company | Process for the preparation of alkylene glycols |
US8569548B2 (en) | 2007-07-20 | 2013-10-29 | Shell Oil Company | Process for the preparation of alkylene glycols |
WO2011065528A1 (en) * | 2009-11-30 | 2011-06-03 | 三菱化学株式会社 | Processes for producing ethylene carbonate and ethylene glycol |
JP5660048B2 (en) * | 2009-11-30 | 2015-01-28 | 三菱化学株式会社 | Process for producing ethylene carbonate and ethylene glycol |
JP2013249244A (en) * | 2012-06-04 | 2013-12-12 | Osaka Gas Co Ltd | Method for refining carbon dioxide |
Also Published As
Publication number | Publication date |
---|---|
JPS6059218B2 (en) | 1985-12-24 |
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