JPS5661433A - Prevention of exudation of plasticizer from soft vinyl chloride type resin molded product - Google Patents

Prevention of exudation of plasticizer from soft vinyl chloride type resin molded product

Info

Publication number
JPS5661433A
JPS5661433A JP13678379A JP13678379A JPS5661433A JP S5661433 A JPS5661433 A JP S5661433A JP 13678379 A JP13678379 A JP 13678379A JP 13678379 A JP13678379 A JP 13678379A JP S5661433 A JPS5661433 A JP S5661433A
Authority
JP
Japan
Prior art keywords
temperature
product
low
resin molded
molded product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13678379A
Other languages
Japanese (ja)
Other versions
JPS6034972B2 (en
Inventor
Kiyoshi Imada
Susumu Ueno
Yasuhide Nishina
Hirokazu Nomura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Chemical Co Ltd
Original Assignee
Shin Etsu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd
Priority to JP13678379A priority Critical patent/JPS6034972B2/en
Priority to GB8033751A priority patent/GB2061968B/en
Priority to NL8005813A priority patent/NL8005813A/en
Priority to DE19803039853 priority patent/DE3039853A1/en
Priority to FR8022544A priority patent/FR2467864B1/en
Publication of JPS5661433A publication Critical patent/JPS5661433A/en
Publication of JPS6034972B2 publication Critical patent/JPS6034972B2/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12Chemical modification
    • C08J7/123Treatment by wave energy or particle radiation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

PURPOSE: To steadily prevent exudation of plasticizer from a soft PVC type resin molded product, by placing the soft PVC type resin molded product within an internal electrode discharge type low-temperature plasma generator, maintaining the product at a specified temperature and treating the product with low-temperature plasma of an inorganic gas.
CONSTITUTION: A soft vinyl chloride type resin molded product is placed within an internal electrode discharge type low-temperature plasma generator. While the temperature of the product (T1°C) and the temperature of an input side electrode (T2°C) are maintained at temperatures represented by formulas I and II, the product is treated with low-temperature plasma of an inorganic gas at below 10 Torr. The input side electrode may be of the type of flat plate, net, coil or rod, but the type of electrode through which a heating medium can be passed to satisfy the temperature requirements is preferred. The low-pressure inorganic gas introduced into the low- temperature plasma generator is converted to plasma in the vicinity of the electrode, and the plasma generated reacts with the surface of the product placed within the generator to form a high-density crosslinked layer.
COPYRIGHT: (C)1981,JPO&Japio
JP13678379A 1979-10-23 1979-10-23 Method for preventing plasticizer elution from soft vinyl chloride resin molded products Expired JPS6034972B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP13678379A JPS6034972B2 (en) 1979-10-23 1979-10-23 Method for preventing plasticizer elution from soft vinyl chloride resin molded products
GB8033751A GB2061968B (en) 1979-10-23 1980-10-20 Method for preventing bleeding of plasticizers on the surface of a shaped article of plasticized polyvinyl chloride resin
NL8005813A NL8005813A (en) 1979-10-23 1980-10-22 METHOD FOR PREVENTING THE SCREAMING OF WEATHER MAKERS ON THE SURFACE OF A FORMED ARTICLE OF PLASTICATED POLYVINYL CHLORIDE RESIN
DE19803039853 DE3039853A1 (en) 1979-10-23 1980-10-22 METHOD FOR SUPPRESSING SOFTENER EXHAUST ON MOLDING SURFACES OF POLYVINYL CHLORIDE RESINS CONTAINING SOFTENERS
FR8022544A FR2467864B1 (en) 1979-10-23 1980-10-22 PROCESS FOR PREVENTING EXUDATION OF PLASTICIZERS ON THE SURFACE OF ARTICLES MADE OF PLASTICIZED POLYVINYL CHLORIDE RESINS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13678379A JPS6034972B2 (en) 1979-10-23 1979-10-23 Method for preventing plasticizer elution from soft vinyl chloride resin molded products

Publications (2)

Publication Number Publication Date
JPS5661433A true JPS5661433A (en) 1981-05-26
JPS6034972B2 JPS6034972B2 (en) 1985-08-12

Family

ID=15183407

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13678379A Expired JPS6034972B2 (en) 1979-10-23 1979-10-23 Method for preventing plasticizer elution from soft vinyl chloride resin molded products

Country Status (5)

Country Link
JP (1) JPS6034972B2 (en)
DE (1) DE3039853A1 (en)
FR (1) FR2467864B1 (en)
GB (1) GB2061968B (en)
NL (1) NL8005813A (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53114875A (en) * 1977-03-18 1978-10-06 Agency Of Ind Science & Technol Method for preventing elusion of plasticizer from polyvinyl chloride medical material

Also Published As

Publication number Publication date
FR2467864A1 (en) 1981-04-30
GB2061968B (en) 1983-05-18
JPS6034972B2 (en) 1985-08-12
GB2061968A (en) 1981-05-20
FR2467864B1 (en) 1985-11-22
DE3039853A1 (en) 1981-05-14
NL8005813A (en) 1981-04-27

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