JPS5632535A - Preparation of doped acetylene polymer - Google Patents
Preparation of doped acetylene polymerInfo
- Publication number
- JPS5632535A JPS5632535A JP10864179A JP10864179A JPS5632535A JP S5632535 A JPS5632535 A JP S5632535A JP 10864179 A JP10864179 A JP 10864179A JP 10864179 A JP10864179 A JP 10864179A JP S5632535 A JPS5632535 A JP S5632535A
- Authority
- JP
- Japan
- Prior art keywords
- acetylene polymer
- benzquinone
- derivative
- polymer
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatments Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PURPOSE: To obtain the titled polymer useful for a material for organic semiconductor, having a given adjusted electric conductance, by treating an acetylene polymer with an organic solvent solution of p-benzquinone derivative and making it dope.
CONSTITUTION: An acetylene polymer is treated with an organic solvent solution of a p-benzquinone derivative, preferably a derivative which has first reduction voltage (-E1/2) not more than -0.2V at 25°C measured in acetonitrile using LiClO4 as a supporting electrolyte and a saturated calomel electrode, more preferably with an organic solvent (e.g., benzone, etc.) solution of 2,3-dichloro-5,6- cicyano-p-benzquinone. After treatment, the acetylene polymer is removed from the solvent and dried in vacuum. Since doped acetylene polymer is unstable to oxygen, it is preferably handled in an inert gas.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10864179A JPS5632535A (en) | 1979-08-28 | 1979-08-28 | Preparation of doped acetylene polymer |
EP80103857A EP0022271B1 (en) | 1979-07-10 | 1980-07-07 | Doped polyacetylenes and their production |
DE8080103857T DE3069926D1 (en) | 1979-07-10 | 1980-07-07 | Doped polyacetylenes and their production |
US06/166,995 US4349664A (en) | 1979-07-10 | 1980-07-09 | Doped acetylene polymer and process for production thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10864179A JPS5632535A (en) | 1979-08-28 | 1979-08-28 | Preparation of doped acetylene polymer |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5632535A true JPS5632535A (en) | 1981-04-02 |
Family
ID=14489938
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10864179A Pending JPS5632535A (en) | 1979-07-10 | 1979-08-28 | Preparation of doped acetylene polymer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5632535A (en) |
-
1979
- 1979-08-28 JP JP10864179A patent/JPS5632535A/en active Pending
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