JPS56149407A - Polymerization of vinyl chloride monomer - Google Patents
Polymerization of vinyl chloride monomerInfo
- Publication number
- JPS56149407A JPS56149407A JP5276380A JP5276380A JPS56149407A JP S56149407 A JPS56149407 A JP S56149407A JP 5276380 A JP5276380 A JP 5276380A JP 5276380 A JP5276380 A JP 5276380A JP S56149407 A JPS56149407 A JP S56149407A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- chloride monomer
- monomer
- peroxydicarbonate
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To produce a polymer within a short time using a small amount of a catalyst, by suspension-polymerizing a vinyl chloride monomer with the aid of a mixed catalyst containing α-cumyl peroxyneodecanoate and a dialkyl peroxy-dicarbonate.
CONSTITUTION: One hundred (100) pts.wt. vinyl chloride monomer alone or mixture containing a predominant proportion of a vinyl chloride monomer and a monomer copolymerizable therewith is suspension-polymerized with the aid of 0.05W 0.15pt.wt. mixed catalyst containing, at a mol ratio of 1:0.1W0.8, α-cumyl peroxyneodecanoate and dialkyl peroxydicarbonate wherein the alkyl groups have 2W8 carbons, such as dibutoxyethyl peroxydicarbonate or diisopropyl peroxydicarbonate. It is possible to complete the polymerization within a short time. Besides, the PVC thus produced shows thermal stability comparable to that of PVC prepared by polyerizing the monomer for a long time by a conventionl process.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5276380A JPS56149407A (en) | 1980-04-21 | 1980-04-21 | Polymerization of vinyl chloride monomer |
GB8107827A GB2074589B (en) | 1980-04-21 | 1981-03-12 | Polymerisation of vinyl chloride |
DE19813113560 DE3113560A1 (en) | 1980-04-21 | 1981-04-03 | METHOD FOR POLYMERIZING VINYL CHLORIDE TYPE MONOMERS |
AU69103/81A AU538443B2 (en) | 1980-04-21 | 1981-04-06 | Catalytic polymerisation of vinyl chloride |
FR8107760A FR2480758A1 (en) | 1980-04-21 | 1981-04-17 | PROCESS FOR POLYMERIZING A MONOMER OF THE VINYL CHLORIDE TYPE IN THE PRESENCE OF PEROXIDE TYPE CATALYSTS |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5276380A JPS56149407A (en) | 1980-04-21 | 1980-04-21 | Polymerization of vinyl chloride monomer |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS56149407A true JPS56149407A (en) | 1981-11-19 |
Family
ID=12923909
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5276380A Pending JPS56149407A (en) | 1980-04-21 | 1980-04-21 | Polymerization of vinyl chloride monomer |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS56149407A (en) |
AU (1) | AU538443B2 (en) |
DE (1) | DE3113560A1 (en) |
FR (1) | FR2480758A1 (en) |
GB (1) | GB2074589B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5716006A (en) * | 1980-07-03 | 1982-01-27 | Mitsui Toatsu Chem Inc | Suspension polymerization of vinyl chloride |
JPS5898312A (en) * | 1981-12-08 | 1983-06-11 | Tokuyama Soda Co Ltd | Production of vinyl chloride polymer |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0096365A1 (en) * | 1982-06-07 | 1983-12-21 | Air Products And Chemicals, Inc. | Shortened reaction cycle times in vinyl chloride-propylene copolymerization |
JPS63289007A (en) * | 1987-05-21 | 1988-11-25 | Nippon Oil & Fats Co Ltd | Polymerization of vinyl chloride |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE315404B (en) * | 1963-05-15 | 1969-09-29 | Stockholms Superfosfat Fab Ab | |
DE1915386B2 (en) * | 1969-03-26 | 1977-02-10 | Basf Ag, 6700 Ludwigshafen | PROCESS FOR THE PREPARATION OF HOMOPOLYMERIZED OR MIXED POLYMERIZES OF VINYL CHLORIDE |
DE2139680B2 (en) * | 1971-08-07 | 1977-09-08 | Chemische Werke Hüls AG, 4370 Mari | PROCESS FOR THE PRODUCTION OF POLYMERIZED OR COPOLYMERIZED OF VINYL CHLORIDE |
US4192785A (en) * | 1977-06-08 | 1980-03-11 | E. R. Squibb & Sons, Inc. | Ostomy adhesive |
-
1980
- 1980-04-21 JP JP5276380A patent/JPS56149407A/en active Pending
-
1981
- 1981-03-12 GB GB8107827A patent/GB2074589B/en not_active Expired
- 1981-04-03 DE DE19813113560 patent/DE3113560A1/en not_active Withdrawn
- 1981-04-06 AU AU69103/81A patent/AU538443B2/en not_active Withdrawn - After Issue
- 1981-04-17 FR FR8107760A patent/FR2480758A1/en active Granted
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5716006A (en) * | 1980-07-03 | 1982-01-27 | Mitsui Toatsu Chem Inc | Suspension polymerization of vinyl chloride |
JPS621605B2 (en) * | 1980-07-03 | 1987-01-14 | Mitsui Toatsu Chemicals | |
JPS5898312A (en) * | 1981-12-08 | 1983-06-11 | Tokuyama Soda Co Ltd | Production of vinyl chloride polymer |
JPH0131762B2 (en) * | 1981-12-08 | 1989-06-28 | Tokuyama Soda Kk |
Also Published As
Publication number | Publication date |
---|---|
FR2480758B1 (en) | 1983-04-22 |
AU6910381A (en) | 1981-10-29 |
AU538443B2 (en) | 1984-08-16 |
GB2074589A (en) | 1981-11-04 |
FR2480758A1 (en) | 1981-10-23 |
GB2074589B (en) | 1983-08-24 |
DE3113560A1 (en) | 1982-04-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5514759A (en) | Multi-phase polymerization process | |
JPS57195714A (en) | Production of copolymer for paint | |
JPS56149407A (en) | Polymerization of vinyl chloride monomer | |
JPS5770112A (en) | Polymerization of fluorine-containing monomer | |
CN86102949A (en) | Method for shortstopping radical polymerization and stabilized resin composition | |
JPS57139104A (en) | Production of polyvinyl chloride | |
JPS57192412A (en) | Production of polyvinyl chloride composition | |
US4273702A (en) | Cobalt aluminate internal colorants for diol bis (allyl carbonate) | |
JPS5686911A (en) | Preparation of polyvinyl chloride having improved thermal stability | |
CA1133196A (en) | Process for the continuous manufacture of vinyl chloride polymers | |
JPS5757708A (en) | Production of aqueous vinylidene chloride polymer dispersion | |
JPS5523126A (en) | Heat-expandable resin composition | |
JPS5757705A (en) | Aqueous dispersion of high-crystallinity vinylidene chloride polymer | |
JPS57198717A (en) | Production of liquid prepolymer | |
JPS5641210A (en) | Preparation of vinyl chloride polymer | |
JPS5643325A (en) | Aqueous emulsion for modifying inorganic molding | |
JPS5450090A (en) | Preparation of vinyl chloride polymer | |
US3062900A (en) | Stabilization of polymerizable halogencontaining monomers with p-methoxy phenol | |
JPS5681317A (en) | Suspension polymerization of vinyl chloride | |
JPS5681315A (en) | Production of water-soluble bead polymer | |
JPS56813A (en) | Preparation of improved vinyl chloride resin | |
JPS5474889A (en) | Preparation of methyl methacrylate polymer | |
JPS5421488A (en) | Preparation of new urethane-vinyl ester resin | |
JPS5554305A (en) | Polymerization of vinyl chloride | |
JPS5753504A (en) | Emulsifying agent for emulsion polymerization |