JPS56108792A - 1-alkyl-4-hydroxymethyl-2,6,7-trioxabicyclo 2,2,2 octane - Google Patents

1-alkyl-4-hydroxymethyl-2,6,7-trioxabicyclo 2,2,2 octane

Info

Publication number
JPS56108792A
JPS56108792A JP1143280A JP1143280A JPS56108792A JP S56108792 A JPS56108792 A JP S56108792A JP 1143280 A JP1143280 A JP 1143280A JP 1143280 A JP1143280 A JP 1143280A JP S56108792 A JPS56108792 A JP S56108792A
Authority
JP
Japan
Prior art keywords
formula
alkyl
trioxabicyclo
octane
hydroxymethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1143280A
Other languages
Japanese (ja)
Other versions
JPS6043354B2 (en
Inventor
Kiyokazu Mizutani
Yoshihisa Ogasawara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toagosei Co Ltd
Original Assignee
Toagosei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toagosei Co Ltd filed Critical Toagosei Co Ltd
Priority to JP55011432A priority Critical patent/JPS6043354B2/en
Priority to US06/230,537 priority patent/US4425473A/en
Priority to DE19813103779 priority patent/DE3103779A1/en
Publication of JPS56108792A publication Critical patent/JPS56108792A/en
Publication of JPS6043354B2 publication Critical patent/JPS6043354B2/en
Expired legal-status Critical Current

Links

Abstract

NEW MATERIAL:A 1-alkyl-4-hydroxymethyl-2,6,7-trioxabicyclo[2,2,2]octane of formula I (R is lower alkyl).
USE: The compound shows volume expansion by polymerization, and is useful as a molding material, composite material, adhesive, casting material, and coating material. It has low strains, warpage, and lowering of adhesive force by shrinkage compared with the known compounds such as those of formula II.
PROCESS: The titled compound of formula I is prepared by the alcohol removal reaction of pentaerythritol of formula III with a trialkyl orthoacylate of formula IV in a proper solvent (e.g. di-n-octyl phthalate) in the presence of e.g. p-toluenesulfonic acid, etc.
COPYRIGHT: (C)1981,JPO&Japio
JP55011432A 1980-02-04 1980-02-04 1-alkynol-4-hydroxymethyl-2,6,7-trioxabicyclo[2,2,2]octane Expired JPS6043354B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP55011432A JPS6043354B2 (en) 1980-02-04 1980-02-04 1-alkynol-4-hydroxymethyl-2,6,7-trioxabicyclo[2,2,2]octane
US06/230,537 US4425473A (en) 1980-02-04 1981-02-02 Polymerizable bicyclic orthoester compounds
DE19813103779 DE3103779A1 (en) 1980-02-04 1981-02-04 POLYMERIZABLE BICYCLIC ORTHOESTER COMPOUNDS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55011432A JPS6043354B2 (en) 1980-02-04 1980-02-04 1-alkynol-4-hydroxymethyl-2,6,7-trioxabicyclo[2,2,2]octane

Publications (2)

Publication Number Publication Date
JPS56108792A true JPS56108792A (en) 1981-08-28
JPS6043354B2 JPS6043354B2 (en) 1985-09-27

Family

ID=11777911

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55011432A Expired JPS6043354B2 (en) 1980-02-04 1980-02-04 1-alkynol-4-hydroxymethyl-2,6,7-trioxabicyclo[2,2,2]octane

Country Status (1)

Country Link
JP (1) JPS6043354B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58109534A (en) * 1981-12-23 1983-06-29 Toagosei Chem Ind Co Ltd Curable composition
US4405798A (en) * 1981-03-30 1983-09-20 Celanese Corporation Acrylate and methacrylate monoesters of pentaerythritol and pentaerythritol orthoesters and polymers and copolymers derived therefrom
JPS60133025A (en) * 1983-12-22 1985-07-16 Tokuyama Soda Co Ltd Ring-opening of bicyclo compound
JP2005206843A (en) * 2004-01-23 2005-08-04 Bayer Materialscience Ag Binder containing orthoester

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1128963A (en) * 1966-08-22 1968-10-02 Grace W R & Co Novel orthoesters

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1128963A (en) * 1966-08-22 1968-10-02 Grace W R & Co Novel orthoesters

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405798A (en) * 1981-03-30 1983-09-20 Celanese Corporation Acrylate and methacrylate monoesters of pentaerythritol and pentaerythritol orthoesters and polymers and copolymers derived therefrom
JPS58109534A (en) * 1981-12-23 1983-06-29 Toagosei Chem Ind Co Ltd Curable composition
JPS6228973B2 (en) * 1981-12-23 1987-06-23 Toa Gosei Chem Ind
JPS60133025A (en) * 1983-12-22 1985-07-16 Tokuyama Soda Co Ltd Ring-opening of bicyclo compound
JPH0149373B2 (en) * 1983-12-22 1989-10-24 Tokuyama Soda Kk
JP2005206843A (en) * 2004-01-23 2005-08-04 Bayer Materialscience Ag Binder containing orthoester

Also Published As

Publication number Publication date
JPS6043354B2 (en) 1985-09-27

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