JPS55119445A - Desulfurization catalyst of petroleum base heavy hydrocarbon oil - Google Patents

Desulfurization catalyst of petroleum base heavy hydrocarbon oil

Info

Publication number
JPS55119445A
JPS55119445A JP2657079A JP2657079A JPS55119445A JP S55119445 A JPS55119445 A JP S55119445A JP 2657079 A JP2657079 A JP 2657079A JP 2657079 A JP2657079 A JP 2657079A JP S55119445 A JPS55119445 A JP S55119445A
Authority
JP
Japan
Prior art keywords
fine pore
diameters
pore volume
volume total
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2657079A
Other languages
Japanese (ja)
Other versions
JPH0117415B2 (en
Inventor
Hidehiro Azuma
Yasuo Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHOKUBAI KASEI KOGYO KK
JGC Catalysts and Chemicals Ltd
Original Assignee
SHOKUBAI KASEI KOGYO KK
Catalysts and Chemicals Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHOKUBAI KASEI KOGYO KK, Catalysts and Chemicals Industries Co Ltd filed Critical SHOKUBAI KASEI KOGYO KK
Priority to JP2657079A priority Critical patent/JPS55119445A/en
Publication of JPS55119445A publication Critical patent/JPS55119445A/en
Publication of JPH0117415B2 publication Critical patent/JPH0117415B2/ja
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/3023—Triangle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30242—Star
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30416—Ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/31—Size details
    • B01J2219/312—Sizes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

PURPOSE: To maintain the activity of the captioned catalyst, which is obtained by holding the specific fine pore distributions in the columnar catalysts comprising carrying hydrogenation components to porous alumina having petal-form cross sections, for a long time stably and reduce pressure losses.
CONSTITUTION: The desulfurization catalysts comprising carrying hydrogenation components on porous alumina are made into columnar bodies, wherein 3W6 circles of the same diameter as that of the central circle are disposed around the circle of diameters about 0.4W5mm in cross section at an equal angle, the center-to-center distance of the central circle and circumferential circles is made about 1/4W3/4 of the diameter of the central circle and the height of the columnar bodies is made about 2W15mm. Further, the fine pore distributions of the catalysts are measured with a N2 gas adsorption method and are so arranged that the mean diameters within the range of fine pore diameters 0W600Å are 100W130Å, that the fine pore volume total of diameters of 90W140Å becomes 70% or more of the fine pore volume total of diameters of 0W600Å and that the fine pore volume total having diameters of 0W60Å becomes 10% or less of the fine pore volume total of diameters of 0W600Å. Further, arrangement is so made that the fine pore distribution conditions measured with a mercury penetration method are satisfied as well.
COPYRIGHT: (C)1980,JPO&Japio
JP2657079A 1979-03-07 1979-03-07 Desulfurization catalyst of petroleum base heavy hydrocarbon oil Granted JPS55119445A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2657079A JPS55119445A (en) 1979-03-07 1979-03-07 Desulfurization catalyst of petroleum base heavy hydrocarbon oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2657079A JPS55119445A (en) 1979-03-07 1979-03-07 Desulfurization catalyst of petroleum base heavy hydrocarbon oil

Publications (2)

Publication Number Publication Date
JPS55119445A true JPS55119445A (en) 1980-09-13
JPH0117415B2 JPH0117415B2 (en) 1989-03-30

Family

ID=12197199

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2657079A Granted JPS55119445A (en) 1979-03-07 1979-03-07 Desulfurization catalyst of petroleum base heavy hydrocarbon oil

Country Status (1)

Country Link
JP (1) JPS55119445A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57195188A (en) * 1981-05-12 1982-11-30 Chevron Res Hydrogenation of hydrocarbon raw material and catalyst therefor
JPS58214346A (en) * 1982-05-28 1983-12-13 モ−ビル　オイル　コ−ポレ−ション Extrusion molded catalyst having hollow shape
US4517077A (en) * 1983-11-14 1985-05-14 Katalco Corporation Shaped catalyst particle for use in hydroprocessing of petroleum oils
JPS61287448A (en) * 1985-05-06 1986-12-17 アメリカン　サイアナミッド　カンパニ− Catalyst for hydroconverting heavy oil
JPS62197150A (en) * 1986-02-26 1987-08-31 Sumitomo Metal Mining Co Ltd Catalyst for hydro-desulfurization/hydrodenitrification of heavy hydrocarbon oil
JP2006505391A (en) * 2002-11-04 2006-02-16 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Long shaped particles, their use as catalyst or support
US7563745B2 (en) 2002-06-07 2009-07-21 Shell Oil Company Shaped catalyst particles for hydrocarbon synthesis
AU2008206983B2 (en) * 2007-01-18 2010-06-24 Shell Internationale Research Maatschappij B.V. Catalyst, catalyst precursor, catalyst carrier, preparation and use of thereof in Fischer-Tropsch synthesis
CN109718862A (en) * 2017-10-27 2019-05-07 中国石油化工股份有限公司 A kind of silicon-containing alumina carrier and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3814684A (en) * 1972-06-14 1974-06-04 Gulf Research Development Co Residue hydrodesulfurization process with catalysts whose pores have a small orifice size
JPS5420962A (en) * 1977-07-15 1979-02-16 Matsuyama Sekyu Kagaku Kk Combined distillation system
JPS5520962A (en) * 1978-08-03 1980-02-14 Shuichi Sakai Rolling roll

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3814684A (en) * 1972-06-14 1974-06-04 Gulf Research Development Co Residue hydrodesulfurization process with catalysts whose pores have a small orifice size
JPS5420962A (en) * 1977-07-15 1979-02-16 Matsuyama Sekyu Kagaku Kk Combined distillation system
JPS5520962A (en) * 1978-08-03 1980-02-14 Shuichi Sakai Rolling roll

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57195188A (en) * 1981-05-12 1982-11-30 Chevron Res Hydrogenation of hydrocarbon raw material and catalyst therefor
JPH0433835B2 (en) * 1981-05-12 1992-06-04 Chevron Res
JPH0420665B2 (en) * 1982-05-28 1992-04-06 Mobil Oil
JPS58214346A (en) * 1982-05-28 1983-12-13 モ−ビル　オイル　コ−ポレ−ション Extrusion molded catalyst having hollow shape
US4517077A (en) * 1983-11-14 1985-05-14 Katalco Corporation Shaped catalyst particle for use in hydroprocessing of petroleum oils
JPS61287448A (en) * 1985-05-06 1986-12-17 アメリカン　サイアナミッド　カンパニ− Catalyst for hydroconverting heavy oil
JPS62197150A (en) * 1986-02-26 1987-08-31 Sumitomo Metal Mining Co Ltd Catalyst for hydro-desulfurization/hydrodenitrification of heavy hydrocarbon oil
US7563745B2 (en) 2002-06-07 2009-07-21 Shell Oil Company Shaped catalyst particles for hydrocarbon synthesis
JP2006505391A (en) * 2002-11-04 2006-02-16 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Long shaped particles, their use as catalyst or support
AU2003298268B2 (en) * 2002-11-04 2007-11-29 Shell Internationale Research Maatschappij B.V. Elongated shaped particles; use as a catalyst or support thereof
US7811963B2 (en) 2002-11-04 2010-10-12 Shell Oil Company Elongated shaped particles use as a catalyst or support thereof
AU2008206983B2 (en) * 2007-01-18 2010-06-24 Shell Internationale Research Maatschappij B.V. Catalyst, catalyst precursor, catalyst carrier, preparation and use of thereof in Fischer-Tropsch synthesis
US7811966B2 (en) 2007-01-18 2010-10-12 Shell Oil Company Catalyst, catalyst precursor, and catalyst carrier
CN109718862A (en) * 2017-10-27 2019-05-07 中国石油化工股份有限公司 A kind of silicon-containing alumina carrier and preparation method thereof
CN109718862B (en) * 2017-10-27 2021-11-09 中国石油化工股份有限公司 Silicon-containing alumina carrier and preparation method thereof

Also Published As

Publication number Publication date
JPH0117415B2 (en) 1989-03-30

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