JPS5511576A - Substituted cyclopropanecarboxylic ester and insecticide containing the same as effective component - Google Patents

Substituted cyclopropanecarboxylic ester and insecticide containing the same as effective component

Info

Publication number
JPS5511576A
JPS5511576A JP7615279A JP7615279A JPS5511576A JP S5511576 A JPS5511576 A JP S5511576A JP 7615279 A JP7615279 A JP 7615279A JP 7615279 A JP7615279 A JP 7615279A JP S5511576 A JPS5511576 A JP S5511576A
Authority
JP
Japan
Prior art keywords
formula
rice
same
compound
substituted cyclopropanecarboxylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7615279A
Other languages
Japanese (ja)
Inventor
Sukeaki Omura
Fumio Mori
Yoshiji Fujita
Takuji Nishida
Takeo Hosogai
Tomio Wada
Fukuji Aihara
Hironobu Tamai
Kazuo Itoi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Publication of JPS5511576A publication Critical patent/JPS5511576A/en
Pending legal-status Critical Current

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  • Indole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Furan Compounds (AREA)
  • Pyrrole Compounds (AREA)

Abstract

NEW MATERIAL:Substituted cyclopropanecarboxylic esters of formula I (X is Cl, Br; Y is H, methyl; R is formula II and others; R1 is alkenyl, alkadienyl, alkynyl, benzyl).
EXAMPLE: 3-Phenoxybenzyl 2, 2-dimethyl-3-( 2, 2-dichloropropyl )cyclopropane carboxylate.
USE: Insecticide; it has effect on injurious insects in agriculture or horticulture as leafhopper, in rice storage as rice weevil and in sanitary as housfly and low toxicity against human, animals and fishes, being suitably applied to rice paddy because of its light stability.
PREPARATION: A compound of formula III (R' is lower alkyl) is hydrolyzed to form its free carboxylic acid, which is treated with a halogenation reagent as thionyl bromide to form the carboxyl halide of formula IV, on which an alcohol of ROH is made to act in the presence of a tertiary amine to give the compound of formula I.
COPYRIGHT: (C)1980,JPO&Japio
JP7615279A 1978-07-11 1979-06-15 Substituted cyclopropanecarboxylic ester and insecticide containing the same as effective component Pending JPS5511576A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US92354278A 1978-07-11 1978-07-11

Publications (1)

Publication Number Publication Date
JPS5511576A true JPS5511576A (en) 1980-01-26

Family

ID=25448855

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7615279A Pending JPS5511576A (en) 1978-07-11 1979-06-15 Substituted cyclopropanecarboxylic ester and insecticide containing the same as effective component

Country Status (1)

Country Link
JP (1) JPS5511576A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981002892A1 (en) * 1980-04-10 1981-10-15 Dainippon Jochugiku Kk Cyclopropanecarboxylic acid ester derivatives,process for their preparation,and insecticidal and acaricidal composition containing such as effective ingredients
EP0155819A2 (en) * 1984-03-15 1985-09-25 Btg International Limited Improvements relating to pesticides

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5283720A (en) * 1976-01-01 1977-07-12 Kuraray Co Ltd Substituted cyclopropanecarboxylic acid derivatives, and insecticides and acaricides containing a-substituted cyclopropanecarboxylic acid deri vatives
JPS5340743A (en) * 1976-09-21 1978-04-13 Roussel Uclaf Novel cyclopropane carboxylate ester containing polyhalogen substituent process for preparing same and agriclutural chemical composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5283720A (en) * 1976-01-01 1977-07-12 Kuraray Co Ltd Substituted cyclopropanecarboxylic acid derivatives, and insecticides and acaricides containing a-substituted cyclopropanecarboxylic acid deri vatives
JPS5340743A (en) * 1976-09-21 1978-04-13 Roussel Uclaf Novel cyclopropane carboxylate ester containing polyhalogen substituent process for preparing same and agriclutural chemical composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981002892A1 (en) * 1980-04-10 1981-10-15 Dainippon Jochugiku Kk Cyclopropanecarboxylic acid ester derivatives,process for their preparation,and insecticidal and acaricidal composition containing such as effective ingredients
EP0155819A2 (en) * 1984-03-15 1985-09-25 Btg International Limited Improvements relating to pesticides
JPS60209541A (en) * 1984-03-15 1985-10-22 ブリティッシュ・テクノロジー・グループ・リミテッド Insecticide

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