JPS5459213A - Oxidative synthesis of ester compounds - Google Patents
Oxidative synthesis of ester compoundsInfo
- Publication number
- JPS5459213A JPS5459213A JP10832978A JP10832978A JPS5459213A JP S5459213 A JPS5459213 A JP S5459213A JP 10832978 A JP10832978 A JP 10832978A JP 10832978 A JP10832978 A JP 10832978A JP S5459213 A JPS5459213 A JP S5459213A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- alcohol
- compound
- ester compounds
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain ester compounds economically in two steps; i.e. the reaction of a primary (secondary) alcohol with bis (tri-n-lower alkyl Sn) oxide, followed by the oxidation with an oxidizer such as haloamides using an aldehyde.
CONSTITUTION: A saturated aliphatic primary alcohol of formula I (R1=saturated aliphatic primary alkyl) or a secondary alcohol of formula II (R=alicyclic alkyl, etc.) is made to react with a molar equivalent or a small excess of bes (tri-n-lower alkyl Sn) oxide in an aprotic solvent, e.g. benzene, carbon tetrachloride, etc., at 0W200°C to afford the corresponding alkoxy Sn alkoxylate. After or without isolation, the compound is subjected to the oxidation with a molar equevalent or a small excess of a haloamide oxidizer, e.g. N-bromoacetamide, in the presence of an aldehyde compound, e.g. formaldehyde, in a non-polar solvent at- 50W100°C to produce an ester compound of formula IV or formula V.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10832978A JPS5459213A (en) | 1978-09-04 | 1978-09-04 | Oxidative synthesis of ester compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10832978A JPS5459213A (en) | 1978-09-04 | 1978-09-04 | Oxidative synthesis of ester compounds |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12802375A Division JPS5251309A (en) | 1975-10-24 | 1975-10-24 | Oxidative synthesis of aldehydes, ketones and esters |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5459213A true JPS5459213A (en) | 1979-05-12 |
JPS5628902B2 JPS5628902B2 (en) | 1981-07-04 |
Family
ID=14481930
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10832978A Granted JPS5459213A (en) | 1978-09-04 | 1978-09-04 | Oxidative synthesis of ester compounds |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5459213A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012020984A (en) * | 2010-07-16 | 2012-02-02 | Nippon Surfactant Kogyo Kk | Ester derivative and cosmetic containing the ester derivative, external preparation, coating material and ink composition |
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1978
- 1978-09-04 JP JP10832978A patent/JPS5459213A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5628902B2 (en) | 1981-07-04 |
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