JPH11513072A - カルバミン酸エステル添加剤を含む硬化性塗料組成物 - Google Patents
カルバミン酸エステル添加剤を含む硬化性塗料組成物Info
- Publication number
- JPH11513072A JPH11513072A JP10504437A JP50443798A JPH11513072A JP H11513072 A JPH11513072 A JP H11513072A JP 10504437 A JP10504437 A JP 10504437A JP 50443798 A JP50443798 A JP 50443798A JP H11513072 A JPH11513072 A JP H11513072A
- Authority
- JP
- Japan
- Prior art keywords
- coating composition
- curable coating
- group
- composition according
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/025—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1494—Polycondensates modified by chemical after-treatment followed by a further chemical treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 下記のものを含んでなることを特徴とする硬化性塗料組成物。 (a)活性水素含有官能基を含んでなる重合体樹脂、 (b)(a)上の前記官能基と反応し得る基を有する硬化剤、および (c)下記のものの反応生成物である、少なくとも1個のカルバミン酸エステル 基を含んでなる化合物。 (1)エポキシ基および有機酸基の間の開環反応により形成される水酸基 、および (2)シアン酸またはカルバミン酸エステル基。 2. 重合体樹脂(a)がカルバミン酸エステル活性水素官能基を含んでなる 、請求項1に記載の硬化性塗料組成物。 3. 重合体樹脂(a)がヒドロキシル活性水素官能基を含んでなる、請求項 1に記載の硬化性塗料組成物。 4. 硬化剤(b)がアミノプラストである、請求項1に記載の硬化性塗料組 成物。 5. アミノプラストがメラミンホルムアルデヒド樹脂である、請求項5に記 載の硬化性塗料組成物。 6. 化合物(c)が、塗料組成物中の総樹脂固体の3〜50重量%存在する 、請求項1に記載の硬化性塗料組成物。 7. 重合体樹脂(a)がアクリル酸エステルまたはメタクリル酸エステル重 合体である、請求項1に記載の硬化性塗料組成物。 8. 化合物(c)が単一のカルバミン酸エステル基を含んでなる、請求項1 に記載の硬化性塗料組成物。 9. 化合物(c)が少なくとも2個のカルバミン酸エステル基を含んでなる 、 請求項1に記載の硬化性塗料組成物。 10. 成分(a)、(b)、および(c)が有機溶剤媒体中に分散している 、請求項1に記載の硬化性塗料組成物。 11. 成分(a)、(b)、および(c)が水性媒体中に分散している、請 求項1に記載の硬化性塗料組成物。 12. 成分(a)、(b)、および(c)が粉末の形態にある、請求項1に 記載の硬化性塗料組成物。 13. 化合物(c)が下記構造のいずれか、またはそれらの組合せで表され る、請求項1に記載の硬化性塗料組成物。 (式中、nは少なくとも1の正の整数であり、R1はH、アルキルまたはシクロ アルキルを表し、R2はアルキル、アリールまたはシクロアルキルを表し、Xは 有機基を表す) 14. nが1である、請求項13に記載の硬化性塗料組成物。 15. nが2〜6の正の整数である、請求項13に記載の硬化性塗料組成物 。 16. VOCが3.8 lbs/ft3未満である、請求項1に記載の硬化性塗料組 成物。 17. VOCが3.0 lbs/ft3未満である、請求項6に記載の硬化性塗料組 成物。 18. VOCが2.0 lbs/ft3未満である、請求項7に記載の硬化性塗料組 成物。 19. VOCが1.0 lbs/ft3未満である、請求項8に記載の硬化性塗料組 成物。 20. 前記有機酸基がカルボキシル基である、請求項1に記載の硬化性塗料 組成物。 21. 請求項1に記載の塗料組成物の反応生成物を含んでなる、硬化済塗料 。 22. ASTM D523−89により規定される20°グロスが少なくと も80である、請求項21に記載の塗料。 23. ASTM E430−91により規定されるDOIが少なくとも80 である、請求項21に記載の塗料。 24. 透明塗料が請求項1に記載の塗料組成物に由来する複合材料カラー− プラス−クリア塗料。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2106896P | 1996-07-01 | 1996-07-01 | |
US60/021,068 | 1996-07-01 | ||
PCT/US1997/011516 WO1998000467A1 (en) | 1996-07-01 | 1997-07-01 | Curable coating compositions containing carbamate additives |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH11513072A true JPH11513072A (ja) | 1999-11-09 |
Family
ID=21802157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10504437A Pending JPH11513072A (ja) | 1996-07-01 | 1997-07-01 | カルバミン酸エステル添加剤を含む硬化性塗料組成物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US5872195A (ja) |
EP (1) | EP0847428A1 (ja) |
JP (1) | JPH11513072A (ja) |
KR (1) | KR19990044150A (ja) |
CN (1) | CN1196748A (ja) |
AU (1) | AU733800B2 (ja) |
BR (1) | BR9706561A (ja) |
CA (1) | CA2227961C (ja) |
MX (1) | MXPA98001339A (ja) |
WO (1) | WO1998000467A1 (ja) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6160058A (en) * | 1993-07-28 | 2000-12-12 | Basf Corporation | Curable coating compositions containing blends of carbamate-functional compounds |
US6084038A (en) * | 1993-07-28 | 2000-07-04 | Basf Corporation | Curable coating compositions containing blends of carbamate-functional compounds |
US5994479A (en) * | 1993-07-28 | 1999-11-30 | Basf Corporation | Curable coating compositions containing blends of carbamate-functional compounds |
US6080825A (en) * | 1993-07-28 | 2000-06-27 | Basf Corporation | Curable coating compositions containing blends of carbamate-functional compounds |
US6117931A (en) * | 1996-07-01 | 2000-09-12 | Basf Corporation | Curable coating compositions having improved effect pigment orientation and a method of using the same |
US6239212B1 (en) * | 1998-10-23 | 2001-05-29 | Basf Corporation. | Clearcoat composition and method for intercoat adhesion |
AU762753B2 (en) | 1999-03-17 | 2003-07-03 | E.I. Du Pont De Nemours And Company | High solids clear coating composition |
US6607833B1 (en) | 1999-03-17 | 2003-08-19 | E. I. Du Pont De Nemours And Company | High solids acid etch resistant clear coating composition |
US6855779B1 (en) | 1999-03-17 | 2005-02-15 | E. I. Du Pont De Nemours And Company | High solid epoxy, melamine and isocyanate compositions |
DE60001162T3 (de) | 1999-03-17 | 2007-02-15 | E.I. Dupont De Nemours And Co., Wilmington | Kratzfeste und säurekorrosionsbeständige klarlackzusammensetzung mit hohem feststoffgehalt |
ES2251369T3 (es) | 1999-03-17 | 2006-05-01 | E.I. Du Pont De Nemours And Company | Composicion de recubrimiento transparente de alto contenido en solidos. |
US6303690B1 (en) * | 1999-12-15 | 2001-10-16 | Basf Corporation | Cathodic electrocoat having a carbamate functional resin and a carbamate functional reactive additive |
US6362285B1 (en) * | 1999-12-15 | 2002-03-26 | Basf Corporation | Curable coating compositions containing carbamate functional reactive additives |
US6391968B1 (en) * | 1999-12-15 | 2002-05-21 | Basf Corporation | Curable coating compositions containing carbamate functional polymers and carbamate functional reactive additives |
US6380323B1 (en) | 1999-12-15 | 2002-04-30 | Basf Corporation | Electrocoat resin compositions containing carbamate functional resins having one or more quaternary ammonium groups and at least one carbamate functional reactive additive |
US6657007B2 (en) * | 2000-09-29 | 2003-12-02 | Basf Corporation | Clearcoat composition with improved adhesion |
US6541577B2 (en) * | 2000-12-06 | 2003-04-01 | Basf Corporation | Carbamate functional polymers and oligomers |
US7226971B2 (en) * | 2000-12-22 | 2007-06-05 | Basf Corporation | Polyester resin with carbamate functionality, a method of preparing the resin, and a coating composition utilizing the resin |
US6861150B2 (en) | 2001-02-26 | 2005-03-01 | Basf Corporation | Rheology control agent, a method of preparing the agent, and a coating composition utilizing the agent |
WO2003052012A1 (en) * | 2001-12-17 | 2003-06-26 | Basf Corporation | Asymmetric polyisocyanate monomers in urethane polymers and oligomers to reduce crystallinity |
WO2003052013A1 (en) * | 2001-12-17 | 2003-06-26 | Basf Corporation | Urethane polymers that reduce the effect of polylactone linkages |
GB0222522D0 (en) | 2002-09-27 | 2002-11-06 | Controlled Therapeutics Sct | Water-swellable polymers |
US7232863B2 (en) | 2002-10-31 | 2007-06-19 | Basf Corporation | Functional addition polymers and a method for their preparation |
US20040087728A1 (en) * | 2002-10-31 | 2004-05-06 | Donald Campbell | Carbamate functional addition polymers and a method for their preparation |
US20060100412A1 (en) * | 2003-02-28 | 2006-05-11 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. | Phenol urea/melamine formaldehyde copolymers, method for the production thereof and use of the same |
JP4553294B2 (ja) * | 2003-06-10 | 2010-09-29 | 関西ペイント株式会社 | 自動車車体外板用水性塗料及び複層塗膜形成方法 |
US8686090B2 (en) * | 2003-12-10 | 2014-04-01 | Basf Coatings Gmbh | Use of urea crystals for non-polymeric coatings |
GB0417401D0 (en) | 2004-08-05 | 2004-09-08 | Controlled Therapeutics Sct | Stabilised prostaglandin composition |
US20070123621A1 (en) * | 2005-09-15 | 2007-05-31 | Basf Corporation | Coating compositions with silylated diols |
US7858190B2 (en) * | 2005-09-15 | 2010-12-28 | Basf Coatings Gmbh | Thermosetting coating compositions with multiple cure mechanisms |
GB0613333D0 (en) | 2006-07-05 | 2006-08-16 | Controlled Therapeutics Sct | Hydrophilic polyurethane compositions |
GB0613638D0 (en) | 2006-07-08 | 2006-08-16 | Controlled Therapeutics Sct | Polyurethane elastomers |
US7807743B2 (en) * | 2006-09-22 | 2010-10-05 | Basf Corporation | Coating composition and film system therefrom |
GB0620685D0 (en) * | 2006-10-18 | 2006-11-29 | Controlled Therapeutics Sct | Bioresorbable polymers |
WO2011059994A2 (en) * | 2009-11-11 | 2011-05-19 | 3M Innovative Properties Company | Polymeric compositions and method of making and articles thereof |
DE102010051226A1 (de) | 2010-11-12 | 2012-05-31 | Dental Care Innovation Gmbh | Ausspültablete mit abrasiven Bestandteilen |
CA3051863C (en) | 2017-02-02 | 2023-12-19 | Water Pik, Inc. | Dental cleaning tablets comprising glycine as abrasive |
KR102245709B1 (ko) * | 2019-01-11 | 2021-04-28 | 주식회사 케이씨씨 | 수용성 베이스 코트 조성물 |
CN114806303B (zh) * | 2022-05-31 | 2023-05-30 | 东风商用车有限公司 | 一种适用于车身一次性喷涂成膜的清漆及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0680988A3 (en) * | 1984-02-17 | 1996-05-22 | Cytec Tech Corp | Carbamic acid ester derivatives and coating compositions containing them. |
US4520167A (en) * | 1984-02-17 | 1985-05-28 | American Cyanamid Co. | Hydroxyalkyl carbamate diluent for coating compositions and compositions containing the same |
US6165618A (en) * | 1994-11-03 | 2000-12-26 | Basf Corporation | Curable coating compositions containing carbamate resin and additives |
US5744550A (en) * | 1994-11-03 | 1998-04-28 | Basf Corporation | Curable coating compositions containing carbamate additives |
US5693723A (en) * | 1996-07-01 | 1997-12-02 | Basf Corporation | Low voc curable coating composition utilizing carbamate-functional compound |
-
1997
- 1997-07-01 CA CA002227961A patent/CA2227961C/en not_active Expired - Fee Related
- 1997-07-01 WO PCT/US1997/011516 patent/WO1998000467A1/en not_active Application Discontinuation
- 1997-07-01 BR BR9706561A patent/BR9706561A/pt active Search and Examination
- 1997-07-01 AU AU35903/97A patent/AU733800B2/en not_active Ceased
- 1997-07-01 CN CN97190790.0A patent/CN1196748A/zh active Pending
- 1997-07-01 KR KR1019980701383A patent/KR19990044150A/ko not_active Application Discontinuation
- 1997-07-01 US US08/886,321 patent/US5872195A/en not_active Expired - Fee Related
- 1997-07-01 EP EP97932441A patent/EP0847428A1/en not_active Withdrawn
- 1997-07-01 JP JP10504437A patent/JPH11513072A/ja active Pending
- 1997-07-01 MX MXPA98001339A patent/MXPA98001339A/es unknown
Also Published As
Publication number | Publication date |
---|---|
CA2227961A1 (en) | 1998-01-08 |
CA2227961C (en) | 2003-09-30 |
BR9706561A (pt) | 1999-07-20 |
WO1998000467A1 (en) | 1998-01-08 |
KR19990044150A (ko) | 1999-06-25 |
AU3590397A (en) | 1998-01-21 |
AU733800B2 (en) | 2001-05-24 |
CN1196748A (zh) | 1998-10-21 |
MXPA98001339A (es) | 2004-10-07 |
US5872195A (en) | 1999-02-16 |
EP0847428A1 (en) | 1998-06-17 |
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