JPH1143651A - Luminous adhesive film - Google Patents

Luminous adhesive film

Info

Publication number
JPH1143651A
JPH1143651A JP20143397A JP20143397A JPH1143651A JP H1143651 A JPH1143651 A JP H1143651A JP 20143397 A JP20143397 A JP 20143397A JP 20143397 A JP20143397 A JP 20143397A JP H1143651 A JPH1143651 A JP H1143651A
Authority
JP
Japan
Prior art keywords
luminous
pressure
sensitive adhesive
film
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20143397A
Other languages
Japanese (ja)
Inventor
Shigeru Ueno
繁 上野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP20143397A priority Critical patent/JPH1143651A/en
Publication of JPH1143651A publication Critical patent/JPH1143651A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To produce a luminous adhesive film easily at a low cost by imparting luminous properties to a pressure-sensitive adhesive of an adhesive layer by adding a luminous pigment thereto. SOLUTION: A luminous film (a) is obtd. by forming an adhesive layer 7 contg. a luminous pigment on one side of a clear film 1 and sticking a separator 5 to the adhesive layer 7. A luminous adhesive film (b) is obtd. by sandwiching an adhesive layer 7 contg. a luminous pigment between a clear film and a white film 3, forming a normal adhesive layer 4 on the side of the white film 3, and sticking thereto a separator 5. The clear film used is selected form films of a polyester, a polycarbonate, polyvinyl chloride, etc., and has a thickness of 12-200 μm. Pref., the adhesive is a clear, solvent-dilutable one such as of an acrylic or rubber-based type. Dysprosium- or europium-activated strontium aluminate. zinc sulfide, etc., are used as the luminous pigment.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、各種建材、照明、
玩具等の分野、例えば、矢印等の表示板、イルミネーシ
ョン、非常サイン、カバーパーツ等のパーツ、スイッ
チ、街灯、シール、ワッペン、アクセサリー等に用いら
れる夜光性(蛍光性等の夜間発光性)を有する粘着フィ
ルムに関する。
The present invention relates to various building materials, lighting,
It has luminous properties (night luminous properties such as fluorescent properties) used in toys and other fields, for example, display boards such as arrows, illuminations, emergency signs, parts such as cover parts, switches, street lights, seals, patches, accessories and the like. It relates to an adhesive film.

【0002】[0002]

【従来の技術】従来の夜光性粘着フィルムとしては、次
のような構成のものがある。 図2(a)に示す如く、透明フィルム1と白色フィ
ルム3との間に夜光剤層2を形成した積層フィルムの白
色フィルム3側に粘着剤層4を形成したもの。 図2(b)に示す如く、フィルムの樹脂自体に夜光
顔料を練り込み、この夜光顔料練り込みフィルム6に粘
着剤層4を形成したもの。 図2(c)に示す如く、透明フィルム1に夜光剤層
2と粘着剤層4を積層形成したもの。 なお、図2(a)〜(c)において、5はセパレータ
(離型紙)である。
2. Description of the Related Art A conventional luminous pressure-sensitive adhesive film has the following structure. As shown in FIG. 2A, a laminated film in which a luminous agent layer 2 is formed between a transparent film 1 and a white film 3 and an adhesive layer 4 is formed on the white film 3 side. As shown in FIG. 2B, a luminous pigment is kneaded into the resin itself of the film, and the adhesive layer 4 is formed on the luminous pigment kneaded film 6. As shown in FIG. 2C, a transparent film 1 having a luminous agent layer 2 and an adhesive layer 4 laminated thereon. In FIGS. 2A to 2C, reference numeral 5 denotes a separator (release paper).

【0003】[0003]

【発明が解決しようとする課題】上記従来の夜光性粘着
フィルムのうち、図2(a),(c)に示すような夜光
剤層と粘着剤層とを設けたものでは、夜光剤層をラミネ
ートすることによる夜光剤層の形成と、粘着剤を塗工、
乾燥することによる粘着剤層の形成の2つの異なる工程
を経なければならず、製造工程が煩雑である。
Among the above-mentioned conventional luminous pressure-sensitive adhesive films, those provided with a luminous agent layer and an adhesive layer as shown in FIGS. The formation of a luminous agent layer by laminating, and the application of an adhesive,
It is necessary to go through two different steps of forming the pressure-sensitive adhesive layer by drying, and the manufacturing process is complicated.

【0004】夜光顔料練り込みフィルムを用いたもので
あれば、粘着剤層形成工程のみで良いが、夜光顔料練り
込みフィルムの製造のための設計が必要となり、装置設
備コストが高騰するなどの欠点がある。
In the case of using a luminous pigment kneaded film, only the pressure-sensitive adhesive layer forming step is sufficient. However, a design for manufacturing the luminous pigment kneaded film is required, and disadvantages such as an increase in equipment cost are required. There is.

【0005】本発明は上記従来の問題点を解決し、容易
かつ安価に製造することができる夜光性粘着フィルムを
提供することを目的とする。
An object of the present invention is to solve the above-mentioned conventional problems and to provide a luminescent adhesive film which can be easily and inexpensively manufactured.

【0006】[0006]

【課題を解決するための手段】本発明の夜光性粘着フィ
ルムは、表面に粘着剤層が形成された粘着フィルムにお
いて、該粘着剤層の粘着剤に夜光顔料を添加して夜光性
を付与したことを特徴とする。
The luminous pressure-sensitive adhesive film of the present invention is a pressure-sensitive adhesive film having a pressure-sensitive adhesive layer formed on the surface thereof, wherein a luminous pigment is added to the pressure-sensitive adhesive of the pressure-sensitive adhesive layer to impart luminous properties. It is characterized by the following.

【0007】夜光顔料を添加した粘着剤を用いることに
より、粘着剤層の形成と夜光性の付与とを同時に行うこ
とができるため、1工程で夜光性粘着フィルムを製造す
ることができる。
By using a pressure-sensitive adhesive to which a luminous pigment is added, the formation of a pressure-sensitive adhesive layer and the provision of luminous properties can be performed simultaneously, so that a luminous pressure-sensitive adhesive film can be produced in one step.

【0008】本発明では、夜光顔料を粘着剤に添加、混
練する工程が必要となるが、この工程は、夜光剤層形成
工程よりもはるかに簡易な工程であり、また、フィルム
製造時にフィルム樹脂に夜光顔料を練り込むよりも極め
て容易に行える。
In the present invention, a step of adding and kneading the luminous pigment to the pressure-sensitive adhesive is required. This step is much simpler than the luminous agent layer forming step. It is much easier than kneading luminous pigments into

【0009】なお、本発明において夜光顔料とは螢光顔
料、蓄光顔料等の発光顔料である。
In the present invention, the luminous pigment is a luminescent pigment such as a fluorescent pigment or a luminous pigment.

【0010】本発明において、フィルムは、ポリエステ
ル、ポリカーボネート又は塩化ビニルよりなる透明フィ
ルムであることが好ましい。
In the present invention, the film is preferably a transparent film made of polyester, polycarbonate or vinyl chloride.

【0011】また、粘着剤としてはアクリル系又はゴム
系の溶剤希釈型透明粘着剤が好ましい。
As the pressure-sensitive adhesive, an acrylic or rubber-based solvent-dilutable transparent pressure-sensitive adhesive is preferable.

【0012】また、夜光顔料としては、ジスプロシウム
又はユウロピウムで賦活されたアルミン酸ストロンチウ
ムよりなる平均粒径4〜50μmのものが好ましく、夜
光顔料は、粘着剤の乾燥重量に対して5〜100重量%
添加するのが好ましい。
The luminous pigment is preferably strontium aluminate activated with dysprosium or europium and has an average particle diameter of 4 to 50 μm. The luminous pigment is 5 to 100% by weight based on the dry weight of the adhesive.
It is preferred to add.

【0013】[0013]

【発明の実施の形態】以下に本発明の実施の形態を詳細
に説明する。
Embodiments of the present invention will be described below in detail.

【0014】図1(a),(b)は本発明の夜光性粘着
フィルムの実施の形態を示す断面図である。
FIGS. 1A and 1B are cross-sectional views showing an embodiment of the luminescent adhesive film of the present invention.

【0015】図1(a)の夜光性粘着フィルムは、透明
フィルム1の一方の面に、夜光顔料を添加した粘着剤層
7を形成し、セパレータ5を張り合わせたものである。
The luminous pressure-sensitive adhesive film shown in FIG. 1A is obtained by forming a luminous pigment-added pressure-sensitive adhesive layer 7 on one surface of a transparent film 1 and laminating a separator 5 thereon.

【0016】透明フィルム1としては、ポリエステル、
ポリカーボネート、塩化ビニル等からなる厚さ12〜2
00μm程度のフィルムを用いることができる。この透
明フィルムの表面には印刷等によりマークや模様等を付
与しても良く、また、フィルム自体に着色を付与しても
良い。
As the transparent film 1, polyester,
Thickness of 12 to 2 made of polycarbonate, vinyl chloride, etc.
A film of about 00 μm can be used. Marks or patterns may be provided on the surface of the transparent film by printing or the like, or coloring may be provided on the film itself.

【0017】粘着剤としては、従来、一般の粘着フィル
ムに用いられているものを用いることができ、特にアク
リル系、ゴム系等の溶剤希釈型の透明粘着剤が好まし
い。
As the pressure-sensitive adhesive, those conventionally used for general pressure-sensitive adhesive films can be used, and particularly, a solvent-dilutable transparent pressure-sensitive adhesive such as an acrylic or rubber-based adhesive is preferable.

【0018】粘着剤に添加する夜光顔料としては、粘着
剤に練り込んでもその夜光性を安定に維持し得る、化学
的に安定なものが好ましく、また、少量の添加で良好な
夜光性を示す高輝度で蓄光性の高いものが好ましい。
The luminous pigment to be added to the pressure-sensitive adhesive is preferably a chemically stable pigment which can stably maintain the luminosity even when kneaded into the pressure-sensitive adhesive, and exhibits good luminosity when added in a small amount. Those having high luminance and high light storage properties are preferable.

【0019】このような夜光顔料としては、ジスプロシ
ウム,ユウロピウムで賦活されたアルミン酸ストロンチ
ウム、その他硫化亜鉛等が挙げられる。
Examples of such a luminous pigment include strontium aluminate activated with dysprosium and europium, and zinc sulfide.

【0020】夜光顔料の粒径は、過度に小さいと輝度が
低下し、十分な夜光性が得られず、過度に大きいと粘着
剤中への分散性が悪くなったり、粘着剤層から脱落し易
くなったりする。このため、夜光顔料の平均粒径は4〜
50μmであることが好ましい。
If the particle size of the luminous pigment is excessively small, the brightness decreases, and sufficient luminous property cannot be obtained. If the particle size is excessively large, dispersibility in the pressure-sensitive adhesive becomes poor, or the pigment falls off the pressure-sensitive adhesive layer. It becomes easy. Therefore, the average particle size of the luminous pigment is 4 to
It is preferably 50 μm.

【0021】粘着剤に対する夜光顔料の添加量は、当該
夜光性粘着フィルムに応じ、必要とする夜光性の程度に
よって決定されるが、添加量が少な過ぎると十分な夜光
性が得られず、多過ぎると相対的に粘着剤量が少なくな
り、粘着剤層の粘着性が不足する。従って、夜光顔料の
添加量は、粘着剤の乾燥重量に対して5〜100重量
%、特に15〜40重量%とするのが好ましい。
The amount of the luminous pigment to be added to the pressure-sensitive adhesive is determined depending on the required luminosity according to the luminous pressure-sensitive adhesive film. However, if the amount is too small, sufficient luminosity cannot be obtained, and If it is too long, the amount of the pressure-sensitive adhesive becomes relatively small, and the pressure-sensitive adhesive layer becomes insufficient in tackiness. Therefore, the amount of the luminous pigment to be added is preferably 5 to 100% by weight, particularly preferably 15 to 40% by weight based on the dry weight of the pressure-sensitive adhesive.

【0022】図1(a)の夜光性粘着フィルムは、所定
量の夜光顔料を添加混合した粘着剤を、通常の粘着フィ
ルム製造技術に従ってフィルムに塗工、乾燥した後、セ
パレータを張り合わすことにより容易に製造することが
できる。
The luminous pressure-sensitive adhesive film shown in FIG. 1 (a) is prepared by applying a predetermined amount of a luminous pigment to a film, applying a predetermined amount of a luminous pigment to the film, drying the film, and then laminating a separator. It can be easily manufactured.

【0023】夜光顔料入り粘着剤のフィルムへの塗工量
は、当該フィルムの用途や夜光顔料の割合等によっても
異なるが、通常の場合、20〜100g/m2 程度で十
分な粘着性を得ることができる。
The amount of the luminous pigment-containing pressure-sensitive adhesive applied to the film varies depending on the use of the film, the ratio of the luminous pigment, and the like. In general, sufficient adhesiveness is obtained at about 20 to 100 g / m 2. be able to.

【0024】なお、セパレータとしては離型紙の他、セ
パレータフィルムを用いることもできる。また、長尺フ
ィルムの場合には、透明フィルムの粘着剤層形成面と反
対側の面に、常法に従って離型処理を施し、直巻きロー
ル状とすることもできる。
The separator may be a release film or a separator film. In the case of a long film, the surface of the transparent film opposite to the surface on which the pressure-sensitive adhesive layer is formed may be subjected to a release treatment according to a conventional method to form a straight roll.

【0025】図1(b)に示す夜光性粘着フィルムは、
透明フィルム1と白色フィルム3との間に夜光顔料入り
粘着剤層7を介在させ、白色フィルム3側に、通常の粘
着剤層4を設け、セパレータ5を張り合わせたものであ
り、この夜光性粘着フィルムにおいて、透明フィルム、
夜光顔料、粘着剤等としては、前述の図1(a)の夜光
性粘着フィルムで例示したものと同様のものを用いるこ
とができる。
The luminous pressure-sensitive adhesive film shown in FIG.
A luminous pigment-containing pressure-sensitive adhesive layer 7 is interposed between the transparent film 1 and the white film 3, a normal pressure-sensitive adhesive layer 4 is provided on the white film 3 side, and a separator 5 is laminated. In the film, a transparent film,
As the luminous pigment, the pressure-sensitive adhesive and the like, those similar to those exemplified for the luminous pressure-sensitive adhesive film in FIG. 1A can be used.

【0026】白色フィルム3としては、ポリエステル、
ポリカーボネート、塩化ビニル等よりなる厚さ12〜2
00μmの白色フィルムを用いることがでいる。この白
色フィルム3は、白色に限らず、他の色に着色したもの
であっても良いが、発光を目立つものとするために、反
射の大きい色が好ましい。
As the white film 3, polyester,
Thickness of 12 to 2 made of polycarbonate, vinyl chloride, etc.
A 00 μm white film can be used. The white film 3 is not limited to white, and may be colored in another color, but a color with large reflection is preferable in order to make light emission conspicuous.

【0027】透明フィルム1と白色フィルム3との間の
夜光顔料入り粘着剤層7の夜光顔料の添加割合は前述の
如く、粘着剤の乾燥重量に対して5〜100重量%、特
に15〜40重量%とするのが好ましく、その塗工量は
30〜200g/m2 程度とするのが好ましい。
As described above, the addition ratio of the luminous pigment in the luminous pigment-containing pressure-sensitive adhesive layer 7 between the transparent film 1 and the white film 3 is 5 to 100% by weight, particularly 15 to 40% by weight, based on the dry weight of the pressure-sensitive adhesive. % By weight, and the coating amount is preferably about 30 to 200 g / m 2 .

【0028】白色フィルム3側の粘着剤層4の粘着剤の
塗工量は10〜50g/m2 程度とするのが好ましい。
The coating amount of the pressure-sensitive adhesive of the pressure-sensitive adhesive layer 4 on the white film 3 side is preferably about 10 to 50 g / m 2 .

【0029】図1(b)のような積層フィルム構造の夜
光性粘着フィルムは、図1(a)の単層フィルム構造の
夜光性粘着フィルムに比べて、被着体の色にかかわら
ず、均一な発光が得られるという効果がある。
The luminous pressure-sensitive adhesive film having a laminated film structure as shown in FIG. 1B is more uniform than the luminous pressure-sensitive adhesive film having a single-layer film structure shown in FIG. 1A regardless of the color of the adherend. There is an effect that an excellent light emission can be obtained.

【0030】この夜光性粘着フィルムでは、夜光顔料入
り粘着剤層7と粘着剤層4との2層を備えるが、共に粘
着剤層であるため、一般的な両面テープの製造技術によ
り、一回の塗工工程で夜光顔料入り粘着剤層7と粘着剤
層4とを同時に形成することができるため、従来の夜光
剤層を設けるものよりも容易に製造することができる。
This luminous pressure-sensitive adhesive film is provided with two layers, ie, a luminous pigment-containing pressure-sensitive adhesive layer 7 and a pressure-sensitive adhesive layer 4. Since both of them are pressure-sensitive adhesive layers, they are formed once by a general double-sided tape manufacturing technique. Since the luminous pigment-containing pressure-sensitive adhesive layer 7 and the pressure-sensitive adhesive layer 4 can be formed at the same time in the application step, the luminous pigment-containing pressure-sensitive adhesive layer 7 can be manufactured more easily than the conventional method in which a luminous agent layer is provided.

【0031】この夜光性粘着フィルムも、図1(a)の
夜光性粘着フィルムと同様、セパレータを設けるタイプ
とする他、直巻きロール状とすることができる。
This luminous pressure-sensitive adhesive film can be of a type provided with a separator, as in the case of the luminous pressure-sensitive adhesive film of FIG.

【0032】[0032]

【実施例】以下に実施例を挙げて本発明をより具体的に
説明する。
The present invention will be described more specifically with reference to the following examples.

【0033】実施例1 図1(a)に示す本発明の夜光性粘着フィルムを製造し
た。
Example 1 A luminous pressure-sensitive adhesive film of the present invention shown in FIG. 1A was produced.

【0034】透明フィルム、粘着剤、夜光顔料、セパレ
ータとしては下記のものを用いた。
The following were used as the transparent film, adhesive, luminous pigment and separator.

【0035】 透明フィルム:厚さ25μmのポリエチレンテレフタレ
ート(PET)フィルム 粘着剤 :アクリル系溶剤希釈型二液硬化型粘着剤
(不揮発分45重量%)(一方社油脂工業社製) 夜光顔料 :ジスプロシウム,ユウロピウムで賦活さ
れたアルミン酸ストロンチウム,平均粒径5μm(根本
特殊化学株式会社製) セパレータ :離型紙 夜光顔料を粘着剤の乾燥重量に対して20重量%添加、
混練したものを、透明フィルムの一方の面に150g/
2 塗工した後乾燥し、形成された夜光顔料入り粘着剤
層にセパレータを張り合わせた。
Transparent film: Polyethylene terephthalate (PET) film having a thickness of 25 μm Adhesive: Acrylic solvent-dilutable two-part curable adhesive (nonvolatile content: 45% by weight) (manufactured by YAS Co., Ltd.) Luminescent pigment: Dysprosium, Strontium aluminate activated with europium, average particle size 5 μm (manufactured by Nemoto Special Chemical Co., Ltd.) Separator: release paper 20% by weight of luminous pigment based on the dry weight of the adhesive,
The kneaded product was added to one side of the transparent film at 150 g /
After applying m 2, drying was performed, and a separator was attached to the formed luminous pigment-containing pressure-sensitive adhesive layer.

【0036】この夜光性粘着フィルムは、離型紙を剥し
取ることにより、良好な粘着性で、プラスチック、金
属、木材、紙、セラミック等の各種材料の部材表面に貼
着することができ、しかも、良好な夜光性を示し、夜間
でも十分に視認することができた。
The luminous pressure-sensitive adhesive film can be adhered to the surface of various materials such as plastic, metal, wood, paper, and ceramic with good adhesiveness by peeling off the release paper. It showed good luminous properties and could be sufficiently recognized even at night.

【0037】実施例2 図1(b)に示す本発明の夜光性粘着フィルムを製造し
た。
Example 2 A luminescent adhesive film of the present invention shown in FIG. 1 (b) was produced.

【0038】透明フィルム、粘着剤、夜光顔料、セパレ
ータとしては実施例1と同様のものを用いた。また、白
色フィルムとしては、厚さ50μmの白色PETフィル
ムを用いた。
The same transparent film, pressure-sensitive adhesive, luminous pigment and separator as in Example 1 were used. In addition, a white PET film having a thickness of 50 μm was used as the white film.

【0039】夜光顔料を粘着剤の乾燥重量に対して20
重量%添加、混練したものを、透明フィルムの一方の面
に200g/m2 塗工した後乾燥し、白色フィルムを貼
り合せ、更に、粘着剤を100g/m2 塗工した後乾燥
し、セパレータを貼り合わせた。
The luminous pigment is added in an amount of 20 to the dry weight of the adhesive.
The mixture obtained by adding and kneading by weight% was coated on one side of a transparent film at 200 g / m 2 , dried, laminated with a white film, further coated with an adhesive at 100 g / m 2 , dried, and then separated. Were pasted together.

【0040】この夜光性粘着フィルムは、離型紙を剥し
取ることにより、良好な粘着性で、プラスチック、金
属、木材、紙、セラミック等の各種材料の部材表面に貼
着することができ、しかも、良好な夜光性を示し、夜間
でも十分に視認することができた。
The luminous pressure-sensitive adhesive film can be adhered to the surface of various materials such as plastic, metal, wood, paper, and ceramics with good adhesiveness by peeling off the release paper. It showed good luminous properties and could be sufficiently recognized even at night.

【0041】[0041]

【発明の効果】以上詳述した通り、本発明の夜光性粘着
フィルムは、少ない工程数で容易かつ安価に製造するこ
とができる。
As described in detail above, the luminescent adhesive film of the present invention can be easily and inexpensively manufactured with a small number of steps.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の夜光性粘着フィルムの実施の形態を示
す断面図である。
FIG. 1 is a sectional view showing an embodiment of a luminescent adhesive film of the present invention.

【図2】従来の夜光性粘着フィルムを示す断面図であ
る。
FIG. 2 is a cross-sectional view showing a conventional luminescent adhesive film.

【符号の説明】[Explanation of symbols]

1 透明フィルム 2 夜光剤層 3 白色フィルム 4 粘着剤層 5 セパレータ 6 夜光顔料練り込みフィルム 7 夜光顔料入り粘着剤層 DESCRIPTION OF SYMBOLS 1 Transparent film 2 Luminescent agent layer 3 White film 4 Adhesive layer 5 Separator 6 Luminous pigment kneading film 7 Luminous pigment-containing adhesive layer

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 表面に粘着剤層が形成された粘着フィル
ムにおいて、該粘着剤層の粘着剤に夜光顔料を添加して
夜光性を付与したことを特徴とする夜光性粘着フィル
ム。
1. A luminous pressure-sensitive adhesive film comprising a pressure-sensitive adhesive film having a pressure-sensitive adhesive layer formed on a surface thereof, wherein a luminous pigment is added to the pressure-sensitive adhesive of the pressure-sensitive adhesive layer to impart luminosity.
【請求項2】 請求項1において、該フィルムは、ポリ
エステル、ポリカーボネート又は塩化ビニルよりなる透
明フィルムであることを特徴とする夜光性粘着フィル
ム。
2. The luminous pressure-sensitive adhesive film according to claim 1, wherein the film is a transparent film made of polyester, polycarbonate or vinyl chloride.
【請求項3】 請求項1又は2において、該粘着剤がア
クリル系又はゴム系の溶剤希釈型透明粘着剤であること
を特徴とする夜光性粘着フィルム。
3. The luminous pressure-sensitive adhesive film according to claim 1, wherein the pressure-sensitive adhesive is an acrylic or rubber-based solvent-dilutable transparent pressure-sensitive adhesive.
【請求項4】 請求項1ないし3のいずれか1項におい
て、夜光顔料の添加量が粘着剤の乾燥重量に対して5〜
100重量%であることを特徴とする夜光性粘着フィル
ム。
4. The pressure-sensitive adhesive according to claim 1, wherein the amount of the luminous pigment is 5 to the dry weight of the adhesive.
A luminous pressure-sensitive adhesive film, which is 100% by weight.
【請求項5】 請求項1ないし4のいずれか1項におい
て、夜光顔料がジスプロシウム及び/又はユウロピウム
で賦活されたアルミン酸ストロンチウムであることを特
徴とする夜光性粘着フィルム。
5. The luminous pressure-sensitive adhesive film according to claim 1, wherein the luminous pigment is strontium aluminate activated with dysprosium and / or europium.
【請求項6】 請求項1ないし5のいずれか1項におい
て、夜光顔料の平均粒径が4〜50μmであることを特
徴とする夜光性粘着フィルム。
6. The luminous pressure-sensitive adhesive film according to claim 1, wherein the luminous pigment has an average particle size of 4 to 50 μm.
JP20143397A 1997-07-28 1997-07-28 Luminous adhesive film Pending JPH1143651A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20143397A JPH1143651A (en) 1997-07-28 1997-07-28 Luminous adhesive film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20143397A JPH1143651A (en) 1997-07-28 1997-07-28 Luminous adhesive film

Publications (1)

Publication Number Publication Date
JPH1143651A true JPH1143651A (en) 1999-02-16

Family

ID=16441015

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20143397A Pending JPH1143651A (en) 1997-07-28 1997-07-28 Luminous adhesive film

Country Status (1)

Country Link
JP (1) JPH1143651A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6251491B1 (en) * 1999-03-03 2001-06-26 Kyung Ja Kim Luminous sticker having ornamental effect
KR20030045588A (en) * 2001-12-01 2003-06-11 정석환 A composition of paste
KR100449159B1 (en) * 2001-11-14 2004-09-16 (주)아해 Phosphorescent-fluorescent film and manufacture method thereof
JP2007291214A (en) * 2006-04-24 2007-11-08 Agatsuma:Kk Seal for toy
JP2008095057A (en) * 2006-10-10 2008-04-24 Yoshihiro Suzuki Functional pressure-sensitive adhesive film and printed release sheet
KR200489876Y1 (en) * 2019-06-14 2019-08-23 임해욱 Cigarette wrapping paper with lighter storage space
CN116262871A (en) * 2021-12-13 2023-06-16 阿特斯阳光电力集团股份有限公司 Packaging adhesive film and preparation method and application thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6251491B1 (en) * 1999-03-03 2001-06-26 Kyung Ja Kim Luminous sticker having ornamental effect
KR100449159B1 (en) * 2001-11-14 2004-09-16 (주)아해 Phosphorescent-fluorescent film and manufacture method thereof
KR20030045588A (en) * 2001-12-01 2003-06-11 정석환 A composition of paste
JP2007291214A (en) * 2006-04-24 2007-11-08 Agatsuma:Kk Seal for toy
JP2008095057A (en) * 2006-10-10 2008-04-24 Yoshihiro Suzuki Functional pressure-sensitive adhesive film and printed release sheet
KR200489876Y1 (en) * 2019-06-14 2019-08-23 임해욱 Cigarette wrapping paper with lighter storage space
WO2020251115A1 (en) * 2019-06-14 2020-12-17 임해욱 Cigarette pack wrapper having lighter storage space formed therein
CN116262871A (en) * 2021-12-13 2023-06-16 阿特斯阳光电力集团股份有限公司 Packaging adhesive film and preparation method and application thereof

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