JPH11309732A - Production of decorated molded article - Google Patents
Production of decorated molded articleInfo
- Publication number
- JPH11309732A JPH11309732A JP11920198A JP11920198A JPH11309732A JP H11309732 A JPH11309732 A JP H11309732A JP 11920198 A JP11920198 A JP 11920198A JP 11920198 A JP11920198 A JP 11920198A JP H11309732 A JPH11309732 A JP H11309732A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- thermosetting resin
- decorative
- resin composition
- molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/10—Thermosetting resins
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、加飾成形品の製造
方法に関し、更に詳しくは、絵柄が周縁部に連続する加
飾成形品の製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a decorative molded product, and more particularly, to a method for manufacturing a decorative molded product in which a picture pattern is continuous at a peripheral portion.
【０００２】[0002]
【従来の技術】熱硬化性樹脂、硬化剤、柄剤及び補強材
を含む加飾用熱硬化性樹脂組成物から成形される加飾成
形品としては、柄剤として、例えば、マーブル模様や石
目模様を形成し得る着色された複数の樹脂コンパウンド
や微粒子が用いられた繊維強化プラスチック（ＦＲＰ）
製品として、キッチンカウンター、壁材、浴室床材、浴
槽等が挙げられる。2. Description of the Related Art A decorative molded article formed from a thermosetting resin composition for decoration containing a thermosetting resin, a curing agent, a patterning agent, and a reinforcing material includes a patterning agent such as a marble pattern or a stone. Fiber reinforced plastic (FRP) using a plurality of colored resin compounds and fine particles capable of forming an eye pattern
Products include kitchen counters, wall materials, bathroom floor materials, bathtubs, and the like.
【０００３】上記加飾用熱硬化性樹脂組成物から成形さ
れるこれらの加飾成形品は、図３に示されるように、可
動型である上型（雄型）１と固定型である下型（雌型）
２からなる加熱圧縮金型が用いられ、下型２の型窩の底
面（加飾成形品の加飾面）内に収容できる平板状の加飾
材３が上記柄剤を含む加飾用熱硬化性樹脂組成物から予
め予備成形されて所定加飾位置にインサートされ、該加
飾材３裏面の型窩に、成形材料、例えば、チョップドス
トランドマットに、不飽和ポリエステル樹脂、充填剤、
離型剤、顔料等を混合した熱硬化性樹脂組成物を含浸し
たシート状の成形材料、略称ＳＭＣ４を必要量だけ計量
して充填し、加熱加圧して成形されていた。As shown in FIG. 3, these decorative molded articles molded from the thermosetting resin composition for decoration are an upper mold (male mold) 1 which is a movable mold and a lower mold which is a fixed mold. Type (female type)
A flat plate-shaped decorating material 3 that can be accommodated in the bottom surface of the mold cavity of the lower mold 2 (decoration surface of a decorative molded product) is used for the heating for decoration including the pattern agent. Precured from the curable resin composition and inserted at a predetermined decorative position, and the molding material, for example, a chopped strand mat, an unsaturated polyester resin, a filler,
A required amount of a sheet-like molding material, abbreviated as SMC4, impregnated with a thermosetting resin composition mixed with a release agent, a pigment, and the like, was weighed and filled, and heated and pressed to mold.
【０００４】加飾成形品が、例えば、皿状に成形される
図４の浴室床材であって、上記平板状の加飾材３が下型
２の型窩の表面をはみ出した大きさの平板を用いて、加
飾面が床表面から浴室周縁に接続する立上り部に亘って
連続した図柄にしようとしても、成形時に、○で囲まれ
た隅角の屈曲部付近で、上型１の圧縮力によって下型２
の型表面に沿って加飾材３が緩やかに撓んでは呉れず、
割れて周囲に不規則に折れ重なって図柄が断続し、甚だ
しい場合には、上記連続する図柄の間に、裏面に充填さ
れた成形材料のＳＭＣ４が割り込んで加飾材３を埋め込
んでしまって、加飾材３を台無しにしてしまう等の成形
上の問題点を有するものであった。The decorative molded product is, for example, a bathroom flooring material shown in FIG. 4 which is formed into a dish shape, and the flat decorative material 3 has a size protruding from the surface of the mold cavity of the lower mold 2. Using a flat plate, even if the decorative surface is to be a continuous pattern from the floor surface to the rising portion connecting to the periphery of the bathroom, at the time of molding, near the bent portion of the corner surrounded by ○, the upper die 1 Lower die 2 by compressive force
The decorating material 3 does not flex if it gently bends along the surface of the mold.
If the pattern breaks and breaks irregularly around and the pattern is interrupted and intermittent, and in severe cases, the SMC 4 of the molding material filled on the back side breaks in between the continuous patterns, embedding the decorative material 3, There was a problem in molding, such as ruining the decorating material 3.
【０００５】これらの加飾材表面に裏面の成形材料が成
形時にしみ出すことを防止する提案として、例えば、特
開昭６３−４９１５号公報に、上記加飾材を予備成形せ
ず、未硬化のＳＭＣの形で供給し、該加飾材ＳＭＣと成
形材料のＳＭＣとの間に、ガラスマットを介在させる発
明が開示されている。[0005] As a proposal for preventing the molding material on the back surface from seeping out on the surface of the decorating material at the time of molding, for example, Japanese Patent Application Laid-Open No. 63-4915 discloses that An invention is disclosed in which a glass mat is interposed between the decorative material SMC and the molding material SMC.
【０００６】しかしながら、特開昭６３−４９１５号公
報に開示されているように、加飾材を予備成形せず、未
硬化のＳＭＣの形で供給し、成形材料のＳＭＣとの間
に、ガラスマットを供給することになると、３種類の異
なる材料を金型に供給することが必要になり、工程が増
えて複雑になるだけでなく、加飾材の位置決めも極めて
面倒な作業を伴うものとなる。即ち、成形材料の不規則
な流れによって、加飾材の位置が乱れ易く、更に、上記
隅角の周縁部付近で、加飾材ＳＭＣと成形材料のＳＭＣ
が、しばしば、相互に混ざり合って加飾材が成形材料の
ＳＭＣ内に埋まってしまい、天板表面ないしは床面から
外周側縁ないしは立上り内周側縁に到るまで完全に連続
した図柄として美麗に加飾を施すことは難しいものであ
った。However, as disclosed in JP-A-63-4915, the decorating material is not preformed, but is supplied in the form of uncured SMC. When supplying mats, it is necessary to supply three different materials to the mold, which increases the number of processes and complicates the process, and also requires extremely complicated positioning of the decorative material. Become. That is, the position of the decorating material is likely to be disturbed by the irregular flow of the molding material, and further, the decorating material SMC and the SMC of the molding material near the periphery of the corner.
However, the decorating material often mixes with each other, and the decorating material is buried in the SMC of the molding material. It was difficult to decorate the area.
【０００７】[0007]
【発明が解決しようとする課題】本発明は、叙上の事実
に鑑みなされたものであって、その目的は、平板状表面
からこれに連なる側縁部に連続した図柄の加飾が施され
た加飾成形品を生産性高く製造する加飾成形品の製造方
法を提供することにある。SUMMARY OF THE INVENTION The present invention has been made in view of the above facts, and has as its object to decorate a continuous pattern from a flat surface to a side edge portion connected thereto. It is an object of the present invention to provide a method of manufacturing a decorative molded product for producing a decorative molded product with high productivity.
【０００８】[0008]
【課題を解決するための手段】請求項１記載の発明は、
熱硬化性樹脂、硬化剤、柄剤及び補強材を含む加飾用熱
硬化性樹脂組成物を金型型窩にチャージし、増粘して賦
形し、該賦形された一面を加飾表面層とし、裏面に熱硬
化性樹脂組成物からなる成形材料を充填して加熱加圧す
ることを特徴とする加飾成形品の製造方法をその要旨と
するものである。According to the first aspect of the present invention,
A thermosetting resin composition for decoration including a thermosetting resin, a curing agent, a patterning agent, and a reinforcing material is charged into a mold cavity, thickened and shaped, and the shaped surface is decorated. The gist of the present invention is a method for producing a decorative molded product, characterized in that a molding material composed of a thermosetting resin composition is filled in a front surface layer, and a back surface is filled with the molding material and heated and pressed.
【０００９】請求項２記載の発明は、上記加熱加圧成形
時に、金型内を減圧する請求項１記載の加飾成形品の製
造方法をその要旨とするものである。The gist of the invention according to a second aspect is the method of manufacturing a decorative molded product according to the first aspect, wherein the inside of the mold is depressurized during the heating and pressing.
【００１０】本発明の加飾成形品の製造方法において、
加飾用熱硬化性樹脂組成物に用いられる熱硬化性樹脂
は、特に限定されるものではないが、例えば、不飽和ポ
リエステル樹脂、エポキシアクリレート樹脂、ウレタン
アクリレート樹脂、ジアリルフタレート樹脂、メラミン
樹脂等が挙げられる。これらの熱硬化性樹脂は、後述す
る柄剤の添加によって形成される図柄を立体的に認識さ
せ、高級な加飾効果を演出するために、透明ないしは図
柄を立体的に透視し得る光線透過率を有するものである
ことが好ましい。In the method for producing a decorative molded product of the present invention,
Thermosetting resin used in the decorative thermosetting resin composition is not particularly limited, for example, unsaturated polyester resin, epoxy acrylate resin, urethane acrylate resin, diallyl phthalate resin, melamine resin and the like No. These thermosetting resins allow the pattern formed by the addition of the patterning agent described later to be three-dimensionally recognized, and in order to produce a high-quality decorative effect, the light transmittance is transparent or the pattern can be viewed three-dimensionally. It is preferable to have.
【００１１】又、上記熱硬化性樹脂には、必要に応じ
て、例えば、スチレン、α−メチルスチレン、ジビニル
ベンゼン、ジビニルトルエン、ジアリルフタレート、各
種（メタ）アクリレートモノマー等の重合性単量体がラ
ジカル反応開始剤と共に添加されてもよい。上記ラジカ
ル反応開始剤としては、例えば、後述する硬化剤がラジ
カル反応開始剤として使用できる。The thermosetting resin may optionally contain polymerizable monomers such as styrene, α-methylstyrene, divinylbenzene, divinyltoluene, diallyl phthalate, and various (meth) acrylate monomers. It may be added together with the radical reaction initiator. As the radical reaction initiator, for example, a curing agent described below can be used as the radical reaction initiator.
【００１２】上記重合性単量体の添加量は、熱硬化性樹
脂と重合性単量体の合計量に対し、好ましくは１〜７０
重量％、より好ましくは３〜５０重量％である。上記添
加量が少な過ぎると、熱硬化性樹脂成形材料の粘度が高
くなり成形時に充分な流動性が得られ難くなり、逆に、
多過ぎる場合には、得られる加飾成形品の機械的強度が
低下する。又、ラジカル反応開始剤の添加量は、熱硬化
性樹脂と重合性単量体の合計量１００重量部に対し、好
ましくは０．３〜５重量部、より好ましくは０．５〜３
重量部である。上記添加量が少な過ぎると、熱硬化性樹
脂組成物の硬化速度が遅くなり生産性を低下させ、逆
に、多過ぎる場合には、熱硬化性樹脂組成物が硬化時に
黄変するおそれがある。The amount of the polymerizable monomer added is preferably from 1 to 70, based on the total amount of the thermosetting resin and the polymerizable monomer.
%, More preferably 3 to 50% by weight. If the addition amount is too small, the viscosity of the thermosetting resin molding material increases, and it becomes difficult to obtain sufficient fluidity during molding, and conversely,
If the amount is too large, the mechanical strength of the obtained decorative molded product decreases. The amount of the radical reaction initiator is preferably 0.3 to 5 parts by weight, more preferably 0.5 to 3 parts by weight, based on 100 parts by weight of the total of the thermosetting resin and the polymerizable monomer.
Parts by weight. If the addition amount is too small, the curing rate of the thermosetting resin composition is slowed and the productivity is reduced.On the contrary, if it is too large, the thermosetting resin composition may be yellowed during curing. .
【００１３】上記熱硬化性樹脂には、必要に応じて、例
えば、ポリ酢酸ビニル、ポリメチル（メタ）アクリレー
ト、ポリエチレン、エチレン−酢酸ビニル共重合体、酢
酸ビニル−スチレン共重合体、ポリブタジエン、飽和ポ
リエステル類、飽和ポリエーテル類等の熱可塑性樹脂を
低収縮剤として添加されてもよい。The thermosetting resin may be, if necessary, for example, polyvinyl acetate, polymethyl (meth) acrylate, polyethylene, ethylene-vinyl acetate copolymer, vinyl acetate-styrene copolymer, polybutadiene, saturated polyester. , Or a thermoplastic resin such as a saturated polyether may be added as a low shrinkage agent.
【００１４】上記熱可塑性樹脂の添加量は、熱硬化性樹
脂と後述する重合性単量体の合計量に対し、好ましくは
０．１〜３０重量％、より好ましくは０．３〜２０重量
％である。上記添加量が多過ぎると、熱硬化性樹脂組成
物の粘度が高くなり成形時に充分な流動性が得られ難く
なり、逆に、少な過ぎる場合には、意図した成形収縮の
改善効果が得られ難くなる。The amount of the thermoplastic resin is preferably 0.1 to 30% by weight, more preferably 0.3 to 20% by weight, based on the total amount of the thermosetting resin and the polymerizable monomer described below. It is. When the amount is too large, the viscosity of the thermosetting resin composition becomes high, and it is difficult to obtain sufficient fluidity during molding.On the other hand, when the amount is too small, the intended effect of improving molding shrinkage is obtained. It becomes difficult.
【００１５】上記硬化剤は、用いられる熱硬化性樹脂の
種類等によって最も適切な硬化剤が選択されるものであ
って、特に限定されるものではないが、例えば、メチル
エチルケトンパーオキサイド、ベンゾイルパーオキサイ
ド、ｔ−ブチルパーオキシアセテート、ｔ−ブチルパー
オキシオクトエート、ｔ−ブチルパーオキシベンゾエー
ト、ジ−ｔ−ブチルパーオキシフタレート、ジ−ｔ−ブ
チルパーオキシイソフタレート、ｔ−ブチルパーオキシ
ラウレート、２，５−ジメチル−２，５−ジベンゾイル
パーオキシヘキサン、ｔ−ブチルパーオキシイソプロピ
ルカーボネート等が挙げられ、中でも、ｔ−ブチルパー
オキシベンゾエート、ｔ−ブチルパーオキシイソプロピ
ルカーボネート等が、安全性等を含んでの取扱易さ、反
応性、コスト等を総合して好適に用いられる。The curing agent is selected from the most suitable curing agents depending on the kind of the thermosetting resin to be used, and is not particularly limited. Examples thereof include methyl ethyl ketone peroxide and benzoyl peroxide. T-butyl peroxy acetate, t-butyl peroxy octoate, t-butyl peroxy benzoate, di-t-butyl peroxyphthalate, di-t-butyl peroxy isophthalate, t-butyl peroxy laurate, 2,5-dimethyl-2,5-dibenzoylperoxyhexane, t-butylperoxyisopropyl carbonate, etc., among which t-butylperoxybenzoate, t-butylperoxyisopropyl carbonate, etc. Ease of handling, reactivity, cost, etc. Preferably used engaged.
【００１６】上記硬化剤の添加量は、反応性不飽和結合
を有する熱硬化性樹脂及び重合性単量体の合計量１００
重量部に対して好ましくは０．１〜８重量部、より好ま
しくは０．５〜５重量部である。上記硬化剤の添加量が
少な過ぎると加飾用熱硬化性樹脂組成物の硬化が不充分
となり、多過ぎると加飾用熱硬化性樹脂組成物が黄変し
易くなる傾向がある。[0016] The amount of the above-mentioned curing agent to be added is a total amount of the thermosetting resin having a reactive unsaturated bond and the polymerizable monomer of 100.
It is preferably 0.1 to 8 parts by weight, more preferably 0.5 to 5 parts by weight based on parts by weight. If the addition amount of the curing agent is too small, the curing of the thermosetting resin composition for decoration becomes insufficient, and if it is too large, the thermosetting resin composition for decoration tends to be easily yellowed.
【００１７】上記柄剤は、特に限定されるものではない
が、例えば、上記熱硬化性樹脂組成物に悪影響を及ぼす
おそれのないものであれば特に限定されるものではな
く、例えば、金属、陶磁器、その他のセラミックス、土
石、プラスチックス、木材、竹材、紙、繊維、織布、不
織布、これらの加工物、複合物等が挙げられる。上記柄
剤の形状は、特に限定されるものではなく、例えば、粒
子状、フレーク状等微細構造の分散体であってもよい。The patterning agent is not particularly limited, but is not particularly limited as long as it does not adversely affect the thermosetting resin composition. And other ceramics, earth and stone, plastics, wood, bamboo, paper, fiber, woven fabric, non-woven fabric, processed products thereof, composites and the like. The shape of the patterning agent is not particularly limited, and may be, for example, a dispersion having a fine structure such as a particle shape or a flake shape.
【００１８】上記柄剤は、例えば、上記ガラス繊維の編
織布や不織布を埋設した１層の樹脂層の上面にのみ分散
されてもよく、２層の透明な樹脂層の上面及び中間層に
分散されてもよく、その他、加飾用熱硬化性樹脂組成物
が形成する絵柄の意匠性を阻害しない範囲において各種
の柄剤分散層の設定が可能である。The patterning agent may be dispersed only on the upper surface of one resin layer in which the woven or nonwoven fabric of the glass fiber is embedded, for example, and may be dispersed on the upper surface of two transparent resin layers and the intermediate layer. In addition, various patterning agent dispersion layers can be set in a range that does not impair the design of the pattern formed by the thermosetting resin composition for decoration.
【００１９】上記柄剤の添加によって、加飾用熱硬化性
樹脂組成物は、得られる加飾成形品表面に、例えば、マ
ーブル様図柄や石目様図柄、その他の加飾用図柄が形成
される。By the addition of the above-mentioned patterning agent, the decorative thermosetting resin composition forms, for example, a marble-like pattern, a stone-like pattern, and other decorative patterns on the surface of the obtained decorative molded product. You.
【００２０】上記補強材は、特に限定されるものではな
いが、例えば、ガラス繊維、カーボン繊維等が挙げられ
る。これらの補強材の添加量は、加飾成形品の用途等に
よって決定されるが、通常、熱硬化性樹脂と重合性単量
体の合計量１００重量部に対し、好ましくは１〜１００
重量部、より好ましくは３〜９０重量部である。上記添
加量が少な過ぎると、熱硬化性樹脂成形材料の補強硬化
が得られず、逆に、多過ぎる場合には、熱硬化性樹脂成
形材料の粘度が高くなり成形時に充分な流動性が得られ
難くなる。The reinforcing material is not particularly limited, and examples thereof include glass fiber and carbon fiber. The amount of these reinforcing materials to be added is determined depending on the application of the decorative molded product, but is usually 1 to 100 parts by weight based on 100 parts by weight of the total amount of the thermosetting resin and the polymerizable monomer.
Parts by weight, more preferably 3 to 90 parts by weight. If the addition amount is too small, reinforcement curing of the thermosetting resin molding material cannot be obtained, and if it is too large, the viscosity of the thermosetting resin molding material increases and sufficient fluidity is obtained at the time of molding. It is difficult to be.
【００２１】上記熱硬化性樹脂組成物は、必要に応じ
て、酸化防止剤、紫外線吸収剤、帯電防止剤、導電性付
与剤、抗菌剤、防黴剤、充填剤、着色剤、硬化促進剤、
重合禁止剤、離型剤等の各種添加剤が添加されてもい。If necessary, the thermosetting resin composition may contain an antioxidant, an ultraviolet absorber, an antistatic agent, a conductivity-imparting agent, an antibacterial agent, an antifungal agent, a filler, a coloring agent, and a curing accelerator. ,
Various additives such as a polymerization inhibitor and a release agent may be added.
【００２２】本発明における加飾成形品の加飾手段は、
上記柄剤が添加された加飾用熱硬化性樹脂組成物を、金
型型窩にチャージし、この状態のまま増粘して賦形し、
該賦形された一面を加飾表面層とし、その背面に成形材
料のＳＭＣを充填して加熱加圧して加飾面が形成される
ものである。In the present invention, the means for decorating a decorative molded product is as follows:
The decorative thermosetting resin composition to which the patterning agent is added is charged into a mold cavity, and is thickened and shaped in this state,
The shaped surface is used as a decorative surface layer, the back surface of which is filled with SMC as a molding material, and heated and pressed to form a decorative surface.
【００２３】上記加飾用熱硬化性樹脂組成物の増粘は、
酸化マグネシウム等の増粘剤が添加され、必要に応じて
加熱熟成して行われ、その増粘を行う場所は、特に限定
されるものではないが、例えば、加飾面を形成し得る型
窩を有する予備成形金型において行われれば、そのまま
の状態で、材料の再移動を必要としないので効率的に作
業できる。上記加飾用熱硬化性樹脂組成物の増粘と同
時、もしくはこれに次いで、加飾成形品成形用プレス金
型型窩にチャージし得る形状に賦形される。The thickening of the decorative thermosetting resin composition is as follows:
A thickening agent such as magnesium oxide is added, and heat-aging is performed as needed. The place where the thickening is performed is not particularly limited. For example, a mold cavity that can form a decorative surface If it is carried out in a preforming die having the above, it is possible to work efficiently because the material does not need to be re-moved as it is. Simultaneously with or subsequent to the increase in the viscosity of the thermosetting resin composition for decorating, it is shaped into a shape that can be charged into the press mold cavity for decorating molded article molding.
【００２４】上記増粘の程度は、用いられる熱硬化性樹
脂組成物の性状、目的とする加飾成形品の形状、用途等
によって決定されるものであって特に限定されるもので
はないが、上記増粘の程度が余り低いと、得られる加飾
表面層が成形材料のＳＭＣを充填して行う加飾成形品の
成形時に乱れるおそれがあり、余り高いと加飾表面層と
成形材料のＳＭＣとの密着性が不十分となるおそれがあ
る。The degree of the thickening is determined by the properties of the thermosetting resin composition used, the shape of the intended decorative molded product, the intended use, etc., and is not particularly limited. If the degree of the thickening is too low, the obtained decorative surface layer may be disturbed at the time of molding of the decorative molded product by filling the SMC of the molding material, and if too high, the decorative surface layer and the SMC of the molding material may be disturbed. Adhesion may be insufficient.
【００２５】又、上記加飾表面層の賦形は、加飾成形品
の成形用金型とは別に、例えば、射出成形法で行われて
もよく、又、多段プレスによって賦形し得る型窩にチャ
ージされ、その金型のまま熟成して増粘と賦形が行われ
てもよい。又、予備賦形用金型が用いられる場合、図１
に示される加飾成形品の成形用金型の下型２を共用して
用い、別途準備された雄型もしくは雌型の上型のみが予
備成形用金型として用いられてもよい。尚、１は加飾成
形品の成形用金型の上型であり、３は加飾用熱硬化性樹
脂組成物、４は、いずれもＳＭＣからなる成形材料を示
している。In addition, the decorative surface layer may be formed by, for example, an injection molding method separately from a molding die for a decorative molded product, or may be formed by a multi-stage press. The cavity may be charged and the mold may be aged and thickened and shaped. In addition, when a preforming mold is used, FIG.
And the lower mold 2 of the molding die for the decorative molded article shown in (1) may be used in common, and only the separately prepared male or female upper mold may be used as the preliminary molding die. In addition, 1 is an upper mold of a molding die of a decorative molded product, 3 is a thermosetting resin composition for decoration, and 4 is a molding material composed of SMC.
【００２６】上記熱硬化性樹脂組成物からなる成形材料
は、特に限定されるものではないが、例えば、チョップ
ドストランドマットに熱硬化性樹脂、充填剤、離型剤、
顔料等を混合した樹脂組成物を含浸したシート状成形材
（以下、ＳＭＣと略称する。）やパテ状成形材（以下、
ＢＭＣと略称する。）等が挙げられる。The molding material comprising the thermosetting resin composition is not particularly limited. For example, a thermosetting resin, a filler, a release agent,
A sheet-like molding material (hereinafter abbreviated as SMC) impregnated with a resin composition mixed with a pigment or the like or a putty-like molding material (hereinafter, referred to as SMC)
Abbreviated as BMC. ) And the like.
【００２７】上記ＳＭＣやＢＭＣ及びこれに用いられる
チョップドストランドマット、チョップドストランド及
び熱硬化性樹脂、充填剤、離型剤、顔料等を混合した樹
脂組成物は特に限定されるものではなく、通常、熱硬化
性樹脂成形品の製造に用いられるチョップドストランド
マット、チョップドストランド及びこれに上記熱硬化性
樹脂、充填剤、離型剤、顔料等を混合した樹脂組成物を
含浸させたＳＭＣやＢＭＣが、加飾成形品の仕様に基づ
き適宜選択使用される。The resin composition obtained by mixing the above-mentioned SMC or BMC and the chopped strand mat, chopped strand and thermosetting resin, filler, release agent, pigment and the like used therein is not particularly limited. SMC or BMC impregnated with a resin composition obtained by mixing a chopped strand mat, a chopped strand and the thermosetting resin, a filler, a release agent, a pigment, and the like used in the production of a thermosetting resin molded product, It is appropriately selected and used based on the specification of the decorative molded product.
【００２８】本発明において用いられる金型は、特に限
定されるものではなく、例えば、通常、ＦＲＰの製造に
用いられる、上型が可動型であり、下型が固定型であプ
レス成形用金型が挙げられる。又、金型温度、成形プレ
ス圧、成形サイクルは、用いられる熱硬化性樹脂組成物
の性状、目的とする加飾成形品の形状、用途等によって
決定されるものであって特に限定されるものではない
が、通常、金型温度：８０〜１８０℃、成形プレス圧：
１０〜１２０ｋｇ／ｃｍ2 、成形サイクル：３０秒間〜
２０分間の成形条件が採られる。The mold used in the present invention is not particularly limited. For example, usually, an upper mold is a movable mold, a lower mold is a fixed mold, and a press molding mold usually used for manufacturing FRP. Type. The mold temperature, molding press pressure, and molding cycle are determined by the properties of the thermosetting resin composition to be used, the shape of the intended decorative molded product, the application, and the like, and are particularly limited. Although not usually, mold temperature: 80 to 180 ° C., molding press pressure:
10 to 120 kg / cm 2 , molding cycle: 30 seconds to
Molding conditions for 20 minutes are employed.
【００２９】更に、上記加熱加圧成形に際して、図２に
示されるように、上型１と下型２を型締めしたとき、加
飾成形品用金型のパーティングライン部に開口する吸引
孔５より、金型内を減圧することによって、加飾用熱硬
化性樹脂組成物３及び成形材料熱硬化性樹脂組成物４が
共に、上記上型１及び下型２表面に密着し、該金型の鏡
面を転写して平滑にして緻密な表面が形成され、且つ、
気泡や膨れ等の外観欠点の極めて少ない加飾成形品を製
造し得るものである。尚、６は、上記金型内を減圧する
際にパーティングラインの隙間を封止するためのシーリ
ング材である。Further, at the time of the above-mentioned heat and pressure molding, as shown in FIG. 2, when the upper die 1 and the lower die 2 are clamped, a suction hole opened in the parting line portion of the decorative molded product die. 5, by reducing the pressure in the mold, both the decorative thermosetting resin composition 3 and the molding material thermosetting resin composition 4 adhere to the surfaces of the upper mold 1 and the lower mold 2, and The mirror surface of the mold is transferred and smoothed to form a dense surface, and
The present invention can produce a decorative molded article having extremely few appearance defects such as bubbles and blisters. Reference numeral 6 denotes a sealing material for sealing a gap between parting lines when depressurizing the inside of the mold.
【００３０】請求項１記載の発明の加飾成形品の製造方
法は、叙上のように、熱硬化性樹脂、硬化剤、柄剤及び
補強材を含む加飾用熱硬化性樹脂組成物を金型型窩にチ
ャージし、増粘して賦形し、加飾表面層を形成するもの
であるので、天板表面ないしは床面から外周側縁ないし
は立上り内周側縁に到るまで完全に連続した図柄からな
る加飾表面層の寸法精度を極めて高いレベルで調製でき
る。従って、立体的深味のある加飾が設計通りに現出さ
れ、且つ、高価な加飾材料を最小量で、効率的に使用で
きるので、上記加飾の製造コストの低減に大いに寄与し
得るものである。As described above, the method for producing a decorative molded article according to the first aspect of the present invention is a method for manufacturing a decorative thermosetting resin composition containing a thermosetting resin, a curing agent, a patterning agent, and a reinforcing material. Since the mold cavity is charged, thickened and shaped to form a decorative surface layer, it is completely formed from the top plate surface or floor surface to the outer peripheral edge or the rising inner peripheral edge. The dimensional accuracy of the decorative surface layer composed of continuous patterns can be adjusted at an extremely high level. Therefore, a decoration with a three-dimensional depth is exhibited as designed, and an expensive decoration material can be efficiently used with a minimum amount, which can greatly contribute to a reduction in the manufacturing cost of the decoration. It is.
【００３１】本発明の加飾成形品の製造方法は、又、加
飾用熱硬化性樹脂組成物が増粘して賦形された状態で、
加飾表面層を形成し、その裏面に成形材料が充填され、
加熱加圧することによって加飾成形品が製造されるもの
であるので、加飾表面層と成形材料が製造時の加熱加圧
によって相互にしみ出して加飾表面を汚損するおそれが
なく、前述する立体的深味のある加飾を施すことができ
ると共に、加飾表面層は、未硬化の状態の熱硬化性樹脂
組成物同士を加熱加圧して硬化させるものであるので、
両層は完全に一体化して強固に固着しているものであ
る。The method for producing a decorative molded article of the present invention further comprises the steps of:
Form a decorative surface layer, the back surface is filled with molding material,
Since the decorative molded article is manufactured by heating and pressing, there is no possibility that the decorative surface layer and the molding material may exude to each other by heating and pressing at the time of manufacturing and stain the decorative surface. Since it is possible to perform decoration with a three-dimensional depth, the decoration surface layer is a material that cures the thermosetting resin compositions in an uncured state by applying heat and pressure.
Both layers are completely integrated and firmly fixed.
【００３２】更に、本発明の加飾成形品の製造方法は、
上記加飾表面層の予備成形が、加飾用熱硬化性樹脂組成
物の単一素材の増粘、賦形であるので、単純な機械的チ
ャージによって原料供給ができ、得られた加飾表面層の
背面の金型型窩に計量された成形材料を充填するだけの
単純原料供給作業によって、製造できるものであって、
複数の取扱い難い原材料を、しかも、加飾位置を正確に
意識してチャージする必要が全くないので、天板表面な
いしは床面から外周側縁ないしは立上り内周側縁に到る
まで完全に連続した図柄からなる加飾成形品を生産性高
く製造することができる。Further, the method for producing a decorative molded product of the present invention comprises:
Since the preforming of the decorative surface layer is a thickening and shaping of a single material of the thermosetting resin composition for decoration, the raw material can be supplied by a simple mechanical charge, and the obtained decorative surface is obtained. It can be manufactured by a simple raw material supply operation that only fills the measured molding material in the mold cavity on the back side of the layer,
Since there is no need to charge a plurality of difficult-to-handle raw materials with accurate awareness of the decoration position, it is completely continuous from the top plate surface or floor surface to the outer peripheral edge or the rising inner peripheral edge. A decorative molded product made of a pattern can be manufactured with high productivity.
【００３３】請求項２記載の発明の加飾成形品の製造方
法は、叙上のように、上記加熱加圧成形時に、金型内を
減圧するものであるので、該金型の鏡面を転写して平滑
にして緻密な表面が形成され、従って、天板表面ないし
は床面から外周側縁ないしは立上り内周側縁に到るまで
完全に連続した図柄からなる加飾成形品表面を、平滑に
して緻密な鏡面に仕上げられるので、前記する立体的深
味のある加飾を更に魅力的なものとし得るものである。In the method for manufacturing a decorative molded product according to the second aspect of the present invention, as described above, the inside of the mold is depressurized at the time of the heat and pressure molding, so that the mirror surface of the mold is transferred. Then, a dense surface is formed, and therefore, the decorative molded product surface composed of a completely continuous pattern from the top plate surface or floor surface to the outer peripheral edge or the rising inner peripheral edge is smoothed. Since it is finished with a fine mirror surface, it is possible to make the three-dimensionally rich decoration described above more attractive.
【００３４】[0034]
【発明の実施の形態】以下実施例に基づき本発明を具体
的に説明する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below based on embodiments.
【００３５】（実施例１） 〔柄剤入り熱硬化性樹脂組成物の調製〕不飽和ポリエス
テル樹脂１００重量部、硬化剤（ｔ−ブチルパーオキシ
ベンゾエート）１重量部、平均粒径１２μｍの水酸化ア
ルミニウム１２０重量部、柄剤として、白色マイカ３重
量部及び黒色マイカ２重量部からなる柄剤、ベージュ色
顔料７重量部、長さ５ｍｍカットのガラス繊維１２重量
部及び酸化マグネシウム１重量部を混練して柄剤入り熱
硬化性樹脂組成物（ＢＭＣ）を調製し、約１７００ｇに
小分けしておく。(Example 1) [Preparation of a thermosetting resin composition containing a patterning agent] 100 parts by weight of an unsaturated polyester resin, 1 part by weight of a curing agent (t-butylperoxybenzoate), and hydroxylation having an average particle diameter of 12 μm 120 parts by weight of aluminum, a patterning agent consisting of 3 parts by weight of white mica and 2 parts by weight of black mica, 7 parts by weight of beige pigment, 12 parts by weight of glass fiber cut to 5 mm in length and 1 part by weight of magnesium oxide as a patterning agent Thus, a thermosetting resin composition (BMC) containing a patterning agent is prepared and divided into about 1700 g.
【００３６】上記柄剤入り熱硬化性樹脂組成物を：長辺
側１６００ｍｍ、短辺側４００ｍｍ、深さ５０ｍｍのプ
レス成形用金型（下型）２に、２４μｍの離型用ポリエ
チレンテレフタレート（ＰＥＴ）フィルムを介して上下
に５層の柄剤入り熱硬化性樹脂組成物をシート状に展開
してチャージし、プレス成形機を用いて上型１を押圧
し、キッチンカウンター用の裏面から外周側縁に連続し
た加飾が連なる皿状の賦形を施す型窩を形成し、更に、
４０℃で４０時間養生して増粘して上記皿状の賦形を施
した加飾表面層を調製する。The above-mentioned thermosetting resin composition containing a patterning agent was placed in a press molding die (lower die) 2 having a long side of 1600 mm, a short side of 400 mm, and a depth of 50 mm, and a polyethylene terephthalate (PET) of 24 μm for release. ) Five layers of the thermosetting resin composition containing the patterning agent are spread in a sheet shape and charged via a film, and the upper mold 1 is pressed by using a press molding machine, and the outer side from the back surface for the kitchen counter is pressed. Forming a mold fossa that performs dish-shaped shaping in which continuous decoration is continued on the edge,
Cured at 40 ° C. for 40 hours to increase the viscosity and prepare the decorative surface layer on which the dish-shaped shaping is performed.
【００３７】〔成形材料用ＳＭＣの調製〕不飽和ポリエ
ステル樹脂１００重量部、硬化剤（ｔ−ブチルパーオキ
シベンゾエート）１重量部、平均粒径１０μｍの炭酸カ
ルシウム１５０重量部、灰色顔料７重量部を含む通常の
ＳＭＣ用熱硬化性樹脂組成物をＳＭＣ製造装置を用い
て、長さ２５ｍｍカットのガラス繊維が２５重量％含有
するように、ガラス繊維に含浸させ、４０℃で４０時間
熟成させて、厚さ２ｍｍのＳＭＣを調製した。[Preparation of SMC for molding material] 100 parts by weight of an unsaturated polyester resin, 1 part by weight of a curing agent (t-butylperoxybenzoate), 150 parts by weight of calcium carbonate having an average particle diameter of 10 μm, and 7 parts by weight of a gray pigment Using a SMC manufacturing apparatus, the ordinary thermosetting resin composition for SMC is impregnated into glass fibers so as to contain 25% by weight of glass fibers having a length of 25 mm, and aged at 40 ° C. for 40 hours. An SMC having a thickness of 2 mm was prepared.
【００３８】図１に示されるプレス成形用金型の下型を
１４５℃、上型を１２５℃に加熱し、下型に上記のよう
に賦形された加飾表面層をチャージし、次いで、該加飾
表面層の上面の型窩に、上記ＳＭＣを充填し、速度１ｍ
ｍ／秒で型閉めし、６５ｋｇ／ｃｍ2 にて１０分間保圧
して冷却し、天板表面から外周側縁に到る連続した石目
模様で加飾されたキッチンカウンターを作製した。The lower mold of the press molding die shown in FIG. 1 is heated to 145 ° C. and the upper mold is heated to 125 ° C., and the lower mold is charged with the decorative surface layer formed as described above. The above-mentioned SMC was filled in the mold cavity on the upper surface of the decorative surface layer, and the speed was 1 m.
The mold was closed at m / sec, the pressure was maintained at 65 kg / cm 2 for 10 minutes, and the kitchen counter was cooled to produce a kitchen counter decorated with a continuous grain pattern extending from the top plate surface to the outer peripheral edge.
【００３９】（実施例２）実施例１の加飾表面層と成形
材料用ＳＭＣ層の間に、目付量４５０ｇ／ｍｍ2のガラ
スマットをインサートしたこと以外、実施例１と同様に
して天板表面から外周側縁に到る連続した石目模様で加
飾されたキッチンカウンターを作製した。Example 2 A top plate was produced in the same manner as in Example 1 except that a glass mat having a basis weight of 450 g / mm 2 was inserted between the decorative surface layer of Example 1 and the SMC layer for molding material. A kitchen counter decorated with a continuous stone pattern extending from the surface to the outer peripheral edge was produced.
【００４０】（実施例３）図１に示される実施例１のプ
レス成形用金型に替えて、図２に示される、加飾成形品
用金型のパーティングライン部に開口する吸引孔５よ
り、金型内を減圧するプレス成形用金型を用い、型閉め
開始後より、金型内を−６００ｍｍＨｇまで減圧した
後、完全に型閉めしたこと以外、実施例１と同様にして
天板表面から外周側縁に到る連続した石目模様で加飾さ
れたキッチンカウンターを作製した。Example 3 Instead of the press-molding mold of Example 1 shown in FIG. 1, a suction hole 5 opened in the parting line portion of the decorative molded product mold shown in FIG. Using a press-molding mold for depressurizing the inside of the mold, the top plate was subjected to the same procedure as in Example 1 except that the inside of the mold was depressurized to -600 mmHg from the start of closing the mold, and the mold was completely closed. A kitchen counter decorated with a continuous stone pattern extending from the surface to the outer peripheral edge was produced.
【００４１】（実施例４）図１に示される実施例２のプ
レス成形用金型に替えて、図２に示される、加飾成形品
用金型のパーティングライン部に開口する吸引孔５よ
り、金型内を減圧するプレス成形用金型を用い、型閉め
開始後より、金型内を−６００ｍｍＨｇまで減圧した
後、完全に型閉めしたこと以外、実施例２と同様にして
天板表面から外周側縁に到る連続した石目模様で加飾さ
れたキッチンカウンターを作製した。Example 4 Instead of the press-molding die of Example 2 shown in FIG. 1, a suction hole 5 opened in the parting line portion of the decorative molded product die shown in FIG. Using a press-molding mold for depressurizing the inside of the mold, the top plate was subjected to the same procedure as in Example 2 except that the inside of the mold was depressurized to -600 mmHg and then completely closed after the start of mold closing. A kitchen counter decorated with a continuous stone pattern extending from the surface to the outer peripheral edge was produced.
【００４２】（実施例５）実施例３の金型内を減圧を−
２００ｍｍＨｇに変更したこと以外、実施例３と同様に
して天板表面から外周側縁に到る連続した石目模様で加
飾されたキッチンカウンターを作製した。(Embodiment 5) The inside of the mold of Embodiment 3 was depressurized.
Except for changing to 200 mmHg, a kitchen counter decorated with a continuous stone pattern extending from the surface of the top plate to the outer peripheral edge was produced in the same manner as in Example 3.
【００４３】（比較例１）実施例１のＢＭＣを実施例１
のＳＭＣと同様の厚さのシート状成形材料に再加工して
用い、予備賦形することなく、実施例１と同様に加熱さ
れた図３に示すプレス成形用金型の下型２に同重量でチ
ャージし、この上から実施例１の成形材料用ＳＭＣを充
填し、実施例１と同じ成形条件で、天板表面から外周側
縁に到る連続した石目模様で加飾されたキッチンカウン
ターを作製した。(Comparative Example 1) The BMC of Example 1 was replaced with Example 1
3 was reworked into a sheet-like molding material having the same thickness as that of SMC, and was used in the same manner as in Example 1 but without preforming to the lower mold 2 of the press molding die shown in FIG. The kitchen was charged by weight, filled with the molding material SMC of Example 1 from above, and decorated with a continuous stone pattern from the top plate surface to the outer peripheral edge under the same molding conditions as in Example 1. A counter was made.
【００４４】（比較例２）比較例１の柄剤入り熱硬化性
樹脂組成物（シート化ＢＭＣ）と成形材料用ＳＭＣ層の
間に、目付量４５０ｇ／ｍｍ2 のガラスマットをインサ
ートしたこと以外、実施例１と同様にして天板表面から
外周側縁に到る連続した石目模様で加飾されたキッチン
カウンターを作製した。Comparative Example 2 A glass mat having a basis weight of 450 g / mm 2 was inserted between the pattern-containing thermosetting resin composition (sheeted BMC) of Comparative Example 1 and the molding material SMC layer. In the same manner as in Example 1, a kitchen counter decorated with a continuous stone pattern extending from the top plate surface to the outer peripheral side edge was manufactured.
【００４５】実施例１〜５及び比較例１、２で得られた
加飾成形品の表面品質を評価するため、目視にて加飾用
熱硬化性樹脂組成物と成形材料の熱硬化性樹脂組成物の
２層の樹脂組成物の混じりの有無を中心に、表面の膨
れ、微細な気泡痕の有無、表面光沢の良否等を併せて検
査し、◎：２層の樹脂組成物の混じりがなく、表面光沢
が良好であって、肉眼的には全く欠点が認められないも
の、○：２層の樹脂組成物の混じりがなく、肉眼的には
全く欠点が認められないが、表面光沢が◎よりやや劣る
もの、×：２層の樹脂組成物の混じりが認められ、その
他表面欠陥が認められるもの（その他表面欠陥は備考欄
に示した。）、の３段階で評価した。In order to evaluate the surface quality of the decorative molded products obtained in Examples 1 to 5 and Comparative Examples 1 and 2, the decorative thermosetting resin composition and the thermosetting resin of the molding material were visually observed. Inspection of the surface swelling, the presence or absence of fine air bubble traces, the surface gloss, etc. are also performed, mainly focusing on the presence or absence of the mixture of the two layers of the resin composition. 、: The mixture of the two layers of the resin composition No surface defects were observed, and no defects were visually observed. ：: No mixture of the two layers of the resin composition was observed, and no defects were visually observed. ◎ Slightly inferior, ×: Two levels of resin composition mixed, and other surface defects were observed (other surface defects are shown in the remarks column).
【００４６】[0046]
【表１】 [Table 1]
【００４７】表１より明らかなように、実施例１〜５で
得られた加飾成形品の表面品質は、いずれも加飾用熱硬
化性樹脂組成物と成形材料の熱硬化性樹脂組成物の２層
の樹脂組成物の混じりは全く認められなかったが、比較
例１及び２で得られた加飾成形品の表面品質は、いずれ
も上記２層の樹脂組成物の混じりが認められ、両グルー
プ間に上記２層の樹脂組成物の混じりにおいて、明らか
な有位差が認められる。又、実施例１及び２で得られた
加飾成形品の表面光沢は、実施例３〜５で得られた加飾
成形品の表面光沢より優れており、本発明の加飾成形品
の製造方法において、金型の−６００ｍｍＨｇ程度の減
圧は、加飾成形品の表面光沢を一層増大させ、加飾効果
を高からしめるものであることを示している。As is clear from Table 1, the surface quality of the decorative molded articles obtained in Examples 1 to 5 was as follows: the decorative thermosetting resin composition and the thermosetting resin composition of the molding material. No mixing of the two-layer resin composition was observed at all, but the surface qualities of the decorative molded products obtained in Comparative Examples 1 and 2 were all mixed with the two-layer resin composition, A clear significant difference is observed between the two groups in the mixing of the two layers of the resin composition. Moreover, the surface gloss of the decorative molded product obtained in Examples 1 and 2 is superior to the surface gloss of the decorative molded product obtained in Examples 3 to 5, and the production of the decorative molded product of the present invention. In the method, it is shown that the reduced pressure of about -600 mmHg of the mold further increases the surface gloss of the decorative molded product and enhances the decorative effect.
【００４８】[0048]
【発明の効果】請求項１記載の発明の加飾成形品の製造
方法は、叙上のように構成されているので、天板表面な
いしは床面から外周側縁ないしは立上り内周側縁に到る
まで完全に連続した図柄からなる加飾表面層の寸法精度
を極めて高いレベルで低コストで調製できる。又、加飾
表面層と成形材料が製造時の加熱加圧によって相互にし
み出して加飾表面を汚損するおそれがなく、立体的深味
のある加飾を施すことができると共に、加飾表面層と成
形材料層の両層は完全に一体化して強固に固着している
ものである。The method for manufacturing a decorative molded product according to the first aspect of the present invention is configured as described above, and thus reaches the outer peripheral edge or the rising inner peripheral edge from the top plate surface or floor surface. The dimensional accuracy of the decorative surface layer consisting of a completely continuous pattern can be adjusted at an extremely high level at a low cost. In addition, the decorative surface layer and the molding material do not exude to each other due to the heating and pressurizing during the production and contaminate the decorative surface, and the decorative surface layer can be decorated with a three-dimensional richness. And the molding material layer are completely integrated and firmly fixed.
【００４９】更に、本発明の加飾成形品の製造方法は、
原料を単純なチャージによって機械化でき、しかも、複
数の取扱い難い原材料を、加飾位置を正確に意識してチ
ャージする必要が全くないので、天板表面ないしは床面
から外周側縁ないしは立上り内周側縁に到るまで完全に
連続した図柄からなる加飾成形品を生産性高く製造する
ことができる。Further, the method for producing a decorative molded article of the present invention
Raw materials can be mechanized by a simple charge, and there is no need to charge multiple difficult-to-handle raw materials accurately while paying attention to the decorating position. It is possible to manufacture a decorative molded product having a pattern completely continuous up to the edge with high productivity.
【００５０】請求項２記載の発明の加飾成形品の製造方
法は、叙上のように構成されているので、金型の鏡面を
転写して平滑にして緻密な表面が形成され、天板表面な
いしは床面から外周側縁ないしは立上り内周側縁に到る
まで完全に連続した図柄からなる加飾成形品表面を一層
魅力的なものとし得るものである。Since the method for manufacturing a decorative molded product according to the second aspect of the present invention is configured as described above, the mirror surface of the mold is transferred to form a smooth and dense surface. It is possible to make the surface of the decorative molded product having a pattern completely continuous from the surface or floor to the outer peripheral edge or the rising inner peripheral edge more attractive.
【図１】本発明の加飾成形品の製造方法の実施の一例を
示す断面図である。FIG. 1 is a cross-sectional view illustrating an embodiment of a method for manufacturing a decorative molded product according to the present invention.
【図２】本発明の加飾成形品の製造方法の実施の他の例
を示す断面図である。FIG. 2 is a cross-sectional view showing another embodiment of the method for manufacturing a decorative molded product according to the present invention.
【図３】従来の加飾成形品の製造方法の実施の一例を示
す断面図である。FIG. 3 is a cross-sectional view illustrating an example of a conventional method for manufacturing a decorative molded product.
【図４】従来の加飾成形品の製造方法の実施の他の例を
示す断面図である。FIG. 4 is a cross-sectional view showing another example of the implementation of the conventional method for manufacturing a decorative molded product.
１ プレス成形用金型（上型） ２ プレス成形用金型（下型） ３ 予備賦形された加飾用熱硬化性樹脂組成物（加飾
材） ４ 熱硬化性樹脂組成物からなる成形材料 ５ 減圧口 ６ 減圧用シーリング材DESCRIPTION OF SYMBOLS 1 Press molding die (upper die) 2 Press molding die (lower die) 3 Preformed thermosetting resin composition for decoration (decorative material) 4 Molding made of thermosetting resin composition Material 5 Decompression port 6 Sealing material for decompression
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ // Ｂ２９Ｋ 101:10 Ｂ２９Ｌ 31:58 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI // B29K 101: 10 B29L 31:58
Claims (2)
を含む加飾用熱硬化性樹脂組成物を金型型窩にチャージ
し、増粘して賦形し、該賦形された一面を加飾表面層と
し、裏面に熱硬化性樹脂組成物からなる成形材料を充填
して加熱加圧することを特徴とする加飾成形品の製造方
法。1. A decorating thermosetting resin composition containing a thermosetting resin, a curing agent, a patterning agent, and a reinforcing material is charged into a mold cavity, and is thickened and shaped. A method for producing a decorative molded product, characterized in that one surface is used as a decorative surface layer, and the rear surface is filled with a molding material made of a thermosetting resin composition and heated and pressed.
る請求項１記載の加飾成形品の製造方法。2. The method for manufacturing a decorative molded product according to claim 1, wherein the inside of the mold is depressurized during the heating and pressing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11920198A JPH11309732A (en) | 1998-04-28 | 1998-04-28 | Production of decorated molded article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11920198A JPH11309732A (en) | 1998-04-28 | 1998-04-28 | Production of decorated molded article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11309732A true JPH11309732A (en) | 1999-11-09 |
Family
ID=14755440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11920198A Pending JPH11309732A (en) | 1998-04-28 | 1998-04-28 | Production of decorated molded article |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11309732A (en) |
-
1998
- 1998-04-28 JP JP11920198A patent/JPH11309732A/en active Pending
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