JPH11209262A - Preparation for external use for skin - Google Patents
Preparation for external use for skinInfo
- Publication number
- JPH11209262A JPH11209262A JP30512798A JP30512798A JPH11209262A JP H11209262 A JPH11209262 A JP H11209262A JP 30512798 A JP30512798 A JP 30512798A JP 30512798 A JP30512798 A JP 30512798A JP H11209262 A JPH11209262 A JP H11209262A
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- JP
- Japan
- Prior art keywords
- water
- agar
- pref
- skin
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、高い冷却効果及び
冷涼感を有し、かつ安定性に優れる皮膚外用剤に関す
る。TECHNICAL FIELD The present invention relates to an external preparation for skin having a high cooling effect and a cool feeling and having excellent stability.
【０００２】[0002]
【従来の技術】寒天は、古くから食品原料として用いら
れている。また、寒天は化粧品や外用医薬品の増粘剤と
しても使用されている。2. Description of the Related Art Agar has long been used as a food material. Agar is also used as a thickener for cosmetics and external medicines.
【０００３】しかしながら、これら化粧品や外用医薬品
において増粘剤として寒天を用いた場合、経時保存や高
温において離水を引き起こすという問題があり、その利
用の範囲は制限されたものであった。例えば、ソビエト
特許第７１９６３０号には、チーズ分解酵素、カルボキ
シメチルセルロース、グリセリン、エタノール、香料及
び水を含む顔面乾燥皮膚用薬剤であって、皮膚組織軟化
作用及び生体組織再生作用を向上させる目的で十分量の
中性プロテアーゼ、エラスターゼ、コラゲナーゼ、寒
天、硼酸、染料及びメントールを含有する顔面乾燥皮膚
用薬剤のように、極めて限定された処方に寒天が配合さ
れているにすぎない。近年では、特開平５−３１７００
８号、特開平６−５６６２５号公報に示される低強度寒
天のような流動性の高いものも開発され、化粧品等での
利用も提案されている。[0003] However, when agar is used as a thickener in these cosmetics and external medicines, there is a problem in that they can be stored over time or cause water separation at high temperatures, and the range of their use has been limited. For example, Soviet Patent No. 719630 discloses a drug for dry skin of the face containing a cheese-decomposing enzyme, carboxymethylcellulose, glycerin, ethanol, a fragrance and water, which is sufficient for the purpose of improving the skin tissue softening action and the living tissue regeneration action. Agar is only incorporated into very limited formulations, such as facial dry skin medications containing amounts of neutral proteases, elastase, collagenase, agar, boric acid, dyes and menthol. In recent years, Japanese Patent Application Laid-Open No. 5-31700
No. 8 and Japanese Unexamined Patent Publication No. 6-56625, a low-strength agar having high fluidity has been developed, and its use in cosmetics and the like has been proposed.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、安定で離水
を起こさず、かつ冷却効果及び冷涼感に優れる外用剤を
提供することを目的とする。SUMMARY OF THE INVENTION An object of the present invention is to provide an external preparation which is stable, does not cause water separation, and has an excellent cooling effect and cool feeling.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、寒天を配
合した外用剤において、寒天として特定のゼリー強度を
有する寒天を用い、これに水溶性高分子を配合して水性
ジェル状とすることにより、系の安定性が顕著に向上す
ると共に、寒天の高い水分保持能に基づく優れた冷却効
果が得られること、また冷感剤を併用すれば冷感剤の効
果をより一層高められることを見出し、本発明を完成し
た。Means for Solving the Problems In an external preparation containing agar, the present inventors use agar having a specific jelly strength as agar, and blend a water-soluble polymer with the agar to form an aqueous gel. Thereby, the stability of the system is remarkably improved, and an excellent cooling effect based on the high water retention ability of agar is obtained, and the effect of the cooling sensation agent can be further enhanced by using a cooling sensation agent in combination. And completed the present invention.
【０００６】すなわち、本発明は、次の成分（Ａ）、
（Ｂ）、（Ｃ）及び（Ｄ）； （Ａ）１．５重量％水溶液のゼリー強度が２５０ｇ／cm
2 以下の低強度寒天、（Ｂ）水溶性高分子、（Ｃ）冷感
剤、（Ｄ）水を含有する皮膚外用剤を提供するものであ
る。That is, the present invention provides the following component (A):
(B), (C) and (D); (A) The jelly strength of a 1.5% by weight aqueous solution is 250 g / cm.
The present invention provides an external preparation for skin containing 2 or less low-strength agar, (B) a water-soluble polymer, (C) a cooling sensation agent, and (D) water.
【０００７】[0007]
【発明の実施の形態】本発明で用いられる成分（Ａ）
は、１．５重量％寒天濃度（水中）でゼリー強度が２５
０ｇ／cm2 以下の低強度寒天であり、当該ゼリー強度が
２５０ｇ／cm2を超えると皮膚外用剤としての使用感が
悪くなる。また、当該ゼリー強度は５０〜２５０ｇ／cm
2 、特に８０〜２００ｇ／cm2 が好ましい。かかる低強
度寒天は、例えば特開平５−３１７００８号公報に記載
の如くして得られ、そのゼリー強度は次のようにして測
定される。BEST MODE FOR CARRYING OUT THE INVENTION Component (A) used in the present invention
Has a jelly strength of 25 at 1.5% by weight agar concentration (in water).
It is a low-strength agar of 0 g / cm 2 or less, and if the jelly strength exceeds 250 g / cm 2 , the feeling of use as an external preparation for skin deteriorates. The jelly strength is 50 to 250 g / cm.
2 , particularly preferably 80 to 200 g / cm 2 . Such low-strength agar is obtained, for example, as described in JP-A-5-317008, and its jelly strength is measured as follows.
【０００８】（１）測定装置 レオメーター ＮＲＭ−２００Ｊ（不動工業製） プランジャー：円筒形プランジャー、面積＝１cm2 試料台上昇速度：２cm／min （２）試料の調製 １）寒天試料３．０ｇを精秤し、風袋を測った容器（容
量０．５Ｌ）に入れ、イオン交換水５０mLを加えて十分
吸水させる。 ２）温イオン交換水を加えて内容量を約２１０ｇにし、
熱水浴にて１５分間加熱溶解する。 ３）内容量を２００．０ｇに調整し、内径４９mm，深さ
５７mmのガラス容器に図１のようにテープを巻きつけた
ものに流し入れる。 ４）室温にて１時間放冷し、ふたをして２０℃の恒温室
で一晩放置する。 （３）ゼリー強度の測定 テープを取り外し、カッターで容器縁部上のゼリーをカ
ットする。得られた１．５％水ゲルのカット面を試料と
してレオメーターで強度を測定する。(1) Measuring device Rheometer NRM-200J (manufactured by Fudo Kogyo) Plunger: cylindrical plunger, area = 1 cm 2 Sample stage lifting speed: 2 cm / min (2) Preparation of sample 1) Agar sample 0 g is precisely weighed, placed in a tared container (volume: 0.5 L), and 50 mL of ion-exchanged water is added to absorb water sufficiently. 2) Add warm ion exchanged water to make the content about 210g,
Heat and dissolve in a hot water bath for 15 minutes. 3) Adjust the content to 200.0 g, and pour it into a glass container having an inner diameter of 49 mm and a depth of 57 mm wound with a tape as shown in FIG. 4) Allow to cool at room temperature for 1 hour, cover and leave in a constant temperature room at 20 ° C. overnight. (3) Measurement of jelly strength Remove the tape and cut the jelly on the edge of the container with a cutter. The cut surface of the obtained 1.5% water gel is used as a sample and the strength is measured with a rheometer.
【０００９】本発明の皮膚外用剤への低強度寒天の配合
量は、系中への十分な水の保持性及びゲルの硬化による
溶解性や使用感の観点から全組成の０．１〜１０重量
％、特に１〜３重量％が好ましい。The amount of low-strength agar to be added to the external preparation for skin of the present invention may be 0.1 to 10 of the total composition in view of sufficient water retention in the system, solubility due to curing of the gel, and feeling of use. % By weight, especially 1-3% by weight, is preferred.
【００１０】本発明で用いられる（Ｂ）水溶性高分子と
しては、例えばキサンタンガム、アルギン酸ナトリウ
ム、カラギーナン、クインスシードガム、ヒアルロン
酸、ペクチン等の天然高分子；メチルセルロース、ヒド
ロキシメチルセルロース、ヒドロキシエチルセルロー
ス、ヒドロキシプロピルセルロース、カルボキシメチル
セルロース等のセルロース誘導体；ポリビニルアルコー
ル、カルボキシビニルポリマー、ポリアクリル酸ナトリ
ウム、ポリメタクリル酸ナトリウム、ポリアクリル酸グ
リセリンエステル、ポリビニルピロリドン等の合成高分
子が挙げられ、なかでもキサンタンガム及びカルボキシ
ビニルポリマーが好ましい。The (B) water-soluble polymer used in the present invention includes, for example, natural polymers such as xanthan gum, sodium alginate, carrageenan, quince seed gum, hyaluronic acid and pectin; methylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropyl Cellulose derivatives such as cellulose and carboxymethylcellulose; synthetic polymers such as polyvinyl alcohol, carboxyvinyl polymer, sodium polyacrylate, sodium polymethacrylate, glycerin polyacrylate, and polyvinylpyrrolidone; among them, xanthan gum and carboxyvinyl polymer Is preferred.
【００１１】これら（Ｂ）水溶性高分子は単独で又は２
種以上を組み合わせて使用することができる。（Ｂ）成
分は、寒天の離水の抑制、及び冷却効果の観点から、皮
膚外用剤中に、（Ａ）低強度寒天の配合量に対して１〜
１００重量％、特に１０〜１００重量％配合するのが好
ましい。These (B) water-soluble polymers may be used alone or
More than one species can be used in combination. The component (B) is contained in the external preparation for skin in an amount of 1 to 1 in the amount of (A) low-strength agar in the skin external preparation from the viewpoints of suppressing water separation of the agar and cooling effect.
It is preferable to add 100% by weight, especially 10 to 100% by weight.
【００１２】本発明で用いられる（Ｃ）冷感剤として
は、例えばl-メントール、dl-メントール、d-カンフ
ル、dl-カンフル、d-ボルネオール、dl-ボルネオール等
のメントール類、カンフル類、ボルネオール類などの化
合物が挙げられる。これらの一種又は二種以上を含む植
物抽出物、例えばペパーミント油、ペパーミントエキ
ス、シソ抽出物、クスノキ抽出物、ラベンダー抽出物等
を用いることもできる。The (C) cooling sensation agent used in the present invention includes, for example, menthols such as l-menthol, dl-menthol, d-camphor, dl-camphor, d-borneol, dl-borneol, camphors and borneol. And the like. Plant extracts containing one or more of these, for example, peppermint oil, peppermint extract, perilla extract, camphor tree extract, lavender extract, etc. can also be used.
【００１３】これら（Ｃ）冷感剤は単独で又は２種以上
を組み合わせて使用することができる。（Ｃ）成分は、
冷涼感と皮膚への刺激の観点から皮膚外用剤中に、０．
００１〜１０重量％、特に０．０１〜１重量％配合する
のが好ましい。These cooling sensates (C) can be used alone or in combination of two or more. The component (C)
From the viewpoint of cooling sensation and irritation to the skin, 0.
001 to 10% by weight, particularly 0.01 to 1% by weight, is preferred.
【００１４】（Ｄ）水は、本発明の皮膚外用剤中に１０
〜９５重量％、特に５０〜９０重量％配合するのが好ま
しい。(D) Water is contained in the external preparation for skin of the present invention in an amount of 10%.
It is preferable that the compounding amount be from 95 to 95% by weight, especially from 50 to 90% by weight.
【００１５】本発明の皮膚外用剤には、上記必須成分の
ほか、本発明の効果を損ねない範囲において、通常、化
粧品、外用医薬部外品、外用医薬品等に配合される成
分、例えばエタノール、油性物質、保湿剤、防腐剤、乳
化剤、薬効成分、粉体、紫外線吸収剤、色素、香料、乳
化安定剤、pH調整剤等を成分を適宜配合することができ
る。The external preparation for skin of the present invention includes, in addition to the above essential components, components usually incorporated in cosmetics, quasi-drugs for external use, and external medicines as long as the effects of the present invention are not impaired. Components such as oily substances, humectants, preservatives, emulsifiers, medicinal ingredients, powders, ultraviolet absorbers, pigments, fragrances, emulsion stabilizers, pH adjusters and the like can be appropriately compounded.
【００１６】本発明の皮膚外用剤は、常法に従って製造
することができ、水性ジェル状の形態であって、皮膚化
粧料、外用医薬品、外用医薬部外品等に適用することが
できる。The external preparation for skin of the present invention can be produced according to a conventional method, is in the form of an aqueous gel, and can be applied to skin cosmetics, external medicines, quasi-drugs and the like.
【００１７】[0017]
【実施例】実施例１〜６及び比較例１〜４ 表１に示す水性ジェルを下記の方法に従って調製し、評
価した。 （製法）成分（ａ）、（ｂ）及び水を混合し、８０℃に
熱して溶解し、撹拌しながら徐々に冷却した後、他の成
分を加え、その後脱気する。EXAMPLES Examples 1 to 6 and Comparative Examples 1 to 4 The aqueous gels shown in Table 1 were prepared and evaluated according to the following methods. (Preparation method) The components (a) and (b) and water are mixed, dissolved by heating to 80 ° C., and gradually cooled with stirring. Then, other components are added, followed by degassing.
【００１８】（評価方法） ・安定性 ４０℃にて１カ月保存後の離水の程度を目視により下記
基準に従って評価した。この結果を表１に示す。 評価基準： ○：離水は見られない △：わずかに水のしみ出しがある ×：水のしみ出しがある(Evaluation Method) Stability The degree of water separation after storage at 40 ° C. for one month was visually evaluated according to the following criteria. Table 1 shows the results. Evaluation criteria: ○: no water separation is observed △: slight seepage of water ×: seepage of water
【００１９】・使用感 ２０〜３５才の日本人女性パネラー２０名に、各水性ジ
ェルのそれぞれを洗顔後の顔の全体に塗布させ、その使
用感を下記基準に従って官能評価した。この結果を表１
に示す。 評価基準： ○：１６名以上が冷涼感があると回答した △：６〜１５名が冷涼感があると回答した ×：５名以下が冷涼感があると回答したEase of Use Twenty Japanese female panelists aged 20 to 35 years old were applied with each of the water-based gels over the entire face after washing their face, and the organoleptic feeling was evaluated according to the following criteria. Table 1 shows the results.
Shown in Evaluation criteria: ○: 16 or more responded that there was a cool feeling Δ: 6 to 15 responded that there was a cool feeling ×: 5 or less answered that there was a cool feeling
【００２０】・冷却効果 同じ女性パネラー２０名に、洗顔後、各水性ジェルを顔
の半面に塗布させ、温度２５℃、湿度４０％のもとで１
分間放置後の皮膚温を測定し、未塗布部との差によって
冷却効果を評価した。２０名の平均値を表１に示す。Cooling effect After washing the face, the same 20 female panelists applied each water-based gel to one half of the face, and applied at 25 ° C and 40% humidity.
The skin temperature after standing for minutes was measured, and the cooling effect was evaluated based on the difference from the uncoated portion. Table 1 shows the average values of the 20 persons.
【００２１】[0021]
【表１】 [Table 1]
【００２２】実施例７〜１０（クリーム） 表２に示すクリームを下記製法に従って調製した。 （製法）成分（イ）を８０℃で３０分間攪拌し、分散さ
せる。油相成分（ロ）を７０℃で加熱溶解したものに、
攪拌しながら７０℃に加熱した水相成分（ハ）を加えて
乳化した後、攪拌しながら６０℃まで冷却し、６０℃に
冷却した成分（イ）及び（ニ）を加え、攪拌しながら室
温まで冷却する。得られたクリームはいずれも冷涼感、
冷却効果及び安定性に優れるものであった。Examples 7 to 10 (cream) The creams shown in Table 2 were prepared according to the following method. (Preparation method) The component (a) is stirred and dispersed at 80 ° C. for 30 minutes. The oil phase component (b) is heated and dissolved at 70 ° C.
The aqueous phase component (c) heated to 70 ° C. was added with stirring, and the mixture was emulsified. The mixture was cooled to 60 ° C. with stirring, and the components (a) and (d) cooled to 60 ° C. were added. Cool down to The resulting creams are all cool,
It was excellent in cooling effect and stability.
【００２３】[0023]
【表２】 [Table 2]
【００２４】実施例１１〜１４（乳液） 表３に示す乳液を下記製法に従って調製した。 （製法）成分（イ）を８０℃で３０分間攪拌し、分散さ
せる。油相成分（ロ）を７０℃で加熱溶解したものに、
攪拌しながら７０℃に加熱した水相成分（ハ）を加えて
乳化した後、攪拌しながら６０℃まで冷却し、６０℃に
冷却した成分（イ）及び（ニ）を加え、攪拌しながら室
温まで冷却する。得られた乳液はいずれも冷涼感、冷却
効果及び安定性に優れるものであった。Examples 11 to 14 (Emulsion) The emulsions shown in Table 3 were prepared according to the following production method. (Preparation method) The component (a) is stirred and dispersed at 80 ° C. for 30 minutes. The oil phase component (b) is heated and dissolved at 70 ° C.
The aqueous phase component (c) heated to 70 ° C. was added with stirring, and the mixture was emulsified. The mixture was cooled to 60 ° C. with stirring, and the components (a) and (d) cooled to 60 ° C. were added. Cool down to All the obtained emulsions were excellent in cooling feeling, cooling effect and stability.
【００２５】[0025]
【表３】 [Table 3]
【００２６】[0026]
【発明の効果】本発明の皮膚外用剤は、高い冷却効果及
び冷涼感を有し、かつ安定性に優れるものである。The external preparation for skin of the present invention has a high cooling effect and a cool feeling, and is excellent in stability.
【図１】寒天のゼリー強度測定時の試料容器及びカット
面を示す図である。FIG. 1 is a view showing a sample container and a cut surface when measuring the jelly strength of agar.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ａ６１Ｋ 7/00 Ａ６１Ｋ 7/00 Ｊ ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI A61K 7/00 A61K 7/00 J
Claims (4)
（Ｄ）；（Ａ）１．５重量％水溶液のゼリー強度が２５
０ｇ／cm2 以下の低強度寒天、（Ｂ）水溶性高分子、
（Ｃ）冷感剤、（Ｄ）水を含有する皮膚外用剤。1. The following components (A), (B), (C) and (D): (A) a 1.5% by weight aqueous solution having a jelly strength of 25
0 g / cm 2 or less low-strength agar, (B) water-soluble polymer,
(C) a cooling agent, and (D) an external preparation for skin containing water.
又はカルボキシビニルポリマーである請求項１記載の皮
膚外用剤。2. The external preparation for skin according to claim 1, wherein the water-soluble polymer (B) is xanthan gum or carboxyvinyl polymer.
ル類及びボルネオール類から選ばれる一種もしくは二種
以上の化合物、又は当該化合物を含む植物抽出物の一種
もしくは二種以上である請求項１又は２記載の皮膚外用
剤。3. The (C) cooling sensation agent is one or more compounds selected from menthols, camphors and borneols, or one or more plant extracts containing the compounds. 3. The external preparation for skin according to 1 or 2.
０．１〜１０重量％であり、かつ（Ｂ）水溶性高分子の
含有量が（Ａ）成分の含有量に対して１０〜１００重量
％である請求項１〜３のいずれかに記載の皮膚外用剤。4. The content of (A) low-strength agar is 0.1 to 10% by weight of the whole composition, and the content of (B) the water-soluble polymer is more than the content of component (A). The external preparation for skin according to any one of claims 1 to 3, which is 10 to 100% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10305127A JP2985083B2 (en) | 1997-10-28 | 1998-10-27 | External preparation for skin |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9-295433 | 1997-10-28 | ||
| JP29543397 | 1997-10-28 | ||
| JP10305127A JP2985083B2 (en) | 1997-10-28 | 1998-10-27 | External preparation for skin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11209262A true JPH11209262A (en) | 1999-08-03 |
| JP2985083B2 JP2985083B2 (en) | 1999-11-29 |
Family
ID=26560272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10305127A Expired - Fee Related JP2985083B2 (en) | 1997-10-28 | 1998-10-27 | External preparation for skin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2985083B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010106779A (en) * | 2000-05-23 | 2001-12-07 | 이우일 | A Cosmetic Formentum Including the Extract from Gelidiaceae as a Major Component |
| JP2003055193A (en) * | 2001-08-07 | 2003-02-26 | Taisho Pharmaceut Co Ltd | Refrigerant-containing gel-like external preparation |
| KR20030028255A (en) * | 2001-09-27 | 2003-04-08 | (주)지씨아이 | Preparation of Burn Ointments using Algin and Xanthane Gum |
| JP2004231619A (en) * | 2003-02-03 | 2004-08-19 | Pola Chem Ind Inc | Emulsion composition, emulsion cosmetic containing the same as constituent and method for producing the same |
| WO2011136270A1 (en) | 2010-04-28 | 2011-11-03 | 株式会社資生堂 | Thickening composition and cosmetics containing same |
| EP2545903A1 (en) * | 2010-03-12 | 2013-01-16 | The Nisshin Oillio Group, Ltd. | Composition for external use on skin, cosmetic, and cleaning agent |
| JP2013139423A (en) * | 2012-01-06 | 2013-07-18 | Fancl Corp | Gel-like composition |
| CN104188864A (en) * | 2014-08-28 | 2014-12-10 | 广州芭薇化妆品有限公司 | Composition with cooling effect, externally applied preparation and preparation method thereof |
-
1998
- 1998-10-27 JP JP10305127A patent/JP2985083B2/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010106779A (en) * | 2000-05-23 | 2001-12-07 | 이우일 | A Cosmetic Formentum Including the Extract from Gelidiaceae as a Major Component |
| JP2003055193A (en) * | 2001-08-07 | 2003-02-26 | Taisho Pharmaceut Co Ltd | Refrigerant-containing gel-like external preparation |
| KR20030028255A (en) * | 2001-09-27 | 2003-04-08 | (주)지씨아이 | Preparation of Burn Ointments using Algin and Xanthane Gum |
| JP2004231619A (en) * | 2003-02-03 | 2004-08-19 | Pola Chem Ind Inc | Emulsion composition, emulsion cosmetic containing the same as constituent and method for producing the same |
| EP2545903A1 (en) * | 2010-03-12 | 2013-01-16 | The Nisshin Oillio Group, Ltd. | Composition for external use on skin, cosmetic, and cleaning agent |
| EP2545903A4 (en) * | 2010-03-12 | 2015-08-05 | Nisshin Oillio Group Ltd | Composition for external use on skin, cosmetic, and cleaning agent |
| JP2015145416A (en) * | 2010-03-12 | 2015-08-13 | 日清オイリオグループ株式会社 | External composition for skin, cosmetic, detergent, and method for producing cosmetic |
| US9125839B2 (en) | 2010-03-12 | 2015-09-08 | The Nisshin Oillio Group, Ltd. | Composition for external use on skin, cosmetic, and cleaning agent |
| JP5861241B2 (en) * | 2010-03-12 | 2016-02-16 | 日清オイリオグループ株式会社 | EXTERNAL SKIN COMPOSITION, COSMETIC, AND CLEANING AGENT |
| WO2011136270A1 (en) | 2010-04-28 | 2011-11-03 | 株式会社資生堂 | Thickening composition and cosmetics containing same |
| JP2013139423A (en) * | 2012-01-06 | 2013-07-18 | Fancl Corp | Gel-like composition |
| CN104188864A (en) * | 2014-08-28 | 2014-12-10 | 广州芭薇化妆品有限公司 | Composition with cooling effect, externally applied preparation and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2985083B2 (en) | 1999-11-29 |
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