JPH1072778A - Finishing composition for clothe and finishing article for clothe - Google Patents
Finishing composition for clothe and finishing article for clotheInfo
- Publication number
- JPH1072778A JPH1072778A JP22665096A JP22665096A JPH1072778A JP H1072778 A JPH1072778 A JP H1072778A JP 22665096 A JP22665096 A JP 22665096A JP 22665096 A JP22665096 A JP 22665096A JP H1072778 A JPH1072778 A JP H1072778A
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- water
- clothing
- clothing according
- silicone
- Prior art date
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は衣料用仕上剤組成物
及び衣料用仕上剤物品に関し、さらに詳しくは、仕上剤
処理工程に高熱が付与される場合の衣料用仕上剤組成物
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a finish composition for clothing and a finish article for clothing, and more particularly to a finish composition for clothing when high heat is applied to the finish treatment step.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】衣料用
仕上剤組成物は、洗濯処理工程のすすぎ時に投与される
のが一般的であり、これらの代表的なものとして柔軟仕
上剤、糊剤等が挙げられる。これらは処理後、自然乾燥
又は乾燥機による温風乾燥されるのが一般的である。し
かしながら、これらとは別に（併用してもかまわない）
衣類が乾燥あるいは生乾きした状態で処理を行う衣料用
仕上剤が存在する。このような衣料用仕上剤の目的は様
々であるが、衣類にハリ・かたさを与えること、シワを
取ること、形を整えること、香りをつけること、殺菌す
ること、折り目をつけることなどが挙げられ、特に限定
されるものではない。BACKGROUND OF THE INVENTION Finishing compositions for clothing are generally administered at the time of rinsing in the washing process, and typical examples thereof are soft finishing agents and sizing agents. And the like. After the treatment, they are generally air-dried or hot-air dried by a dryer. However, apart from these (may be used in combination)
There is a finish for clothing that performs treatment in a state where clothes are dried or freshly dried. The purpose of such a finishing agent for clothing varies, but it can be used to give the clothing firmness, to remove wrinkles, to shape it, to give a scent, to sterilize it, to make folds, etc. It is not particularly limited.
【０００３】それらは処理後、アイロンによる乾燥を行
うのが常である。従って、それらの衣料用仕上剤組成物
にはアイロンの表面温度でも分解しない耐熱性が要求さ
れる。家庭用のアイロンの表面温度は繊維の種類に合わ
せた設定にもよるが、高温の場合、 200℃を越える。従
来のアイロンによる乾燥を必要とする衣料用仕上剤組成
物は、主に化工澱粉を含んだ水溶液であった。化工澱粉
水溶液はアイロンかけを繰り返すうちに、アイロンに付
着し、黄変し、衣料を汚すことがあった。[0003] After treatment, they are usually dried by ironing. Therefore, these finishing compositions for clothing are required to have heat resistance that does not decompose even at the surface temperature of the iron. The surface temperature of household irons, depending on the type of fiber used, can exceed 200 ° C at high temperatures. Conventional finish compositions for clothing that require drying with an iron have been aqueous solutions containing predominantly modified starch. During repeated ironing, the modified starch aqueous solution sometimes adhered to the iron, turned yellow, and stained clothing.
【０００４】[0004]
【課題を解決するための手段】本発明者らは鋭意研究の
結果、アイロンの表面温度では熱分解しない特定の水溶
性高分子を用いることにより、上記問題点のない衣料用
仕上剤組成物が得られることを見いだし、本発明を完成
するに至った。Means for Solving the Problems As a result of intensive studies, the present inventors have found that the use of a specific water-soluble polymer that does not thermally decompose at the surface temperature of an iron makes it possible to obtain a finish composition for clothing that does not have the above-mentioned problems. The inventors have found that the present invention can be obtained, and have completed the present invention.
【０００５】すなわち本発明は、下記 (i)〜(v) から選
ばれ、且つ熱分解温度が 200℃以上である水溶性高分子
を含むことを特徴とする衣料用仕上剤組成物を提供する
ものである。 (i) アクリル酸もしくはメタクリル酸のホモポリマー及
びアクリル酸もしくはメタクリル酸と他のビニル系モノ
マーの１種又は２種以上とのコポリマー並びにこれらの
塩（以下ポリマー(i) という） (ii)アクリル酸及び／又はメタクリル酸と、それらのア
ルキルエステルの１種又は２種以上とを重合して得られ
るコポリマー又はその塩（以下ポリマー(ii)という） (iii) ポリエチレンオキシド（以下ポリマー(iii)とい
う） (iv)ポリアクリルアミド（以下ポリマー(iv)という） (v) ポリビニルエーテル（以下ポリマー(v)という） 以下、本発明の衣料用仕上剤組成物に用いられる水溶性
ポリマーについて説明する。That is, the present invention provides a finish composition for clothing, comprising a water-soluble polymer selected from the following (i) to (v) and having a thermal decomposition temperature of 200 ° C. or higher. Things. (i) a homopolymer of acrylic acid or methacrylic acid and a copolymer of acrylic acid or methacrylic acid with one or more other vinyl monomers and salts thereof (hereinafter referred to as polymer (i)) (ii) acrylic acid And / or a copolymer thereof obtained by polymerizing methacrylic acid and one or more alkyl esters thereof or a salt thereof (hereinafter referred to as polymer (ii)) (iii) Polyethylene oxide (hereinafter referred to as polymer (iii)) (iv) Polyacrylamide (hereinafter referred to as polymer (iv)) (v) Polyvinyl ether (hereinafter referred to as polymer (v)) Hereinafter, the water-soluble polymer used in the finish composition for clothing of the present invention will be described.
【０００６】＜ポリマー(i)＞本発明の組成物に用いら
れるポリマー(i) は、アクリル酸もしくはメタクリル酸
のホモポリマー及び／又はアクリル酸もしくはメタクリ
ル酸と他のビニル系モノマーの１種又は２種以上とのコ
ポリマー並びにこれらの塩である。その他のビニル系モ
ノマーとしては、マレイン酸、無水マレイン酸、ヒドロ
キシエチルアクリル酸、ヒドロキシエチルメタクリル
酸、エチレン、プロピレン、ｎ−ブテン、イソブテン、
ペンテン、イソプレン、２−メチル−１−ブテン、ｎ−
ヘキセン、２−メチル−１−ペンテン、３−メチル−１
−ペンテン、４−メチル−１−ペンテン、２−エチル−
１−ブテン、スチレン、α−メチルスチレン、ビニルト
ルエン、ビニルナフタレン、インデン、ブタジエン、シ
クロペンタジエン、ジシクロペンタジエン等が挙げられ
る。これらの中でも、マレイン酸、無水マレイン酸、ヒ
ドロキシエチルアクリル酸、ヒドロキシエチルメタクリ
ル酸等の水溶性モノマー及びこれらのモノマーの塩が好
ましい。ポリマー(i) の分子量は 100〜 100万、好まし
くは 500〜50万、特に好ましくは1000〜10万である。<Polymer (i)> The polymer (i) used in the composition of the present invention may be a homopolymer of acrylic acid or methacrylic acid and / or one or two of acrylic acid or methacrylic acid and another vinyl monomer. Copolymers with more than one species and salts thereof. Other vinyl monomers include maleic acid, maleic anhydride, hydroxyethyl acrylic acid, hydroxyethyl methacrylic acid, ethylene, propylene, n-butene, isobutene,
Pentene, isoprene, 2-methyl-1-butene, n-
Hexene, 2-methyl-1-pentene, 3-methyl-1
-Pentene, 4-methyl-1-pentene, 2-ethyl-
Examples thereof include 1-butene, styrene, α-methylstyrene, vinyl toluene, vinyl naphthalene, indene, butadiene, cyclopentadiene, dicyclopentadiene and the like. Among them, water-soluble monomers such as maleic acid, maleic anhydride, hydroxyethylacrylic acid, and hydroxyethylmethacrylic acid, and salts of these monomers are preferable. The molecular weight of the polymer (i) is from 100 to 1,000,000, preferably from 500 to 500,000, particularly preferably from 1,000 to 100,000.
【０００７】＜ポリマー(ii)＞本発明の組成物に用いら
れるポリマー(ii)は、アクリル酸及び／又はメタクリル
酸とそれらのアルキルエステルの１種又は２種以上とを
重合して得られるコポリマー又はその塩であり、アルキ
ルエステルのアルキル基の炭素数は１〜20、好ましくは
２〜18である。ポリマー(ii)の分子量は 100〜 100万、
好ましくは 500〜50万、特に好ましくは1000〜10万であ
る。<Polymer (ii)> The polymer (ii) used in the composition of the present invention is a copolymer obtained by polymerizing acrylic acid and / or methacrylic acid and one or more alkyl esters thereof. Or a salt thereof, wherein the alkyl group of the alkyl ester has 1 to 20, preferably 2 to 18 carbon atoms. The molecular weight of the polymer (ii) is 1 to 1,000,000,
It is preferably from 500 to 500,000, particularly preferably from 1,000 to 100,000.
【０００８】＜ポリマー（iii）＞本発明の組成物に用
いられるポリマー(iii) は、エチレンオキサイドを重合
して得られるポリマーである。このポリマー(iii) の分
子量は1000〜 600万、好ましくは 10000から 100万、特
に好ましくは10万から 100万である。<Polymer (iii)> The polymer (iii) used in the composition of the present invention is a polymer obtained by polymerizing ethylene oxide. The molecular weight of this polymer (iii) is from 10 to 6,000,000, preferably from 10,000 to 1,000,000, particularly preferably from 100,000 to 1,000,000.
【０００９】＜ポリマー(iv)＞本発明の組成物に用いら
れるポリマー(iv)は、アクリルアミドを重合して得られ
るポリマーを指す。このポリマー(iv)の分子量は 100〜
600万、好ましくは1000〜 100万、特に好ましくは 100
00〜10万である。<Polymer (iv)> The polymer (iv) used in the composition of the present invention refers to a polymer obtained by polymerizing acrylamide. The molecular weight of this polymer (iv) is 100-
6 million, preferably 1000 to 1 million, particularly preferably 100
It is 100,000 to 100,000.
【００１０】＜ポリマー(v)＞本発明の組成物に用いら
れるポリマー(v) は、ポリビニル系ポリマーであり、具
体的には、ポリビニルメチルエーテル、ポリビニルエチ
ルエーテル、ポリビニルイソブチルエーテルが挙げられ
るが、水溶性の観点からポリビニルメチルエーテルが好
ましい。このポリマー(v) の分子量は 100〜 600万、好
ましくは1000〜100万、特に好ましくは 10000〜10万で
ある。<Polymer (v)> The polymer (v) used in the composition of the present invention is a polyvinyl polymer, and specific examples thereof include polyvinyl methyl ether, polyvinyl ethyl ether and polyvinyl isobutyl ether. From the viewpoint of water solubility, polyvinyl methyl ether is preferred. The molecular weight of the polymer (v) is from 1 to 6,000,000, preferably from 1,000 to 100,000, particularly preferably from 10,000 to 100,000.
【００１１】本発明では、上記したポリマー(i) 〜(v)
のうち、熱分解温度が 200℃以上、好ましくは250 ℃以
上、更に好ましくは300 ℃以上のポリマーが使用され
る。熱分解温度が200 ℃以上のポリマーを用いることに
より、アイロン処理等による黄変の発生が充分に抑制さ
れる。In the present invention, the above-mentioned polymers (i) to (v)
Among them, a polymer having a thermal decomposition temperature of 200 ° C. or higher, preferably 250 ° C. or higher, more preferably 300 ° C. or higher is used. By using a polymer having a thermal decomposition temperature of 200 ° C. or higher, the occurrence of yellowing due to ironing or the like is sufficiently suppressed.
【００１２】これらのポリマー(i) 〜(v) は、風合いの
観点から、組成物中に0.01〜20重量％配合されるのが好
ましく、より好ましくは0.1 〜15重量％である。These polymers (i) to (v) are preferably incorporated in the composition in an amount of 0.01 to 20% by weight, more preferably 0.1 to 15% by weight, from the viewpoint of feeling.
【００１３】[0013]
【発明の実施の形態】本発明の衣料用仕上剤組成物は、
上記特定の水溶性高分子を含有するものであるが、更に
シリコーンを含有することが好ましい。シリコーンとし
ては、水溶性シリコーンやシリコーン乳化物を用いるこ
とができ、水溶性シリコーンとしては、シリコーンに修
飾基を導入して水溶性としたものが使用できる。シリコ
ーンに修飾基を導入して水溶性にする場合の修飾基には
ポリオキシエチレン基及び／又はポリオキシプロピレン
基、あるいは４級アンモニウム基などのカチオン変性
基、カルボキシル基などのアニオン変性基などが挙げら
れ、シリコーン主鎖の側鎖又は末端のいずれか片方ある
いは両方に導入してもよい。水溶性シリコーンとして
は、ポリオキシエチレン及び／又はポリオキシプロピレ
ン変性シリコーンが好ましい。これらのエチレンオキサ
イド、プロピレンオキサイド変性シリコーンのシロキサ
ン含量は10〜90％程度である。BEST MODE FOR CARRYING OUT THE INVENTION The finish composition for clothing of the present invention comprises
It contains the above specific water-soluble polymer, but preferably further contains silicone. As the silicone, a water-soluble silicone or a silicone emulsion can be used. As the water-soluble silicone, a silicone which has been made water-soluble by introducing a modifying group into the silicone can be used. In the case where a modifying group is introduced into a silicone to make it water-soluble, the modifying group includes a polyoxyethylene group and / or a polyoxypropylene group, or a cation-modified group such as a quaternary ammonium group, or an anion-modified group such as a carboxyl group. And may be introduced into one or both of the side chain and the terminal of the silicone main chain. As the water-soluble silicone, polyoxyethylene and / or polyoxypropylene-modified silicone is preferable. The siloxane content of these ethylene oxide and propylene oxide modified silicones is about 10 to 90%.
【００１４】また、シリコーン乳化物は、適当な乳化剤
でシリコーンを乳化するが、乳化剤としては、非イオン
界面活性剤、陰イオン界面活性剤、陽イオン界面活性
剤、両性界面活性剤、ポリオキシエチレン及び／又はポ
リオキシプロピレン変性シリコーンから選ばれる１種又
は２種以上の乳化剤が用いられる。シリコーンの乳化に
使われるシリコーンは未変性シリコーンでも構わない
し、変性シリコーンでも構わない。変性シリコーンとし
ては、カルボキシ変性、アミノ変性、エポキシ変性、ア
ルキル変性などが挙げられるが、これら１種類の変性で
も構わないし、共変性でもよい。The silicone emulsion emulsifies the silicone with a suitable emulsifier. Examples of the emulsifier include a nonionic surfactant, an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and polyoxyethylene. And / or one or more emulsifiers selected from polyoxypropylene-modified silicones. The silicone used for emulsifying the silicone may be an unmodified silicone or a modified silicone. Examples of the modified silicone include carboxy-modified, amino-modified, epoxy-modified and alkyl-modified silicones. These modified silicones may be used alone or may be co-modified.
【００１５】更に本発明の衣料用仕上剤組成物には、任
意成分として、抗菌剤、殺菌剤、香料、無機塩、ｐＨ調
整剤、耐圧缶に充填する場合は防錆剤、消泡剤などを配
合することができる。また、衣料用仕上剤組成物の残部
は、通常、水である。The finishing composition for clothing of the present invention may further contain, as optional components, an antibacterial agent, a bactericide, a fragrance, an inorganic salt, a pH adjuster, a rust preventive, a defoaming agent when filled in a pressure can, and the like. Can be blended. The balance of the finish composition for clothing is usually water.
【００１６】本発明の衣料用仕上剤組成物を、スプレー
噴霧可能な容器に充填することにより、スプレー式の衣
料用仕上剤物品とすることができる。具体的には、スプ
レー手段を備えた耐圧びん又は耐圧缶などの容器に、LP
G （液化石油ガス）、DME （ジメチルエーテル）、C
O2 、N2などのガスとともに組成物を充填する。組成物
とガスの割合は重量比で95：５〜30：70、好ましくは9
0：10〜40：60である。また、スプレー手段としては、
手動式スプレーの場合、ポンプ式、トリガー式、蓄圧式
スプレーヤーが使用しうる。By filling the finish composition for clothing of the present invention into a container capable of being spray-sprayed, a spray-type finish article for clothing can be obtained. Specifically, LP is placed in a container such as a pressure bottle or pressure can equipped with spray means.
G (liquefied petroleum gas), DME (dimethyl ether), C
The composition is filled together with a gas such as O 2 and N 2 . The ratio of composition to gas is 95: 5 to 30:70 by weight, preferably 9: 5.
0:10 to 40:60. Also, as spray means,
In the case of a manual spray, a pump, trigger or accumulator sprayer can be used.
【００１７】[0017]
【実施例】以下実施例により本発明をより詳細に説明す
るが、本発明はこれらの実施例に限定されるものではな
い。The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.
【００１８】実施例１ 表１に示す水溶性高分子５重量％、表２に示すシリコー
ン0.5 重量％と、残部の水とから表３に示す組成の衣料
用仕上剤組成物を調製した。得られた衣料用仕上剤組成
物を用いて下記の方法で加熱下での着色の有無を評価し
た。その結果を表３に示す。 （評価方法）組成物 5.0ｇを直径５cmのシャーレに入
れ、電気乾燥機にて 200℃、１時間乾燥する。乾燥後の
着色の有無で判定する。組成物の熱による分解は、ＤＳ
Ｃ（示差走査熱量測定）により判別することもできる
が、実際的には、電熱器、電気乾燥器等の加熱器具を用
い、加熱した後の組成物の変化、特に着色を目視により
判定するのが実情に即し、好ましい。従って、本実施例
では、電気乾燥機による加熱試験を行った。Example 1 A finishing composition for clothing having the composition shown in Table 3 was prepared from 5% by weight of the water-soluble polymer shown in Table 1, 0.5% by weight of silicone shown in Table 2, and the balance of water. The presence or absence of coloring under heating was evaluated by the following method using the obtained finish composition for clothing. Table 3 shows the results. (Evaluation method) 5.0 g of the composition was placed in a petri dish having a diameter of 5 cm, and dried at 200 ° C for 1 hour using an electric drier. Judgment is made based on the presence or absence of coloring after drying. Decomposition of the composition by heat is DS
C (differential scanning calorimetry) can be used, but in practice, changes in the composition after heating, particularly coloring, are visually determined using a heating device such as an electric heater or an electric dryer. Is preferred according to the actual situation. Therefore, in this example, a heating test using an electric dryer was performed.
【００１９】[0019]
【表１】 [Table 1]
【００２０】（注）表１中、Ａ−１〜Ａ−５の水溶性高
分子は、熱分解温度が200 ℃以上であり、Ａ−６、Ａ−
７の水溶性高分子は、熱分解温度が200 ℃未満であっ
た。(Note) In Table 1, the water-soluble polymers of A-1 to A-5 have a thermal decomposition temperature of 200 ° C. or higher, and A-6 and A-
The water-soluble polymer of No. 7 had a thermal decomposition temperature of less than 200 ° C.
【００２１】[0021]
【表２】 [Table 2]
【００２２】[0022]
【表３】 [Table 3]
【００２３】（注）表３中の判定は以下の意味である。 ○：着色なし又は白色 ×：着色有り(Note) The judgments in Table 3 have the following meanings. ○: no coloring or white ×: coloring
Claims (10)
温度が 200℃以上である水溶性高分子を含むことを特徴
とする衣料用仕上剤組成物。 (i) アクリル酸もしくはメタクリル酸のホモポリマー及
びアクリル酸もしくはメタクリル酸と他のビニル系モノ
マーの１種又は２種以上とのコポリマー並びにこれらの
塩 (ii)アクリル酸及び／又はメタクリル酸と、それらのア
ルキルエステルの１種又は２種以上とを重合して得られ
るコポリマー又はその塩 (iii) ポリエチレンオキシド (iv)ポリアクリルアミド (v) ポリビニルエーテル1. A finishing composition for clothing comprising a water-soluble polymer selected from the following (i) to (v) and having a thermal decomposition temperature of 200 ° C. or higher. (i) a homopolymer of acrylic acid or methacrylic acid and a copolymer of acrylic acid or methacrylic acid with one or more other vinyl monomers and salts thereof (ii) acrylic acid and / or methacrylic acid; (Iii) Polyethylene oxide (iv) Polyacrylamide (v) Polyvinyl ether obtained by polymerizing one or more alkyl esters of (1) or (2)
である請求項１記載の衣料用仕上剤組成物。2. The finishing composition for clothing according to claim 1, wherein the thermal decomposition temperature of the water-soluble polymer is 250 ° C. or higher.
である請求項１又は２記載の衣料用仕上剤組成物。3. The finishing composition for clothing according to claim 1, wherein the thermal decomposition temperature of the water-soluble polymer is 300 ° C. or higher.
項１〜３の何れか１項記載の衣料用仕上剤組成物。4. The finishing composition for clothing according to claim 1, further comprising a water-soluble silicone.
及び／又はポリオキシプロピレン変性シリコーンである
請求項４記載の衣料用仕上剤組成物。5. The finish composition for clothing according to claim 4, wherein the water-soluble silicone is a polyoxyethylene and / or polyoxypropylene-modified silicone.
求項１〜３の何れか１項記載の衣料用仕上剤組成物。6. The finish composition for clothing according to claim 1, further comprising a silicone emulsified with an emulsifier.
界面活性剤、陽イオン界面活性剤、両性界面活性剤、ポ
リオキシエチレン及び／又はポリプロピレン変性シリコ
ーンから選ばれる１種又は２種以上の乳化剤である請求
項６記載の衣料用仕上剤組成物。7. The emulsifier is one or more emulsifiers selected from nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polyoxyethylene and / or polypropylene-modified silicones. The finish composition for clothing according to claim 6, which is:
01〜１μｍである請求項６又は７記載の衣料用仕上剤組
成物。8. The silicone emulsion having an average particle size of 0.0
The finish composition for clothing according to claim 6 or 7, wherein the thickness is from 01 to 1 µm.
仕上剤組成物をスプレー噴霧可能な容器に充填してなる
衣料用仕上剤物品。9. A finish article for clothing obtained by filling the finish composition for clothing according to any one of claims 1 to 8 into a container capable of being sprayed and sprayed.
器である請求項９記載の衣料用仕上剤物品。10. The finish article for clothing according to claim 9, which is a container in which spraying is manually performed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22665096A JPH1072778A (en) | 1996-08-28 | 1996-08-28 | Finishing composition for clothe and finishing article for clothe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22665096A JPH1072778A (en) | 1996-08-28 | 1996-08-28 | Finishing composition for clothe and finishing article for clothe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1072778A true JPH1072778A (en) | 1998-03-17 |
Family
ID=16848513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22665096A Pending JPH1072778A (en) | 1996-08-28 | 1996-08-28 | Finishing composition for clothe and finishing article for clothe |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH1072778A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000178598A (en) * | 1998-12-17 | 2000-06-27 | Asahi Denka Kogyo Kk | Detergent composition |
| JP2001234474A (en) * | 2000-02-23 | 2001-08-31 | Kao Corp | Treating agent for textile product for spraying |
| KR100359058B1 (en) * | 1999-11-18 | 2002-11-04 | 주식회사옥시 | a Composition for the Ironing Aid |
| US6491840B1 (en) | 2000-02-14 | 2002-12-10 | The Procter & Gamble Company | Polymer compositions having specified PH for improved dispensing and improved stability of wrinkle reducing compositions and methods of use |
| US6495058B1 (en) | 2000-02-14 | 2002-12-17 | The Procter & Gamble Company | Aqueous wrinkle control compositions dispensed using optimal spray patterns |
| JP2012509412A (en) * | 2008-11-21 | 2012-04-19 | 張家港市徳宝化工有限公司 | Modifier for polyester fiber and its production method and application |
| CN103881613A (en) * | 2014-04-17 | 2014-06-25 | 西达（无锡）生物科技有限公司 | Acrylic acid copolymerization composite adhesive as well as preparation method and application thereof |
-
1996
- 1996-08-28 JP JP22665096A patent/JPH1072778A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000178598A (en) * | 1998-12-17 | 2000-06-27 | Asahi Denka Kogyo Kk | Detergent composition |
| KR100359058B1 (en) * | 1999-11-18 | 2002-11-04 | 주식회사옥시 | a Composition for the Ironing Aid |
| US6491840B1 (en) | 2000-02-14 | 2002-12-10 | The Procter & Gamble Company | Polymer compositions having specified PH for improved dispensing and improved stability of wrinkle reducing compositions and methods of use |
| US6495058B1 (en) | 2000-02-14 | 2002-12-17 | The Procter & Gamble Company | Aqueous wrinkle control compositions dispensed using optimal spray patterns |
| US6645392B2 (en) | 2000-02-14 | 2003-11-11 | The Procter & Gamble Company | Method of removing wrinkles from fabric |
| US6652766B1 (en) | 2000-02-14 | 2003-11-25 | The Procter & Gamble Company | Articles to aid the ironing of fabrics and methods of use |
| JP2001234474A (en) * | 2000-02-23 | 2001-08-31 | Kao Corp | Treating agent for textile product for spraying |
| JP2012509412A (en) * | 2008-11-21 | 2012-04-19 | 張家港市徳宝化工有限公司 | Modifier for polyester fiber and its production method and application |
| CN103881613A (en) * | 2014-04-17 | 2014-06-25 | 西达（无锡）生物科技有限公司 | Acrylic acid copolymerization composite adhesive as well as preparation method and application thereof |
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