JPH105005A - Antislip shoe sole - Google Patents
Antislip shoe soleInfo
- Publication number
- JPH105005A JPH105005A JP18145796A JP18145796A JPH105005A JP H105005 A JPH105005 A JP H105005A JP 18145796 A JP18145796 A JP 18145796A JP 18145796 A JP18145796 A JP 18145796A JP H105005 A JPH105005 A JP H105005A
- Authority
- JP
- Japan
- Prior art keywords
- water
- rubber
- parts
- weight
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【0001】[0001]
【日常生活上の利用分野】一般に乾いている路面を歩行
する場合は滑りの問題はあまり発生しないが、雨降りの
場合や、労働の範囲が水場であったり、始終水で濡れて
いる場所では滑りの危険にしばしば直面する。[Usage area in daily life] Generally, when walking on a dry road, the problem of slippage does not occur much. However, in the case of rain, or in a place where the work area is water, or where the water is wet all the time. Often face the danger of slippage.
【0002】本発明の主な目的は、水に濡れて滑り易い
場所で履く靴の靴底を提供する事にある。特に屋外の階
段、玄関、アプローチ、歩道、屋上等は雨天時には滑り
易い。又、レストラン等の厨房、工事現場、水産物加工
工場、水産物市場又は店舗の床も水に濡れていて滑り易
い。これらの環境で履く靴の靴底の提供を目的とする。It is a primary object of the present invention to provide a shoe sole that is worn in places that are wet and slippery with water. In particular, outdoor stairs, entrances, approaches, sidewalks, and rooftops are slippery in rainy weather. Also, kitchens such as restaurants, construction sites, marine products processing factories, marine products markets or store floors are wet with water and easily slip. The purpose is to provide soles for shoes worn in these environments.
【0003】[0003]
【従来の技術】従来、水に濡れた場所で履く靴の底はゴ
ム製の場合が多い。しかし一般のゴムの場合は水に濡れ
た場合、非常に滑り易くなる。この原因は地面とゴム底
の間に水の膜が介在し、潤滑の働きをする為である。2. Description of the Related Art Conventionally, the soles of shoes worn in places wet with water are often made of rubber. However, general rubber becomes very slippery when wet with water. This is because a water film intervenes between the ground and the rubber bottom, and acts as a lubricant.
【0004】これに対し本発明の靴底は、水に濡れた地
面に対しても滑り止めの効果を発揮するので極めて安全
である。又、材質が柔らかいので、屋内の床材や屋外の
舗装材に傷をつける事もない。この意味でスパイクで滑
りをくい止めるスパイクシューズとはその発想を異にす
る。[0004] On the other hand, the shoe sole of the present invention is extremely safe because it exerts an anti-slip effect even on the ground wet with water. Further, since the material is soft, there is no possibility of damaging indoor floor materials and outdoor pavement materials. In this sense, the idea is different from spike shoes that stop slippage with spikes.
【0005】[0005]
【課題を解決するための手段】本発明者らは滑りを防止
する手段として次に述べる滑り防止靴底を付けた靴の使
用を提案する。本発明靴底は、天然ゴム又は合成ゴムあ
るいは両者のブレンドからなる配合物のゴム分100重
量部に対して融点180℃以上で水溶性の結晶物質を1
0〜500重量部、吸水性物質を0〜50重量部配合し
て加硫した後、水で結晶物質を溶出してなる多孔性エラ
ストマーを接地面の全面に、あるいは部分的に使用して
なる滑り防止靴底である。The present inventors propose the use of a shoe with an anti-slip sole as described below as a means for preventing slip. The shoe sole according to the present invention is characterized in that a water-soluble crystalline substance having a melting point of 180 ° C. or more is added to 100 parts by weight of a rubber component of a natural rubber, a synthetic rubber or a blend of both.
0 to 500 parts by weight, 0 to 50 parts by weight of a water-absorbing substance is blended and vulcanized, and then a porous elastomer obtained by eluting a crystalline substance with water is used over the entire surface of the ground contact surface or partially. Anti-slip soles.
【0006】勿論種々の発泡剤、例えばジニトロソペン
タメチレンテトラミン、アゾジカハバナミド、パラトル
エンスルフェニルヒドラジン、P,P'- オキシビスベンゼ
ンスルフォニルヒドラジン、炭酸水素ナトリウム等をゴ
ムに練り込み、加硫と同時に発泡させたスポンジ状シー
トも多孔質エラストマーの一種であり、靴底として使用
されてはいるが、次の次点を有している。つまり発泡時
の体積増加が部分的に偏りが出易い事。種々のデザイン
の靴底金型で加硫した場合、脱型後直ちに体積が膨張す
るので、一般の金型が使えない事。多孔質ではあるが気
泡は本質的に独立しているので、靴底と地面の間に介在
する水を吸い込む能力が弱い為に、滑り防止の機能が今
一つ発揮されない事等の欠点が存在する。Of course, various foaming agents such as dinitrosopentamethylenetetramine, azodicahavanamide, paratoluenesulfenylhydrazine, P, P'-oxybisbenzenesulfonylhydrazine, sodium hydrogen carbonate and the like are kneaded into rubber and vulcanized. At the same time, a foamed sponge-like sheet is also a kind of porous elastomer and is used as a shoe sole, but has the following points. That is, the volume increase during foaming tends to be partially biased. When vulcanizing with shoe sole molds of various designs, the volume expands immediately after demolding, so that general molds cannot be used. Although it is porous, the bubbles are essentially independent, and there is a drawback that the ability to absorb water existing between the shoe sole and the ground is weak, so that the function of preventing slippage is not exhibited anymore.
【0007】一方本発明の水溶性結晶物質の溶出によっ
て製造された多孔質エラストマ−からなる靴底は、一般
の靴底用金型を使用してデザイン通りの靴底が得られる
事、二色以上の異なった色の材料によって、正確均等の
多色模様靴底が多孔質であるにもかかわらず、加硫と同
時に得られる事、本多孔質エラストマ−は連続孔を形成
しており、靴底と地面の間に介在する水を吸い込み能力
が強く滑り防止の機能が発揮される事等の長所を有して
いる。以下本発明について詳細に説明する。On the other hand, a sole made of a porous elastomer produced by elution of a water-soluble crystalline substance according to the present invention can obtain a sole as designed using a general sole mold, and can be used in two colors. By using the above-mentioned materials of different colors, despite the fact that the sole of the shoe is porous evenly and accurately, it can be obtained at the same time as vulcanization. It has the advantage that the ability to suck water existing between the bottom and the ground is strong and the function of preventing slippage is exhibited. Hereinafter, the present invention will be described in detail.
【0008】多孔質エラストマ−の空隙率は滑り対策上
5%以上に調整するのが好ましい。結晶物質の量はゴム
分100重量部に対し10から500重量部、好ましく
は50から400重量部、更に好ましくは100から2
00重量部配合にするのが良い。結晶物質が少ない場合
は加硫後溶出しても多孔性エラストマ−とはなり難く、
多過ぎると配合作業が困難になり、加硫した後の材料の
強度が低下する。The porosity of the porous elastomer is preferably adjusted to 5% or more in order to prevent slippage. The amount of the crystalline substance is 10 to 500 parts by weight, preferably 50 to 400 parts by weight, more preferably 100 to 2 parts by weight, per 100 parts by weight of the rubber component.
It is good to make it 00 parts by weight. When the crystalline substance is small, it is difficult to become a porous elastomer even if eluted after vulcanization,
If the amount is too large, the compounding operation becomes difficult, and the strength of the material after vulcanization decreases.
【0009】本発明で使用する水溶性であり、且つ18
0℃以上の融点を有する結晶物質には塩化ナトリウム、
塩化カリウム、塩化マグネシウム、塩化カルシウム、硫
酸ナトリウム等がある。水溶性結晶であっても加硫温度
域つまり180℃より低い温度で分解したり融解したり
する結晶物質は好ましくない。本発明で最も好適に使用
出来る結晶物質は塩化ナトリウムである。[0009] The water-soluble and 18
Sodium chloride is a crystalline substance having a melting point of 0 ° C. or higher.
There are potassium chloride, magnesium chloride, calcium chloride, sodium sulfate and the like. Even if it is a water-soluble crystal, a crystalline substance that decomposes or melts in a vulcanization temperature range, that is, a temperature lower than 180 ° C. is not preferable. The crystalline material most preferably used in the present invention is sodium chloride.
【0010】出来ればこの時、結晶物質の溶出を容易に
する為に、吸水性物質をゴム分100重量部に対し0〜
50重量部、好ましくは5〜15重量部配合する。但
し、滑り性能にはあまり影響を与えないので全く配合し
なくても構わない。吸水性物質としては澱粉、ポリビニ
ルアルコ−ル、ポリアクリル酸ナトリウム、ポリアクリ
ル酸アミド等の天然あるいは合成の吸水性ポリマ−から
選ぶ事が出来る。If possible, at this time, in order to facilitate elution of the crystalline substance, the water-absorbing substance is added in an amount of 0 to 100 parts by weight of rubber.
50 parts by weight, preferably 5 to 15 parts by weight. However, since it does not significantly affect the sliding performance, it does not need to be added at all. The water-absorbing substance can be selected from natural or synthetic water-absorbing polymers such as starch, polyvinyl alcohol, sodium polyacrylate and polyacrylamide.
【0011】本発明に用いられる合成ゴムはポリイソプ
レンゴム、ポリブタジエンゴム、スチレンブタジエン共
重合ゴム、アクリロニトリルブタジエン共重合ゴム、ポ
リクロロプレンゴム、ポリイソブチレンブタジエン共重
合ゴム、エチレンプロピレンジエン共重合ゴムその他の
ゴムがある。又、ゴム組成物にはカ−ボンブラックやシ
リカの様な補強剤、炭酸カルシウムやクレイの様な無機
充填剤、硫黄や過酸化物の様な加硫剤ないしは架橋剤、
加硫助剤、加硫促進剤、鉱物油、植物油等の伸展油ない
しは加工助剤が好適に用いられる。The synthetic rubber used in the present invention includes polyisoprene rubber, polybutadiene rubber, styrene butadiene copolymer rubber, acrylonitrile butadiene copolymer rubber, polychloroprene rubber, polyisobutylene butadiene copolymer rubber, ethylene propylene diene copolymer rubber and other rubbers. There is. Further, the rubber composition may include a reinforcing agent such as carbon black or silica, an inorganic filler such as calcium carbonate or clay, a vulcanizing agent or a cross-linking agent such as sulfur or peroxide,
Vulcanization aids, vulcanization accelerators, extender oils such as mineral oils and vegetable oils or processing aids are preferably used.
【0012】これらのゴム組成物はオ−プンロ−ル又は
密閉式混練機で混練して得られる。成形加硫は金型プレ
ス加硫や蒸気缶加硫でデザインどおりの物が支障なく得
られる。この時結晶物質を配合しないゴムと積層加硫し
て一体化する事は容易である。本発明の趣旨に従い地面
に接する方は結晶物質を含むゴム、足測には結晶物質を
含まないゴムにする事により水密性の高い靴が得られ
る。These rubber compositions can be obtained by kneading with an open roll or a closed kneader. Mold vulcanization can be carried out as designed by die press vulcanization or steam can vulcanization without any problems. At this time, it is easy to laminate and vulcanize with a rubber that does not contain a crystalline substance to integrate them. According to the gist of the present invention, shoes having high watertightness can be obtained by using rubber containing a crystalline substance for rubber contact with the ground and rubber not containing a crystalline substance for foot measurement.
【0013】本発明滑り防止靴底が何故に水に濡れた面
に対しても高い摩擦係数を確保し滑りを防止するかは、
種々複雑な要因関係が存在し、トライボロジ−の見地か
ら説明する事はなかなか難しいが、多孔質の微小な孔の
一つ一つがミクロな吸盤として作用し、更に微小な孔は
互いに連通しているので、地面と靴底の間に存在してい
た水を吸い込み、水の潤滑剤としての作用を抑止する為
であると説明出来る。次に本発明を実施例で説明する。The reason why the anti-slip shoe sole of the present invention secures a high coefficient of friction on a surface wet with water and prevents slippage is as follows.
Although there are various complicated factors, it is difficult to explain from the viewpoint of tribology, but each of the microscopic pores acts as a micro suction cup, and the microscopic pores communicate with each other. Therefore, it can be explained that this is because the water existing between the ground and the sole of the shoe is sucked in and the action of the water as a lubricant is suppressed. Next, the present invention will be described with reference to examples.
【0014】表1に従い材料をオ−プンロ−ルで混練
し、サイズ26.0の布靴に使用するゴム底をプレス加
硫で成型した後、水に浸漬して塩化ナトリウムを溶出さ
せた。ゴム底の表面は微細な多孔質面であった。この時
用いた塩化ナトリウムは粉砕機にかけて粉砕し、60メ
ッシュの篩にかけて通過したものである。次にこのゴム
底を乾燥した。比較対照として塩化ナトリウムを配合し
ないゴム底を同様に作成した。ビニルタイルの面に対し
て、乾燥している場合と水に濡れている場合の静的摩擦
を測定し、表2に示す結果を得た。本実施例によって本
発明靴底は水に濡れている面に対しても滑りにくい事が
わかる。According to Table 1, the materials were kneaded with an open roll, the rubber sole used for a shoe of size 26.0 was molded by press vulcanization, and then immersed in water to elute sodium chloride. The surface of the rubber bottom was a fine porous surface. The sodium chloride used at this time was pulverized by a pulverizer and passed through a 60-mesh sieve. Next, the rubber bottom was dried. As a control, a rubber sole without sodium chloride was prepared in the same manner. Static friction was measured against the surface of the vinyl tile when it was dry and when it was wet with water, and the results shown in Table 2 were obtained. According to this example, it can be seen that the shoe sole of the present invention does not easily slip on the surface that is wet with water.
【0015】[0015]
【表1】 [Table 1]
【0016】ゴム底の平滑なビニルタイルに対する静的
摩擦係数を測定した。[0016] The static coefficient of friction on a rubber bottom smooth vinyl tile was measured.
【表2】 [Table 2]
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 //(C08L 21/00 3:00) ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification number Agency reference number FI Technical display location // (C08L 21/00 3:00)
Claims (3)
レンドゴムからなる配合物のゴム分100重量部に対
し、融点180℃以上で水溶性の結晶物質を10〜50
0重量部、吸水性物質を0〜50重量部配合して加硫し
た後、水で結晶物質を溶出してなる多孔性エラストマー
を接地面の全面に、あるいは部分的に使用してなる滑り
防止靴底。1. A water-soluble crystalline substance having a melting point of 180 ° C. or higher and 10 to 50 parts by weight per 100 parts by weight of a rubber composition of a natural rubber, a synthetic rubber or a blend of both rubbers.
0 parts by weight, 0 to 50 parts by weight of a water-absorbing substance are mixed and vulcanized, and then a crystalline elastomer is eluted with water. Shoe sole.
1の滑り防止靴底。2. The anti-slip sole according to claim 1, wherein the crystalline substance is sodium chloride.
防止靴底。3. The shoe sole according to claim 2, wherein the water-absorbing substance is starch.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18145796A JPH105005A (en) | 1996-06-21 | 1996-06-21 | Antislip shoe sole |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18145796A JPH105005A (en) | 1996-06-21 | 1996-06-21 | Antislip shoe sole |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH105005A true JPH105005A (en) | 1998-01-13 |
Family
ID=16101101
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18145796A Pending JPH105005A (en) | 1996-06-21 | 1996-06-21 | Antislip shoe sole |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH105005A (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8207102B2 (en) * | 2007-05-04 | 2012-06-26 | Ecolab Usa Inc. | Compositions including hardness ion and threshold agent and methods employing them to reduce corrosion and etch |
CN103694508A (en) * | 2014-01-09 | 2014-04-02 | 张子亮 | Natural product and rubber synthetic sole as well as formula and manufacturing process thereof |
US9392841B2 (en) | 2014-08-27 | 2016-07-19 | Nike Innovate C.V. | Article of footwear with soil-shedding performance |
KR101883641B1 (en) * | 2017-02-22 | 2018-07-31 | 한국신발피혁연구원 | Composite of rubber having improved adhesion strength for outsole |
US10070686B2 (en) | 2014-08-27 | 2018-09-11 | Nike, Inc. | Soil-shedding article of footwear, components thereof, and methods of making the article |
US10314364B2 (en) | 2014-08-27 | 2019-06-11 | Nike, Inc. | Soil-shedding article of footwear, and method of using the same |
US10362834B2 (en) | 2016-03-02 | 2019-07-30 | Nike, Inc. | Hydrogel connection |
US10405604B2 (en) | 2014-08-27 | 2019-09-10 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10455893B2 (en) | 2016-03-02 | 2019-10-29 | Nike, Inc. | Hydrogel with mesh for soil deflection |
US10463105B2 (en) | 2014-08-27 | 2019-11-05 | Nike, Inc. | Articles of footwear, apparel, and sports equipment with soil-shedding properties |
US10531705B2 (en) | 2016-03-02 | 2020-01-14 | Nike, Inc. | Hydrogel tie layer |
US10675609B2 (en) | 2016-03-02 | 2020-06-09 | Nike, Inc. | Articles with soil-shedding performance |
US10919257B2 (en) | 2017-10-19 | 2021-02-16 | Nike, Inc. | Composite materials, methods of making, methods of use, and articles incorporating the composite materials |
US11084239B2 (en) | 2017-08-01 | 2021-08-10 | Nike, Inc. | Method of manufacturing a component of an outsole for use in an article of footwear |
WO2022085180A1 (en) * | 2020-10-23 | 2022-04-28 | 株式会社アシックス | Anti-slip member for wearable article or sports article, wearable article, and sports article |
-
1996
- 1996-06-21 JP JP18145796A patent/JPH105005A/en active Pending
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US8207102B2 (en) * | 2007-05-04 | 2012-06-26 | Ecolab Usa Inc. | Compositions including hardness ion and threshold agent and methods employing them to reduce corrosion and etch |
CN103694508A (en) * | 2014-01-09 | 2014-04-02 | 张子亮 | Natural product and rubber synthetic sole as well as formula and manufacturing process thereof |
US10314364B2 (en) | 2014-08-27 | 2019-06-11 | Nike, Inc. | Soil-shedding article of footwear, and method of using the same |
US10051913B2 (en) | 2014-08-27 | 2018-08-21 | Nike, Inc. | Article of footwear with soil-shedding performance |
US9392841B2 (en) | 2014-08-27 | 2016-07-19 | Nike Innovate C.V. | Article of footwear with soil-shedding performance |
US11517071B2 (en) | 2014-08-27 | 2022-12-06 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10064447B2 (en) | 2014-08-27 | 2018-09-04 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10405604B2 (en) | 2014-08-27 | 2019-09-10 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10070686B2 (en) | 2014-08-27 | 2018-09-11 | Nike, Inc. | Soil-shedding article of footwear, components thereof, and methods of making the article |
US10076154B2 (en) | 2014-08-27 | 2018-09-18 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10076158B2 (en) | 2014-08-27 | 2018-09-18 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10076157B2 (en) | 2014-08-27 | 2018-09-18 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10076156B2 (en) | 2014-08-27 | 2018-09-18 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10076159B2 (en) | 2014-08-27 | 2018-09-18 | Nike, Inc. | Soil-shedding article of footwear, and method of using the same |
US10076155B2 (en) | 2014-08-27 | 2018-09-18 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10085513B2 (en) | 2014-08-27 | 2018-10-02 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10092062B2 (en) | 2014-08-27 | 2018-10-09 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10130140B2 (en) | 2014-08-27 | 2018-11-20 | Nike, Inc. | Article of footwear with soil-shedding performance |
US11445782B2 (en) | 2014-08-27 | 2022-09-20 | Nike, Inc. | Articles of footwear, apparel, and sports equipment with soil-shedding properties |
US9456654B2 (en) | 2014-08-27 | 2016-10-04 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10070685B2 (en) | 2014-08-27 | 2018-09-11 | Nike, Inc. | Article of footwear with soil-shedding performance |
US11178933B2 (en) | 2014-08-27 | 2021-11-23 | Nike, Inc. | Article of footwear with soil-shedding performance |
US10463105B2 (en) | 2014-08-27 | 2019-11-05 | Nike, Inc. | Articles of footwear, apparel, and sports equipment with soil-shedding properties |
US11103026B2 (en) | 2014-08-27 | 2021-08-31 | Nike, Inc. | Article of footwear with soil-shedding performance |
US11540591B2 (en) | 2016-03-02 | 2023-01-03 | Nike, Inc. | Hydrogel tie layer |
US10531705B2 (en) | 2016-03-02 | 2020-01-14 | Nike, Inc. | Hydrogel tie layer |
US10675609B2 (en) | 2016-03-02 | 2020-06-09 | Nike, Inc. | Articles with soil-shedding performance |
US10455893B2 (en) | 2016-03-02 | 2019-10-29 | Nike, Inc. | Hydrogel with mesh for soil deflection |
US10362834B2 (en) | 2016-03-02 | 2019-07-30 | Nike, Inc. | Hydrogel connection |
KR101883641B1 (en) * | 2017-02-22 | 2018-07-31 | 한국신발피혁연구원 | Composite of rubber having improved adhesion strength for outsole |
US11840036B2 (en) | 2017-08-01 | 2023-12-12 | Nike, Inc. | Method of manufacturing a component of an outsole for use in an article of footwear |
US11084239B2 (en) | 2017-08-01 | 2021-08-10 | Nike, Inc. | Method of manufacturing a component of an outsole for use in an article of footwear |
US11130309B2 (en) | 2017-10-19 | 2021-09-28 | Nike, Inc. | Color change materials, methods of making, methods of use, and articles incorporating the color change materials |
US11001031B2 (en) | 2017-10-19 | 2021-05-11 | Nike, Inc. | Composite materials, methods of making, methods of use, and articles incorporating the composite materials |
US10919257B2 (en) | 2017-10-19 | 2021-02-16 | Nike, Inc. | Composite materials, methods of making, methods of use, and articles incorporating the composite materials |
US11975517B2 (en) | 2017-10-19 | 2024-05-07 | Nike, Inc. | Color change materials, methods of making, methods of use, and articles incorporating the color change materials |
WO2022085180A1 (en) * | 2020-10-23 | 2022-04-28 | 株式会社アシックス | Anti-slip member for wearable article or sports article, wearable article, and sports article |
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