JPH1046522A - Antifouling balustrade - Google Patents

Antifouling balustrade

Info

Publication number
JPH1046522A
JPH1046522A JP8299445A JP29944596A JPH1046522A JP H1046522 A JPH1046522 A JP H1046522A JP 8299445 A JP8299445 A JP 8299445A JP 29944596 A JP29944596 A JP 29944596A JP H1046522 A JPH1046522 A JP H1046522A
Authority
JP
Japan
Prior art keywords
part showing
exposed
hydrophilic
hydrophilic property
outside air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8299445A
Other languages
Japanese (ja)
Inventor
Mitsuyoshi Machida
町田　　光義
Makoto Hayakawa
信 早川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toto Ltd
Original Assignee
Toto Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toto Ltd filed Critical Toto Ltd
Priority to JP8299445A priority Critical patent/JPH1046522A/en
Publication of JPH1046522A publication Critical patent/JPH1046522A/en
Pending legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00—Tubular elements; Assemblies of tubular elements
    • F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
    • F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
    • F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
    • F24F8/22—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using UV light
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/02—Arrangements for de-icing; Arrangements for drying-out ; Arrangements for cooling; Arrangements for preventing corrosion
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/40—Radiating elements coated with or embedded in protective material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2245/00—Coatings; Surface treatments
    • F28F2245/02—Coatings; Surface treatments hydrophilic
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2245/00—Coatings; Surface treatments
    • F28F2245/04—Coatings; Surface treatments hydrophobic

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Geometry (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Surface Treatment Of Glass (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Laminated Bodies (AREA)
  • Bridges Or Land Bridges (AREA)
  • Devices Affording Protection Of Roads Or Walls For Sound Insulation (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Refuge Islands, Traffic Blockers, Or Guard Fence (AREA)
  • Tents Or Canopies (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Rear-View Mirror Devices That Are Mounted On The Exterior Of The Vehicle (AREA)
  • Non-Portable Lighting Devices Or Systems Thereof (AREA)
  • Photovoltaic Devices (AREA)
  • Finishing Walls (AREA)
  • Food-Manufacturing Devices (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Road Signs Or Road Markings (AREA)
  • Details Of Aerials (AREA)
  • Paints Or Removers (AREA)
  • Insulators (AREA)
  • Lining And Supports For Tunnels (AREA)
  • Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
  • Freezers Or Refrigerated Showcases (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Table Devices Or Equipment (AREA)
  • Bathtubs, Showers, And Their Attachments (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an antifouling balustrade by forming a surface layer having structure microscopically dispersed a part showing a hydrophilic property where photocatalytic oxide particulates are exposed to make contact with outside air and a part showing water repellency where water repellent fluorine contained resin is exposed to make contact with the outside air on a surface of a base material. SOLUTION: A surface layer having structure microscopically dispersing both of a part showing a hydrophilic property and a part showing repellency by repellent fluorine contained resin is formed on a surface of a base material. Consequently, a hydrophilic attachment is made not to become attached to the part showing repellency and a hydrophobic attachement is made not to become attached to the part showing the hydrophilic property. Additionally, the hydrophilic property of the part showing the hydrophilic property in accordance with light excitation is maintained by making photocatalytic oxide particulates exist on the part showing the hydrophilic property. Consequently, neither hydrophilic attaching matters nor hydrophobia attaching matters are fastened on a surface of a member, and it is possible to maintain the surface in a clean state.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【０００１】[0001]

【発明の属する技術分野】本発明は、煤煙などで汚れに
くい防汚性高欄に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an antifouling balustrade which is hardly contaminated with smoke or the like.

【０００２】[0002]

【従来の技術】高欄とは、橋梁用の転落防止柵であり、
歩行者や車両が橋梁外に転落することを防止するために
設置されるものである。近年は、従来の転落防止という
機能面だけでなく、景観性を重視した個別のデザイン設
計により他の高欄との差別化が図られている。高欄に
は、鋼鉄、鋳鉄、アルミニウム、ステンレス等が使用さ
れている。2. Description of the Related Art A railing is a fall prevention fence for a bridge,
It is installed to prevent pedestrians and vehicles from falling outside the bridge. In recent years, in addition to the conventional function of preventing falling, a distinctive design has been made from the other high rails by an individual design design emphasizing landscape. Steel, cast iron, aluminum, stainless steel, and the like are used in the columns.

【０００３】[0003]

【発明が解決しようとする課題】高欄は排気ガス中の煤
煙やタイヤの摩耗粉や、路面や大地から舞い上がった煤
塵によって汚れる。高欄が薄黒く汚れると不快な印象を
与え、景観が損なわれる。そこで、本発明では、汚れに
くい高欄を提供することを目的とする。The high section is contaminated with soot in exhaust gas, abrasion powder of tires, and dust soaring from a road surface or the ground. If the railing is dark and dirty, it gives an unpleasant impression and the scenery is damaged. In view of the above, an object of the present invention is to provide a high-stained high rail.

【０００４】[0004]

【課題を解決するための手段】本発明では、上記課題を
解決すべく、基材表面に、基材表面に、光触媒性酸化物
粒子が外気と接するように露出した親水性を呈する部分
と、撥水性フッ素樹脂が外気と接するように露出した撥
水性を呈する部分の双方が表面に微視的に分散された構
造を有する表面層が形成されていることを特徴とする防
汚性高欄を提供する。このような構造では、親水性表面
と撥水性表面が隣接するため、親水性表面になじみやす
い親水性の付着物は隣接する撥水性部分になじまない。
逆に撥水性表面になじみやすい疎水性の付着物は隣接す
る親水性部分になじまない。そのため、親水性付着物
も、疎水性付着物も部材表面に固着されることはなく、
表面は清浄な状態に維持される。さらに、光触媒が存在
することにより、光触媒の光励起に応じて光触媒性酸化
物粒子が外気と接するように露出した親水性を呈する部
分は恒久的に親水性を維持するので、上記親水性を呈す
る部分と撥水性を呈する部分の双方が表面に微視的に分
散された構造は維持される。According to the present invention, in order to solve the above-mentioned problems, a photocatalytic oxide particle is exposed on a surface of a base material so as to be in contact with the outside air, and a hydrophilic portion is provided on the surface of the base material; Provided is an antifouling column having a surface layer having a structure in which both the water-repellent portion exposed to contact the outside and the water-repellent fluororesin is microscopically dispersed on the surface. I do. In such a structure, since the hydrophilic surface and the water-repellent surface are adjacent to each other, the hydrophilic adherent that easily adapts to the hydrophilic surface does not adapt to the adjacent water-repellent portion.
Conversely, hydrophobic deposits that are easily adapted to the water-repellent surface do not adapt to adjacent hydrophilic portions. Therefore, neither the hydrophilic deposit nor the hydrophobic deposit is fixed to the member surface.
The surface is kept clean. Furthermore, the presence of the photocatalyst causes the photocatalytic oxide particles to be exposed so as to be in contact with the outside air in response to the photoexcitation of the photocatalyst, so that the hydrophilic portion is permanently maintained. The structure in which both the water-repellent and water-repellent portions are microscopically dispersed on the surface is maintained.

【０００５】[0005]

【発明の実施の形態】本発明では、高欄基材表面には、
光触媒性酸化物粒子が外気と接するように露出した親水
性を呈する部分と、撥水性フッ素樹脂が外気と接するよ
うに露出した撥水性を呈する部分の双方が表面に微視的
に分散された構造を有する表面層が形成されている。高
欄基材には、従来同様に、鋼鉄、鋳鉄、アルミニウム、
ステンレス等が使用できる。BEST MODE FOR CARRYING OUT THE INVENTION In the present invention,
A structure in which both the photocatalytic oxide particles are exposed to the outside air and exhibit hydrophilicity, and the water-repellent fluororesin is exposed to the outside air and exhibit water repellency, both of which are microscopically dispersed on the surface. Is formed. For the balustrade, as before, steel, cast iron, aluminum,
Stainless steel or the like can be used.

【０００６】光触媒とは、その結晶の伝導帯と価電子帯
との間のエネルギーギャップよりも大きなエネルギー
（すなわち短い波長）の光（励起光）を照射したとき
に、価電子帯中の電子の励起（光励起）が生じて、伝導
電子と正孔を生成しうる物質をいい、光触媒性酸化物に
は、例えば、アナターゼ型酸化チタン、ルチル型酸化チ
タン、酸化亜鉛、酸化錫、酸化第二鉄、三酸化二ビスマ
ス、三酸化タングステン、チタン酸ストロンチウム等の
酸化物が好適に利用できる。光触媒の光励起に用いる光
源としては、日中は太陽光に晒されるので、太陽光が利
用できる。また、夜間は道路照明や走行車の照明灯を光
源として利用できる。光触媒の光励起により、基材表面
が高度に親水化されるためには、励起光の照度は０．０
０１ｍＷ／ｃｍ2以上あればよいが、０．０１ｍＷ／ｃ
ｍ2以上だと好ましく、０．１ｍＷ／ｃｍ2以上だとより
好ましい。[0006] A photocatalyst emits light (excitation light) having an energy (ie, shorter wavelength) larger than the energy gap between the conduction band and the valence band of the crystal when the electrons in the valence band are irradiated. A substance capable of generating conduction electrons and holes by excitation (photoexcitation). Photocatalytic oxides include, for example, anatase-type titanium oxide, rutile-type titanium oxide, zinc oxide, tin oxide, and ferric oxide. And oxides such as bismuth trioxide, tungsten trioxide and strontium titanate. As a light source used for photoexcitation of the photocatalyst, sunlight can be used because it is exposed to sunlight during the day. Also, at night, road lighting or running vehicle lighting can be used as a light source. In order for the substrate surface to be highly hydrophilic by photoexcitation of the photocatalyst, the illuminance of the excitation light is 0.0
0.01 mW / cm 2 or more, but 0.01 mW / c 2 or more.
m 2 or more, more preferably 0.1 mW / cm 2 or more.

【０００７】撥水性フッ素樹脂には、ポリテトラフルオ
ロエチレン、ポリクロロトリフルオロエチレン、ポリヘ
キサフルオロプロピレン、テトラフルオロエチレンーヘ
キサフルオロプロピレンコポリマー等が好適に利用でき
る。As the water-repellent fluororesin, polytetrafluoroethylene, polychlorotrifluoroethylene, polyhexafluoropropylene, tetrafluoroethylene-hexafluoropropylene copolymer and the like can be suitably used.

【０００８】表面層の膜厚は、０．４μｍ以下にするの
が好ましい。そうすれば、光の乱反射による白濁を防止
することができ、表面層は実質的に透明となる。さら
に、表面層の膜厚を、０．２μｍ以下にすると一層好ま
しい。そうすれば、光の干渉による表面層の発色を防止
することができる。また、表面層が薄ければ薄いほどそ
の透明度は向上する。更に、膜厚を薄くすれば、表面層
の耐摩耗性が向上する。The thickness of the surface layer is preferably set to 0.4 μm or less. Then, cloudiness due to irregular reflection of light can be prevented, and the surface layer becomes substantially transparent. Further, it is more preferable that the thickness of the surface layer be 0.2 μm or less. Then, it is possible to prevent the surface layer from being colored by light interference. Also, the thinner the surface layer, the better its transparency. Further, when the film thickness is reduced, the wear resistance of the surface layer is improved.

【０００９】表面層には、Ａｇ、Ｃｕ、Ｚｎのような金
属を添加することができる。前記金属を添加した表面層
は、表面に付着した細菌や黴を暗所でも死滅させること
ができる。Metals such as Ag, Cu and Zn can be added to the surface layer. The surface layer to which the metal is added can kill bacteria and fungi attached to the surface even in a dark place.

【００１０】表面層にはＰｔ、Ｐｄ、Ｒｕ、Ｒｈ、Ｉ
ｒ、Ｏｓのような白金族金属を添加することができる。
前記金属を添加した表面層は、光触媒の酸化還元活性を
増強でき、有機物汚れの分解性、有害気体や悪臭の分解
性を向上させることができる。Pt, Pd, Ru, Rh, I
A platinum group metal such as r or Os can be added.
The surface layer to which the metal is added can enhance the redox activity of the photocatalyst, and can improve the decomposability of organic contaminants and the decomposability of harmful gases and odors.

【００１１】光触媒性酸化物粒子が外気と接するように
露出した親水性を呈する部分と、撥水性フッ素樹脂が外
気と接するように露出した撥水性を呈する部分の双方が
表面に微視的に分散された構造を有するか否かは、以下
の方法により確認可能である。 その１つの方法は以下
のように行う。すなわち、まず、硝酸銀、乳酸銀、塩化
白金酸、塩化パラジウムなどのＡｇ、Ｐｔ、Ｐｄといっ
た原子番号の大きな金属を含む溶液を基材表面に塗布
し、基材表面に光触媒の励起光を照射して、Ａｇ、Ｐ
ｔ、Ｐｄといった原子番号の大きな金属を基材表面に析
出させる。上記金属の析出反応は光触媒による上記金属
の還元作用に基づくので、このとき、金属は光触媒性酸
化物粒子が外気と接するように露出した親水性を呈する
部分には付着するが、撥水性フッ素樹脂が外気と接する
ように露出した撥水性を呈する部分には付着しにくい。
次に、走査型電子顕微鏡の反射電子像の観察により、濃
淡（コントラスト）が分散して生じていれば、光触媒性
酸化物粒子が外気と接するように露出した親水性を呈す
る部分と、撥水性フッ素樹脂が外気と接するように露出
した撥水性を呈する部分の双方が表面に微視的に分散さ
れた構造を有すると結論づけられる。他の観察方法とし
ては、反射電子像による濃淡の観察の代わりに、エネル
ギー分散型Ｘ線分析装置（ＥＤＸ）、或いはエレクトロ
ンプローブマイクロアナライザー（ＥＰＭＡ）等によ
り、表面の元素分析を行うようにしてよい。他の観察方
法としては、上記金属が銀のように有色であれば、反射
電子像による濃淡の観察の代わりに、光学顕微鏡によ
り、色の観察を行うようにしてよい。The photocatalytic oxide particles are exposed to the outside air and exhibit hydrophilicity, and the water-repellent fluororesin is exposed to the air and exhibit water repellency. Whether or not it has the structure described above can be confirmed by the following method. One such method is performed as follows. That is, first, a solution containing a metal having a large atomic number such as Ag, Pt, or Pd such as silver nitrate, silver lactate, chloroplatinic acid, or palladium chloride is applied to the substrate surface, and the substrate surface is irradiated with excitation light of a photocatalyst. Ag, P
A metal having a large atomic number, such as t or Pd, is deposited on the substrate surface. Since the deposition reaction of the metal is based on the reduction action of the metal by the photocatalyst, at this time, the metal adheres to the hydrophilic portion exposed by the photocatalytic oxide particles in contact with the outside air, but the water-repellent fluororesin Is hardly adhered to a portion exhibiting water repellency exposed so as to be in contact with the outside air.
Next, by observing the reflected electron image of the scanning electron microscope, if the density (contrast) is dispersed, the photocatalytic oxide particles are exposed so as to be in contact with the outside air and exhibit a hydrophilic property. It is concluded that both the water-repellent portions exposed so that the fluororesin comes into contact with the outside air have a structure microscopically dispersed on the surface. As another observation method, elemental analysis of the surface may be performed using an energy dispersive X-ray analyzer (EDX) or an electron probe microanalyzer (EPMA) instead of observing the density using a backscattered electron image. . As another observation method, if the metal is colored such as silver, the color may be observed by an optical microscope instead of observing the density by a reflected electron image.

【００１２】次に、基材表面に、光触媒性酸化物粒子が
外気と接するように露出した親水性を呈する部分と、撥
水性フッ素樹脂が外気と接するように露出した撥水性を
呈する部分の双方が表面に微視的に分散された構造を有
する表面層が形成されている防汚性部材の製法について
説明する。この場合の製法は、基本的には、基材表面に
コーティング組成物を塗布し、コーティング組成物を基
材表面に固着せしめることによる。Next, on the surface of the base material, both a portion exhibiting hydrophilicity where the photocatalytic oxide particles are exposed to the outside air and a portion exhibiting water repellency where the water-repellent fluororesin is exposed so as to contact the outside air A method for producing an antifouling member having a surface layer having a structure in which is dispersed microscopically on the surface will be described. The manufacturing method in this case is basically based on applying the coating composition to the surface of the substrate and fixing the coating composition to the surface of the substrate.

【００１３】ここでコーティング組成物は、光触媒粒子
と撥水性フッ素樹脂を必須構成要件とし、その他に水、
エタノール、プロパノール等の溶媒、フッ素樹脂の架橋
剤や、コーティング液の分散性を向上させる界面活性剤
などを添加してもよい。Here, the coating composition includes photocatalyst particles and a water-repellent fluororesin as essential components, and water,
A solvent such as ethanol or propanol, a cross-linking agent for a fluororesin, or a surfactant for improving the dispersibility of a coating solution may be added.

【００１４】上記コーティング組成物の塗布方法として
は、スプレーコーティング法、ディップコーティング
法、フローコーティング法、スピンコーティング法、ロ
ールコーティング法、刷毛塗り、スポンジ塗り等の方法
が好適に利用できる。上記コーティング組成物は、フッ
素樹脂の溶融する３００℃以上の温度での熱処理、フッ
素樹脂の架橋剤を添加する場合には、架橋剤によりフッ
素樹脂が硬化する温度での熱処理、加圧処理、加圧処理
と上記熱処理との併用、衝撃圧力による固定等の方法で
固着できる。また、上記方法で固着させる前に、基材表
面をブラスト処理等して凹凸を設けるようにしてもよ
い。そうすれば、基材と表面層との固着性を向上させる
ことができる。As a method of applying the coating composition, methods such as spray coating, dip coating, flow coating, spin coating, roll coating, brush coating, and sponge coating can be suitably used. The coating composition is heat-treated at a temperature of 300 ° C. or higher at which the fluororesin melts, and when a crosslinking agent for the fluororesin is added, heat treatment at a temperature at which the fluororesin is cured by the crosslinking agent, pressure treatment, and heat treatment. It can be fixed by a method such as a combination of pressure treatment and the above heat treatment, or fixing by impact pressure. Further, before fixing by the above method, the surface of the substrate may be blasted or the like to provide irregularities. Then, the adhesion between the substrate and the surface layer can be improved.

【００１５】[0015]

【実施例】【Example】

実施例１．アナターゼ型酸化チタンゾル（石原産業、Ｓ
ＴＳ−１１）と、ポリテトラフルオロエチレン（ＰＴＦ
Ｅ）粒子（ダイキン工業、Ｄ−１）と蒸留水を混合し、
３０分撹拌して得たコーティング液を、スプレーコーテ
ィング法にて１０ｃｍ角のアルミニウム基材上に塗布
し、３５０℃で３分熱処理して、アナターゼ型酸化チタ
ン粒子４重量部、ポリテトラフルオロエチレン粒子６重
量部からなる表面層を形成した＃１試料を得た。＃１試
料の表面観察により光触媒性酸化物粒子が外気と接する
ように露出した親水性を呈する部分と、撥水性フッ素樹
脂が外気と接するように露出した撥水性を呈する部分の
双方が表面に微視的に分散された構造を有する表面層が
形成されていることが確認された。Embodiment 1 FIG. Anatase type titanium oxide sol (Ishihara Sangyo, S
TS-11) and polytetrafluoroethylene (PTF
E) mixing the particles (Daikin Industries, D-1) and distilled water,
The coating liquid obtained by stirring for 30 minutes is applied on an aluminum substrate of 10 cm square by a spray coating method, and heat-treated at 350 ° C. for 3 minutes to obtain 4 parts by weight of anatase type titanium oxide particles and polytetrafluoroethylene particles. A # 1 sample having a surface layer composed of 6 parts by weight was obtained. In the surface observation of the # 1 sample, both the photocatalytic oxide particles exposed to be in contact with the outside air and exhibiting hydrophilicity, and the water-repellent fluororesin exposed in contact with the outside were exposed to water. It was confirmed that a surface layer having a visually dispersed structure was formed.

【００１６】次に、＃１試料及び比較のためポリテトラ
フルオロエチレン（ＰＴＦＥ）板を交通の頻繁な道路橋
の高欄の脚部に固定して、７０日放置し、堆積物や汚染
物に対する表面の清浄維持性を調べた。表面の清浄維持
性は、放置前後の色差の変化で調べた。ここで色差は色
差計（東京電色）を用い、日本工業規格（ＪＩＳ）Ｈ０
２０１に従い、ΔＥ＊表示を用いて調べた。その結果、
色差の変化は、ポリテトラフルオロエチレン（ＰＴＦ
Ｅ）板では７と汚れが目立ったのに対し、＃１試料では
色差の変化は０．８程度でほとんど汚れは観察されなか
った。Next, the # 1 sample and a polytetrafluoroethylene (PTFE) plate for comparison were fixed to the rails on the railing of a high-traffic road bridge, and allowed to stand for 70 days. Was examined for its cleanliness. The cleanliness of the surface was checked by the change in color difference before and after standing. Here, the color difference is measured using a color difference meter (Tokyo Denshoku) and measured according to Japanese Industrial Standards (JIS) H0.
In accordance with 201, it was examined using the ΔE * designation. as a result,
The change in color difference is determined by polytetrafluoroethylene (PTF
E) Stain was conspicuous at 7 on the plate, whereas the # 1 sample showed a change in color difference of about 0.8 and almost no stain was observed.

【００１７】[0017]

【発明の効果】本発明では、高欄において、基材表面
に、光触媒性酸化物粒子が外気と接するように露出した
親水性を呈する部分と、撥水性フッ素樹脂が外気と接す
るように露出した撥水性を呈する部分の双方が表面に微
視的に分散された構造を有する表面層が形成されている
ようにすることにより、親水性付着物も、疎水性付着物
も部材表面に固着されることはなく、表面は清浄な状態
に維持されるようになる。According to the present invention, in the high column, the hydrophilic portion exposed on the surface of the base material so that the photocatalytic oxide particles are in contact with the outside air, and the repellent portion exposed on the water-repellent fluororesin in contact with the outside air. By forming a surface layer having a structure in which both aqueous portions are microscopically dispersed on the surface, both hydrophilic and hydrophobic deposits are fixed to the member surface. And the surface is kept clean.

Claims (1)

【特許請求の範囲】[Claims] 【請求項１】 基材表面に、光触媒性酸化物粒子が外気
と接するように露出した親水性を呈する部分と、撥水性
フッ素樹脂が外気と接するように露出した撥水性を呈す
る部分の双方が表面に微視的に分散された構造を有する
表面層が形成されていることを特徴とする防汚性高欄。1. The photocatalytic oxide particles are exposed on the surface of the base material such that the photocatalytic oxide particles are exposed to the outside air and exhibit hydrophilicity, and the water-repellent fluororesin is exposed and exposed to the outside air. An antifouling high column, wherein a surface layer having a microscopically dispersed structure is formed on the surface.
JP8299445A 1996-05-31 1996-10-23 Antifouling balustrade Pending JPH1046522A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8299445A JPH1046522A (en) 1996-05-31 1996-10-23 Antifouling balustrade

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP8-175386 1996-05-31
JP17538696 1996-05-31
JP8299445A JPH1046522A (en) 1996-05-31 1996-10-23 Antifouling balustrade

Publications (1)

Publication Number Publication Date
JPH1046522A true JPH1046522A (en) 1998-02-17

Family

ID=37857701

Family Applications (28)

Application Number Title Priority Date Filing Date
JP8299444A Pending JPH1046526A (en) 1996-05-31 1996-10-23 Antifouling noise insulating wall
JP8299443A Pending JPH1046989A (en) 1996-05-31 1996-10-23 Inner wall of antifouling property tunnel
JP8299447A Pending JPH1046534A (en) 1996-05-31 1996-10-23 Antifouling guard fence
JP8299446A Pending JPH1046527A (en) 1996-05-31 1996-10-23 Decorative sheet for antifouling road
JP8299445A Pending JPH1046522A (en) 1996-05-31 1996-10-23 Antifouling balustrade
JP8299679A Pending JPH1045431A (en) 1996-05-31 1996-10-24 Window glass for vehicle having both antifouling property and property of preventing sticking of drop of water
JP8299676A Pending JPH1044301A (en) 1996-05-31 1996-10-24 Building material for stain-proofing outer wall
JP8299678A Pending JPH1043069A (en) 1996-05-31 1996-10-24 Stain preventing plate
JP8301042A Pending JPH1045432A (en) 1996-05-31 1996-10-25 Mirror for vehicle having both antifouling property and property of preventing sticking of drop of water
JP8301045A Pending JPH1051014A (en) 1996-05-31 1996-10-25 Solar battery equipped with stainproof cover
JP8301044A Pending JPH1046530A (en) 1996-05-31 1996-10-25 Road mirror doubly furnished with antifouling property and droplet attachment preventive property
JP8301047A Pending JPH1043019A (en) 1996-05-31 1996-10-25 Lavatory mirror with water droplet antisticking property
JP8302446A Pending JPH1046054A (en) 1996-05-31 1996-10-28 Antifouling wheel
JP8302448A Pending JPH1046952A (en) 1996-05-31 1996-10-28 Dirt preventive blind
JP8303613A Pending JPH1047890A (en) 1996-05-31 1996-10-29 Fins for heat exchanger having properties of preventing sticking of waterdrop and heat exchanger equipped with them
JP8303611A Pending JPH1050159A (en) 1996-05-31 1996-10-29 Insulator provided with stain-proofness and dew drop deposit preventive property
JP8306998A Pending JPH1044302A (en) 1996-05-31 1996-11-01 Stain-proofing membrane structure material
JP8311419A Pending JPH1043078A (en) 1996-05-31 1996-11-07 Bathtub
JP8311416A Pending JPH1043013A (en) 1996-05-31 1996-11-07 Heat insulating showcase with water droplet antisticking property
JP8311415A Pending JPH1043024A (en) 1996-05-31 1996-11-07 Pollution free dish and dish housing apparatus for the same
JP8323518A Pending JPH1043682A (en) 1996-05-31 1996-11-19 Stain-proof automobile body face
JP8323515A Pending JPH1050118A (en) 1996-05-31 1996-11-19 Pollution-proof luminaire
JP8324651A Pending JPH1050111A (en) 1996-05-31 1996-11-20 Pollution-proof lighting system for tunnel
JP8335174A Pending JPH1051214A (en) 1996-05-31 1996-11-29 Antenna with anti-attachment property against ice and snow
JP8335175A Pending JPH1046759A (en) 1996-05-31 1996-11-29 Roof material having ice-snow sticking preventive performance
JP8344586A Pending JPH1045433A (en) 1996-05-31 1996-12-09 Cover for motor-cycle instrument panel having property for preventing waterdrop sticking and motor-cycle instrument panel
JP8346741A Pending JPH1048578A (en) 1996-05-31 1996-12-10 Glass lens having preventing ability of sticking waterdrop
JP8354953A Pending JPH1045428A (en) 1996-05-31 1996-12-21 Window glass for construction

Family Applications Before (4)

Application Number Title Priority Date Filing Date
JP8299444A Pending JPH1046526A (en) 1996-05-31 1996-10-23 Antifouling noise insulating wall
JP8299443A Pending JPH1046989A (en) 1996-05-31 1996-10-23 Inner wall of antifouling property tunnel
JP8299447A Pending JPH1046534A (en) 1996-05-31 1996-10-23 Antifouling guard fence
JP8299446A Pending JPH1046527A (en) 1996-05-31 1996-10-23 Decorative sheet for antifouling road

Family Applications After (23)

Application Number Title Priority Date Filing Date
JP8299679A Pending JPH1045431A (en) 1996-05-31 1996-10-24 Window glass for vehicle having both antifouling property and property of preventing sticking of drop of water
JP8299676A Pending JPH1044301A (en) 1996-05-31 1996-10-24 Building material for stain-proofing outer wall
JP8299678A Pending JPH1043069A (en) 1996-05-31 1996-10-24 Stain preventing plate
JP8301042A Pending JPH1045432A (en) 1996-05-31 1996-10-25 Mirror for vehicle having both antifouling property and property of preventing sticking of drop of water
JP8301045A Pending JPH1051014A (en) 1996-05-31 1996-10-25 Solar battery equipped with stainproof cover
JP8301044A Pending JPH1046530A (en) 1996-05-31 1996-10-25 Road mirror doubly furnished with antifouling property and droplet attachment preventive property
JP8301047A Pending JPH1043019A (en) 1996-05-31 1996-10-25 Lavatory mirror with water droplet antisticking property
JP8302446A Pending JPH1046054A (en) 1996-05-31 1996-10-28 Antifouling wheel
JP8302448A Pending JPH1046952A (en) 1996-05-31 1996-10-28 Dirt preventive blind
JP8303613A Pending JPH1047890A (en) 1996-05-31 1996-10-29 Fins for heat exchanger having properties of preventing sticking of waterdrop and heat exchanger equipped with them
JP8303611A Pending JPH1050159A (en) 1996-05-31 1996-10-29 Insulator provided with stain-proofness and dew drop deposit preventive property
JP8306998A Pending JPH1044302A (en) 1996-05-31 1996-11-01 Stain-proofing membrane structure material
JP8311419A Pending JPH1043078A (en) 1996-05-31 1996-11-07 Bathtub
JP8311416A Pending JPH1043013A (en) 1996-05-31 1996-11-07 Heat insulating showcase with water droplet antisticking property
JP8311415A Pending JPH1043024A (en) 1996-05-31 1996-11-07 Pollution free dish and dish housing apparatus for the same
JP8323518A Pending JPH1043682A (en) 1996-05-31 1996-11-19 Stain-proof automobile body face
JP8323515A Pending JPH1050118A (en) 1996-05-31 1996-11-19 Pollution-proof luminaire
JP8324651A Pending JPH1050111A (en) 1996-05-31 1996-11-20 Pollution-proof lighting system for tunnel
JP8335174A Pending JPH1051214A (en) 1996-05-31 1996-11-29 Antenna with anti-attachment property against ice and snow
JP8335175A Pending JPH1046759A (en) 1996-05-31 1996-11-29 Roof material having ice-snow sticking preventive performance
JP8344586A Pending JPH1045433A (en) 1996-05-31 1996-12-09 Cover for motor-cycle instrument panel having property for preventing waterdrop sticking and motor-cycle instrument panel
JP8346741A Pending JPH1048578A (en) 1996-05-31 1996-12-10 Glass lens having preventing ability of sticking waterdrop
JP8354953A Pending JPH1045428A (en) 1996-05-31 1996-12-21 Window glass for construction

Country Status (2)

Country Link
JP (28) JPH1046526A (en)
CN (1) CN1927474A (en)

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Also Published As

Publication number Publication date
JPH1043013A (en) 1998-02-17
JPH1043024A (en) 1998-02-17
JPH1044301A (en) 1998-02-17
JPH1046534A (en) 1998-02-17
JPH1046759A (en) 1998-02-17
JPH1043019A (en) 1998-02-17
JPH1046054A (en) 1998-02-17
JPH1043682A (en) 1998-02-17
JPH1050159A (en) 1998-02-20
JPH1046952A (en) 1998-02-17
JPH1045428A (en) 1998-02-17
JPH1045433A (en) 1998-02-17
JPH1046526A (en) 1998-02-17
JPH1047890A (en) 1998-02-20
JPH1046530A (en) 1998-02-17
JPH1046989A (en) 1998-02-17
JPH1046527A (en) 1998-02-17
JPH1050118A (en) 1998-02-20
JPH1044302A (en) 1998-02-17
CN1927474A (en) 2007-03-14
JPH1043069A (en) 1998-02-17
JPH1045431A (en) 1998-02-17
JPH1048578A (en) 1998-02-20
JPH1043078A (en) 1998-02-17
JPH1051014A (en) 1998-02-20
JPH1045432A (en) 1998-02-17
JPH1050111A (en) 1998-02-20
JPH1051214A (en) 1998-02-20

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