JPH10316540A - Hair cosmetic - Google Patents
Hair cosmeticInfo
- Publication number
- JPH10316540A JPH10316540A JP14461097A JP14461097A JPH10316540A JP H10316540 A JPH10316540 A JP H10316540A JP 14461097 A JP14461097 A JP 14461097A JP 14461097 A JP14461097 A JP 14461097A JP H10316540 A JPH10316540 A JP H10316540A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- group
- modified silicone
- embedded image
- silicone compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、親水性基としてポ
リグリセリンを有するポリグリセリン変性シリコーン化
合物を配合することによって、コンディショニング効
果、使用性に優れ、又、毛髪に対し、べたつかず、艶が
良く、セット力に優れた頭髪化粧料に関するものであ
る。BACKGROUND OF THE INVENTION The present invention relates to a polyglycerin-modified silicone compound having polyglycerin as a hydrophilic group, which is excellent in conditioning effect and usability, and has good non-stickiness and good gloss to hair. The present invention relates to a hair cosmetic composition having excellent set ability.
【０００２】さらに詳しくは、ポリグリセリン変性シリ
コーン化合物をコンディショニング剤として用いた場合
は、コンディショニング効果、使用性に優れたシャンプ
ー、リンス、コンディショナーが得られ、又、セット剤
として用いた場合は、毛髪に対し、べたつかず、艶が良
く、セット力に優れ、セット効果の持続するもちの良い
整髪剤に関するものである。More specifically, when a polyglycerin-modified silicone compound is used as a conditioning agent, shampoos, rinses, and conditioners having excellent conditioning effects and usability can be obtained. On the other hand, the present invention relates to a hair styling agent which is non-greasy, has good luster, has excellent setting power, and has a good sticky property.
【０００３】[0003]
【従来の技術】ヘアーケア製品中のシャンプーのような
洗浄剤においては、洗浄性や起泡性等の洗浄剤としての
基本的機能の他に、洗髪中とすすぎ時の泡質や指通りが
良く、髪がきしまない等使用性が良いこと、また、乾燥
後の髪のまとまりやすさ、しなやかさ、櫛通りが良い等
の仕上がり感が良いことが、重要なポイントになってい
る。そこで、洗浄剤基剤にカチオン性ポリマーやエステ
ル油、シリコーン油等の各種油剤を配合したものが提案
されている。2. Description of the Related Art Detergents such as shampoos in hair care products not only have basic functions as detergents such as detergency and foaming property, but also have good foam quality and finger passing during and during hair washing. The important points are that the hair has good usability, for example, the hair does not squeak, and that the hair has a good finished feeling, such as ease of uniting, suppleness, and good combability after drying. Therefore, there has been proposed a composition in which various oils such as a cationic polymer, an ester oil, and a silicone oil are blended in a detergent base.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、従来の
カチオン性ポリマーやシリコーン油を配合したもので
は、充分なコンディショニング効果を得ることができな
かった。さらに、近年、これらの効果を向上する目的
で、アルキルポリアルキレングリコールエーテル、シリ
コーン誘導体やパーフルオロポリエーテル等の配合が試
みられているが、毛髪特性が充分でなかったり、他の化
粧品原料との相溶性が悪いため、満足する使用感や仕上
がり感が得られない等の問題があった。However, in the case where a conventional cationic polymer or silicone oil is blended, a sufficient conditioning effect cannot be obtained. Furthermore, in recent years, for the purpose of improving these effects, blending of an alkyl polyalkylene glycol ether, a silicone derivative, a perfluoropolyether, or the like has been attempted. Due to poor compatibility, there was a problem that satisfactory feeling of use and finish could not be obtained.
【０００５】一方、整髪剤には、毛髪にしなやかさや艶
を与える目的で、シリコーン油などの油剤やカチオン界
面活性剤等が用いられている。特にシリコーン油は、表
面張力が低く毛髪の潤滑性に優れ、艶を与えるため、近
年広く使用されている。しかしながら、シリコーン油を
多量に用いたり、長い間使用したりすると、毛髪にきし
み感が出るなどの欠点があった。従って、コンディショ
ニング効果、使用性に優れ、毛髪に対し、べたつかず、
艶が良く、セット力に優れたコンディショニング剤、セ
ット剤の開発が求められていた。On the other hand, oils such as silicone oil and cationic surfactants are used as hair styling agents for the purpose of giving the hair suppleness and luster. Particularly, silicone oil has been widely used in recent years because of its low surface tension, excellent lubricity of hair, and luster. However, when the silicone oil is used in a large amount or used for a long time, there is a drawback that the hair has a squeaky feeling. Therefore, it has excellent conditioning effect and usability, and it is not sticky to hair,
There has been a demand for the development of a conditioning agent and a setting agent having a good luster and excellent setting power.
【０００６】[0006]
【課題を解決するための手段】上記実情に鑑み、鋭意研
究した結果、ポリグリセリン変性シリコーン化合物をコ
ンディショニング剤として用いた場合は、コンディショ
ニング効果、使用性に優れたシャンプー、リンス、コン
ディショナーが得られ、また、セット剤として用いた場
合は、毛髪に対し、べたつかず、艶が良く、セット力に
優れ、セット効果の持続するもちの良い整髪剤が得られ
ることを見出し、本発明を完成するに至った。In view of the above-mentioned circumstances, as a result of intensive studies, when a polyglycerin-modified silicone compound is used as a conditioning agent, a shampoo, rinse and conditioner excellent in conditioning effect and usability are obtained. Further, when used as a setting agent, the present inventors have found that a hair styling agent which is non-greasy, has good luster, has excellent setting power, and has a good sticky property can be obtained, and has completed the present invention. Was.
【０００７】すなわち、本発明は、下記一般式（１）で
示される、ポリグリセリン変性シリコーン化合物を配合
することによって、コンディショニング効果、使用性に
優れ、また、毛髪に対し、べたつかず、艶が良く、セッ
ト力に優れた頭髪化粧料に関するものである。[0007] That is, the present invention is excellent in conditioning effect and usability by blending a polyglycerin-modified silicone compound represented by the following general formula (1), and is non-sticky and glossy to hair. The present invention relates to a hair cosmetic composition having excellent set ability.
【０００８】[0008]
【化５】 Embedded image
【０００９】［式中、Ｒ1〜Ｒ10は同一又は異なっても
良く、炭素数１〜１０のアルキル基、フェニル基を示
し、そのうち、少なくとも１つは下記式（Ａ）、（Ｂ）
又は（Ｃ）[Wherein R 1 to R 10 may be the same or different and represent an alkyl group having 1 to 10 carbon atoms or a phenyl group, at least one of which is represented by the following formulas (A) and (B)
Or (C)
【００１０】[0010]
【化６】 Embedded image
【００１１】[0011]
【化７】 Embedded image
【００１２】[0012]
【化８】 Embedded image
【００１３】（但し、Ｑは炭素数１〜１０の２価炭化水
素基、ｌは３〜２０、ｍは２〜２０の正の整数であ
る。）で表わされる基を示し、ｐ、ｑはそれぞれ０以上
の整数であるが、ｐ＝０、ｑ≠０のときＲ1〜Ｒ3、Ｒ6
〜Ｒ10の少なくとも１つは上記式（Ａ）、（Ｂ）又は
（Ｃ）で表わされる基を示し、ｐ≠０、ｑ＝０のときＲ
1〜Ｒ5、Ｒ8〜Ｒ10の少なくとも１つは上記式（Ａ）、
（Ｂ）又は（Ｃ）で表わされる基を示し、ｐ＝ｑ＝０の
ときＲ1〜Ｒ3、Ｒ8〜Ｒ10の少なくとも１つは上記式
（Ａ）、（Ｂ）又は（Ｃ）で表わされる基を示す。］ 以下、本発明について詳細に説明する。(Wherein Q is a divalent hydrocarbon group having 1 to 10 carbon atoms, l is a positive integer of 3 to 20, m is a positive integer of 2 to 20), and p and q are Each is an integer of 0 or more, but when p = 0 and q ≠ 0, R 1 to R 3 and R 6
At least one of R 10 to R 10 represents a group represented by the above formula (A), (B) or (C), and when p ≠ 0 and q = 0,
At least one of 1 to R 5 and R 8 to R 10 is the above formula (A);
And a group represented by (B) or (C), and when p = q = 0, at least one of R 1 to R 3 and R 8 to R 10 is a group represented by the above formula (A), (B) or (C) Represents a group represented by Hereinafter, the present invention will be described in detail.
【００１４】本発明で用いられるポリグリセリン変性シ
リコーン化合物は、上記一般式（１）に示すごとく、ポ
リグリセリンがスペーサーを介してシリコーン鎖に結合
した化合物である。上記一般式（１）で示される化合物
において、式中、Ｒ1〜Ｒ10は同一又は異なっても良
く、炭素数１〜１０のアルキル基、フェニル基を示し、
例えば、メチル基、エチル基、プロピル基、ブチル基、
ペンチル基、ヘキシル基、ヘプチル基、オクチル基、ノ
ニル基、デケル基、シクロペンチル基、シクロヘキシル
基、フェニル基、トリル基等が挙げられ、さらにＲ1〜
Ｒ10の少なくとも１つは上記式（Ａ）、（Ｂ）又は
（Ｃ）で示される基であるが、ジグリセリン、トリグリ
セリン、テトラグリセリン等が挙げられる。The polyglycerin-modified silicone compound used in the present invention is a compound in which polyglycerin is bonded to a silicone chain via a spacer as shown in the general formula (1). In the compound represented by the general formula (1), R 1 to R 10 may be the same or different, and represent an alkyl group having 1 to 10 carbon atoms or a phenyl group;
For example, methyl group, ethyl group, propyl group, butyl group,
Pentyl group, a hexyl group, heptyl group, octyl group, nonyl group, Dekeru group, a cyclopentyl group, a cyclohexyl group, a phenyl group, a tolyl group and the like, further R 1 ~
At least one of R 10 is a group represented by the above formula (A), (B) or (C), and examples thereof include diglycerin, triglycerin, and tetraglycerin.
【００１５】本発明のポリグリセリン変性シリコーン化
合物を頭髪化粧料に配合する場合、化粧料の剤型により
異なるが、化粧料に対して、０．００１〜８０重量％
（以下、単に「％」と記す）、特に０．１〜４０重量％
配合するのが好ましい。When the polyglycerin-modified silicone compound of the present invention is incorporated into a hair cosmetic, it varies depending on the dosage form of the cosmetic, but 0.001 to 80% by weight based on the cosmetic.
(Hereinafter simply referred to as “%”), particularly 0.1 to 40% by weight
It is preferable to mix them.
【００１６】本発明において、頭髪化粧料とは、シャン
プー、ヘアーリンス、リンスインシャンプー、ヘアート
リートメント、ヘアーコンディショナー、整髪料など、
外用医薬品も含めて頭髪に外用されるすべての頭髪製品
を包含する。In the present invention, hair cosmetics include shampoos, hair rinses, rinse-in shampoos, hair treatments, hair conditioners, hair styling agents, and the like.
Includes all hair products topically applied to hair, including topical medicines.
【００１７】本発明の頭髪化粧料では、上記の成分に加
え、本発明の効果を妨げない範囲で通常の頭髪化粧料に
使用されるカチオン性界面活性剤、ノニオン性界面活性
剤、アニオン性界面活性剤、両性界面活性剤等の活性
剤、固体、半固体、液状の油剤、水、水溶性高分子、多
価アルコール、高級アルコール、粉体、樹脂、有機変性
粘土鉱物、高分子化合物、紫外線吸収剤、保湿剤、防腐
剤、殺菌剤、香料、酸化防止剤、金属イオン封鎖剤、ｐ
Ｈ調製剤、色素、美肌用成分、生理活性成分、溶剤、噴
射剤などを配合することができる。In the hair cosmetic composition of the present invention, in addition to the above-mentioned components, cationic surfactants, nonionic surfactants and anionic surfactants used in ordinary hair cosmetics as long as the effects of the present invention are not impaired. Activator, activator such as amphoteric surfactant, solid, semi-solid, liquid oil, water, water-soluble polymer, polyhydric alcohol, higher alcohol, powder, resin, organically modified clay mineral, polymer compound, ultraviolet light Absorbent, humectant, preservative, bactericide, fragrance, antioxidant, sequestering agent, p
An H preparation agent, a pigment, a component for beautiful skin, a physiologically active component, a solvent, a propellant, and the like can be added.
【００１８】[0018]
【実施例】以下に、本発明を実施例を挙げて説明する
が、本発明は、これらの実施例によって限定されるもの
ではない。EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples.
【００１９】製造例１ 攪拌機、温度計及び還流冷却器を付したガラス製フラス
コに下記式のジグリセリンモノアリルエーテル１００．
０ｇ、Production Example 1 A diglycerin monoallyl ether of the following formula was placed in a glass flask equipped with a stirrer, thermometer and reflux condenser.
0 g,
【００２０】[0020]
【化９】 Embedded image
【００２１】及び下記式で表わされるメチルハイドロジ
ェンポリシロキサン２４８．７ｇ、And 248.7 g of methyl hydrogen polysiloxane represented by the following formula:
【００２２】[0022]
【化１０】 Embedded image
【００２３】イソプロピルアルコール２００ｇ、酢酸カ
リウムの１０％エタノール溶液０．５ｇ及び塩化白金酸
のイソプロピルアルコール溶液（白金濃度２％以上、以
下白金触媒と記載する）０．５ｇを仕込み、加熱してイ
ソプロピルアルコールの還流温度で３時間反応を行なっ
た。反応終了後、イソプロピルアルコールを減圧留去し
て、下記式のジグリセリン変性シリコーン化合物３２
３．０ｇを得た。200 g of isopropyl alcohol, 0.5 g of a 10% ethanol solution of potassium acetate, and 0.5 g of an isopropyl alcohol solution of chloroplatinic acid (platinum concentration: 2% or more, hereinafter referred to as a platinum catalyst) were charged, and heated to isopropyl alcohol. At reflux temperature for 3 hours. After completion of the reaction, isopropyl alcohol was distilled off under reduced pressure to obtain a diglycerin-modified silicone compound 32 represented by the following formula.
3.0 g were obtained.
【００２４】[0024]
【化１１】 Embedded image
【００２５】製造例２ 前記した製造例１と同様に、攪拌機、温度計及び還流冷
却器を付したガラス製フラスコに下記式のジグリセリン
モノアリルエーテル１００．０ｇ、Production Example 2 In the same manner as in Production Example 1 described above, 100.0 g of diglycerin monoallyl ether of the following formula was placed in a glass flask equipped with a stirrer, a thermometer and a reflux condenser.
【００２６】[0026]
【化１２】 Embedded image
【００２７】及び製造例１で用いたメチルハイドロジェ
ンポリシロキサン２４８．７ｇ、イソプロピルアルコー
ル２００ｇ、酢酸カリウムの１０％エタノール溶液０．
５ｇ及び白金触媒０．５ｇを仕込み、加熱してイソプロ
ピルアルコールの還流温度で３時間反応を行なった。反
応終了後、イソプロピルアルコールを減圧留去して、下
記式のジグリセリン変性シリコーン化合物３２３．０ｇ
を得た。Further, 248.7 g of methyl hydrogen polysiloxane used in Production Example 1, 200 g of isopropyl alcohol, and a 10% ethanol solution of potassium acetate in 0.1% were used.
5 g and 0.5 g of a platinum catalyst were charged, heated and reacted at the reflux temperature of isopropyl alcohol for 3 hours. After completion of the reaction, isopropyl alcohol was distilled off under reduced pressure to obtain 323.0 g of a diglycerin-modified silicone compound represented by the following formula.
I got
【００２８】[0028]
【化１３】 Embedded image
【００２９】製造例３ 前記した製造例１と同様に、攪拌機、温度計及び還流冷
却器を付したガラス製フラスコに下記式のトリグリセリ
ンモノアリルエーテル５０．０ｇ、Production Example 3 In the same manner as in Production Example 1 described above, 50.0 g of triglycerin monoallyl ether of the following formula was placed in a glass flask equipped with a stirrer, thermometer and reflux condenser.
【００３０】[0030]
【化１４】 Embedded image
【００３１】及び下記式で表わされるメチルハイドロジ
ェンポリシロキサン３２３．２ｇ、And 323.2 g of methyl hydrogen polysiloxane represented by the following formula:
【００３２】[0032]
【化１５】 Embedded image
【００３３】イソプロピルアルコール２００ｇ、酢酸カ
リウムの１０％エタノール溶液１．０ｇ及び白金触媒
０．５ｇを仕込み、加熱し、イソプロピルアルコールの
還流温度で５時間反応を行なった。反応終了後、イソプ
ロピルアルコールを減圧留去して、下記式のトリグリセ
リン変性シリコーン化合物３５０．２ｇを得た。得られ
たトリグリセリン変性シリコーン化合物は、粘度が３．
７万ｃｓ（２５℃）、屈折率１．４１６４（２５℃）の
粘ちょうな液体であった。200 g of isopropyl alcohol, 1.0 g of a 10% ethanol solution of potassium acetate and 0.5 g of a platinum catalyst were charged, heated, and reacted at the reflux temperature of isopropyl alcohol for 5 hours. After completion of the reaction, isopropyl alcohol was distilled off under reduced pressure to obtain 350.2 g of a triglycerin-modified silicone compound represented by the following formula. The obtained triglycerin-modified silicone compound has a viscosity of 3.
It was a viscous liquid having a viscosity of 70,000 cs (25 ° C.) and a refractive index of 1.4164 (25 ° C.).
【００３４】[0034]
【化１６】 Embedded image
【００３５】製造例４ 前記した製造例１と同様に、攪拌機、温度計及び還流冷
却器を付したガラス製フラスコに下記式で表わされるメ
チルハイドロジェンポリシロキサン１２０．０ｇ、Production Example 4 In the same manner as in Production Example 1 described above, 120.0 g of methyl hydrogen polysiloxane represented by the following formula was placed in a glass flask equipped with a stirrer, a thermometer and a reflux condenser.
【００３６】[0036]
【化１７】 Embedded image
【００３７】及び製造例３で用いたトリグリセリンモノ
アリルエーテル１５４．０ｇ、イソプロピルアルコール
１２０ｇ、酢酸カリウムの１０％エタノール溶液０．３
ｇ及び白金触媒０．３ｇを仕込み、加熱してイソプロピ
ルアルコールの還流温度で５時間反応を行なった。反応
終了後、イソプロピルアルコールを減圧留去して、下記
式のトリグリセリン変性シリコーン化合物２４６．８ｇ
を得た。In addition, 154.0 g of triglycerin monoallyl ether, 120 g of isopropyl alcohol and 0.3% of a 10% ethanol solution of potassium acetate used in Production Example 3 were used.
g of platinum catalyst and 0.3 g of platinum catalyst were heated and reacted at the reflux temperature of isopropyl alcohol for 5 hours. After completion of the reaction, isopropyl alcohol was distilled off under reduced pressure, and 246.8 g of a triglycerin-modified silicone compound represented by the following formula was obtained.
I got
【００３８】[0038]
【化１８】 Embedded image
【００３９】実施例１〜４及び比較例１〜４ シャンプ
ー 次の表１に示す各組成のシャンプーを製造し、その使用
性について評価を行なった。Examples 1 to 4 and Comparative Examples 1 to 4 Shampoos Shampoos having the respective compositions shown in the following Table 1 were produced, and their usability was evaluated.
【００４０】[0040]
【表１】 [Table 1]
【００４１】（製造方法） Ａ：成分１〜６を攪拌混合し、製品を得た。(Production method) A: Components 1 to 6 were mixed with stirring to obtain a product.
【００４２】（評価）女性５０名のパネルにより使用テ
ストを行ない、起泡性、洗浄性、洗髪時の使用感、仕上
がり感について下記の基準で評価を行ない、その平均点
で判定した。 ［評価基準］ ５点：非常に良好 ４点：良好 ３点：普通 ２点：やや不良 １点：不良 ［判定］ ◎：平均点４．５以上 ○：平均点３．５以上４．５未満 △：平均点２．５以上３．５未満 ×：平均点２．５未満 得られた結果を表２に示す。(Evaluation) A use test was conducted by a panel of 50 women, and the foaming property, detergency, feeling of use during hair washing, and feeling of finish were evaluated according to the following criteria, and the average score was determined. [Evaluation criteria] 5 points: Very good 4 points: Good 3 points: Normal 2 points: Somewhat poor 1 point: Poor [Judgment] ：: Average score of 4.5 or more ○: Average score of 3.5 or more and less than 4.5 Δ: Average score of 2.5 or more and less than 3.5 ×: Average score of less than 2.5 The obtained results are shown in Table 2.
【００４３】[0043]
【表２】 [Table 2]
【００４４】表２の結果より明らかなように、本発明の
ポリグリセリン変性シリコーン化合物を配合した実施例
１〜４のシャンプーは比較例１〜４に比べ、起泡性、洗
浄性に優れ、また、指通りが良く、髪がきしまない等、
洗髪時の使用感も仕上がり感も良く、非常に優れてい
た。As is clear from the results shown in Table 2, the shampoos of Examples 1 to 4 containing the polyglycerin-modified silicone compound of the present invention are superior in foamability and detergency as compared with Comparative Examples 1 to 4. , Fingers are good, hair does not come off,
The feeling of use and the finish at the time of washing the hair were good and very excellent.
【００４５】実施例５〜６及び比較例５〜６ ヘアーコ
ンディショナー 次の表３に示す各組成のヘアーコンディショナーを製造
し、その使用性について評価した。Examples 5 to 6 and Comparative Examples 5 to 6 Hair conditioners Hair conditioners having the compositions shown in Table 3 below were produced, and their usability was evaluated.
【００４６】[0046]
【表３】 [Table 3]
【００４７】（製造方法） Ａ：成分１〜４を攪拌混合し、製品を得た。(Production Method) A: Components 1 to 4 were stirred and mixed to obtain a product.
【００４８】（評価）女性５０名のパネルにより使用テ
ストを行ない、塗布時ののび、塗布時の指通り、すすぎ
時の指通り、乾燥時の艶、仕上がり感について前述した
基準で評価を行ない、その平均点で判定した。その結果
を表４に示す。(Evaluation) A use test was conducted by a panel of 50 women, and evaluation was performed on the above-mentioned criteria for spreading at the time of application, fingering at the time of application, fingering at the time of rinsing, gloss at the time of drying, and finish feeling. The judgment was made based on the average score. Table 4 shows the results.
【００４９】[0049]
【表４】 [Table 4]
【００５０】表４の結果より明らかなように、本発明の
ポリグリセリン変性シリコーン化合物を配合した実施例
５〜６のヘアーコンディショナーは比較例５〜６に比
べ、塗布時ののびや指通り、すすぎ時の指通りが良く、
乾燥時においての艶、仕上がり感が非常に良いものであ
った。As is evident from the results in Table 4, the hair conditioners of Examples 5 to 6 in which the polyglycerin-modified silicone compound of the present invention was blended were compared with Comparative Examples 5 to 6 in terms of stretching, finger rinsing, and rinsing. Good finger passage at the time,
The gloss and the finished feeling at the time of drying were very good.
【００５１】実施例７ スタイリングムース 次に示す組成のスタイリングムースを製造し、その使用
性について評価した。Example 7 Styling mousse A styling mousse having the following composition was produced and its usability was evaluated.
【００５２】 （組成） （％） １．ポリビニルピロリドン・酢酸ビニル共重合体 ５．０ ２．ポリグリセリン変性シリコーン化合物（製造例４） １．０ ３．エタノール １０．０ ４．防腐剤 適 量 ５．香料 適 量 ６．精製水 残 量 ７．噴射剤 ３．０(Composition) (%) 1. Polyvinylpyrrolidone / vinyl acetate copolymer 5.0 2. Polyglycerin-modified silicone compound (Production Example 4) 1.0 Ethanol 10.0 4. Preservative qs. Appropriate amount of fragrance 6. Remaining purified water 7. Propellant 3.0
【００５３】（製造方法） Ａ：成分１〜６を均一に混合する。 Ｂ：Ａと成分７をエアゾール缶に充填して、スタイリン
グムースを得た。 実施例７のスタイリングムースは、べたつかず、艶が良
く、セット力に優れた非常に使用性の良いものであっ
た。(Production method) A: Components 1 to 6 are uniformly mixed. B: A and Component 7 were filled in an aerosol can to obtain a styling mousse. The styling mousse of Example 7 was non-greasy, glossy, and excellent in setability, and very easy to use.
【００５４】[0054]
【発明の効果】以上詳述したように、ポリグリセリン変
性シリコーン化合物を配合した頭髪化粧料は、コンディ
ショニング効果、使用性に優れ、又、毛髪に対し、べた
つかず、艶が良く、セット力に優れ、セット効果の持続
する持ちの非常に良いものである。As described in detail above, hair cosmetics containing a polyglycerin-modified silicone compound are excellent in conditioning effect and usability, and are non-greasy, glossy, and excellent in setting power to hair. It is a very good, lasting set effect.
─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成９年１２月９日[Submission date] December 9, 1997
【手続補正１】[Procedure amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００４０[Correction target item name] 0040
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００４０】[0040]
【表１】 [Table 1]
【手続補正２】[Procedure amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００４１[Correction target item name] 0041
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００４１】（製造方法） Ａ：成分１〜５を攪拌混合し、製品を得た。(Production method) A: Components 1 to 5 were mixed by stirring to obtain a product.
Claims (1)
セリン変性シリコーン化合物を含有することを特徴とす
る頭髪化粧料。 【化１】 ［式中、Ｒ1〜Ｒ10は同一又は異なっても良く、炭素数
１〜１０のアルキル基、フェニル基を示し、そのうち、
少なくとも１つは下記式（Ａ）、（Ｂ）又は（Ｃ） 【化２】 【化３】 【化４】 （但し、Ｑは炭素数１〜１０の２価炭化水素基、ｌは３
〜２０、ｍは２〜２０の正の整数である。）で表わされ
る基を示し、ｐ、ｑはそれぞれ０以上の整数であるが、
ｐ＝０、ｑ≠０のときＲ1〜Ｒ3、Ｒ6〜Ｒ10の少なくと
も１つは上記式（Ａ）、（Ｂ）又は（Ｃ）で表わされる
基を示し、ｐ≠０、ｑ＝０のときＲ1〜Ｒ5、Ｒ8〜Ｒ10
の少なくとも１つは上記式（Ａ）、（Ｂ）又は（Ｃ）で
表わされる基を示し、ｐ＝ｑ＝０のときＲ1〜Ｒ3、Ｒ8
〜Ｒ10の少なくとも１つは上記式（Ａ）、（Ｂ）又は
（Ｃ）で表わされる基を示す。］1. A hair cosmetic comprising a polyglycerin-modified silicone compound represented by the following general formula (1). Embedded image [Wherein, R 1 to R 10 may be the same or different and represent an alkyl group having 1 to 10 carbon atoms or a phenyl group;
At least one is represented by the following formula (A), (B) or (C): Embedded image Embedded image (However, Q is a divalent hydrocarbon group having 1 to 10 carbon atoms, l is 3
-20 and m are positive integers of 2-20. ) Represents a group represented by p and q are each an integer of 0 or more,
When p = 0 and q ≠ 0, at least one of R 1 to R 3 and R 6 to R 10 represents a group represented by the above formula (A), (B) or (C), and p ≠ 0, q = R 1 to R 5 when 0, R 8 ~R 10
At least one represents a group represented by the above formula (A), (B) or (C), and when p = q = 0, R 1 to R 3 and R 8
At least one of R 10 represents a group represented by the above formula (A), (B) or (C). ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14461097A JPH10316540A (en) | 1997-05-19 | 1997-05-19 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14461097A JPH10316540A (en) | 1997-05-19 | 1997-05-19 | Hair cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH10316540A true JPH10316540A (en) | 1998-12-02 |
Family
ID=15366037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14461097A Pending JPH10316540A (en) | 1997-05-19 | 1997-05-19 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH10316540A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6150311A (en) * | 1998-06-16 | 2000-11-21 | L'oreal | Detergent cosmetic compositions and their use |
| JP2007008915A (en) * | 2005-01-17 | 2007-01-18 | Shiseido Co Ltd | Cosmetic |
| EP1847262A1 (en) * | 2005-01-17 | 2007-10-24 | Shiseido Company, Limited | Cosmetic |
| DE102006031152A1 (en) * | 2006-07-04 | 2008-01-10 | Byk-Chemie Gmbh | Polyhydroxy-functional polysiloxanes as anti-adhesive and dirt-repellent additives in coatings, polymeric molding compounds and thermoplastics, process for their preparation and their use |
| DE102008032064A1 (en) | 2008-07-08 | 2010-01-14 | Byk-Chemie Gmbh | Polyhydroxy-functional polysiloxanes for increasing the surface energy of thermoplastics, processes for their preparation and their use |
| DE102008032066A1 (en) | 2008-07-08 | 2010-01-14 | Byk-Chemie Gmbh | Polyhydroxy-functional polysiloxanes as anti-adhesive and dirt-repellent additives in coatings, polymeric molding compounds and thermoplastics, process for their preparation and their use |
| US8080239B2 (en) | 2005-01-17 | 2011-12-20 | Shiseido Co., Ltd. | Cosmetic |
| EP2554572A1 (en) | 2011-08-03 | 2013-02-06 | Evonik Goldschmidt GmbH | Use of polysiloxanes containing branched polyether residues in preparation of polyurethane foams |
| WO2013100169A1 (en) | 2011-12-27 | 2013-07-04 | Dow Corning Toray Co., Ltd. | Co-modified organopolysiloxane, emulsifier for water-in-oil emulsion, external use preparation, and cosmetic composition using the same |
| WO2013103147A1 (en) | 2011-12-27 | 2013-07-11 | Dow Corning Toray Co., Ltd. | Diglycerin derivate-modified silicone, emulsifier for water-in-oil emulsion using the same, external use preparation, and cosmetic composition |
| WO2014104255A1 (en) * | 2012-12-28 | 2014-07-03 | 東レ・ダウコーニング株式会社 | High-purity monoalkenyl-containing glycerin derivative, and method for producing same |
| JP2018076268A (en) * | 2016-11-11 | 2018-05-17 | ホーユー株式会社 | Cleansing agent composition, and cleansing method |
| JP2019001729A (en) * | 2017-06-13 | 2019-01-10 | 株式会社ミルボン | Cosmetic composition |
-
1997
- 1997-05-19 JP JP14461097A patent/JPH10316540A/en active Pending
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6150311A (en) * | 1998-06-16 | 2000-11-21 | L'oreal | Detergent cosmetic compositions and their use |
| JP2007008915A (en) * | 2005-01-17 | 2007-01-18 | Shiseido Co Ltd | Cosmetic |
| EP1847262A1 (en) * | 2005-01-17 | 2007-10-24 | Shiseido Company, Limited | Cosmetic |
| US8080239B2 (en) | 2005-01-17 | 2011-12-20 | Shiseido Co., Ltd. | Cosmetic |
| EP1847262A4 (en) * | 2005-01-17 | 2012-10-03 | Shiseido Co Ltd | Cosmetic |
| DE102006031152A1 (en) * | 2006-07-04 | 2008-01-10 | Byk-Chemie Gmbh | Polyhydroxy-functional polysiloxanes as anti-adhesive and dirt-repellent additives in coatings, polymeric molding compounds and thermoplastics, process for their preparation and their use |
| WO2008003470A1 (en) | 2006-07-04 | 2008-01-10 | Byk-Chemie Gmbh | Polyhydroxyfunktional polysiloxanes, method for the production and use thereof |
| JP2009541542A (en) * | 2006-07-04 | 2009-11-26 | ベーイプシロンカー ヘミー ゲゼルシャフト ミット ベシュレンクター ハフトゥング | Polyhydroxy-functional polysiloxane, process for its production and use |
| US8486188B2 (en) | 2008-07-08 | 2013-07-16 | Byk-Chemie Gmbh | Polyhydroxyfunctional polysiloxane as anti-adhesive and dirt-repellant additives |
| DE102008032064A1 (en) | 2008-07-08 | 2010-01-14 | Byk-Chemie Gmbh | Polyhydroxy-functional polysiloxanes for increasing the surface energy of thermoplastics, processes for their preparation and their use |
| DE102008032066A1 (en) | 2008-07-08 | 2010-01-14 | Byk-Chemie Gmbh | Polyhydroxy-functional polysiloxanes as anti-adhesive and dirt-repellent additives in coatings, polymeric molding compounds and thermoplastics, process for their preparation and their use |
| EP2554572A1 (en) | 2011-08-03 | 2013-02-06 | Evonik Goldschmidt GmbH | Use of polysiloxanes containing branched polyether residues in preparation of polyurethane foams |
| DE102011109541A1 (en) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Use of polysiloxanes containing branched polyether radicals for the production of polyurethane foams |
| WO2013100169A1 (en) | 2011-12-27 | 2013-07-04 | Dow Corning Toray Co., Ltd. | Co-modified organopolysiloxane, emulsifier for water-in-oil emulsion, external use preparation, and cosmetic composition using the same |
| WO2013103147A1 (en) | 2011-12-27 | 2013-07-11 | Dow Corning Toray Co., Ltd. | Diglycerin derivate-modified silicone, emulsifier for water-in-oil emulsion using the same, external use preparation, and cosmetic composition |
| KR20140106745A (en) | 2011-12-27 | 2014-09-03 | 다우 코닝 도레이 캄파니 리미티드 | Co-modified organopolysiloxane, emulsifier for water-in-oil emulsion, external use preparation, and cosmetic composition using the same |
| KR20140127231A (en) | 2011-12-27 | 2014-11-03 | 다우 코닝 도레이 캄파니 리미티드 | Diglycerin derivative-modified silicone, emulsifier for water-in-oil emulsion using the same, external use preparation, and cosmetic composition |
| US9480630B2 (en) | 2011-12-27 | 2016-11-01 | Dow Corning Toray Co., Ltd. | Co-modified organopolysiloxane, emulsifier for water-in-oil emulsion, external use preparation, and cosmetic composition using the same |
| US10085928B2 (en) | 2011-12-27 | 2018-10-02 | Dow Corning Toray Co., Ltd. | Diglycerin derivate-modified silicone, emulsifier for water-in-oil emulsion using the same, external use preparaton, and cosmetic composition |
| WO2014104255A1 (en) * | 2012-12-28 | 2014-07-03 | 東レ・ダウコーニング株式会社 | High-purity monoalkenyl-containing glycerin derivative, and method for producing same |
| US9663432B2 (en) | 2012-12-28 | 2017-05-30 | Dow Corning Toray Co., Ltd. | High-purity monoalkenyl-containing glycerin derivative and method of manufacturing same |
| JP2018076268A (en) * | 2016-11-11 | 2018-05-17 | ホーユー株式会社 | Cleansing agent composition, and cleansing method |
| JP2019001729A (en) * | 2017-06-13 | 2019-01-10 | 株式会社ミルボン | Cosmetic composition |
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