JPH10194904A - Insecticidal mat for long time and thermal vaporization insecticidal method using the same - Google Patents
Insecticidal mat for long time and thermal vaporization insecticidal method using the sameInfo
- Publication number
- JPH10194904A JPH10194904A JP9281054A JP28105497A JPH10194904A JP H10194904 A JPH10194904 A JP H10194904A JP 9281054 A JP9281054 A JP 9281054A JP 28105497 A JP28105497 A JP 28105497A JP H10194904 A JPH10194904 A JP H10194904A
- Authority
- JP
- Japan
- Prior art keywords
- mat
- insecticidal
- pyrethroid
- area
- radiating plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、殺虫成分を含有する繊
維質製マット、及びこれを発熱体放熱板上に載置して該
殺虫成分を蒸散させる加熱蒸散殺虫方法に関するもので
ある。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fibrous mat containing a pesticidal component, and a method of heating and transpirating insects by placing the fibrous mat on a heat radiating plate and evaporating the pesticidal component.
【０００２】[0002]
【従来の技術】従来より殺虫等の目的で殺虫成分を加熱
蒸散させる方法として、（１）蚊取線香、（２）電気蚊
取マットなどが愛好され、近年、（３）液体蚊取、すな
わち薬液中に吸液芯を浸漬し、芯上部を加熱して薬液を
加熱蒸散させる方法も普及している。このうち、電気蚊
取マットは、殺虫成分を含浸させた繊維質製マットを、
加熱蒸散装置の該マットと略同形状の放熱板上に載置
し、通電により加熱して殺虫成分を蒸散させるもので、
放熱板の中心部の渦度は１４０〜１８０℃の範囲に設定
されている。電気蚊取マットは使いやすい製剤である
が、マットの底面全体が放熱板により加熱されるので、
揮散調整剤を添加しても殺虫成分の揮散量は経時的に減
少する。このため、通常１枚のマットには、１日毎にマ
ットを取り替える設計で１日使用分のピレスロイド系殺
虫成分しか配合されておらず、製剤の特性上、長時間用
殺虫マットの開発は困難と考えられてきた。一方、液体
蚊取でも、電気蚊取マットの場合と同じピレスロイド系
殺虫成分が使用されるが、芯上部を間接加熱する構成の
ため発熱体の温度は電気蚊取マットに比べて若干低くな
っている。この方式は１度薬液ボトルを装着するだけで
３０〜６０日間効果が継続するので便利である反面、液
漏れ等の危惧は避けられない。2. Description of the Related Art Conventionally, (1) mosquito coils and (2) electric mosquito mats have been favored as methods for heating and evaporating insecticidal components for the purpose of insect killing. A method of immersing a liquid-absorbing wick in a chemical solution and heating the upper portion of the wick to heat and evaporate the chemical solution has also been widely used. Among them, the electric mosquito collecting mat is a fibrous mat impregnated with insecticidal components.
It is placed on a heat radiating plate of substantially the same shape as the mat of the heating and transpiration device, and heated by energization to evaporate the insecticidal component,
The vorticity at the center of the heat sink is set in the range of 140 to 180 ° C. The electric mosquito mat is an easy-to-use preparation, but the entire bottom of the mat is heated by the heat sink,
Even if the volatilization modifier is added, the volatilization amount of the insecticidal component decreases with time. For this reason, a single mat is usually designed to replace the mat every day and contains only the pyrethroid-based insecticide used for one day, and it is difficult to develop a long-term insecticide mat due to the characteristics of the formulation. Has been considered. On the other hand, in the case of liquid mosquito collection, the same pyrethroid-based insecticidal ingredients are used as in the case of electric mosquito collection mats. I have. This method is convenient because the effect lasts for 30 to 60 days just by installing the chemical bottle once, but the fear of liquid leakage is inevitable.
【０００３】電気蚊取マット方式の使いやすい長所を取
り入れ、かつ長期間効果の持続する製剤の開発も試みら
れ、例えば特開平５−１９４１０３号公報や特開平６−
１９２００７号公報には、熱可塑性樹脂粉末と無機粉末
及び／又は有機粉末からなる混合物を熱可塑性樹脂粉末
の融点付近に加熱してなる加熱蒸散用薬剤含有体が開示
され、熱伝導性のよい担体を用いることにより加熱温度
を下げえることが記載されている。しかしながら、長期
間にわたり安定した蒸散性能を得るのが難しく実用には
至っていない。[0003] Attempts have been made to develop formulations that incorporate the easy-to-use advantages of the electric mosquito collecting mat system and have a long-lasting effect. For example, JP-A-5-194103 and JP-A-6-194103
Japanese Patent No. 192007 discloses a heat-evaporating drug-containing substance obtained by heating a mixture of a thermoplastic resin powder and an inorganic powder and / or an organic powder near the melting point of the thermoplastic resin powder. It is described that the heating temperature can be reduced by using. However, it is difficult to obtain stable transpiration performance over a long period of time, and it has not been put to practical use.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、殺虫成分を
含有する繊維質製マットを発熱体放熱板上に載置して該
殺虫成分を蒸散させる電気蚊取マット方式において、従
来の知見を覆し、５日間以上の長期間にわたり安定した
殺虫効力を持続しえる長時間用殺虫マット、及びこれを
用いた加熱蒸散殺虫方法を提供することを目的とする。SUMMARY OF THE INVENTION The present invention relates to an electric mosquito collecting system in which a fibrous mat containing an insecticidal component is placed on a heat radiating plate to evaporate the insecticidal component. It is an object of the present invention to provide a long-time insecticidal mat that can be covered and maintain a stable insecticidal effect for a long period of 5 days or more, and a heat-transpiration insecticidal method using the same.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するた
め、本発明者らは、繊維質製マットに含浸される殺虫成
分の物理化学的性質、ならびにマットの面積と放熱板の
面積との関係が蒸散性能に及ぼす影響を詳細に調べ、特
定のマットと特定の放熱板を有する加熱蒸散装置を組み
合わせることによって、５日間以上にわたり連続して殺
虫効力を持続できうることを発見した。Means for Solving the Problems In order to achieve the above object, the present inventors have studied the physicochemical properties of insecticidal components impregnated in a fibrous mat, and the relationship between the area of the mat and the area of a heat sink. Investigations into the effects of sulphate on the transpiration performance were carried out in detail, and it was found that the combination of a specific mat and a heat transpiration device having a specific heat radiating plate could maintain the insecticidal effect continuously for 5 days or more.
【０００６】すなわち、請求項１の発明は、２０℃にお
ける蒸気圧が４．０×１０−６ｍｍＨｇ以上のピレスロ
イド系殺虫成分を１枚あたり５０ｍｇ以上含浸させた繊
維質製マットであって、このマットの底面積の０．２〜
０．６倍の面積を有しかつ加熱温度が７０〜１７０℃の
放熱板上に載置して使用され、５日間以上連続して殺虫
効力を持続しえる長時間用殺虫マットに係る。That is, the first aspect of the present invention is a fibrous mat impregnated with a pyrethroid-based insecticidal component having a vapor pressure at 20 ° C. of 4.0 × 10 −6 mmHg or more per sheet of 50 mg or more. 0.2 ~ of the bottom area of the mat
The present invention relates to a long-time insecticidal mat which has a 0.6 times area and is used by being placed on a heat radiating plate having a heating temperature of 70 to 170 ° C. and which can maintain insecticidal efficacy continuously for 5 days or more.
【０００７】本発明で用いられる殺虫成分は、安全性の
高いピレスロイド系化合物で、２０℃における蒸気圧が
４．０×１０−６ｍｍＨｇ以上であることを必須とす
る。蒸気圧が４．０×１０−６ｍｍＨｇより小さいと、
特定の放熱板を有する加熱蒸散装置を組み合わせたとし
ても所望の効果が得られない。好適な殺虫成分として、
例えば、アレスリン、フラメトリン、プラレトリン、テ
フラメトリン（５−プロパルギル−２−フリルメチル
２，２，３，３−テトラメチルシクロプロパンカルボキ
シレート）、テラレスリン、エムペントリン、５−プロ
パルギル−２−メチル−３−フリルメチル ２，２，
３，３−テトラメチルシクロプロパンカルボキシレー
ト、トランスフルスリン、フェンフルスリン等をあげる
ことができ、用途や目的に応じて適宜選択することがで
きる。なかでも、アレスリン、フラメトリン、プラレト
リン、テフラメトリンが性能上好ましい。なお、化学構
造上、不斉炭素や二重結合に基づく光学異性体や幾何異
性体が存在する場合は、それぞれの各々ならびに任意の
混合物も本発明の殺虫成分に包含されるのはもちろんで
ある。The insecticidal component used in the present invention is a highly safe pyrethroid compound, and it is essential that the vapor pressure at 20 ° C. be 4.0 × 10 −6 mmHg or more. When the vapor pressure is lower than 4.0 × 10 −6 mmHg,
Even if a heating and evaporating device having a specific heat radiating plate is combined, a desired effect cannot be obtained. As a suitable insecticidal component,
For example, allethrin, framethrin, praletrin, teframethrin (5-propargyl-2-furylmethyl)
2,2,3,3-tetramethylcyclopropanecarboxylate), terarethrine, empentrin, 5-propargyl-2-methyl-3-furylmethyl 2,2,2
Examples include 3,3-tetramethylcyclopropanecarboxylate, transfluthrin, fenfluthrin and the like, which can be appropriately selected depending on the use and purpose. Among them, allethrin, framethrin, praletrin, and teframethrin are preferable in terms of performance. In the case where an optical isomer or a geometric isomer based on an asymmetric carbon or a double bond is present on the chemical structure, each of them and any mixture is naturally included in the insecticidal component of the present invention. .
【０００８】本発明では、繊維質製マットに前記ピレス
ロイド系殺虫成分が１枚あたり５０ｍｇ以上配合され
る。５０ｍｇより少ないと当然のことながら、長期間に
わたり殺虫効力を発揮しえない。なお、繊維質製マット
に含浸させるにあたっては、通常、ピレスロイド系殺虫
成分の外、必要に応じて殺虫成分の安定剤、揮散調整
剤、溶剤、香料、色素等を添加した原液が用いられる。
ただし、マットの最大保持液量には限度があるので、例
えば、大きさが２２×３５ｍｍで厚さが２．８ｍｍのマ
ットでは、原液量を１枚あたり１．２ｇ以内に抑えるの
が適当である。殺虫成分の安定剤としては、例えばジブ
チルヒドロキシトルエン、ジブチルハイドロキノン、
２，２’−メチレンビス−（４−エチル−６−ｔ−ブチ
ルフェノール）〔ヨシノックス４２５〕があり、揮散調
整剤としては、例えばピペロニルブトキサイド、Ｎ−
（２−エチルヘキシル）−１−イソプロピル−４−メチ
ルビシクロ（２，２，２）オクト−５−エン−２，３−
ジカルボキシイミド〔サイネピリン５００〕、ステアリ
ン酸ブチル等があげられるが、もちろんこれらに限定さ
れるものではない。[0008] In the present invention, the pyrethroid insecticidal component is blended in a fibrous mat in an amount of 50 mg or more per sheet. When the amount is less than 50 mg, the insecticidal effect cannot be exerted for a long period. When the fiber mat is impregnated, a stock solution containing a pyrethroid-based insecticidal component and, where necessary, a stabilizer for the insecticide component, a volatilization regulator, a solvent, a fragrance, a dye, and the like are used as needed.
However, since there is a limit to the maximum amount of retentate of the mat, for example, in the case of a mat having a size of 22 × 35 mm and a thickness of 2.8 mm, it is appropriate to suppress the stock solution to within 1.2 g per sheet. is there. Examples of insecticidal component stabilizers include dibutylhydroxytoluene, dibutylhydroquinone,
There is 2,2'-methylenebis- (4-ethyl-6-t-butylphenol) [Yoshinox 425], and as a volatilization modifier, for example, piperonyl butoxide, N-
(2-ethylhexyl) -1-isopropyl-4-methylbicyclo (2,2,2) oct-5-ene-2,3-
Examples thereof include dicarboximide [Sinepiline 500] and butyl stearate, but are not limited thereto.
【０００９】また、本発明では、ピレスロイド系殺虫成
分以外の有効成分、例えば殺ダニ剤、忌避剤、ヒノキチ
オール、リナロール、シトラール、ピネン、メントー
ル、テルペンアルコール類等の空間用殺菌・抗菌剤、防
黴剤等をピレスロイド系殺虫成分の蒸散性を損なわない
範囲で添加し多目的組成物とすることもできる。Further, in the present invention, active ingredients other than pyrethroid insecticides, such as acaricides, repellents, bactericidal and antibacterial agents for space such as hinokitiol, linalool, citral, pinene, menthol, terpene alcohols, and fungicides. An agent or the like can be added to the extent that the transpiration of the pyrethroid-based insecticidal component is not impaired, so that a multipurpose composition can be obtained.
【００１０】本発明は、前記特定のマットと、このマッ
トの底面積の０．２〜０．６倍の面積を有しかつ加熱温
度が７０〜１７０℃の放熱板を備えた加熱蒸散装置とを
組み合わせたことに特徴を有する。殺虫成分のマットか
らの蒸散が一定して継続する機構としては次のように考
えられる。まず通電すると、放熱板上に位置するマット
部から殺虫成分が蒸散するが、放熱板の面積がマットの
底面積の０．２〜０．６倍に狭められているので、初期
蒸散量が従来品のように過剰に高すぎることがない。し
かる後通電休止時に、生じた殺虫成分の濃度勾配が平衡
になるように、非加熱部上に位置するマット部の殺虫成
分が放熱板上マット部に移動する。こうして放熱板上マ
ット部には常に所望の殺虫成分量が補給されるため、１
日内の経時的な蒸散量は従来品と異なりほぼ一定で推移
し、しかも５日以上の長期間にわたって蒸散の継続が可
能となるのである。なお、マット底面における放熱板の
占有部は、マット中央部であっても辺部であってもよい
が、より安定した性能を得るうえでマット中央部の方が
好ましい。[0010] The present invention relates to a heating and evaporating apparatus having the specific mat and a heat radiating plate having an area 0.2 to 0.6 times the bottom area of the mat and having a heating temperature of 70 to 170 ° C. The feature is that they are combined. The mechanism by which the transpiration of the insecticidal component from the mat is kept constant is considered as follows. First, when electricity is supplied, the insecticidal component evaporates from the mat located on the heat sink, but since the area of the heat sink is reduced to 0.2 to 0.6 times the bottom area of the mat, the initial evaporation amount is It is not too high like a product. Thereafter, when the power supply is stopped, the insecticidal component of the mat portion located on the non-heated portion moves to the mat on the heat sink so that the concentration gradient of the generated insecticidal component becomes equilibrium. Thus, the desired amount of the insecticidal component is always supplied to the mat on the heat sink,
Unlike the conventional products, the amount of transpiration with the passage of time during the day is almost constant, and the transpiration can be continued for a long period of 5 days or more. The occupied portion of the heat radiating plate on the bottom surface of the mat may be the center portion or the side portion of the mat, but is preferably the center portion of the mat in order to obtain more stable performance.
【００１１】請求項２の発明は、請求項１の構成におい
て、特にピレスロイド系殺虫成分として、アレスリン、
フラメトリン、プラレトリン、及びテフラメトリンから
選ばれた１種または２種を用いた長時間用殺虫マットで
ある。[0011] The invention according to claim 2 is the composition according to claim 1, wherein in particular, as a pyrethroid insecticidal component,
This is a long-time insecticidal mat using one or two selected from flametrin, praletrin, and teframethrin.
【００１２】請求項３の発明は、請求項１又は２の構成
において、ピレスロイド系殺虫成分としてフラメトリン
を選択し、マット１枚あたり１５０〜４００ｍｇを含有
させ、かつ揮散調整剤としてピペロニルブトキサイド５
０〜３００ｍｇを配合すると共に、放熱板の面積をマッ
トの底面積の０．５倍としたものである。According to a third aspect of the present invention, there is provided the composition according to the first or second aspect, wherein flamethrin is selected as a pyrethroid insecticidal component, 150 to 400 mg is contained per mat, and piperonyl butoxide is used as a volatilization regulator. 5
0 to 300 mg was added, and the area of the heat radiating plate was 0.5 times the bottom area of the mat.
【００１３】請求項４の発明は、請求項１の長時間用殺
虫マットを用いた加熱蒸散殺虫方法、すなわち、２０℃
における蒸気圧が４．０×１０−６ｍｍＨｇ以上のピレ
スロイド系殺虫成分を１枚あたり５０ｍｇ以上含浸させ
た繊維質製マットを、このマットの底面積の０．２〜
０．６倍の面積を有しかつ加熱温度が７０〜１７０℃の
放熱板上に載置して使用することにより、５日間以上連
続して殺虫効力を持続せしめる加熱蒸散殺虫方法に係る
ものである。この方法は、電気蚊取マットのクリーンな
長所を踏襲し、液体蚊取と異なって液漏れ等の心配がな
く、しかも長期間にわたり殺虫効力を持続せしめること
ができるので極めて実用性の高い加熱蒸散殺虫方法であ
る。According to a fourth aspect of the present invention, there is provided a method for killing insects by heating using the long-time insecticidal mat according to the first aspect of the present invention.
A fibrous mat impregnated with a pyrethroid-based insecticidal component having a vapor pressure of 4.0 × 10 −6 mmHg or more at a concentration of 50 mg or more per sheet was prepared using a mat having a base area of 0.2 to
The present invention relates to a method of heating and transpiring insecticidal insecticidal insecticide which has an area 0.6 times as large and has a heating temperature of 70 to 170 ° C. and is used on a heat radiating plate to maintain the insecticidal effect continuously for 5 days or more. is there. This method follows the clean advantages of electric mosquito collection mats, and unlike liquid mosquito collection, there is no need to worry about liquid leakage, etc., and the insecticidal effect can be maintained for a long period of time. Insect killing method.
【００１４】請求項５の発明は、請求項４の構成におい
て、特にピレスロイド系殺虫成分として、アレスリン、
フラメトリン、プラレトリン、及びテフラメトリンから
選ばれた１種または２種を用いた加熱蒸散殺虫方法であ
る。According to a fifth aspect of the present invention, there is provided the composition according to the fourth aspect, wherein in particular, as a pyrethroid insecticidal component,
This is a heat-transpiration and insecticidal method using one or two selected from flamethrin, praletrin, and teframethrin.
【００１５】請求項６の発明は、請求項４又は５の構成
において、ピレスロイド系殺虫成分としてフラメトリン
を選択し、マット１枚あたり１５０〜４００ｍｇを含有
させ、かつ揮散調整剤としてピペロニルブトキサイド５
０〜３００ｍｇを配合すると共に、放熱板の面積をマッ
トの底面積の０．５倍としたものである。According to the invention of claim 6, in the constitution of claim 4 or 5, framethrin is selected as a pyrethroid insecticidal component, 150-400 mg is contained per mat, and piperonyl butoxide is used as a volatilization regulator. 5
0 to 300 mg was added, and the area of the heat radiating plate was 0.5 times the bottom area of the mat.
【００１６】[0016]
【発明の実施の形態】請求項１の構成によると、繊維質
製マットに含浸される殺虫成分の物理化学的性質、なら
びにマットの面積と放熱板の面積との関係を組み合わせ
ることによって、５日間以上にわたり連続して殺虫効力
を持続できうる長時間用殺虫マットが提供される。繊維
質製マットの材質としては、パルプ、リンター、あるい
はその混成品等、従来蚊取マットと同質のものを使用で
きる。大きさ、形状についても任意であるが従来規格の
ものが使いやすい。このマットには、２０℃における蒸
気圧が４．０×１０−６ｍｍＨｇ以上のピレスロイド系
殺虫成分が１枚あたり５０ｍｇ以上含浸されるが、製造
工程、用途や目的を考慮の上、殺虫成分に適合した安定
剤や揮散調整剤、あるいは溶剤、香料、色素等を適宜添
加してマット原液を調整するのが適当である。According to the first aspect of the present invention, the physicochemical properties of the insecticidal component impregnated in the fibrous mat and the relationship between the area of the mat and the area of the heat sink are combined for 5 days. A long-term insecticidal mat capable of continuously maintaining the insecticidal effect over the above is provided. As the material of the fibrous mat, the same material as that of the conventional mosquito collecting mat, such as pulp, linter, or a hybrid product thereof, can be used. The size and shape are arbitrary, but those of conventional standards are easy to use. This mat is impregnated with 50 mg or more of a pyrethroid-based insecticidal component having a vapor pressure of 4.0 × 10 −6 mmHg or more at 20 ° C. per sheet. It is appropriate to add a suitable stabilizer or volatilization modifier, or a solvent, a fragrance, a dye, or the like as appropriate to adjust the stock solution of the mat.
【００１７】また、前記マットの底面積の０．２〜０．
６倍の面積を有しかつ加熱温度が７０〜１７０℃の放熱
板の加熱蒸散装置における位置関係、形状等についても
任意に決定できる。例えば、中央部に直径１４〜１８ｍ
ｍ程度の円形もしくは幅８〜１８ｍｍ程度の帯状放熱板
を設け、その周囲にマットの周辺部を支える支柱を配し
てもよいし、この支柱の代わりに適当な載置板を、前記
放熱板との間に間隙が存するように組み合わせても構わ
ない。Further, the bottom area of the mat is 0.2 to 0.1.
The positional relationship, shape, and the like of the radiator plate having a six-fold area and a heating temperature of 70 to 170 ° C. in the heating and evaporating apparatus can be arbitrarily determined. For example, a diameter of 14 to 18 m in the center
m or a band-shaped heat radiating plate having a width of about 8 to 18 mm may be provided, and a support for supporting the periphery of the mat may be provided around the heat radiating plate. Alternatively, a suitable mounting plate may be provided in place of the support. May be combined so that a gap exists between them.
【００１８】請求項２の構成によると、ピレスロイド系
殺虫成分として、特にアレスリン、フラメトリン、プラ
レトリン、及びテフラメトリンから選ばれた１種または
２種を用いたのでより性能のすぐれた長時間用殺虫マッ
トが提供される。According to the second aspect of the present invention, since a pyrethroid insecticidal component is used, in particular, one or two selected from allethrin, framethrin, praletrin and teframethrin, a long-term insecticidal mat having better performance can be obtained. Provided.
【００１９】請求項３の構成によると、ピレスロイド系
殺虫成分として性能的に最適なフラメトリンとその配合
量ならびに揮散調整剤を選択し、しかも放熱板面積のマ
ットの面積に対する効率的な比率を特定したので一層性
熊のすぐれた長時間用殺虫マットが提供される。According to the third aspect of the present invention, the most suitable performance of the pyrethroid-based insecticidal component is selected for the flamethrin and its compounding amount and the volatilization modifier, and the ratio of the area of the heat radiation plate to the area of the mat is specified efficiently. Therefore, a long-term insecticidal mat having more excellent sex bears is provided.
【００２０】請求項４の構成によると、請求項１の長時
間用殺虫マットを用いることにより、電気蚊取マットの
クリーンな長所を踏襲し、液体蚊取と異なって液漏れ等
の心配がなく、しかも長期間にわたり殺虫効力を持続せ
しめることができる極めて実用的な加熱蒸散殺虫方法が
提供される。According to the configuration of claim 4, the long-time insecticidal mat of claim 1 is used to follow the clean advantage of the electric mosquito collecting mat, and unlike the liquid mosquito collecting, there is no fear of liquid leakage or the like. In addition, an extremely practical method of heat evaporation and insecticidal insecticidal method capable of maintaining the insecticidal effect for a long period of time is provided.
【００２１】請求項５の構成によると、ピレスロイド系
殺虫成分として、特にアレスリン、フラメトリン、プラ
レトリン、及びテフラメトリンから選ばれた１種または
２種を用いたのでより有用な加熱蒸散殺虫方法が提供さ
れる。According to the constitution of claim 5, since the pyrethroid insecticidal component is used in particular, one or two selected from allethrin, framethrin, praletrin, and teframethrin, a more useful heat transpiration insecticidal method is provided. .
【００２２】請求項６の構成によると、ピレスロイド系
殺虫成分として性能的に最適なフラメトリンとその配合
量ならびに揮散調整剤を選択し、しかも放熱板面積のマ
ットの面積に対する効率的な比率を特定したので一層有
用な加熱蒸散殺虫方法が提供される。According to the structure of the sixth aspect, the most suitable flamethrin and its compounding amount and the volatilization modifier are selected as the pyrethroid-based insecticidal components in terms of performance, and the efficient ratio of the area of the heat radiating plate to the area of the mat is specified. Thus, a more useful method of heat-transpiration insecticidal treatment is provided.
【００２３】[0023]
【実施例】次に、本発明を実施例及び試験例を用いて更
に詳細に説明する。Next, the present invention will be described in more detail with reference to Examples and Test Examples.
【００２４】実施例１．大きさが２２×３５ｍｍで厚み
が２．８ｍｍの繊維質製マットに、ｄ−トランス−アレ
スリン（商品名：エスバイオスリン）を３００ｍｇ、揮
散調整剤としてのピペロニルブトキサイドを２００ｍ
ｇ、安定剤１０ｍｇ、微量の香料及び青色染料を配合し
たマット原液を含浸させた。直径１６ｍｍで発熱温度が
１５０℃の円形放熱板を中央部に有し、その周囲４ケ所
にマットを支える支柱を配した加熱蒸散装置に、前記マ
ットを載置して使用したところ、１日・１２時間あたり
のｄ−トランス−アレスリンの蒸散量は約３０ｍｇであ
った。このマットは１０日間にわたり安定した蒸散性能
と殺虫効力を奏し、しかも液洩れ等の心配がなく使用性
にも優れたものであった。Embodiment 1 FIG. On a fibrous mat having a size of 22 × 35 mm and a thickness of 2.8 mm, 300 mg of d-trans-aresulin (trade name: Esbiothrine) and 200 m of piperonyl butoxide as a volatilization modifier were used.
g, 10 mg of a stabilizer, a trace amount of a perfume and a matting stock solution containing a blue dye were impregnated. When the mat was placed and used in a heating and evaporating apparatus having a circular heat radiating plate having a diameter of 16 mm and a heat generation temperature of 150 ° C. in the center and supporting the mat in four places around the heat radiating plate, The amount of d-trans-aresulin evaporated per 12 hours was about 30 mg. This mat exhibited stable transpiration performance and insecticidal efficacy over 10 days, and was excellent in usability without fear of liquid leakage.
【００２５】実施例２．大きさが２２×３５ｍｍで厚み
が２．８ｍｍの繊維質製マットに、ｄ−シス、トランス
−フラメトリン（商品名：ピナミンＤ−ｆ）を２５０ｍ
ｇ、揮散調整剤としてのピペロニルブトキサイドを１５
０ｍｇ、安定剤２０ｍｇと微量の青色染料を含む灯油溶
液を含浸させた。加熱蒸散装置としては、マット底面積
の０．５倍の面積を有し帯状の放熱板を中央部に配設し
たものを用い、夜間１２時間通電し昼間休止するサイク
ルを１０日間継続した。その結果、ｄ−シス、トランス
−フラメトリンの蒸散量は毎日約２０ｍｇずつで経時的
にも安定しており、１０日間にわたり十分な蚊防除効果
を示した。Embodiment 2 FIG. On a fibrous mat having a size of 22 × 35 mm and a thickness of 2.8 mm, d-cis and trans-flametrin (trade name: Pinamine Df) are 250 m.
g, 15 parts of piperonyl butoxide as a volatilization regulator
A kerosene solution containing 0 mg, 20 mg of stabilizer and a trace amount of blue dye was impregnated. As the heating and evaporating device, a device having a band-shaped heat radiating plate arranged at the center having an area 0.5 times the mat bottom area was used, and a cycle in which electricity was supplied for 12 hours at night and stopped during the day was continued for 10 days. As a result, the amount of transpiration of d-cis and trans-framethrin was about 20 mg every day, which was stable over time, showing a sufficient mosquito control effect for 10 days.
【００２６】試験例１．実施例１及び実施例２に準じて
表１に示す殺虫マットを調製し、種々の加熱蒸散装置に
装填して各種性能試験を行った。 （１）蒸散性能：蒸散した殺虫成分を所定時間毎にシリ
カゲル充填カラムでトラップし、アセトンで殺虫成分を
抽出後、ガズクロマトグラフで分析し、殺虫成分の時間
あたりの蒸散量を求めた。表１に示す値は、それぞれの
製剤の初期の値を１．００とした場合の相対比で示し
た。 （２）殺虫効力：所定時間毎に下記の連続通気法により
アカイエカに対する仰転効果を評価した。表１に示す値
は、ｄ１，ｄ−シス、トランス−アレスリン４０ｍｇを
含有する１日用マットの初期の値を１．００とした場合
の相対有効比で示した。Test Example 1 Insecticidal mats shown in Table 1 were prepared according to Examples 1 and 2, and loaded into various heat evaporation devices to perform various performance tests. (1) Transpiration performance: The transpired insecticidal components were trapped by a silica gel packed column at predetermined time intervals, and the insecticidal components were extracted with acetone and analyzed by gaz chromatography to determine the amount of transpiring per hour of the insecticidal components. The values shown in Table 1 are shown as relative ratios when the initial value of each preparation is 1.00. (2) Insecticidal efficacy: The erecting effect on Culex pipiens was evaluated by the following continuous aeration method at predetermined time intervals. The values shown in Table 1 are shown as relative effective ratios when the initial value of a daily mat containing 40 mg of d1, d-cis and trans-arrestrin is 1.00.
【００２７】（連続通気法）内径２０ｃｍ、高さ４３ｃ
ｍのプラスチック製円筒を２段に重ね、その上に１６メ
ッシュの金網で上下に仕切った内径及び高さが共に２０
ｃｍの円筒（供試蚊を入れる場所）を載せ、さらに内径
２０ｃｍ、高さ２０ｃｍ円筒を載せる。この４段重ねの
円筒を台に載せ、台の中央に加熱蒸散装置を置いて供試
マット中の殺虫成分を蒸散させる。そして、上部円筒に
供試蚊約２０匹を放ち、時間の経過に伴う該蚊の仰転数
を観察する。暴露２０分後に全供試蚊を清潔なポリエチ
レン容器に移し、３％砂糖水を与え、保存２４時間後に
死虫率を調べる。(Continuous ventilation method) Inner diameter 20 cm, height 43 c
m plastic cylinders are piled up in two stages, and the inside diameter and height of both are vertically separated by a 16 mesh wire mesh.
cm cylinder (a place where a test mosquito is to be placed), and a cylinder having an inner diameter of 20 cm and a height of 20 cm. The four-tiered cylinder is placed on a table, and a heat evaporation device is placed in the center of the table to evaporate the insecticidal components in the test mat. Then, about 20 test mosquitoes are released into the upper cylinder, and the number of elevations of the mosquitoes over time is observed. Twenty minutes after exposure, all test mosquitoes are transferred to a clean polyethylene container, given 3% sugar water, and examined for mortality 24 hours after storage.
【００２８】[0028]
【表１】 [Table 1]
【００２９】試験の結果、特定のマットと、特定の放熱
板を有する加熱蒸散装置を組み合わせた本発明は、５日
間以上にわたり優れた蒸散性能と殺虫効力を示し、便利
なうえ極めて実用的であった。これに対し、２０℃にお
ける蒸気圧が４．０×１０−６ｍｍＨｇより小さいピレ
スロイド系殺虫成分を用いた場合（対照例１）、蒸気圧
が４．０×１０−６ｍＨｇ以上であっても１枚あたりの
殺虫成分量が５０ｍｇに満たない場合（対照例２）、放
熱板の条件に適合しない場合（対照例３〜４）や特開平
５−１９４１０３号開示の薬剤含有体を用いた場合（対
照例５）のいずれも満足のいく性能が得られなかった。As a result of the test, the present invention combining a specific mat and a heat evaporation device having a specific heat radiating plate shows excellent transpiration performance and insecticidal efficacy over 5 days or more, and is convenient and extremely practical. Was. In contrast, when a pyrethroid insecticidal component having a vapor pressure at 20 ° C. of less than 4.0 × 10 −6 mmHg is used (Control Example 1), even if the vapor pressure is 4.0 × 10 −6 mHg or more. When the amount of the insecticidal component per sheet is less than 50 mg (Comparative Example 2), when it does not conform to the condition of the heat sink (Comparative Examples 3 to 4), or when the drug-containing substance disclosed in JP-A-5-194103 is used No satisfactory performance was obtained in any of (Control Example 5).
【００３０】[0030]
【発明の効果】請求項１ないし３のいずれかの発明によ
ると、液洩れ等の心配がなくクリーンな製剤で、５日間
以上の長期間にわたり安定した殺虫効力を持続しえる長
時間用殺虫マットが提供される。According to any one of the first to third aspects of the present invention, a long-term insecticidal mat that can maintain a stable insecticidal effect for a long period of 5 days or more with a clean preparation without fear of liquid leakage or the like. Is provided.
【００３１】請求項４ないし６のいずれかの発明による
と、請求項１ないし３の長時間用殺虫マットと特定の放
熱板を有する加熱蒸散装置を組み合わせることによっ
て、電気蚊取マット方式でしかも長期間有効な極めて実
用的な加熱蒸散殺虫方法が提供される。According to any one of the fourth to sixth aspects of the present invention, by combining the long-time insecticidal mat of the first to third aspects with a heating and evaporating apparatus having a specific heat radiating plate, an electric mosquito collecting mat type and a long-lasting type. A very practical heat transpiration insecticidal method is provided which is effective for a period of time.
Claims (6)
−６ｍｍＨｇ以上のピレスロイド系殺虫成分を１枚あた
り５０ｍｇ以上含浸させた繊維質製マットであって、こ
のマットの底面積の０．２〜０．６倍の面積を有しかつ
加熱温度が７０〜１７０℃の放熱板上に載置して使用さ
れ、５日間以上連続して殺虫効力を持続しえることを特
徴とする長時間用殺虫マット。1. The vapor pressure at 20 ° C. is 4.0 × 10
A fibrous mat impregnated with a pyrethroid-based insecticidal component of -6 mmHg or more in an amount of 50 mg or more per sheet, having an area 0.2 to 0.6 times the bottom area of the mat and a heating temperature of 70 mm. A long-time insecticidal mat which is used by being placed on a heat radiating plate at a temperature of up to 170 ° C. and which can maintain insecticidal efficacy continuously for 5 days or more.
ン、フラメトリン、プラレトリン、及びテフラメトリン
から選ばれた１種または２種であることを特徴とする請
求項１に記載の長時間用殺虫マット。2. The long-term insecticidal mat according to claim 1, wherein the pyrethroid insecticidal component is at least one member selected from allethrin, framethrin, praletrin, and teframethrin.
分としてフラメトリン１５０〜４００ｍｇと、揮散調整
剤としてピペロニルブトキサイド５０〜３００ｍｇを含
有し、放熱板の面積がマットの底面積の０．５倍である
ことを特徴とする請求項１又は２に記載の長時間用殺虫
マット。3. A mat containing 150 to 400 mg of pyrethroid insecticide as a pyrethroid insecticidal component and 50 to 300 mg of piperonyl butoxide as a volatilization regulator, wherein the area of the heat radiating plate is 0.5 times the bottom area of the mat. The long-term insecticidal mat according to claim 1 or 2, wherein:
−６ｍｍＨｇ以上のピレスロイド系殺虫成分を１枚あた
り５０ｍｇ以上含浸させた繊維質製マットを、このマッ
トの底面積の０．２〜０．６倍の面積を有しかつ加熱温
度が７０〜１７０℃の放熱板上に載置して使用すること
により、５日間以上連続して殺虫効力を持続せしめるこ
とを特徴とする加熱蒸散殺虫方法。4. The vapor pressure at 20 ° C. is 4.0 × 10
A fibrous mat impregnated with a pyrethroid-based insecticidal component of -6 mmHg or more in an amount of 50 mg or more per sheet has an area 0.2 to 0.6 times the bottom area of the mat and a heating temperature of 70 to 170. A method for killing insects by heating, wherein the insecticidal effect is maintained continuously for 5 days or more by being placed on a heat radiating plate at ℃.
ン、フラメトリン、プラレトリン、及びテフラメトリン
から選ばれた１種または２種であることを特徴とする請
求項４に記載の加熱蒸散殺虫方法。5. The method according to claim 4, wherein the pyrethroid insecticidal component is one or two selected from allethrin, framethrin, praletrin, and teframethrin.
分としてフラメトリン１５０〜４００ｍｇと、揮散調整
剤としてピペロニルブトキサイド５０〜３００ｍｇを含
有し、放熱板の面積がマットの底面積の０．５倍である
ことを特徴とする請求項４又は５に記載の長時間用殺虫
マット。6. A mat contains 150 to 400 mg of pyrethroid insecticide as a pyrethroid insecticidal component and 50 to 300 mg of piperonyl butoxide as a volatilization regulator, and the area of the heat radiating plate is 0.5 times the bottom area of the mat. The long-time insecticidal mat according to claim 4 or 5, wherein
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28105497A JP3286833B2 (en) | 1996-11-12 | 1997-09-04 | Insecticidal mat for long-term use and method of heat transpiration using the same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33743396 | 1996-11-12 | ||
| JP8-337433 | 1996-11-12 | ||
| JP28105497A JP3286833B2 (en) | 1996-11-12 | 1997-09-04 | Insecticidal mat for long-term use and method of heat transpiration using the same |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24259098A Division JP3383869B2 (en) | 1996-11-12 | 1998-08-13 | Insecticidal mat for long-term use and method of heat transpiration and insecticidal using the mat |
| JP2001221887A Division JP3820515B2 (en) | 1996-11-12 | 2001-07-23 | Long-term insecticidal mat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10194904A true JPH10194904A (en) | 1998-07-28 |
| JP3286833B2 JP3286833B2 (en) | 2002-05-27 |
Family
ID=26554035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28105497A Expired - Fee Related JP3286833B2 (en) | 1996-11-12 | 1997-09-04 | Insecticidal mat for long-term use and method of heat transpiration using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3286833B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001078508A1 (en) * | 2000-04-13 | 2001-10-25 | Fumakilla Limited | Method for controlling insect pests by vaporization of pesticides |
| JP2002053406A (en) * | 2000-05-31 | 2002-02-19 | Dainippon Jochugiku Co Ltd | Insecticidal mat and thermal dissipation insecticidal method using the mat |
| JP2012090539A (en) * | 2010-10-25 | 2012-05-17 | Dainippon Jochugiku Co Ltd | Device for controlling noxious insect |
-
1997
- 1997-09-04 JP JP28105497A patent/JP3286833B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001078508A1 (en) * | 2000-04-13 | 2001-10-25 | Fumakilla Limited | Method for controlling insect pests by vaporization of pesticides |
| JP2002053406A (en) * | 2000-05-31 | 2002-02-19 | Dainippon Jochugiku Co Ltd | Insecticidal mat and thermal dissipation insecticidal method using the mat |
| US6709666B2 (en) | 2000-05-31 | 2004-03-23 | Dainihon Jochugiku Co., Ltd. | Insecticidal mat and heat-transpiration insecticidal method using the same |
| JP2012090539A (en) * | 2010-10-25 | 2012-05-17 | Dainippon Jochugiku Co Ltd | Device for controlling noxious insect |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3286833B2 (en) | 2002-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6551560B1 (en) | Two-stage dispensing mat | |
| US6031967A (en) | Device for dispensing volatile materials | |
| CZ20012995A3 (en) | Device for proportioning evaporating substances | |
| KR100463455B1 (en) | Long-term insecticide mat and heating evaporation method using the same | |
| US6447795B2 (en) | Gel formulations containing insecticide | |
| TWI829942B (en) | Insecticidal efficacy enhancer, insect pest control method, and aqueous insecticidal composition for thermal vaporization/diffusion | |
| JPH10194904A (en) | Insecticidal mat for long time and thermal vaporization insecticidal method using the same | |
| JP2001316212A (en) | Method for thermal transpiring to kill insect | |
| JP2533332B2 (en) | Insecticide mat for heating evaporation | |
| US5468497A (en) | Fuming, hot-vaporizing insecticide for killing flies, and method for killing flies with the same | |
| KR101942886B1 (en) | Water-based insecticidal composition to be vaporized and diffused by being heated, and method for vaporizing and diffusing said composition by heating | |
| JP3383869B2 (en) | Insecticidal mat for long-term use and method of heat transpiration and insecticidal using the mat | |
| JPH09285247A (en) | Thermal transpiration device and thermal transpiration of chemical agent with the device | |
| JP3820515B2 (en) | Long-term insecticidal mat | |
| JP4445459B2 (en) | Chemical transpiration device | |
| JP2005095107A (en) | Heat-transpiring device | |
| JPH10203904A (en) | Gel composition for heat-fumigation and heat-fumigating insecticidal method of using the same | |
| JPH0826908A (en) | Smoking and heat-transpiring insecticide for killing fly and method for killing fly using the same | |
| KR100763862B1 (en) | Method for controlling insect pests by vaporization of pesticides | |
| JPH1072302A (en) | Volatility sustaining agent for insecticidal mat and insecticidal mat for long hour containing insecticidal component and the same volatility sustaining agent | |
| JP2003081707A (en) | Insecticidal mat for long time and method for thermal volatilizing insecticidal method using the same | |
| JP3704647B2 (en) | Roasting and heating transpiration insecticide for slaughter, and slaughter method using the same | |
| JP2003081708A (en) | Insecticidal mat for long time and method for thermal volatilizing insecticidal method using the same | |
| JP2003012408A (en) | Long-lasting insecticidal mat and method for killing insect using the same by heat-volatilization | |
| JPH11302103A (en) | Thermal fumigation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080315 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090315 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090315 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100315 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110315 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110315 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120315 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120315 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130315 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130315 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140315 Year of fee payment: 12 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |