JPH0987685A - Detergent composition for sports shoes - Google Patents
Detergent composition for sports shoesInfo
- Publication number
- JPH0987685A JPH0987685A JP7279551A JP27955195A JPH0987685A JP H0987685 A JPH0987685 A JP H0987685A JP 7279551 A JP7279551 A JP 7279551A JP 27955195 A JP27955195 A JP 27955195A JP H0987685 A JPH0987685 A JP H0987685A
- Authority
- JP
- Japan
- Prior art keywords
- sports shoes
- hydrogen peroxide
- weight
- bleaching
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、刺激臭がなく、しかも
運動靴に付着した汚れを効果的に漂白洗浄できる過酸化
物系運動靴用洗浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a peroxide-based detergent composition for sports shoes which has no irritating odor and is capable of effectively bleaching and cleaning stains adhering to sports shoes.
【０００２】[0002]
【従来の技術】運動靴は、その使用頻度が多くなると、
汚れが付着したり、運動靴内に付着した汗や皮脂汚れ等
にバクテリアが繁殖し、不快な臭いが発生したりする。
従来は、これら運動靴の洗浄には、市販の衣料用洗濯洗
剤や運動靴専用洗剤が使用されている。しかし、一般に
漂白効果が充分でなく、漂白効果を高めるために塩素系
漂白剤を併用することも試みられている。塩素系漂白剤
の併用により、特有の臭気が発生して使用者に不快感を
与える問題があった。2. Description of the Related Art Sports shoes are often used when they are used frequently.
Contamination is attached, or bacteria are propagated on sweat or sebum stains attached to the inside of the athletic shoes, and an unpleasant odor is generated.
Conventionally, commercially available laundry detergents and detergents for sports shoes have been used for cleaning these sports shoes. However, generally, the bleaching effect is not sufficient, and it has been attempted to use a chlorine bleach together in order to enhance the bleaching effect. There is a problem that a peculiar odor is generated and a user feels uncomfortable when the chlorine-based bleaching agent is used together.
【０００３】[0003]
【発明が解決しようとする課題】本発明の目的は、刺激
臭が無く、しかも運動靴の汚れに対する漂白洗浄力及び
除菌効果に優れた運動靴用洗浄剤組成物を提供すること
にある。SUMMARY OF THE INVENTION An object of the present invention is to provide a cleaning composition for sports shoes, which has no irritating odor and is excellent in bleaching cleaning power and disinfecting effect against dirt of sports shoes.
【０００４】[0004]
【課題を解決するための手段】本発明者らは上記課題に
ついて鋭意研究の結果、シアン酸塩と過酸化水素あるい
は水溶液中で過酸化水素を生成する過酸化物を必須成分
とし、さらに必要により酵素及び／又は界面活性剤を含
有した組成物が特定のｐＨ領域において運動靴の汚れに
対し飛躍的に高い漂白洗浄力を示し、しかも刺激臭を有
しないことを見出し本発明を完成させたものである。即
ち、本発明は（Ａ）過酸化水素あるいは水溶液中で過酸
化水素を生成する過酸化物を生成過酸化水素換算で０．
１％〜６０重量％、（Ｂ）シアン酸のアルカリ金属塩又
はシアン酸のアンモニウム塩を０．１％〜３０重量％含
有し、その水溶液のｐＨが７〜１３であることを特徴と
する運動靴用洗浄剤組成物である。尚、本発明者の一人
は先に特願平７−７７０７４号において、過酸化水素と
シアン酸塩との組成物のｐＨが７〜１３であるときに、
カビの除去効果が優れていることを認めたが、該組成物
が本願の課題である用途に使用できるという記載は皆無
である。As a result of intensive studies on the above problems, the present inventors have found that cyanate and hydrogen peroxide or a peroxide that produces hydrogen peroxide in an aqueous solution are essential components, and if necessary, The present invention has been completed by discovering that a composition containing an enzyme and / or a surfactant exhibits a dramatically high bleaching and detergency against dirt on sports shoes in a specific pH range and has no irritating odor. Is. That is, according to the present invention, (A) hydrogen peroxide or a peroxide that produces hydrogen peroxide in an aqueous solution is converted into hydrogen peroxide in terms of hydrogen peroxide.
1% to 60% by weight, (B) 0.1% to 30% by weight of an alkali metal salt of cyanic acid or an ammonium salt of cyanic acid, and the pH of the aqueous solution is 7 to 13. A cleaning composition for shoes. Incidentally, one of the inventors of the present invention has previously described in Japanese Patent Application No. 7-77074, when the pH of the composition of hydrogen peroxide and cyanate is 7 to 13,
Although it was confirmed that the mold removal effect is excellent, there is no description that the composition can be used for the purpose of the present application.
【０００５】[0005]
（Ａ）過酸化水素あるいは水溶液中で過酸化水素を生成
する過酸化物としては、市販されている過酸化水素水溶
液あるいは炭酸ソーダ過酸化水素付加物、過ほう酸ソー
ダ水和物、過ほう酸ソーダ四水和物が例示される。酸化
水素は、０．１〜９０重量％の一般公知のもの全てが使
用できるが、一般的には０．５〜３５重量％までの範囲
のものが好ましい。本発明の運動靴用洗浄剤組成物中の
（Ａ）成分の配合量は、生成する過酸化水素換算で０．
１〜６０重量％であり、好ましくは０．１〜３０重量
％、さらに好ましくは０．１〜１０重量％である。実用
上は０．１〜６重量％が最も好ましい。含有量がこの範
囲より少ないと漂白洗浄力が低く、この範囲より多いと
洗浄効果に大きな差が無く、また取り扱いが難しくな
る。(A) As hydrogen peroxide or a peroxide that produces hydrogen peroxide in an aqueous solution, commercially available hydrogen peroxide aqueous solution or sodium carbonate hydrogen peroxide adduct, sodium perborate hydrate, sodium perborate tetrahydrate A hydrate is illustrated. As the hydrogen oxide, all the known ones of 0.1 to 90% by weight can be used, but those of 0.5 to 35% by weight are generally preferable. The blending amount of the component (A) in the detergent composition for sports shoes of the present invention is 0.
It is 1 to 60% by weight, preferably 0.1 to 30% by weight, and more preferably 0.1 to 10% by weight. Practically, 0.1 to 6% by weight is most preferable. When the content is less than this range, the bleaching detergency is low, and when it is more than this range, there is no great difference in the cleaning effect and the handling becomes difficult.
【０００６】（Ｂ）シアン酸塩としてはシアン酸のアル
カリ金属塩、シアン酸のアンモニウム塩であり、シアン
酸カリウム、シアン酸ナトリウム、シアン酸アンモニウ
ムが例示でき、その１種又は２種以上を使用する。
（Ｂ）成分の配合量は、０．１〜３０重量％であり、好
ましくは０．１〜１０重量％、さらに好ましくは０．５
〜５重量％である。含有量がこの範囲より少ないと活性
化効果がなく、この範囲より多い使用は、それ以上の効
果を高める事が期待できない。シアン酸塩は市販の固体
又は水溶液が使用できる。The cyanate (B) is an alkali metal salt of cyanic acid or an ammonium salt of cyanic acid, and examples thereof include potassium cyanate, sodium cyanate and ammonium cyanate, and one or more of them are used. To do.
The blending amount of the component (B) is 0.1 to 30% by weight, preferably 0.1 to 10% by weight, more preferably 0.5.
~ 5% by weight. If the content is less than this range, there is no activating effect, and if the content is more than this range, it cannot be expected to enhance the effect any further. As the cyanate, a commercially available solid or aqueous solution can be used.
【０００７】洗浄剤組成物のｐＨを調整することは高い
洗浄力を得るために必須の条件である。洗浄剤組成物の
水溶液又は洗浄剤組成物を溶解した水溶液のｐＨは通常
７〜１３であり、好ましくは８〜１３である。さらに好
ましくは、９〜１３である。ｐＨがこの範囲より低いと
漂白洗浄作用が弱く、この範囲より高いと過酸化物が不
安定になるなど、運動靴用洗浄剤組成物として取り扱い
が難しくなる。尚ｐＨについては、洗浄剤組成物を水溶
液状態で使用する場合は原液を、洗浄剤組成物が粉体の
場合は、洗浄剤組成物を１％水溶液にし、そのｐＨを測
定する。ｐＨを調整するためにアルカリ剤を加えても良
く、アルカリ剤としては、アルカリ金属水酸化物、アル
カリ土類金属水酸化物、アルカリ金属珪酸塩等が例示で
きる。中でも、珪酸カリウム等のアルカリ金属の珪酸塩
を使用すると、漂白洗浄力が著しく向上することから好
ましい。Adjusting the pH of the detergent composition is an essential condition for obtaining high detergency. The pH of the aqueous solution of the cleaning composition or the aqueous solution in which the cleaning composition is dissolved is usually 7 to 13, preferably 8 to 13. More preferably, it is 9 to 13. If the pH is lower than this range, the bleaching and cleaning action is weak, and if it is higher than this range, the peroxide becomes unstable, and it becomes difficult to handle as a detergent composition for sports shoes. Regarding the pH, when the cleaning composition is used in the form of an aqueous solution, the stock solution is used, and when the cleaning composition is a powder, the cleaning composition is made into a 1% aqueous solution, and the pH is measured. An alkali agent may be added to adjust the pH, and examples of the alkali agent include alkali metal hydroxides, alkaline earth metal hydroxides and alkali metal silicates. Of these, it is preferable to use an alkali metal silicate such as potassium silicate because the bleaching detergency is significantly improved.
【０００８】本発明の運動靴用洗浄剤組成物の洗浄力を
さらに向上させるため、必要により酵素及び／又は界面
活性剤を使用することができる。酵素は、運動靴に付着
した有機質の汚れを効果的に分解することにより、さら
に本発明の洗浄剤の漂白洗浄力を向上することができ
る。酵素としては、プロテアーゼ等のタンパク質分解酵
素、リパーゼ等の脂質分解酵素、セルラーゼ等の繊維素
分解酵素等が例示できる。酵素の添加量は、運動靴用洗
浄剤組成物１００重量部０．０５〜５重量部となる量が
好ましい。In order to further improve the detergency of the detergent composition for sports shoes of the present invention, an enzyme and / or a surfactant can be used if necessary. Enzymes can further improve the bleaching detergency of the cleaning agent of the present invention by effectively decomposing organic stains attached to sports shoes. Examples of the enzyme include proteolytic enzymes such as protease, lipolytic enzymes such as lipase, and fibrinolytic enzymes such as cellulase. The amount of the enzyme added is preferably such that 100 parts by weight of the detergent composition for sports shoes is 0.05 to 5 parts by weight.
【０００９】界面活性剤は、洗浄剤組成物の付着物汚れ
への浸透を助け、また運動靴への汚れの再汚染を防止
し、付着物汚れの漂白洗浄・除去効果を高めることがで
きる。界面活性剤としては、ポリオキシエチレンアルキ
ルエーテル、ポリオキシエチレン脂肪酸エステル、アミ
ンオキサイド等の非イオン界面活性剤、石鹸、アルキル
硫酸塩、アルキルベンゼンスルホン酸塩等の陰イオン界
面活性剤が例示される。界面活性剤の添加量は、運動靴
用洗浄剤組成物１００重量部に０．１〜３０重量部であ
り、好ましくは０．５〜１０重量部である。本発明の運
動靴用洗浄剤組成物には、任意の成分として溶剤、殺菌
剤、香料、着色剤、金属イオン封鎖剤等を適宜添加する
ことができる。尚、ここで言う運動靴とは、水洗いので
きる綿・ナイロン・合成皮革等の運動靴、スニーカー、
上ばき等を意味する。The surfactant can help the detergent composition to permeate the stains on the deposits, prevent the stains from re-contaminating the sports shoes, and enhance the bleaching / cleaning effect of the stains on the deposits. Examples of the surfactant include nonionic surfactants such as polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters and amine oxides, and anionic surfactants such as soaps, alkyl sulfates and alkylbenzene sulfonates. The amount of the surfactant added is 0.1 to 30 parts by weight, preferably 0.5 to 10 parts by weight, based on 100 parts by weight of the detergent composition for sports shoes. A solvent, a bactericide, a fragrance, a colorant, a sequestering agent, and the like can be appropriately added to the cleaning composition for sports shoes of the present invention as optional components. In addition, the sports shoes mentioned here are sports shoes such as cotton, nylon and synthetic leather that can be washed with water, sneakers,
It means upper exposure.
【００１０】本発明の運動靴用洗浄剤組成物の使用方法
としては、洗浄剤組成物を直接運動靴にまんべんなくふ
りかける。あるいは、バケツ等に水又は湯にて洗浄剤組
成物を溶解させた中に、運動靴を浸け置き洗浄する使用
方法である。As a method of using the detergent composition for sports shoes of the present invention, the detergent composition is directly sprinkled evenly on the sports shoes. Alternatively, it is a method of use in which sports shoes are soaked and washed in a detergent composition dissolved in a bucket or the like with water or hot water.
【００１１】[0011]
【実施例】以下、本発明を実施例および比較例を挙げて
更に詳細に説明するが、本発明はこれらに限定されるも
のではない。EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto.
【００１２】実施例１〜２ 過酸化水素濃度が３．０重量％、シアン酸カリウム濃度
が５．０重量％となるように過酸化水素水溶液及びシア
ン酸カリウムを水に混合溶解して運動靴用洗浄剤組成物
を調製した。尚、実施例１の組成物は、ｐＨをアルカリ
剤にて９．２に調製した。また実施例２の組成物は、ｐ
Ｈをアルカリ剤にて１１．０に調製した。次に、得られ
た運動靴用洗浄剤組成物を使用して、運動靴内に付着し
た汚れの洗浄試験を以下のようにして行った。また、洗
浄剤組成物及び洗浄試験後の運動靴の臭気判定を以下の
ようにして行った。 ［Ｉ］＜付着汚れの洗浄試験方法とその評価方法＞ １）付着汚れの洗浄試験方法 長期間洗浄していない運動靴を、本発明の運動靴用洗浄
剤組成物の入った容器に３０分間浸け置きし、水で洗い
流した後の汚れの漂白洗浄力の程度をみた。 ２）評価方法 漂白洗浄の程度を目視により以下の４段階に判定した。 漂白洗浄度 ： ◎ ほぼ完全に漂白洗浄された。 ： ○ かなり良く漂白洗浄された。 ： △ ある程度漂白洗浄された。 ： Ｘ ほとんど又は全く漂白洗浄されなかった。 ［ＩＩ］＜洗浄剤組成物の臭気及び洗浄試験後の運動靴
の臭気の判定とその評価方法＞ １）臭気の判定方法 １０人のパネラーに洗浄剤組成物及び洗浄試験後の運動
靴の臭気を嗅いでもらい官能評価した。 ２）臭気の判定方法 臭気を以下のように評価する。 臭気評価 ： ○ ７人以上のパネラーが刺激臭も悪
臭も感じなかった。 ： △ ４〜６人以上のパネラーが刺激臭又は悪臭を感
じた。 ： Ｘ ７人以上のパネラーが刺激臭又は悪臭を感じ
た。 その結果を第１表に示す。Examples 1-2: Sports shoes by mixing and dissolving an aqueous hydrogen peroxide solution and potassium cyanate in water so that the hydrogen peroxide concentration is 3.0% by weight and the potassium cyanate concentration is 5.0% by weight. A cleaning composition was prepared. The composition of Example 1 was adjusted to pH 9.2 with an alkaline agent. Also, the composition of Example 2 has p
H was adjusted to 11.0 with an alkaline agent. Next, using the thus obtained detergent composition for sports shoes, a cleaning test for dirt adhering to the inside of the sports shoes was conducted as follows. Further, the odor of the cleaning composition and the sports shoes after the cleaning test was evaluated as follows. [I] <Method for cleaning adherent stains and evaluation method therefor> 1) Method for cleaning adherent stains A sports shoe which has not been cleaned for a long time is placed in a container containing the detergent composition for sports shoes of the present invention for 30 minutes. The degree of bleaching detergency of stains after immersing and rinsing with water was observed. 2) Evaluation method The degree of bleaching and washing was visually evaluated according to the following four levels. Degree of Bleaching: ◎ Almost completely bleached and washed. : ○ It was bleached and washed fairly well. : △ Bleached and washed to some extent. : X Little or no bleach wash. [II] <Odor of cleaning composition and odor of sports shoes after cleaning test and its evaluation method> 1) Odor determination method The cleaning composition and odor of sports shoes after cleaning test were evaluated by 10 panelists. It was smelled and sensory evaluated. 2) Odor determination method The odor is evaluated as follows. Odor evaluation: ○ Seven or more panelists did not feel any irritating odor or bad odor. : Δ 4 to 6 or more panelists felt an irritating odor or a bad odor. : X 7 or more panelists felt an irritating odor or a bad odor. The results are shown in Table 1.
【００１３】実施例３〜４ 第１表に示すように運動靴用洗浄剤組成物を調製した。
組成物の水溶液のｐＨはアルカリ剤にて調整した。次
に、得られた運動靴用洗浄剤を使用して、付着汚れの漂
白洗浄試験及び臭気判定を実施例１と同様に行った。結
果は第１表に示す。Examples 3 to 4 As shown in Table 1, a cleaning composition for sports shoes was prepared.
The pH of the aqueous solution of the composition was adjusted with an alkaline agent. Next, using the thus obtained detergent for sports shoes, a bleaching washing test for adhering stains and odor determination were conducted in the same manner as in Example 1. The results are shown in Table 1.
【００１４】比較例１ 次亜塩素酸ソーダを第１表に示すように使用して漂白洗
浄組成物を調整した。組成物のｐＨはアルカリ剤にて第
１表に示すように調整した。また得られた漂白洗浄組成
物を使用して行った付着汚れの漂白洗浄試験及び臭気判
定を実施例１と同様に行った。結果を第１表に示す。漂
白洗浄性は良かったが、塩素臭が強かった。Comparative Example 1 A bleaching cleaning composition was prepared using sodium hypochlorite as shown in Table 1. The pH of the composition was adjusted with an alkaline agent as shown in Table 1. In addition, the bleaching cleaning test and the odor determination of the adhered stain using the obtained bleaching cleaning composition were performed in the same manner as in Example 1. The results are shown in Table 1. Bleachability was good, but chlorine odor was strong.
【００１５】比較例２ シアン酸カリウムを使用しなかった他は、実施例２と同
様に漂白洗浄組成物を調製した。また得られた漂白洗浄
組成物を使用して行なった付着汚れの漂白洗浄試験及び
臭気判定を実施例１と同様に行なった。結果は第１表に
示す。漂白洗浄性能は認められなかった。Comparative Example 2 A bleaching cleaning composition was prepared in the same manner as in Example 2 except that potassium cyanate was not used. Further, a bleaching washing test for adhered stains and an odor judgment using the obtained bleaching washing composition were carried out in the same manner as in Example 1. The results are shown in Table 1. No bleach cleaning performance was observed.
【００１６】比較例３ シアン酸塩の代わりにテトラアセチルエチレンジアミン
を使用した他は実施例２と同様に漂白洗浄組成物を調製
した。また得られた漂白洗浄組成物を使用して行なった
付着汚れの漂白洗浄試験及び臭気判定をと同様に行なっ
た。結果は第１表に示す。漂白洗浄力がやや低下すると
ともに、有機酸の臭気が強かった。Comparative Example 3 A bleaching and cleaning composition was prepared in the same manner as in Example 2 except that tetraacetylethylenediamine was used instead of cyanate. Further, the bleaching cleaning test and the odor judgment of the adhered stain, which were carried out using the obtained bleaching cleaning composition, were carried out in the same manner. The results are shown in Table 1. The bleaching detergency was slightly reduced and the odor of organic acids was strong.
【００１７】[0017]
【表１】 [Table 1]
【００１８】実施例５〜７ 実施例１で調製された洗浄剤組成物１００重量部にドデ
シルベンゼンスルホン酸ナトリウム２重量部を加えて調
製した運動靴用洗浄剤組成物を実施例５とし、また実施
例１の洗浄剤組成物１００重量部にプロテアーゼ０．１
重量部、リパーゼ０．１重量部及びセルラーゼ０．１重
量部を加えて調製した運動靴用洗浄剤組成物を実施例６
とした。さらに実施例１の洗浄剤組成物１００重量部に
ドデシルベンゼンスルホン酸ナトリウム２重量部、プロ
テアーゼ０．１重量部、リパーゼ０．１重量部及びセル
ラーゼ０．１重量部を加えて調製した運動靴用洗浄剤組
成物を実施例７とした。それぞれの組成物のｐＨは、ア
ルカリ剤にて第２表に示すように調製した。次に、得ら
れた運動靴用洗浄剤組成物を使用して、運動靴に付着し
た汚れの漂白洗浄試験及び臭気判定を実施例１と同様に
行った。結果は第２表に示す。Examples 5 to 7 A cleaning composition for sports shoes prepared by adding 2 parts by weight of sodium dodecylbenzenesulfonate to 100 parts by weight of the cleaning composition prepared in Example 1 was used as Example 5, and To 100 parts by weight of the detergent composition of Example 1, 0.1 parts of protease was added.
Example 6 A detergent composition for sports shoes prepared by adding 0.1 part by weight of lipase and 0.1 part by weight of cellulase.
And Furthermore, for sports shoes prepared by adding 2 parts by weight of sodium dodecylbenzenesulfonate, 0.1 part by weight of protease, 0.1 part by weight of lipase and 0.1 part by weight of cellulase to 100 parts by weight of the detergent composition of Example 1. The cleaning composition was set as Example 7. The pH of each composition was adjusted with an alkaline agent as shown in Table 2. Next, using the obtained detergent composition for sports shoes, the bleaching cleaning test and the odor judgment of the dirt adhering to the sports shoes were conducted in the same manner as in Example 1. The results are shown in Table 2.
【００１９】[0019]
【表２】 [Table 2]
【００２０】[0020]
【発明の効果】本発明によれば、刺激臭が無く、しかも
運動靴に付着した汚れに対する漂白洗浄力に優れた運動
靴用洗浄剤組成物が提供される。EFFECTS OF THE INVENTION According to the present invention, there is provided a cleaning composition for sports shoes which has no irritating odor and is excellent in bleaching and cleaning power against stains attached to the sports shoes.
フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 (Ｃ１１Ｄ 3/60 3:39 3:04） Continuation of front page (51) Int.Cl. 6 Identification code Office reference number FI technical display area (C11D 3/60 3:39 3:04)
Claims (2)
化水素を生成する過酸化物を生成過酸化水素換算で０．
１％〜６０重量％、（Ｂ）シアン酸のアルカリ金属塩又
はシアン酸のアンモニウム塩を０．１％〜３０重量％含
有し、その水溶液のｐＨが７〜１３であることを特徴と
する運動靴用洗浄剤組成物。1. (A) Hydrogen peroxide or a peroxide that produces hydrogen peroxide in an aqueous solution is converted into hydrogen peroxide in the form of hydrogen peroxide.
1% to 60% by weight, (B) 0.1% to 30% by weight of an alkali metal salt of cyanic acid or an ammonium salt of cyanic acid, and the pH of the aqueous solution is 7 to 13. A cleaning composition for shoes.
００重量部に酵素０．０５〜５重量部及び／又は界面活
性剤を０．１〜３０重量部を含有することを特徴とする
運動靴用の洗浄剤組成物。2. A cleaning composition 1 for sports shoes according to claim 1.
A detergent composition for sports shoes, characterized in that 0.05 to 5 parts by weight of an enzyme and / or 0.1 to 30 parts by weight of a surfactant are contained in 00 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27955195A JP3875292B2 (en) | 1995-09-21 | 1995-09-21 | Cleaning composition for athletic shoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27955195A JP3875292B2 (en) | 1995-09-21 | 1995-09-21 | Cleaning composition for athletic shoes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0987685A true JPH0987685A (en) | 1997-03-31 |
| JP3875292B2 JP3875292B2 (en) | 2007-01-31 |
Family
ID=17612548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27955195A Expired - Lifetime JP3875292B2 (en) | 1995-09-21 | 1995-09-21 | Cleaning composition for athletic shoes |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3875292B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001030955A1 (en) * | 1999-10-22 | 2001-05-03 | The Procter & Gamble Company | Compositions for treating shoes and methods and articles employing same |
| WO2002016538A1 (en) * | 2000-08-18 | 2002-02-28 | The University Of Leeds | Use of percarbamic acids and diacyl percarbamates and precursors therefor |
| US6861396B2 (en) | 2000-10-20 | 2005-03-01 | The Procter & Gamble Company | Compositions for pre-treating shoes and methods and articles employing same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4854280A (en) * | 1971-11-15 | 1973-07-30 | ||
| JPS4854279A (en) * | 1971-11-15 | 1973-07-30 | ||
| JPS62149800A (en) * | 1985-05-28 | 1987-07-03 | ライオン株式会社 | Bleaching composition |
| JPH07173495A (en) * | 1993-12-20 | 1995-07-11 | Koyo Kasei Kk | Cleaning with exothermic foaming detergent |
| JPH08245987A (en) * | 1995-03-09 | 1996-09-24 | Mitsubishi Gas Chem Co Inc | Fungi removing agent composition |
-
1995
- 1995-09-21 JP JP27955195A patent/JP3875292B2/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4854280A (en) * | 1971-11-15 | 1973-07-30 | ||
| JPS4854279A (en) * | 1971-11-15 | 1973-07-30 | ||
| JPS62149800A (en) * | 1985-05-28 | 1987-07-03 | ライオン株式会社 | Bleaching composition |
| JPH07173495A (en) * | 1993-12-20 | 1995-07-11 | Koyo Kasei Kk | Cleaning with exothermic foaming detergent |
| JPH08245987A (en) * | 1995-03-09 | 1996-09-24 | Mitsubishi Gas Chem Co Inc | Fungi removing agent composition |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001030955A1 (en) * | 1999-10-22 | 2001-05-03 | The Procter & Gamble Company | Compositions for treating shoes and methods and articles employing same |
| US6750188B2 (en) | 1999-10-22 | 2004-06-15 | The Procter & Gamble Company | Compositions for treating shoes and methods and articles employing same |
| US6866888B2 (en) | 1999-10-22 | 2005-03-15 | The Procter & Gamble Company | Compositions for treating shoes and methods and articles employing same |
| WO2002016538A1 (en) * | 2000-08-18 | 2002-02-28 | The University Of Leeds | Use of percarbamic acids and diacyl percarbamates and precursors therefor |
| JP2004507577A (en) * | 2000-08-18 | 2004-03-11 | ザ ユニバーシティ オブ リーズ | Use of percarbamic acids and diacyl percarbamic acids and precursors of these compounds |
| US7159333B2 (en) | 2000-08-18 | 2007-01-09 | The University Of Leeds | Use of percarbamic acids and diacyl percarbamates and precursors therefor |
| US6861396B2 (en) | 2000-10-20 | 2005-03-01 | The Procter & Gamble Company | Compositions for pre-treating shoes and methods and articles employing same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3875292B2 (en) | 2007-01-31 |
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