JPH0931866A - Printing of web - Google Patents
Printing of webInfo
- Publication number
- JPH0931866A JPH0931866A JP7201417A JP20141795A JPH0931866A JP H0931866 A JPH0931866 A JP H0931866A JP 7201417 A JP7201417 A JP 7201417A JP 20141795 A JP20141795 A JP 20141795A JP H0931866 A JPH0931866 A JP H0931866A
- Authority
- JP
- Japan
- Prior art keywords
- web
- ink
- alkali
- printing
- printed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Ink Jet (AREA)
- Coloring (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明はインクジェット方式
による布帛の捺染方法に係わり、更に詳細には極性基を
持つ繊維を含有する布帛に、高温反応型の反応性染料を
用いてインクジェット方式にて印捺するに際して品質の
低下がなく、しかも発色性に優れた印捺をし得る捺染方
法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for printing a cloth by an ink jet method, and more specifically, a cloth containing fibers having a polar group is printed by an ink jet method using a reactive dye of a high temperature reaction type. The present invention relates to a printing method capable of performing printing with excellent color developability without deterioration in quality upon printing.
【０００２】[0002]
【従来の技術】従来、布帛に図柄を印捺する方法として
は、スクリーン捺染法，ローラ捺染法，ロータリースク
リーン捺染法，転写捺染法等が用いられてきたが、図柄
の変更毎にスクリーン枠，彫刻ローラ、転写紙等を用意
する必要があり、これらスクリーン枠，彫刻ローラ，転
写紙の作成はかなり高価であるため、かなりのロットを
生産しないと経済的な面で合わない点のみならず、ファ
ッションの多様化に迅速に対応出来ないという欠点を有
する。2. Description of the Related Art Conventionally, as a method for printing a pattern on a cloth, a screen printing method, a roller printing method, a rotary screen printing method, a transfer printing method, etc. have been used. It is necessary to prepare engraving rollers, transfer paper, etc., and since the production of these screen frames, engraving rollers, transfer paper is quite expensive, not only is it economically incompatible unless a large lot is produced, It has the drawback of not being able to quickly respond to the diversification of fashion.
【０００３】これ等の欠点を解決するために、スキャナ
ーで見本を読み取り、コンピュータで画像処理を行い、
その結果をインクジェット方式で印捺する技術が開発さ
れてきたが、これ等は被捺染物を紙に限定していたた
め、染料を固着させる必要はなかったが、布帛に適用し
た場合には染料を固着せしめる必要があり、高温反応型
の反応性染料を用いて印捺する場合には、炭酸ナトリウ
ム，重炭酸ナトリウム，炭酸カルシウム等のアルカリで
前処理することや、染料インクにアルカリや潜在アルカ
リを添加することが行われてきた。In order to solve these drawbacks, a sample is read by a scanner, and image processing is performed by a computer.
Techniques for printing the results with an inkjet method have been developed, but since these were limited to paper to be printed, it was not necessary to fix the dye, but when applied to cloth, the dye was not applied. When printing with a reactive dye of high temperature reaction type that needs to be fixed, pretreatment with an alkali such as sodium carbonate, sodium bicarbonate, or calcium carbonate, and dye ink with alkali or latent alkali Additions have been made.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、炭酸ナ
トリウム，重炭酸ナトリウム，炭酸カルシウム等で前処
理した布帛はにじみ易くなり、高精度にプリントができ
ないという問題があった。また、布帛が長時間保管され
てから印捺が行われるような場合、アルカリによる布帛
の劣化、変色が起こり、品質の低下を招くという問題が
あった。また、染料インクにアルカリや潜在アルカリを
添加する方法は、インクジェット方式にて印捺するに際
しノズル詰まり等が発生し、それにより白スジ等が発生
し、品質の低下を招くという問題があった。However, there is a problem in that the cloth pretreated with sodium carbonate, sodium bicarbonate, calcium carbonate or the like is likely to bleed and cannot be printed with high precision. Further, when printing is performed after the cloth is stored for a long time, there is a problem that deterioration of the cloth and discoloration of the cloth due to alkali occur, resulting in deterioration of quality. In addition, the method of adding an alkali or a latent alkali to the dye ink has a problem that nozzle clogging occurs during printing by an inkjet method, which causes white stripes and the like, resulting in deterioration of quality.
【０００５】本発明者等は、布帛の高温反応型反応染料
によるインクジェット方式による捺染方法について鋭意
研究を続けた結果、既存法の有する諸問題点の悉くが解
決された新規捺染法を見出し本発明を完成したものであ
る。本発明の目的は、高温反応型反応性染料を用いてイ
ンクジェット方式にて印捺するに際して品質の低下がな
く、しかも発色性に優れた印捺をし得る捺染方法を提供
するにある。The present inventors, as a result of continuing diligent research on a printing method by an ink jet method using a high temperature reactive type reactive dye for a cloth, have found a new printing method in which the problems of the existing method are solved. Is completed. It is an object of the present invention to provide a printing method capable of performing printing with excellent color developability without deterioration in quality when printing by an inkjet method using a high temperature reactive reactive dye.
【０００６】[0006]
【課題が解決するための手段】上述の目的は、極性基を
持つ繊維を含有する布帛に高温反応型反応性染料を含む
インクをインクジェット方式にて印捺し、次いでアルカ
リを用いて発色することを特徴とする布帛の捺染方法に
より達成される。The above object is to print an ink containing a high temperature reactive reactive dye on a cloth containing a fiber having a polar group by an inkjet method, and then to develop a color by using an alkali. This is achieved by a characteristic textile printing method.
【０００７】[0007]
【発明の実施の形態】以下、本発明を詳細に説明する。BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.
【０００８】本発明で用いる極性基を持つ繊維として
は、綿，レーヨン等のセルロース系繊維、羊毛，絹等の
ように反応性染料と反応する極性基を持つ繊維が挙げら
れる。また、布帛としては、かかる極性基を持つ繊維か
らなる織物，編物，不織布等が挙げられる。Fibers having a polar group used in the present invention include cellulosic fibers such as cotton and rayon, and fibers having a polar group that reacts with a reactive dye such as wool and silk. Examples of the cloth include woven fabrics, knitted fabrics, and non-woven fabrics made of fibers having such polar groups.
【０００９】かかる極性基を持つ繊維からなる布帛に対
して公知の準備処理を行い、その後必要であれば撥水剤
等のにじみ防止剤、尿素等の保湿剤、メタニトロベンゼ
ンスルホン酸ソーダ等の還元防止剤等で前処理を行う。A known preparation treatment is performed on the cloth made of fibers having such a polar group, and thereafter, if necessary, an anti-bleeding agent such as a water repellent, a moisturizing agent such as urea, and a reduction of sodium metanitrobenzenesulfonate and the like. Pre-treatment with inhibitors etc.
【００１０】次いで、かかる布帛にインクジェット方式
により染料インクを付与する。Then, a dye ink is applied to the cloth by an ink jet method.
【００１１】本発明に使用するインクジェット方式とし
てはノズル内に発熱抵抗素子を埋め込み、その発熱によ
りインクを沸騰させ、その泡の圧力によりインクを吐出
させるバブルジェット方式、圧電素子に電気信号を加え
て変形させインク室の体積変化を励起してインク粒子を
飛ばすパルスジェット方式、超音波振動しているノズル
からインクを加圧連続噴射させて粒子化し、粒子を荷電
量に制御一定電界中を通過偏向させ、記録，非記録粒子
に分けて記録する荷電制御方式が挙げられる。As the ink jet method used in the present invention, a heating resistance element is embedded in a nozzle, the ink is boiled by the heat generation, and the ink is ejected by the pressure of the bubbles, and an electric signal is applied to a piezoelectric element. Pulse jet method that deforms and excites volume change of ink chamber to fly ink particles, ink is continuously jetted under pressure from nozzles that are vibrating ultrasonically to make particles, and the particles are controlled to charge amount Deflection through a constant electric field A charge control method in which recording is performed separately for recording and non-recording particles can be given.
【００１２】本発明で用いる高温反応型反応性染料は、
所謂ホットタイプと呼ばれるもので、具体的にはモノク
ロロトリアジン系，モノクロロジフルオロピリミジン
系，フロロメチルクロロピリミジン系等が挙げられる。The high temperature reactive reactive dye used in the present invention is
It is a so-called hot type, and specific examples thereof include monochlorotriazine type, monochlorodifluoropyrimidine type, fluoromethylchloropyrimidine type and the like.
【００１３】本発明において高温反応型反応性染料を溶
解もしくは分散せしめる媒体としては、従来の一般的捺
染における媒体、従来のインクジェット方式に用いられ
る媒体が使用出来、水又は水と有機溶剤との混合物が挙
げられるが、水を用いるのが一般的である。そして染料
には各種の分散剤，界面活性剤，粘度調整剤，表面張力
調整剤，ｐＨ調整剤，電導度調整剤等を必要に応じて添
加し、インクとなす。As a medium for dissolving or dispersing the high temperature reactive type reactive dye in the present invention, a medium used in conventional general printing and a medium used in a conventional ink jet system can be used, and water or a mixture of water and an organic solvent can be used. However, it is common to use water. Then, various dispersants, surfactants, viscosity modifiers, surface tension modifiers, pH modifiers, conductivity modifiers, etc. are added to the dyes as required to form an ink.
【００１４】かかる印捺を施した布帛は次にアルカリを
用いて発色するが、発色方法はホットタイプの二相法で
用いられる方法が採用でき、例えば温度９５〜１００
℃、好ましくは９８〜１００℃のアルカリに５〜３０
秒、好ましくは１０〜２０秒浸漬するアルカリショック
法やアルカリを付与した後、温度１３０〜１９０℃，好
ましくは１６０〜１８０℃で５〜６０秒、好ましくは１
０〜３０秒ハイテンパラチャースチーマで蒸熱処理する
方法が挙げられる。そして、アルカリとしてはケイ酸ソ
ーダ，ケイ酸ソーダとソーダ灰の組み合わせ、苛性ソー
ダとソーダ灰と食塩又は芒硝の組合せが挙げられる。ア
ルカリを用いて発色した後は洗浄し、乾燥する。The printed fabric is then colored with an alkali. The coloring method may be a hot type two-phase method, for example, a temperature of 95 to 100.
5 to 30 ° C., preferably 98 to 100 ° C. alkali
Second, preferably 10 to 20 seconds, after an alkali shock method of dipping or applying alkali, the temperature is 130 to 190 ° C., preferably 160 to 180 ° C. for 5 to 60 seconds, preferably 1
A method of steam heat treatment with a high temperature parachar steamer for 0 to 30 seconds can be mentioned. Examples of the alkali include sodium silicate, a combination of sodium silicate and soda ash, and a combination of caustic soda and soda ash and salt or mirabilite. After coloring with an alkali, the product is washed and dried.
【００１５】本発明においては、高温反応型反応性染料
を含むインクをインクジェット方式で印捺し、次いでア
ルカリを用いて発色するようにしているので、アルカリ
による前処理を施す必要がなく、アルカリによるにじみ
の問題がなく、またアルカリによる布帛の劣化、変色が
起こることがない。また、インクにアルカリや潜在アル
カリを添加していないので、インクジェツト方式にて印
捺するに際し、ノズル詰まり等が発生することが少なく
なり、白スジ等が発生することが少なくなる。In the present invention, since the ink containing the high temperature reactive type reactive dye is printed by the ink jet system and then the color is developed by using the alkali, it is not necessary to perform the pretreatment with the alkali, and the bleeding with the alkali is not required. Does not occur, and there is no deterioration or discoloration of the fabric due to alkali. Further, since no alkali or latent alkali is added to the ink, nozzle clogging or the like is less likely to occur when printing is performed by the ink jet method, and white lines or the like are less likely to occur.
【００１６】[0016]
【実施例】次に実施例に基づき本発明を具体的に説明す
る。尚、実施例及び比較例中の数値の基本となる試験方
法は次の通りである。 １．測色 マクベス分光光度計 Ｍ２０２０型 Ｋ／Ｓ濃度：最大吸収波長の反射率をＲとして以下の式にて算 出 Ｋ／Ｓ＝２Ｒ／（１−Ｒ2 ） 白度：４５０ｍｍの反射率 ２．引裂強力 ＪＩＳ Ｌ−１０９６ Ｄ法 ペンジュラム法 ３．にじみ １０人の専門検査員の目視判断にて ○：にじみ少ない、△： にじみやや有、×：にじみ有で評価EXAMPLES The present invention will be described in detail with reference to Examples. The test methods which are the basis of the numerical values in the examples and comparative examples are as follows. 1. Colorimetry Macbeth spectrophotometer M2020 type K / S concentration: Calculated by the following formula with reflectance at the maximum absorption wavelength as R. K / S = 2R / (1-R 2 ) Whiteness: reflectance at 450 mm 2. Tear strength JIS L-1096 D method Pendulum method 3. Bleeding: Visual inspection by 10 professional inspectors ○: Little bleeding, △: Slightly bleeding, ×: Evaluated as bleeding
【００１７】実施例１ 経糸５０番手、緯糸５０番手からなる経密度１３６本／
インチ，緯密度７２本／インチの綿１００％の平織物を
通常公知の方法にて毛焼，糊抜，精練，晒，シルケット
処理を行ったものを用いた。Example 1 136 warps having a warp yarn count of 50 and a weft yarn count of 136 /
A plain woven fabric made of 100% cotton, having an inch density and a weft density of 72 threads / inch, was subjected to wicking, desizing, scouring, bleaching, and mercerizing by a known method.
【００１８】該平織物に、保湿剤として尿素６部，にじ
み防止剤としてスミフルオイルＥＭ２１（住友化学工業
（株）製、フッ素樹脂のエマルジョン）１部、還元防止
剤としてダイヤテックスＤＹ−６０（長瀬産業（株）
製、メタニトロベンゼンスルホン酸ソーダ）２部及び残
部を水で調整した処理液をパディングした後、直ちにマ
ングルでピックアップ率７０％で絞り、１２０℃で２分
乾燥した。6 parts of urea as a moisturizing agent, 1 part of Sumiflule oil EM21 (Sumitomo Chemical Co., Ltd., fluororesin emulsion) as an anti-bleeding agent, DIATEX DY-60 (as a reduction inhibitor) Nagase & Co., Ltd.
Manufactured by Sodium Metanitrobenzene Sulfonate) and the rest was adjusted with water and padded, then immediately squeezed with a mangle at a pickup rate of 70% and dried at 120 ° C. for 2 minutes.
【００１９】一方、Ｃ．Ｉ．Ｒｅａｃｔｉｖｅ Ｙｅ
ｌｌｏｗ ９５ １５部，水８５部からなるインク、
Ｃ．Ｉ．Ｒｅａｃｔｉｖｅ Ｒｅｄ ４５ １５部，水
８５部からなるインク、Ｃ．Ｉ．Ｒｅａｃｔｉｖｅ
Ｂｌｕｅ ４９ １５部，水８５部からなるインクの３
種類をパルスジェット方式のインクジェット プリンタ
ーに搭載した。On the other hand, C.I. I. Reactive Ye
Ink consisting of 15 parts of low 95 and 85 parts of water,
C. I. Ink consisting of 15 parts of Reactive Red 45 and 85 parts of water, C.I. I. Reactive
3 of ink consisting of 15 parts of Blue 49 and 85 parts of water
The types were installed in a pulse jet type inkjet printer.
【００２０】そして、上記の前処理した平織物に直ち
に１ケ月放置後上記のインクジェットプリンターで１
２ドット／ｍｍの連続プリント（布とノズルの間隔は
１．５ｍｍとする）を行い、次いで１２０℃にて２分間
乾燥した。次いで、ケイ酸ソーダ（４８°Ｂｅ）をパデ
ィングした後、直ちにマングルでピックアップ率８０％
で絞り、ハイテンペラチャースチーマにて温度１７０
℃、時間１０秒で蒸熱処理した後、洗浄を行い、実施例
１の製品を得た。Immediately after leaving the above pretreated plain woven fabric for one month, the plain fabric was
A continuous print of 2 dots / mm (the distance between the cloth and the nozzle was 1.5 mm) was performed, and then the product was dried at 120 ° C. for 2 minutes. Next, after padding with sodium silicate (48 ° Be), immediately picked up with a mangle of 80%.
Squeeze at, temperature at high tempera steamer 170
After steaming at 10 ° C. for 10 seconds, washing was performed to obtain the product of Example 1.
【００２１】比較例１ 実施例１と同様のシルケット上がりの平織物に、保湿剤
として尿素 ６部、にじみ防止剤としてスミフルオイル
ＥＭ２１（住友化学工業（株）製、フッ素樹脂のエマ
ルジョン）１部、還元防止剤としてダイヤテックスＤＹ
−６０（長瀬産業（株）製、メタニトロベンゼンスルホ
ン酸ソーダ）２部、反応固着剤として重ソウ ３部及び
残部を水で処理した処理液をパディングした後、直ちに
マングルでピックアップ率７０％で絞り、１２０℃で２
分乾燥した。このように前処理した平織物に直ちに
１ケ月放置後実施例１と同様のインクジェット方式によ
る印捺を行い、１２０℃にて２分間乾燥した。次いで飽
和蒸気にて１０５℃で１０分間蒸熱処理した後、洗浄を
行い、比較例１の製品を得た。Comparative Example 1 A plain weave with the same mercerity as in Example 1 was added with 6 parts of urea as a moisturizer and 1 part of Sumiflu Oil EM21 (a fluorine resin emulsion manufactured by Sumitomo Chemical Co., Ltd.) as an anti-bleeding agent. , DIATEX DY as reduction inhibitor
-60 parts (manufactured by Nagase & Co., Ltd., sodium metanitrobenzene sulfonate), 3 parts of heavy soda as a reaction sticker, and the rest treated with water were padded and immediately squeezed with a mangle at a pick-up rate of 70%. , At 120 ℃ 2
And dried. The plain fabric pretreated in this way was immediately left for 1 month, then printed by the same inkjet method as in Example 1, and dried at 120 ° C. for 2 minutes. Then, after steaming with saturated steam at 105 ° C. for 10 minutes, washing was performed to obtain a product of Comparative Example 1.
【００２２】実施例１及び比較例１で得られた製品のＫ
／Ｓ濃度，白度，引裂強力を表１に示す。K of the products obtained in Example 1 and Comparative Example 1
Table 1 shows the / S density, whiteness, and tear strength.
【００２３】[0023]
【表１】 [Table 1]
【００２４】表１から明らかなように、実施例１で得ら
れた製品は布帛の劣化や変色が少なく、しかも、にじみ
が少なく発色性に優れることがわかる。As is clear from Table 1, the product obtained in Example 1 has less deterioration and discoloration of the fabric, less bleeding, and excellent color developability.
【００２５】実施例２ 経糸４０番手、緯糸４０番手からなる経密度１２２本／
インチ、緯密度９２本／インチのレーヨンの紡績糸使い
の平織物を通常公知の方法にて毛焼，糊抜，晒，アルカ
リ処理を行ったものを用いた。Example 2 122 warps having a 40 count warp and a 40 weft count
A plain weave fabric made of spun yarn of inch and weft density of 92 yarns / inch, which had been wicked, desizing, bleached, and alkali-treated by a generally known method, was used.
【００２６】該平織物に、保湿剤として尿素９部、にじ
み防止剤としてスミフルオイルＥＭ２１（住友化学工業
（株）製、フッ素樹脂のエマルジョン）２部、還元防止
剤としてダイヤテックスＤＹ−６０（長瀬産業（株）
製、メタニトロベンゼンスルホン酸ソーダ）２部及び残
部を水で調整した処理液をパディングした後、直ちにマ
ングルでピックアップ率７０％で絞り、１２０℃で１２
分乾燥した。To the plain weave, 9 parts of urea as a moisturizing agent, 2 parts of Sumiflule oil EM21 (a fluorine resin emulsion manufactured by Sumitomo Chemical Co., Ltd.) as an anti-bleeding agent, and Diatex DY-60 (as a reduction inhibitor) Nagase & Co., Ltd.
Manufactured by Sodium Metanitrobenzene Sulfonate) and padded with a treatment solution in which the balance is water.
And dried.
【００２７】一方、Ｃ．Ｉ．Ｒｅａｃｔｉｖｅ Ｙｅ
ｌｌｏｗ ２ １５部，水８５部からなるインク、
Ｃ．Ｉ．Ｒｅａｃｔｉｖｅ Ｒｅｄ ２２６ １５部，
水８５部からなるインク、Ｃ．Ｉ．Ｒｅａｃｔｉｖｅ
Ｂｌｕｅ １５ １５部，水８５部からなるインクの
３種類をパルスジェット方式のインクジェットプリンタ
ーに搭載した。On the other hand, C.I. I. Reactive Ye
Ink consisting of 15 parts of low 2 and 85 parts of water,
C. I. 15 parts of Reactive Red 226,
An ink consisting of 85 parts of water, C.I. I. Reactive
Three types of ink consisting of 15 parts of Blue 15 and 85 parts of water were mounted on a pulse jet type inkjet printer.
【００２８】そして、上記の前処理した平織物に直ち
に１ケ月放置後上記のインクジェット プリンターで
１２ドット／ｍｍの連続プリント（布とノズルの間隔は
１．５ｍｍとする）を行い、次いで１２０℃にて２分間
乾燥した。次いで、ケイ酸ソーダ（４８°Ｂｅ）の９８
℃の液の中に１０秒間浸漬した後、洗浄を行い実施例２
の製品を得た。Immediately after leaving the above pretreated plain woven fabric for 1 month, a continuous printing of 12 dots / mm (the distance between the cloth and the nozzle is 1.5 mm) was performed by the above ink jet printer, and then at 120 ° C. And dried for 2 minutes. Then 98 of sodium silicate (48 ° Be)
Example 2
Got the product.
【００２９】比較例２ 実施例２と同様のアルカリ処理上がりの平織物に、保湿
剤として尿素 ９部、にじみ防止剤としてスミフルオイ
ル ＥＭ２１（住友化学工業（株）製、フッ素樹脂のエ
マルジョン）１部、還元防止剤としてダイヤテックスＤ
Ｙ−６０（長瀬産業（株）製、メタニトロベンゼンスル
ホン酸ソーダ）２部、反応固着剤として重ソウ ３部及
び残部を水で処理した処理液をパディングした後、直ち
にマングルでピックアップ率７０％で絞り、１２０℃で
２分乾燥した。Comparative Example 2 The same alkali-treated plain weave as in Example 2 was mixed with 9 parts of urea as a moisturizing agent and Sumiflule Oil EM21 (a fluororesin emulsion manufactured by Sumitomo Chemical Co., Ltd.) as an anti-bleeding agent. Part, Diatex D as anti-reduction agent
Y-60 (manufactured by Nagase & Co., Ltd., sodium metanitrobenzene sulfonate) 2 parts, heavy soda 3 parts as a reaction fixing agent, and the rest treated with water were padded, and then immediately picked up by a mangle with a pick-up rate of 70%. Squeezed and dried at 120 ° C. for 2 minutes.
【００３０】このように前処理した平織物に直ちに
１ケ月放置後実施例２と同様のインクジェット方式によ
る印捺を行い、１２０℃にて２分間乾燥した。次いで飽
和蒸気にて１０５℃で１０分間蒸熱処理した後、洗浄を
行い、比較例２の製品を得た。Immediately after leaving the plain fabric thus pretreated for 1 month, it was printed by the same ink jet method as in Example 2 and dried at 120 ° C. for 2 minutes. Then, after steaming with saturated steam at 105 ° C. for 10 minutes, washing was performed to obtain a product of Comparative Example 2.
【００３１】実施例２及び比較例２で得られた製品のＫ
／Ｓ濃度，白度，引裂強力を表２に示す。K of the products obtained in Example 2 and Comparative Example 2
Table 2 shows the / S density, whiteness, and tear strength.
【００３２】[0032]
【表２】 [Table 2]
【００３３】表２から明らかなように、実施例２で得ら
れた製品は布帛の劣化や変色が少なく、しかも、にじみ
が少なく発色性に優れることがわかる。As is clear from Table 2, the product obtained in Example 2 has less deterioration and discoloration of the fabric, less bleeding, and excellent color developability.
【００３４】[0034]
【発明の効果】以上詳述したように、本発明方法によれ
ば品質の低下がなく、しかも発色性に優れた布帛が得ら
れるのでインクジェット方式による布帛への印捺が可能
となり、ファッションの多様化に即応出来るので頗る有
用である。As described in detail above, according to the method of the present invention, since a cloth having no deterioration in quality and excellent in color development can be obtained, it is possible to print on a cloth by an ink jet method, and various kinds of fashion can be achieved. It is extremely useful because it can respond quickly to changes.
Claims (1)
反応型反応性染料を含むインクをインクジェット方式に
て印捺し、次いでアルカリを用いて発色することを特徴
とする布帛の捺染方法。1. A method for printing a fabric, which comprises printing an ink containing a high-temperature-reactive reactive dye on a fabric containing a fiber having a polar group by an inkjet method, and then developing a color using an alkali.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7201417A JPH0931866A (en) | 1995-07-14 | 1995-07-14 | Printing of web |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7201417A JPH0931866A (en) | 1995-07-14 | 1995-07-14 | Printing of web |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0931866A true JPH0931866A (en) | 1997-02-04 |
Family
ID=16440742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7201417A Pending JPH0931866A (en) | 1995-07-14 | 1995-07-14 | Printing of web |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0931866A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001146689A (en) * | 1999-11-16 | 2001-05-29 | Murakami:Kk | Printing substrate based on flexible woven fabric, printed body using the same and method for printing the printing substrate made of flexible woven fabric |
| JP2006214030A (en) * | 2005-02-03 | 2006-08-17 | Seiko Epson Corp | Fixation promoting composition for ink jet textile printing, set for ink jet textile printing and method for ink jet textile printing |
| US9006509B2 (en) | 2003-07-18 | 2015-04-14 | Kimberly-Clark Worldwide, Inc. | Absorbent article with high quality ink jet image produced at line speed |
| CN106758406A (en) * | 2016-12-14 | 2017-05-31 | 翁后科 | A kind of bafta Non-water washing dyestuff |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012014869A (en) * | 2010-06-29 | 2012-01-19 | Kyoraku Sangyo Kk | Wiring structure for flexible cable |
| JP2012110433A (en) * | 2010-11-22 | 2012-06-14 | Heiwa Corp | Game machine |
-
1995
- 1995-07-14 JP JP7201417A patent/JPH0931866A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012014869A (en) * | 2010-06-29 | 2012-01-19 | Kyoraku Sangyo Kk | Wiring structure for flexible cable |
| JP2012110433A (en) * | 2010-11-22 | 2012-06-14 | Heiwa Corp | Game machine |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001146689A (en) * | 1999-11-16 | 2001-05-29 | Murakami:Kk | Printing substrate based on flexible woven fabric, printed body using the same and method for printing the printing substrate made of flexible woven fabric |
| US9006509B2 (en) | 2003-07-18 | 2015-04-14 | Kimberly-Clark Worldwide, Inc. | Absorbent article with high quality ink jet image produced at line speed |
| US9901492B2 (en) | 2003-07-18 | 2018-02-27 | Kimberly-Clark Worldwide, Inc. | Absorbent article with high quality ink jet image produced at line speed |
| JP2006214030A (en) * | 2005-02-03 | 2006-08-17 | Seiko Epson Corp | Fixation promoting composition for ink jet textile printing, set for ink jet textile printing and method for ink jet textile printing |
| JP4710337B2 (en) * | 2005-02-03 | 2011-06-29 | セイコーエプソン株式会社 | Fixing accelerating composition for inkjet printing, inkjet printing set, and inkjet printing method |
| CN106758406A (en) * | 2016-12-14 | 2017-05-31 | 翁后科 | A kind of bafta Non-water washing dyestuff |
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