JPH09221698A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH09221698A JPH09221698A JP5239396A JP5239396A JPH09221698A JP H09221698 A JPH09221698 A JP H09221698A JP 5239396 A JP5239396 A JP 5239396A JP 5239396 A JP5239396 A JP 5239396A JP H09221698 A JPH09221698 A JP H09221698A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- detergent composition
- arginine
- temperature stability
- purified water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、透明なゲルより成
る、優れた温度安定性と生分解性を有し、しかも皮膚に
対する刺激性の低い洗浄剤組成物に関する。さらに詳し
くは、特定量の脂肪酸のアルギニン塩に加えて、分子中
に水酸基を3個以上含有する多価アルコールと、精製水
とを特定の重量比で配合して成ることを特徴とする、洗
浄剤組成物に関する。TECHNICAL FIELD The present invention relates to a cleansing composition comprising a transparent gel, which has excellent temperature stability and biodegradability and has low skin irritation. More specifically, in addition to a specific amount of an arginine salt of fatty acid, a polyhydric alcohol containing 3 or more hydroxyl groups in the molecule and purified water are blended in a specific weight ratio. Agent composition.
【0002】[0002]
【従来の技術】従来より、生分解性が高く、皮膚に対す
る刺激が低い洗浄剤組成物を得るため、脂肪酸のアルギ
ニン塩より成るセッケンが用いられてきた。しかしなが
ら、脂肪酸のアルギニン塩を用いた洗浄剤組成物におい
ては、温度安定性が悪く、高温で不必要な流動性を呈
し、また外観が糊状となったり、或いは曳糸性が見られ
るといった問題点があった。2. Description of the Related Art Soaps composed of arginine salts of fatty acids have hitherto been used in order to obtain a detergent composition having high biodegradability and low skin irritation. However, a detergent composition using an arginine salt of a fatty acid has poor temperature stability, exhibits unnecessary fluidity at high temperatures, and has a pasty appearance or spinnability. There was a point.
【0003】[0003]
【発明が解決しようとする課題】従って、本発明は上記
した従来の問題点を解決するべく、脂肪酸のアルギニン
塩の有する良好な生分解性及び低刺激性といった特徴を
生かしながら、温度安定性を向上させ、さらに透明で良
好な外観及び使用性を有する洗浄剤組成物を得ることを
目的とする。SUMMARY OF THE INVENTION Therefore, in order to solve the above-mentioned conventional problems, the present invention provides temperature stability while taking advantage of the good biodegradability and hypoallergenicity of arginine salts of fatty acids. It is an object of the present invention to obtain a cleaning composition which is improved and is transparent and has a good appearance and usability.
【0004】[0004]
【課題を解決するための手段】本発明者は上記課題を解
決するべく検討を行ったところ、脂肪酸のアルギニン塩
の1種又は2種以上を20.0〜40.0重量%含有す
る洗浄剤組成物において、分子中に水酸基を3個以上含
有する多価アルコールの1種又は2種以上と、精製水と
を重量比で3:7〜5:5となるように配合することに
より、温度安定性に優れ、良好な外観及び使用性を有す
る透明なゲルが得られることを見い出し、本発明を解決
するに至った。Means for Solving the Problems The present inventor has conducted studies to solve the above problems, and has found that a detergent containing 20.0-40.0% by weight of one or more arginine salts of fatty acids. In the composition, one or two or more polyhydric alcohols containing three or more hydroxyl groups in the molecule and purified water are mixed at a weight ratio of 3: 7 to 5: 5 to obtain a temperature of It was found that a transparent gel having excellent stability, good appearance and usability can be obtained, and the present invention has been accomplished.
【0005】脂肪酸のアルギニン塩としては、炭素数8
〜30程度の直鎖又は分岐鎖脂肪酸,直鎖又は分岐鎖モ
ノエン酸,ジ,トリ,テトラエン酸,ヒドロキシ脂肪酸
等のアルギニン塩が用いられる。またアルギニンとして
は、D-アルギニン,DL-アルギニン,L-アルギニンの1
種又は2種以上を用いることができる。The arginine salt of fatty acid has 8 carbon atoms.
About 30 to about 30 linear or branched fatty acids, linear or branched monoenoic acids, di-, tri-, tetraenoic acids, arginine salts such as hydroxy fatty acids are used. As arginine, 1 of D-arginine, DL-arginine and L-arginine
Species or two or more can be used.
【0006】アルギニンと塩を形成させる脂肪酸を例示
すると、オクタン酸(カプリル酸),ノナン酸(ペラル
ゴン酸),デカン酸(カプリン酸),ウンデカン酸,ド
デカン酸(ラウリン酸),テトラデカン酸(ミリスチン
酸),ヘキサデカン酸(パルミチン酸),ヘプタデカン
酸(マルガリン酸),オクタデカン酸(ステアリン
酸),エイコサン酸(アラキン酸),ドコサン酸(ベヘ
ン酸),イソパルミチン酸,イソステアリン酸,9-デセ
ン酸(カプロレイン酸),9-ウンデセン酸(9-ウンデシ
レン酸),10-ウンデセン酸(10-ウンデシレン酸),2-
ドデセン酸(2-ラウロレイン酸),5-ドデセン酸(5-ラ
ウロレイン酸),11-ドデセン酸(11-ラウロレイン
酸),5-テトラデセン酸(5-ミリストレイン酸),9-テ
トラデセン酸(9-ミリストレイン酸),2-ヘキサデセン
酸(2-パルミトレイン酸),cis-7-ヘキサデセン酸(7-
パルミトレイン酸),cis-9-オクタデセン酸(オレイン
酸),trans-9-オクタデセン酸(エライジン酸),cis-
13-ドコセン酸(エルカ酸),cis-9,cis-12-オクタデカ
ジエン酸(リノール酸),trans-9,trans-12-オクタデ
カジエン酸(リノエライジン酸),cis-9,cis-12,cis-1
5-オクタデカトリエン酸(リノレン酸),5,8,11,14-エ
イコサテトラエン酸(アラキドン酸),12-ヒドロキシ
ステアリン酸等が挙げられる。また、牛脂,羊脂,パー
ム油,オリーブ油,ヒマシ油,ヤシ油等の天然油脂より
得られる脂肪酸混合物のアルギニン塩も用いることがで
きる。本発明においては、これらより1種又は2種以上
を選択して配合する。Examples of fatty acids that form salts with arginine include octanoic acid (caprylic acid), nonanoic acid (pelargonic acid), decanoic acid (capric acid), undecanoic acid, dodecanoic acid (lauric acid), and tetradecanoic acid (myristic acid). ), Hexadecanoic acid (palmitic acid), heptadecanoic acid (margaric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), isopalmitic acid, isostearic acid, 9-decenoic acid (caproleic acid) Acid), 9-undecenoic acid (9-undecylenic acid), 10-undecenoic acid (10-undecylenic acid), 2-
Dodecenoic acid (2-lauroleic acid), 5-dodecenoic acid (5-lauroleic acid), 11-dodecenoic acid (11-lauroleic acid), 5-tetradecenoic acid (5-myristoleic acid), 9-tetradecenoic acid (9- Myristoleic acid), 2-hexadecenoic acid (2-palmitoleic acid), cis-7-hexadecenoic acid (7-
Palmitoleic acid), cis-9-octadecenoic acid (oleic acid), trans-9-octadecenoic acid (elaidic acid), cis-
13-docosenoic acid (erucic acid), cis-9, cis-12-octadecadienoic acid (linoleic acid), trans-9, trans-12-octadecadienoic acid (linoelaidic acid), cis-9, cis- 12, cis-1
Examples include 5-octadecatrienoic acid (linolenic acid), 5,8,11,14-eicosatetraenoic acid (arachidonic acid), and 12-hydroxystearic acid. Also, an arginine salt of a fatty acid mixture obtained from natural fats and oils such as beef tallow, sheep fat, palm oil, olive oil, castor oil, and coconut oil can be used. In the present invention, one kind or two or more kinds are selected from these and blended.
【0007】分子中に水酸基を3個以上含有する多価ア
ルコールとしては、グリセリン、ジグリセリン,デカグ
リセリン等のポリグリセリン、エリスリトール,スレイ
トール,ペンタエリスリトール,アドニトール,アラビ
トール,キシリトール,ソルビトール,マンニトール,
ガラクチトール,イノシトール,マルチトール等の糖ア
ルコール、ブドウ糖,ショ糖等の糖類が挙げられ、これ
らより1種又は2種以上を選択して配合する。Examples of polyhydric alcohols containing three or more hydroxyl groups in the molecule include polyglycerin such as glycerin, diglycerin and decaglycerin, erythritol, threitol, pentaerythritol, adonitol, arabitol, xylitol, sorbitol, mannitol,
Examples thereof include sugar alcohols such as galactitol, inositol, and maltitol, and sugars such as glucose and sucrose, and one kind or two or more kinds are selected from these and mixed.
【0008】また、本発明に係る洗浄剤組成物には、本
発明の特徴を損なわない範囲で、通常洗浄剤組成物に配
合される他の成分、たとえば色素,酸化防止剤,防腐
剤,香料等を配合することもできる。Further, the cleaning composition according to the present invention may contain other components, such as dyes, antioxidants, preservatives, and fragrances, which are usually added to the cleaning composition within a range not impairing the features of the present invention. It is also possible to mix the like.
【0009】[0009]
【作用】本発明に係る洗浄剤組成物においては、外観の
良好な透明なゲルが得られる。そして、この透明ゲルは
優れた温度安定性を示し、また良好な使用性を有し、さ
らに皮膚に対して低刺激性で、生分解性も高い。In the detergent composition according to the present invention, a transparent gel having a good appearance can be obtained. The transparent gel exhibits excellent temperature stability, good usability, is less irritating to the skin, and is highly biodegradable.
【0010】[0010]
【発明の実施の形態】本発明は特に、顔,手,身体等の
皮膚用洗浄剤組成物として好適に実施できる。BEST MODE FOR CARRYING OUT THE INVENTION The present invention is particularly suitable for use as a cleansing composition for the skin of the face, hands, body and the like.
【0011】[0011]
【実施例】さらに本発明の特徴について、実施例により
詳細に説明する。EXAMPLES Further, the features of the present invention will be described in detail with reference to examples.
【0012】まず、ラウリン酸2.80重量%,ミリス
チン酸13.9重量%,ステアリン酸1.80重量%及
びL-アルギニン15.7重量%を含有する洗浄剤組成物
において、グリセリンと精製水との重量比を表1に示す
ように変化させ、それぞれ実施例1〜実施例3、及び比
較例1〜比較例5とした。これらは、精製水にアルギニ
ンを溶解させた後、グリセリンを添加して70℃に加熱
し、これにあらかじめ混合加熱して融解させ、70℃に
保ったラウリン酸,ミリスチン酸,ステアリン酸を添加
し、ケン化反応を進行させて調製する。First, in a detergent composition containing 2.80% by weight of lauric acid, 13.9% by weight of myristic acid, 1.80% by weight of stearic acid and 15.7% by weight of L-arginine, glycerin and purified water were used. The weight ratio of and was changed as shown in Table 1 to obtain Examples 1 to 3 and Comparative Examples 1 to 5, respectively. These are prepared by dissolving arginine in purified water, adding glycerin and heating to 70 ° C., mixing and heating the mixture in advance to melt it, and adding lauric acid, myristic acid, and stearic acid kept at 70 ° C. , The saponification reaction proceeds to prepare.
【表1】 [Table 1]
【0013】上記の実施例1〜実施例3及び比較例1〜
比較例5について、組成物の状態と温度安定性の観察を
行った。温度安定性は各試料を5℃,25℃,50℃に
それぞれ6カ月間保存し、6カ月後の状態の変化を観察
して評価し、「○;状態の変化を認めない」,「△;白
濁や析出或いは硬度の変化が若干認められる」,「×;
白濁や析出或いは硬度の変化が顕著に認められる」とし
て表した。結果は表2に示した。The above Examples 1 to 3 and Comparative Examples 1 to 1
Regarding Comparative Example 5, the state of the composition and the temperature stability were observed. Regarding temperature stability, each sample was stored at 5 ° C, 25 ° C, and 50 ° C for 6 months, and the state change after 6 months was observed and evaluated. “○; No state change”, “△ ; White turbidity, precipitation, or slight change in hardness is observed. ","X;
White turbidity, precipitation, or change in hardness is noticeable ". The results are shown in Table 2.
【表2】 [Table 2]
【0014】表2より明らかなように、本発明の実施例
においてはいずれも透明なゲルが得られ、温度安定性も
良好であった。これに対し、グリセリンと精製水との重
量比が3:7〜5:5の範囲外である比較例1〜比較例
5においては、いずれも透明なゲルは得られず、また温
度安定性も悪く、5℃及び50℃のいずれにおいても状
態の変化が認められていた。As is clear from Table 2, in each of the examples of the present invention, a transparent gel was obtained and the temperature stability was good. On the other hand, in Comparative Examples 1 to 5 in which the weight ratio of glycerin to purified water is outside the range of 3: 7 to 5: 5, no transparent gel was obtained and the temperature stability was also high. Poorly, a change in state was observed at both 5 ° C and 50 ° C.
【0015】続いて、本発明の他の実施例の処方を示
す。Next, a formulation of another embodiment of the present invention will be shown.
【0016】 [実施例4] 洗顔フォーム (1)ラウリン酸 2.8(重量%) (2)ミリスチン酸 13.9 (3)ステアリン酸 1.8 (4)L-アルギニン 15.7 (5)グリセリン 25.9 (6)パラオキシ安息香酸メチル 0.1 (7)香料 0.1 (8)精製水 39.7 製法:(8)に(4)〜(6)の水相成分を添加して加熱,溶解
して70℃に保つ。一方、(1)〜(3)の油相成分を混合
し、加熱融解して70℃に保ち、先の水相に添加,混合
してケン化する。冷却後、40℃にて(7)の香料を添
加,混合する。Example 4 Face Wash Foam (1) Lauric Acid 2.8 (wt%) (2) Myristic Acid 13.9 (3) Stearic Acid 1.8 (4) L-Arginine 15.7 (5) Glycerin 25.9 (6) Methyl paraoxybenzoate 0.1 (7) Perfume 0.1 (8) Purified water 39.7 Production method: The aqueous phase components (4) to (6) are added to (8) Heat, melt and maintain at 70 ° C. On the other hand, the oil phase components (1) to (3) are mixed, heated and melted and kept at 70 ° C., added to the previous aqueous phase, mixed and saponified. After cooling, the flavor of (7) is added and mixed at 40 ° C.
【0017】 [実施例5] 洗顔フォーム (1)ヤシ油脂肪酸 16.1(重量%) (2)イソパルミチン酸 5.0 (3)DL-アルギニン 17.9 (4)グリセリン 12.3 (5)エリスリトール 12.0 (6)パラオキシ安息香酸メチル 0.1 (7)香料 0.1 (8)精製水 36.5 製法:実施例4と同様に調製する。Example 5 Face Wash Foam (1) Coconut Oil Fatty Acid 16.1 (wt%) (2) Isopalmitic Acid 5.0 (3) DL-Arginine 17.9 (4) Glycerin 12.3 (5 ) Erythritol 12.0 (6) Methyl paraoxybenzoate 0.1 (7) Perfume 0.1 (8) Purified water 36.5 Production method: Prepared in the same manner as in Example 4.
【0018】 [実施例6] ハンドクレンジングジェル (1)ラウリン酸 2.5(重量%) (2)ミリスチン酸 12.5 (3)ステアリン酸 1.5 (4)D-アルギニン 14.0 (5)ジグリセリン 8.0 (6)ソルビトール 14.2 (7)パラオキシ安息香酸メチル 0.1 (8)香料 0.1 (9)精製水 47.1 製法:実施例4と同様に調製する。Example 6 Hand Cleansing Gel (1) Lauric Acid 2.5 (wt%) (2) Myristic Acid 12.5 (3) Stearic Acid 1.5 (4) D-Arginine 14.0 (5) ) Diglycerin 8.0 (6) Sorbitol 14.2 (7) Methyl paraoxybenzoate 0.1 (8) Perfume 0.1 (9) Purified water 47.1 Production method: Prepared in the same manner as in Example 4.
【0019】 [実施例7] ハンドクレンジングジェル (1)ラウリン酸 2.4(重量%) (2)パルミチン酸 11.0 (3)12-ヒドロキシステアリン酸 1.5 (4)リノール酸 0.5 (5)酢酸トコフェロール 0.2 (6)L-アルギニン 12.3 (7)マンニトール 18.0 (8)ペンタエリスリトール 18.0 (9)パラオキシ安息香酸メチル 0.1 (10)香料 0.1 (11)精製水 35.9 製法:(11)に(6)〜(9)の水相成分を添加して加熱,溶解
して70℃に保つ。一方、(1)〜(5)の油相成分を混合
し、加熱融解して70℃に保ち、先の水相に添加,混合
してケン化する。冷却後、40℃にて(10)の香料を添
加,混合する。Example 7 Hand Cleansing Gel (1) Lauric Acid 2.4 (wt%) (2) Palmitic Acid 11.0 (3) 12-Hydroxystearic Acid 1.5 (4) Linoleic Acid 0.5 (5) Tocopherol acetate 0.2 (6) L-arginine 12.3 (7) Mannitol 18.0 (8) Pentaerythritol 18.0 (9) Methyl paraoxybenzoate 0.1 (10) Perfume 0.1 ( 11) Purified water 35.9 Production method: The water phase components (6) to (9) are added to (11), heated, dissolved and kept at 70 ° C. On the other hand, the oil phase components (1) to (5) are mixed, heated and melted and kept at 70 ° C., added to the previous water phase, mixed and saponified. After cooling, the fragrance (10) is added and mixed at 40 ° C.
【0020】 [実施例8] 身体用洗浄剤 (1)ラノリン脂肪酸 10.7(重量%) (2)イソステアリン酸 1.8 (3)DL-アルギニン 10.0 (4)ガラクチトール 18.2 (5)ブドウ糖 5.0 (6)パラオキシ安息香酸メチル 0.2 (7)青色1号 0.001 (8)香料 0.1 (9)精製水 53.999 製法:(9)に(3)〜(7)の水相成分を添加して加熱,溶解
して70℃に保つ。一方、(1),(2)の油相成分を混合
し、加熱融解して70℃に保ち、先の水相に添加,混合
してケン化する。冷却後、40℃にて(8)の香料を添
加,混合する。Example 8 Body Cleanser (1) Lanolin Fatty Acid 10.7 (wt%) (2) Isostearic Acid 1.8 (3) DL-Arginine 10.0 (4) Galactitol 18.2 ( 5) Glucose 5.0 (6) Methyl paraoxybenzoate 0.2 (7) Blue No. 1 0.001 (8) Perfume 0.1 (9) Purified water 53.999 Manufacturing method: (9) to (3)- The aqueous phase component of (7) is added, heated, dissolved and kept at 70 ° C. On the other hand, the oil phase components (1) and (2) are mixed, heated and melted and kept at 70 ° C., added to the above aqueous phase, mixed and saponified. After cooling, the flavor of (8) is added and mixed at 40 ° C.
【0021】上記実施例4〜実施例8について、温度安
定性及び使用感の評価を行った。温度安定性の評価につ
いては、実施例1〜実施例3と同様に行った。使用感の
評価は、女性パネラー20名を1群として各群にブライ
ンドにて実施例及び比較例を使用させ、外観,使用性及
び皮膚刺激性について官能評価させて行った。官能評価
結果は、外観については「良好;5点」,「やや良好;
4点」,「普通;3点」,「やや悪い;2点」,「悪
い;1点」、使用性については「良い;5点」,「やや
良い;4点」,「普通;3点」,「やや悪い;2点」,
「悪い;1点」、皮膚刺激性については「刺激を感じな
い;5点」,「微妙に刺激を感じる;4点」,「少し刺
激を感じる;3点」,「明確に刺激を感じる;2点」,
「強い刺激を感じる;1点」として点数化し、20名の
平均値にて示した。なお、各実施例において3個以上の
水酸基を有する多価アルコールを精製水に代替したもの
をそれぞれ比較例6〜比較例10とした。結果は表3に
まとめて示した。The temperature stability and the feeling of use of the above Examples 4 to 8 were evaluated. The temperature stability was evaluated in the same manner as in Examples 1 to 3. The evaluation of the feeling of use was carried out by using 20 female panelists as one group and blindly using the examples and comparative examples in each group, and sensory-evaluating the appearance, usability and skin irritation. The sensory evaluation results were "good; 5 points" and "somewhat good" for the appearance.
"4 points", "ordinary; 3 points", "slightly bad; 2 points", "poor; 1 point", usability "good; 5 points", "somewhat good; 4 points", "normal; 3 points" , "Slightly bad; 2 points",
"Poor; 1 point", for skin irritation "No irritation; 5 points", "Slightly irritation; 4 points", "Slightly irritation; 3 points", "Clearly irritation; 2 points ",
It was scored as "feeling strong irritation; 1 point" and shown as an average value of 20 persons. In addition, what replaced the polyhydric alcohol which has a 3 or more hydroxyl group in each Example with purified water was set to Comparative Example 6-Comparative Example 10, respectively. The results are summarized in Table 3.
【表3】 [Table 3]
【0022】表3より明らかなように、本発明の実施例
はいずれも良好な温度安定性を示し、また使用試験にお
いても、各実施例使用群では、ほとんどのパネラーが良
好な外観を有し、使用性も良好であると評価していた。
さらに皮膚刺激性はほとんどのパネラーが感じておら
ず、比較例に比べて皮膚刺激性は一層低下していた。こ
れに対し、比較例はいずれも温度安定性が悪く、各比較
例使用群では、外観,使用性についての評価も、実施例
使用群に比べて顕著に低い評価となっていた。As is clear from Table 3, all the examples of the present invention showed good temperature stability, and in the use test, most of the panelists in each use group of the examples had a good appearance. It was evaluated that the usability was also good.
Further, most panelists did not feel the skin irritation, and the skin irritation was further reduced as compared with the comparative example. On the other hand, the comparative examples were all poor in temperature stability, and the appearance and usability of each comparative example use group were significantly lower than those of the example use group.
【0023】[0023]
【発明の効果】以上詳述したように、本発明により、低
刺激性で生分解性に優れるという脂肪酸のアルギニン塩
の有する特徴を生かしながら、透明で外観が美しく、使
用性が良好で、温度安定性に優れるゲル状の洗浄剤組成
物を得ることができた。As described in detail above, according to the present invention, while utilizing the characteristic of the arginine salt of a fatty acid, which is hypoallergenic and excellent in biodegradability, it is transparent and has a beautiful appearance, good usability and temperature. It was possible to obtain a gel-like detergent composition having excellent stability.
Claims (1)
上を20.0〜40.0重量%含有する洗浄剤組成物に
おいて、分子中に水酸基を3個以上含有する多価アルコ
ールの1種又は2種以上及び精製水を、重量比にして
3:7〜5:5となるように配合することを特徴とす
る、洗浄剤組成物。1. A detergent composition containing 20.0-40.0% by weight of one or more arginine salts of fatty acids, and one polyhydric alcohol containing three or more hydroxyl groups in the molecule. Alternatively, two or more kinds and purified water are mixed in a weight ratio of 3: 7 to 5: 5, and a cleaning composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5239396A JPH09221698A (en) | 1996-02-14 | 1996-02-14 | Detergent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5239396A JPH09221698A (en) | 1996-02-14 | 1996-02-14 | Detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH09221698A true JPH09221698A (en) | 1997-08-26 |
Family
ID=12913565
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5239396A Pending JPH09221698A (en) | 1996-02-14 | 1996-02-14 | Detergent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH09221698A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001039857A (en) * | 1999-07-29 | 2001-02-13 | Nonogawa Shoji Kk | Skin cleaning agent |
JP2002146389A (en) * | 2000-11-15 | 2002-05-22 | Kawaken Fine Chem Co Ltd | Transparent gel-like detergent composition |
JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
-
1996
- 1996-02-14 JP JP5239396A patent/JPH09221698A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001039857A (en) * | 1999-07-29 | 2001-02-13 | Nonogawa Shoji Kk | Skin cleaning agent |
JP2002146389A (en) * | 2000-11-15 | 2002-05-22 | Kawaken Fine Chem Co Ltd | Transparent gel-like detergent composition |
JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
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