JPH09146461A - Adhesive identification label - Google Patents
Adhesive identification labelInfo
- Publication number
- JPH09146461A JPH09146461A JP30261295A JP30261295A JPH09146461A JP H09146461 A JPH09146461 A JP H09146461A JP 30261295 A JP30261295 A JP 30261295A JP 30261295 A JP30261295 A JP 30261295A JP H09146461 A JPH09146461 A JP H09146461A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- pressure
- label
- sensitive adhesive
- adhesive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、主として建築材料
の標識用に用いられる標識粘着ラベルに関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a labeled adhesive label mainly used for marking building materials.
【０００２】[0002]
【従来の技術】建築中や改装中の建物、部屋に設置され
たガラス板や鏡等が工事中に損傷を受けないように、例
えば「ガラス注意」とか「鏡あり」のように注意を促す
ためのラベルが貼り付けられる。このようなものとし
て、登録実用新案第３００９５７８号公報に記載の「建
築用識別ラベル」がある。このものは、ラベル表面に印
刷インキと粘着剤とを混合したもので印刷を施し、裏面
は表面の印刷版を利用して粘着剤だけを塗工したもので
ある。[Prior Art] Calling attention such as "glass caution" or "with mirror" so that glass plates and mirrors installed in buildings or rooms under construction or renovation will not be damaged during construction Label is attached. As such, there is a "building identification label" described in Registered Utility Model No. 3009578. In this product, the label surface is printed with a mixture of a printing ink and an adhesive, and the back surface is coated with only the adhesive using the printing plate on the surface.
【０００３】[0003]
【発明が解決しようとする課題】上記公報に記載のラベ
ルによると、ラベル表面には粘着剤と印刷インキの混合
物で印刷が施されるので、表面に粘着剤が必要な場合に
は一工程で製造することができる。しかし、裏面の粘着
剤により被着体に貼り付けた場合、印刷インキ混合物中
の粘着剤が露出されている為、塵などが付着して見苦し
くなり、又、表面側をガラス等に貼り付けると裏面側の
粘着剤が露出する。According to the label described in the above publication, since the label surface is printed with a mixture of an adhesive and a printing ink, if an adhesive is required on the surface, one step is required. It can be manufactured. However, when it is attached to the adherend with the adhesive on the back side, the adhesive in the printing ink mixture is exposed, so it becomes unsightly due to dust and the like. The adhesive on the back side is exposed.
【０００４】又、粘着剤としては通常のラベルに使用さ
れている粘着剤が用いられるので、粘着力が強く、用済
み後にこれを剥がす作業に手間を要する。更に、剥がし
た後のガラスや鏡の表面に粘着剤や粘着剤とともに基材
の紙が残ることがあり、これを削り取る作業で傷が付い
たりするという問題がある。Further, since the pressure-sensitive adhesive used for ordinary labels is used as the pressure-sensitive adhesive, the pressure-sensitive adhesive has a strong adhesive force, and it takes a lot of time and labor to remove it after use. Furthermore, there is a problem that the base material paper may remain with the adhesive or the adhesive on the surface of the glass or the mirror after peeling off, and the work of scraping it off may cause scratches.
【０００５】本発明は上記従来の問題点を解消し、ガラ
ス等の被着体に貼り付けたラベルの剥離作業が容易で、
且つ、剥がした後の被着体表面に粘着剤が残っても除去
作業が容易な標識粘着ラベルを提供することを目的とす
る。The present invention solves the above-mentioned problems of the prior art, and makes it easy to peel off a label attached to an adherend such as glass,
Another object of the present invention is to provide a labeled adhesive label that can be easily removed even if the adhesive remains on the surface of the adherend after peeling.
【０００６】[0006]
【課題を解決するための手段】本発明の標識粘着ラベル
は、基材シートの少なくとも片面に表示用の印刷がなさ
れ、該印刷面もしくは他の面に粘着剤層が設けられてい
る粘着ラベルにおいて、粘着剤層を形成する粘着剤が、
粘着性微球体をバインダー樹脂に分散してなる粘着剤か
らなることを特徴とするものである。The labeled pressure-sensitive adhesive label of the present invention is a pressure-sensitive adhesive label in which at least one surface of a substrate sheet is printed for display and an adhesive layer is provided on the printed surface or other surface. , The adhesive forming the adhesive layer is
It is characterized by comprising a pressure-sensitive adhesive obtained by dispersing a pressure-sensitive adhesive microsphere in a binder resin.
【０００７】本発明の標識粘着ラベルに使用できる基材
シートとしては、紙、合成樹脂フィルム等があるが、特
に紙は手で簡単に切り取ることができるので使い易く、
１枚単位でミシン目を設けると切りやすくて更に好まし
い。The base sheet that can be used for the labeled adhesive label of the present invention includes paper, synthetic resin film and the like. Especially, since paper can be easily cut by hand, it is easy to use.
It is more preferable to provide perforations for each sheet because it is easy to cut.
【０００８】表示のための印刷は基材シートの片面もし
くは両面に行ってもよく、粘着剤層はいずれか一方の面
に設けられる。本発明で使用する粘着剤は、例えば特開
昭６３−２６０９７３号公報に記載されているような、
（メタ）アクリレート、該（メタ）アクリレートと共重
合性を有する水溶性モノマー、及び分子内に２個以上の
重合性不飽和基を有する油溶性の多官能モノマーを含有
する組成物を油溶性重合開始剤及び界面活性剤の存在下
で水性懸濁重合することにより得られた粘着性微球体を
バインダー樹脂に分散させたものなどが好適である。Printing for display may be performed on one side or both sides of the substrate sheet, and the adhesive layer is provided on either side. The pressure-sensitive adhesive used in the present invention is, for example, as described in JP-A-63-260973.
Oil-soluble polymerization of a composition containing (meth) acrylate, a water-soluble monomer copolymerizable with the (meth) acrylate, and an oil-soluble polyfunctional monomer having two or more polymerizable unsaturated groups in the molecule. Those in which the adhesive microspheres obtained by aqueous suspension polymerization in the presence of an initiator and a surfactant are dispersed in a binder resin are suitable.
【０００９】上記粘着性微球体の平均粒子径は、小さい
と粘着力が高くなり再剥離性が得られず、また、大きい
と被着体との接着面積が低下し、充分な粘着力が得られ
ないので、好ましくは１０〜１００μｍであり、より好
ましくは２０〜７０μｍである。If the average particle size of the above-mentioned tacky microspheres is small, the tackiness becomes high and removability cannot be obtained, and if it is too large, the adhesive area with the adherend is reduced and sufficient tackiness is obtained. Therefore, the thickness is preferably 10 to 100 μm, more preferably 20 to 70 μm.
【００１０】上記粘着剤は従来から用いられている各種
のロールコーターにより基材シートに塗工すればよい。
又、特開平４−１１７４７８号公報に記載のような、上
記粘着性微球体をエアゾル用分散媒に分散させたものと
し、これを基材シートに吹きつけてもよい。The above-mentioned pressure-sensitive adhesive may be applied to the base sheet by various conventionally used roll coaters.
Further, as described in JP-A-4-117478, the above-mentioned adhesive microspheres may be dispersed in a dispersion medium for aerosol, and this may be sprayed onto a base material sheet.
【００１１】上記粘着性微球体を用いた粘着剤層は紙や
ガラス等の被着体に貼り付けても、容易に剥離できるも
のであるが、このような粘着ラベルをロール状に巻回し
たり、一定寸法に裁断した枚葉ものとして積み重ねたり
したものを使用するために剥離するときに、一層容易に
剥離作業ができるように粘着剤層と反対側の面には離型
処理を施しておくのが好ましい。離型処理に使用する離
型剤は有機系やシリコーン系の他、種々のものが使用で
きる。The pressure-sensitive adhesive layer using the above-mentioned pressure-sensitive adhesive microspheres can be easily peeled off even when it is adhered to an adherend such as paper or glass. However, such a pressure-sensitive adhesive label is wound in a roll. , In order to use peeled pieces that have been cut into a certain size and stacked, use a release treatment on the surface opposite to the adhesive layer so that peeling work can be done more easily. Is preferred. As the release agent used for the release treatment, various types can be used in addition to organic type and silicone type.
【００１２】また、若干量の粘着剤が被着体表面に残留
しても、湿った雑巾等でふけば落とすことができ、又、
洗剤を用いればより簡単にきれいに落とすことができ
る。Further, even if a small amount of the adhesive remains on the surface of the adherend, it can be removed by wiping it with a damp cloth or the like.
It can be removed more easily and cleanly with a detergent.
【００１３】（作用）本発明の標識粘着ラベルは、粘着
剤層として粘着性微球体をバインダー樹脂に分散したも
のを用いるので、良好な再剥離性を示し、使用後に被着
体から容易に剥離することができ、又、再接着すること
もできる。そのため、貼り直し作業も容易にでき、剥離
した後の被着体に粘着剤が残っても水又は洗剤で粘着剤
の拭き取り作業を非常に簡単にできる。(Function) The labeled adhesive label of the present invention uses an adhesive layer in which adhesive microspheres are dispersed in a binder resin, and therefore exhibits good removability and is easily released from an adherend after use. It can also be re-bonded. Therefore, the re-adhesion work can be easily performed, and even if the adherend remains on the adherend after peeling, the work of wiping the adhesive with water or a detergent can be very easily performed.
【００１４】[0014]
【発明の実施の形態】次に、本発明の標識粘着ラベルの
実施例を図面を参照して説明する。 （実施例）図１は本発明の標識粘着ラベルの実施例を示
す断面図、図２は同じ実施例を示す斜視図である。標識
粘着ラベル１は、基材シート２として上質紙を使用し、
表面に「ガラス注意」の文字を印刷し、印刷した側の表
面全体にアルキル系離型剤３（一方社油脂工業社製，商
品名「ピーロイル１０１０」）のトルエン１％溶液を塗
布乾燥することにより離型処理した。２１は印刷面であ
る。BEST MODE FOR CARRYING OUT THE INVENTION Next, an embodiment of the labeled adhesive label of the present invention will be described with reference to the drawings. (Embodiment) FIG. 1 is a sectional view showing an embodiment of the labeled adhesive label of the present invention, and FIG. 2 is a perspective view showing the same embodiment. The label adhesive label 1 uses high-quality paper as the base material sheet 2,
Print the word "Glass caution" on the surface, and apply a 1% toluene solution of Alkyl mold release agent 3 (manufactured by Yasusha Yushi Kogyo Co., Ltd., trade name "Pyrroyl 1010") to the entire printed surface and dry. Release treatment was performed by. 21 is a printing surface.
【００１５】ｎ−ブチルアクリレート５０重量部、２−
エチルヘキシルアクリレート５０重量部、スチレン３重
量部、酢酸ビニル１重量部及びプロピオン酸ビニル２重
量部の混合モノマーを、油溶性開始剤と界面活性剤の存
在下で水性懸濁重合し、遠心分離で脱水・脱溶剤を行
い、平均粒径３５μｍの粘着性微球体を得た。50 parts by weight of n-butyl acrylate, 2-
50 parts by weight of ethylhexyl acrylate, 3 parts by weight of styrene, 1 part by weight of vinyl acetate, and 2 parts by weight of vinyl propionate are subjected to aqueous suspension polymerization in the presence of an oil-soluble initiator and a surfactant, and dehydrated by centrifugation. -The solvent was removed to obtain adhesive microspheres having an average particle size of 35 µm.
【００１６】このアクリル系の粘着性微球体８０重量部
をトルエン４５５重量部とメチルイソブチルケトン４５
５重量部との混合溶剤に分散させた後、溶剤系アクリル
系粘着剤（綜研化学社製，商品名「ＳＫダイン７０
１」，固形分４０％）１０重量部を添加混合して固形分
８．４％、粘度２００００ｃｐｓ（２３℃）である粘着
性微球体を含む粘着剤を作製した。80 parts by weight of the acrylic sticky microspheres were mixed with 455 parts by weight of toluene and 45 parts of methyl isobutyl ketone.
After being dispersed in a mixed solvent with 5 parts by weight, a solvent-based acrylic pressure-sensitive adhesive (manufactured by Soken Chemical Co., Ltd., trade name “SKDyne 70
1 ", solid content 40%) 10 parts by weight were added and mixed to prepare an adhesive containing adhesive microspheres having a solid content of 8.4% and a viscosity of 20000 cps (23 ° C).
【００１７】上記粘着剤を基材シート２の離型処理面と
は反対側の面に塗布、乾燥して粘着剤層４を形成した。
この粘着剤層４の表面は粘着性微球体４１による凹凸状
であり、乾燥後の粘着剤層の厚みは約３６μｍであっ
た。この基材シート２を印刷の表示単位で切断し、台紙
の上に重ねたものと、紙管にロール状に巻き取ったもの
とした。The above-mentioned pressure-sensitive adhesive was applied to the surface of the base sheet 2 opposite to the release-treated surface and dried to form a pressure-sensitive adhesive layer 4.
The surface of the adhesive layer 4 was uneven due to the adhesive microspheres 41, and the thickness of the adhesive layer after drying was about 36 μm. The base sheet 2 was cut in print display units, stacked on a backing sheet, and wound on a paper tube in a roll shape.
【００１８】（比較例）粘着性微球体を含む粘着剤の代
わりに、アクリル系粘着剤（綜研化学社製，商品名「Ｓ
Ｋダイン７０１」，固形分４０％）を乾燥後の厚みが２
５μｍとなるように塗布乾燥して粘着剤層を形成し、該
粘着剤層面に剥離紙を貼り合わせた。(Comparative Example) Instead of the adhesive containing the adhesive microspheres, an acrylic adhesive (manufactured by Soken Chemical Co., Ltd., trade name "S") was used.
K Dyne 701 ", solid content 40%) has a thickness of 2 after drying.
A pressure-sensitive adhesive layer was formed by coating and drying so as to have a thickness of 5 μm, and release paper was attached to the pressure-sensitive adhesive layer surface.
【００１９】性能評価 上記実施例と比較例で得た標識粘着ラベルを以下の項目
で評価した。 （１）接着性：ガラス板に貼り付けて貼り付け状態を観
察した。 （２）剥離性：上記（１）のガラス板に貼り付けたもの
を室内で１０日間放置した後、手で剥がす作業を行った
際の剥離状態を観察した。 （３）拭き取り性：上記（２）で粘着ラベルを剥離した
後、スプレー性ガラス洗剤（ジョンソン社製，商品名
「ガラス用クルー」）を吹きつけ、布製ウエスを使用し
て拭き取り、その結果を観察した。Performance Evaluation The labeled adhesive labels obtained in the above Examples and Comparative Examples were evaluated in the following items. (1) Adhesiveness: Adhered to a glass plate, and the adhered state was observed. (2) Peelability: The peeled state was observed when the work stuck on the glass plate of (1) above was left indoors for 10 days and then peeled by hand. (3) Wipeability: After the adhesive label was peeled off in (2) above, a sprayable glass detergent (manufactured by Johnson Co., trade name "crew for glass") was sprayed and wiped off using a cloth cloth, and the result was obtained. I observed.
【００２０】以上の結果を表１に示す。The above results are shown in Table 1.
【００２１】[0021]
【表１】 [Table 1]
【００２２】表１から明らかなとおり、実施例の本発明
によるものは粘着性、剥離性共にすぐれ、粘着剤の拭き
取り作業を簡単にできるものである。As is clear from Table 1, the examples according to the present invention are excellent in both tackiness and releasability and can easily wipe off the tackiness agent.
【００２３】[0023]
【発明の効果】本発明の標識粘着ラベルは以上の構成で
あり、粘着剤層として粘着性微球体をバインダー樹脂に
分散したものを用いるので、ガラス等の被着体に貼り付
けた後、容易に剥離することができ、貼り直し作業も容
易である。又、剥離した後の被着体に粘着剤が残っても
粘着剤の拭き取り作業は非常に容易である。EFFECTS OF THE INVENTION The labeled adhesive label of the present invention has the above-mentioned constitution, and since the adhesive microspheres are prepared by dispersing the adhesive microspheres in the binder resin, they can be easily adhered to an adherend such as glass. It can be peeled off and the re-pasting work is easy. Further, even if the pressure-sensitive adhesive remains on the adherend after peeling, the work of wiping the pressure-sensitive adhesive is very easy.
【００２４】[0024]
【図１】本発明標識粘着ラベルの実施例を示す断面図。FIG. 1 is a cross-sectional view showing an example of a labeled adhesive label of the present invention.
【図２】本発明標識粘着ラベルの実施例を示す斜視図。FIG. 2 is a perspective view showing an embodiment of the labeled adhesive label of the present invention.
１ ：標識粘着ラベル ２ ：基材シート ３ ：離型剤層 ４ ：粘着剤層 ２１：印刷面 ４１：粘着性微球体 1: Labeled adhesive label 2: Base material sheet 3: Release agent layer 4: Adhesive layer 21: Printing surface 41: Adhesive microspheres
Claims (1)
印刷がなされ、該印刷面もしくは他の面に粘着剤層が設
けられている粘着ラベルにおいて、粘着剤層を形成する
粘着剤が、粘着性微球体を主成分とすることを特徴とす
る標識粘着ラベル。1. In a pressure-sensitive adhesive label, wherein at least one surface of a substrate sheet is printed for display, and the pressure-sensitive adhesive layer is provided on the printed surface or the other surface, the pressure-sensitive adhesive forming the pressure-sensitive adhesive layer is adhesive. A labeled adhesive label, which is characterized in that it has a main component of crystalline microspheres.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30261295A JPH09146461A (en) | 1995-11-21 | 1995-11-21 | Adhesive identification label |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30261295A JPH09146461A (en) | 1995-11-21 | 1995-11-21 | Adhesive identification label |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH09146461A true JPH09146461A (en) | 1997-06-06 |
Family
ID=17911087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30261295A Pending JPH09146461A (en) | 1995-11-21 | 1995-11-21 | Adhesive identification label |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH09146461A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005120184A (en) * | 2003-10-15 | 2005-05-12 | Sato Corp | Removable pressure-sensitive adhesive label and manufacturing method |
| JPWO2005040297A1 (en) * | 2003-10-29 | 2007-11-22 | 王子タック株式会社 | Adhesive label for linerless inkjet recording |
-
1995
- 1995-11-21 JP JP30261295A patent/JPH09146461A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005120184A (en) * | 2003-10-15 | 2005-05-12 | Sato Corp | Removable pressure-sensitive adhesive label and manufacturing method |
| JP4493971B2 (en) * | 2003-10-15 | 2010-06-30 | 株式会社サトー | Method for producing releasable adhesive label |
| JPWO2005040297A1 (en) * | 2003-10-29 | 2007-11-22 | 王子タック株式会社 | Adhesive label for linerless inkjet recording |
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