JPH08504452A - 澱粉を主成分とする腐食性肉薄成形体の製造方法 - Google Patents
澱粉を主成分とする腐食性肉薄成形体の製造方法Info
- Publication number
- JPH08504452A JPH08504452A JP6513546A JP51354694A JPH08504452A JP H08504452 A JPH08504452 A JP H08504452A JP 6513546 A JP6513546 A JP 6513546A JP 51354694 A JP51354694 A JP 51354694A JP H08504452 A JPH08504452 A JP H08504452A
- Authority
- JP
- Japan
- Prior art keywords
- water
- starch
- coating
- weight
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/048—Forming gas barrier coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/056—Forming hydrophilic coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/10—Esters of organic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/26—Cellulose ethers
- C09D101/28—Alkyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2493/00—Characterised by the use of natural resins; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/02—Shellac
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Medicinal Preparation (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Noodles (AREA)
- General Preparation And Processing Of Foods (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Biological Depolymerization Polymers (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 2つの半成形型の間で澱粉含有物質をベーキングすることによってまたは 澱粉含有物質を押出成形することによって得られる成形体の少なくとも一つの面 あるいは内側を撥水性−あるいは耐水性被覆する方法において、人間への毒性お よび/または生態学的毒性において問題がなく、水と混和し得る低沸点溶剤の他 に1種以上の腐食性の造膜物質および1種以上の腐食性疎水性可塑剤を含有する 塗料を塗布するのと同時に、被覆すべき成形体の表面から吸着した水和水の少な くとも1部を除去し、次いで該溶剤(混合物)を5重量%の基体の湿分含有量を 維持しなから臭いが無くなるまで除くことを特徴とする、上記方法。 2. 造膜性物質として、セルロースアセテートブチラート、セルロースアセテ ートプロピオナートおよびセルロースアセテートより成る群の内の疎水性アルキ ルセルロース、非水溶性セルロースエステルを含有する請求項1に記載の方法。 3. 塗料が可塑剤として中鎖−および長鎖の脂肪酸(鎖長C4以上)のトリグ ボン酸、完全エステル化シトロネン酸エステル、サッカロース−アセテート−イ ソブチラートおよび他の疎水性糖類エステルを含有する請求項1または2に記載 の方法。 4. 塗料が追加的に1種類以上の腐食性結合剤を含有する請求項1〜3のいず れか一つに記載の方法。 5. 塗料が結合剤としてシュラック、コパル、マステック、サンダラック、シ ェラック、コロホニウムを基本成分とする水素化された二量体のおよび重合体樹 脂および脂肪族炭化水素樹脂より成る群の天然樹脂を含有する請求項4に記載の 方法。 6.塗料が溶剤としてアルコール、ケトンまたはエステルより成る100℃以下 、好ましくは80℃以下で沸騰する1種以上の溶剤を含有する請求項1〜5のい ずれか一つに記載の方法。 7. 溶剤と使用する塗料の層成分との重量比が1.5〜17である請求項1〜 6のいずれか一つに記載の方法。 8. 被覆物が15〜150μm、好ましくは40〜150μmの厚さを有してい る請求項1〜7のいずれか一つに記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT2402/92 | 1992-12-04 | ||
AT240292 | 1992-12-04 | ||
PCT/AT1993/000185 WO1994013734A1 (de) | 1992-12-04 | 1993-12-06 | Verfahren zur herstellung von verrottbaren, dünnwandigen formkörpern auf stärkebasis |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08504452A true JPH08504452A (ja) | 1996-05-14 |
JP3497507B2 JP3497507B2 (ja) | 2004-02-16 |
Family
ID=3533695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51354694A Expired - Fee Related JP3497507B2 (ja) | 1992-12-04 | 1993-12-06 | 澱粉を主成分とする生分解性肉薄成形体の製造方法 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5576049A (ja) |
EP (1) | EP0672080B1 (ja) |
JP (1) | JP3497507B2 (ja) |
AT (1) | ATE156161T1 (ja) |
CA (1) | CA2150929A1 (ja) |
CZ (1) | CZ131295A3 (ja) |
DE (1) | DE59307028D1 (ja) |
DK (1) | DK0672080T3 (ja) |
HU (1) | HU220250B (ja) |
PL (1) | PL180951B1 (ja) |
SK (1) | SK69995A3 (ja) |
WO (1) | WO1994013734A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012515835A (ja) * | 2009-01-21 | 2012-07-12 | バイオスフィア・インダストリーズ・リミテッド・ライアビリティ・カンパニー | 耐湿性コーティング |
JP2018145426A (ja) * | 2017-03-07 | 2018-09-20 | 花王株式会社 | 疎水変性セルロース繊維及び油を有する膜 |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5830305A (en) * | 1992-08-11 | 1998-11-03 | E. Khashoggi Industries, Llc | Methods of molding articles having an inorganically filled organic polymer matrix |
US5662731A (en) | 1992-08-11 | 1997-09-02 | E. Khashoggi Industries | Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix |
US5660900A (en) | 1992-08-11 | 1997-08-26 | E. Khashoggi Industries | Inorganically filled, starch-bound compositions for manufacturing containers and other articles having a thermodynamically controlled cellular matrix |
US5716675A (en) | 1992-11-25 | 1998-02-10 | E. Khashoggi Industries | Methods for treating the surface of starch-based articles with glycerin |
CN1127817A (zh) * | 1995-01-26 | 1996-07-31 | 拉比多秤和机器工场有限公司 | 由可生物降解材料生产成型体的方法和成型体 |
NL1001036C1 (nl) * | 1995-08-04 | 1997-02-07 | Avebe Coop Verkoop Prod | Werkwijze voor het vervaardigen van een voorwerp door spuitgieten van een zetmeelprodukt. |
ATE187472T1 (de) * | 1995-09-12 | 1999-12-15 | Fvp Formverpackung Gmbh | Verfahren zur herstellung von formkörpern mit barriereschicht aus biologisch abbaubarem material und formkörper |
US5756194A (en) * | 1996-01-25 | 1998-05-26 | The United States Of America, As Represented By The Secretary Of Agriculture | Enhanced water resistance of starch-based materials |
US6479164B1 (en) | 1996-02-05 | 2002-11-12 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Method for preparing composite materials from renewable raw materials |
EP0925323A1 (de) * | 1996-09-11 | 1999-06-30 | Tils, Peter | Verfahren zum herstellen von lösungen biologisch abbaubarer kunststoffe, insbesondere aliphatischer polyesteramide |
NL1006548C2 (nl) * | 1997-07-10 | 1999-01-12 | Sara Lee De Nv | Biodegradeerbare folie. |
DE19814373C2 (de) * | 1998-03-31 | 2000-05-31 | Aig Allg Immobilienverwaltungs | Biologisch abbaubares Material für Verpackungen, Verfahren und Verwendung |
DE19911209A1 (de) * | 1999-03-13 | 2000-09-14 | Wolff Walsrode Ag | Halbzeuge aus biologisch abbaubaren Polymeren mit verbesserter Hydrolysestabilität und Spannungsrißbeständigkeit |
US6231970B1 (en) | 2000-01-11 | 2001-05-15 | E. Khashoggi Industries, Llc | Thermoplastic starch compositions incorporating a particulate filler component |
US6379446B1 (en) | 2000-04-03 | 2002-04-30 | E. Khashoggi Industries, Llc. | Methods for dispersing fibers within aqueous compositions |
AU2000273123A1 (en) * | 2000-09-13 | 2002-03-26 | Seiko Sato | Composition for manufacturing formed article comprising starch, pulverized plantfiber or organic fertilizer obtained by treating garbage as main material, meth od for producing the same, method for manufacturing formed article using the same, and formed article and method for use |
US20030033960A1 (en) * | 2001-08-17 | 2003-02-20 | Hudzinski Michael E. | Line trimmer, biodegradable trim line for use therewith, and method of making same |
US7947766B2 (en) | 2003-06-06 | 2011-05-24 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
EP1699952A1 (en) * | 2003-12-18 | 2006-09-13 | The Procter and Gamble Company | Rotary spinning processes for forming hydroxyl polymer-containing fibers |
US6955850B1 (en) | 2004-04-29 | 2005-10-18 | The Procter & Gamble Company | Polymeric structures and method for making same |
US6977116B2 (en) | 2004-04-29 | 2005-12-20 | The Procter & Gamble Company | Polymeric structures and method for making same |
EP1596361A3 (de) * | 2004-05-11 | 2012-06-20 | IGV Institut für Getreideverarbeitung GmbH | Geformtes Schalldämmaterial und Verfahren zu seiner Herstellung |
FI20041439A (fi) * | 2004-11-09 | 2006-05-10 | Eriksson Capital Ab | Putkimainen elintarvikekuori |
US20060107041A1 (en) * | 2004-11-18 | 2006-05-18 | Michael Fiske | Assembling a security access system |
US20070092712A1 (en) * | 2005-10-25 | 2007-04-26 | Hodson Simon K | Articles having a moisture-resistant protective coating and methods of manufacturing such articles |
US7931778B2 (en) | 2005-11-04 | 2011-04-26 | Cargill, Incorporated | Lecithin-starches compositions, preparation thereof and paper products having oil and grease resistance, and/or release properties |
US20070196581A1 (en) * | 2006-01-31 | 2007-08-23 | Elizabeth Marcu | Process for coating a biodegradable item |
US7618485B2 (en) * | 2006-06-16 | 2009-11-17 | The Biodegradable Technologies General Partnership | Biodegradable compositions, articles prepared from biodegradable compositions and manufacturing methods |
JP2008260919A (ja) * | 2007-03-16 | 2008-10-30 | Fujifilm Corp | セルロースアセテートプロピオネートフィルム、セルロースアセテートプロピオネートフィルムの製造方法、光学補償シート、偏光板および液晶表示装置 |
TW200914524A (en) * | 2007-09-18 | 2009-04-01 | Grace Biotech Corp | Totally biodegradable starch resin, manufacturing method thereof, film product made the same and resin composition used for preparing the starch resin |
US8286561B2 (en) | 2008-06-27 | 2012-10-16 | Ssw Holding Company, Inc. | Spill containing refrigerator shelf assembly |
US11786036B2 (en) | 2008-06-27 | 2023-10-17 | Ssw Advanced Technologies, Llc | Spill containing refrigerator shelf assembly |
AU2009302806B9 (en) | 2008-10-07 | 2015-10-01 | Ross Technology Corporation | Highly durable superhydrophobic, oleophobic and anti-icing coatings and methods and compositions for their preparation |
TWI496725B (zh) | 2009-01-20 | 2015-08-21 | Chamness Biodegradables Llc | 多層次容器 |
EP2496886B1 (en) | 2009-11-04 | 2016-12-21 | SSW Holding Company, Inc. | Cooking appliance surfaces having spill containment pattern and methods of making the same |
BR112012023312A2 (pt) | 2010-03-15 | 2019-09-24 | Ross Tech Corporation | desentupidor e métodos de produção de superfícies hidrofóbicas |
JP2014512417A (ja) | 2011-02-21 | 2014-05-22 | ロス テクノロジー コーポレーション. | 低voc結合剤系を含む超疎水性および疎油性被覆物 |
DE102011085428A1 (de) | 2011-10-28 | 2013-05-02 | Schott Ag | Einlegeboden |
WO2013090939A1 (en) | 2011-12-15 | 2013-06-20 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
WO2014003852A2 (en) | 2012-06-25 | 2014-01-03 | Ross Technology Corporation | Elastomeric coatings having hydrophobic and/or oleophobic properties |
US20140186644A1 (en) * | 2012-12-31 | 2014-07-03 | David A. Dellinger | Moisture resistant coating |
WO2014198999A1 (en) * | 2013-06-13 | 2014-12-18 | Opes Corporation Oy | Matrix |
CN103348858B (zh) * | 2013-07-11 | 2014-12-03 | 扬州大学 | 钵体毯状苗的育苗方法 |
AT521488B1 (de) * | 2018-07-17 | 2020-02-15 | Josef Haas | Grundkörper für eine Getränkeportionskapsel |
CN114269824B (zh) | 2019-06-20 | 2024-02-20 | Eps全球营销有限公司 | 可生物降解可堆肥的模塑物料组合物、模塑制品和制造方法 |
US11518860B1 (en) | 2022-06-06 | 2022-12-06 | Seyed Farshid Bahari | Biodegradable and waterproof shaped articles based on thermoplastic starch with lower retrogradation and improved mechanical properties |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0378646A1 (de) * | 1988-07-20 | 1990-07-25 | TOMKA, Ivan | Hydrophiles polymer mit gegenüber hydrophilen lösungsmitteln erhöhter beständigkeit |
WO1991012186A1 (de) * | 1990-02-06 | 1991-08-22 | Biopac Biologische Verpackungssysteme Gesellschaftm.B.H. | Verfahren zur herstellung von verrottbaren, dünnwandigen formkörpern auf stärkebasis |
DE69125965T2 (de) * | 1990-02-28 | 1997-09-25 | Agency Ind Science Techn | Verfahren zur Herstellung eines bioabbaubaren, formbaren Materials |
-
1993
- 1993-12-06 EP EP94900626A patent/EP0672080B1/de not_active Expired - Lifetime
- 1993-12-06 DK DK94900626.6T patent/DK0672080T3/da active
- 1993-12-06 SK SK699-95A patent/SK69995A3/sk unknown
- 1993-12-06 AT AT94900626T patent/ATE156161T1/de not_active IP Right Cessation
- 1993-12-06 DE DE59307028T patent/DE59307028D1/de not_active Expired - Fee Related
- 1993-12-06 US US08/446,677 patent/US5576049A/en not_active Expired - Fee Related
- 1993-12-06 CA CA002150929A patent/CA2150929A1/en not_active Abandoned
- 1993-12-06 PL PL93309250A patent/PL180951B1/pl unknown
- 1993-12-06 WO PCT/AT1993/000185 patent/WO1994013734A1/de not_active Application Discontinuation
- 1993-12-06 JP JP51354694A patent/JP3497507B2/ja not_active Expired - Fee Related
- 1993-12-06 HU HU9501099A patent/HU220250B/hu not_active IP Right Cessation
- 1993-12-06 CZ CZ951312A patent/CZ131295A3/cs unknown
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012515835A (ja) * | 2009-01-21 | 2012-07-12 | バイオスフィア・インダストリーズ・リミテッド・ライアビリティ・カンパニー | 耐湿性コーティング |
JP2018145426A (ja) * | 2017-03-07 | 2018-09-20 | 花王株式会社 | 疎水変性セルロース繊維及び油を有する膜 |
JP2022111127A (ja) * | 2017-03-07 | 2022-07-29 | 花王株式会社 | 疎水変性セルロース繊維及び油を有する滑液表面膜 |
US11499034B2 (en) | 2017-03-07 | 2022-11-15 | Kao Corporation | Film comprising hydrophobized cellulose fibers and oil |
US11884798B2 (en) | 2017-03-07 | 2024-01-30 | Kao Corporation | Film comprising hydrophobized cellulose fibers and oil |
Also Published As
Publication number | Publication date |
---|---|
CZ131295A3 (en) | 1995-12-13 |
HU9501099D0 (en) | 1995-06-28 |
PL309250A1 (en) | 1995-10-02 |
HU220250B (hu) | 2001-11-28 |
SK69995A3 (en) | 1995-12-06 |
EP0672080A1 (de) | 1995-09-20 |
PL180951B1 (pl) | 2001-05-31 |
HUT71954A (en) | 1996-02-28 |
CA2150929A1 (en) | 1994-06-23 |
JP3497507B2 (ja) | 2004-02-16 |
US5576049A (en) | 1996-11-19 |
DK0672080T3 (da) | 1998-02-23 |
EP0672080B1 (de) | 1997-07-30 |
WO1994013734A1 (de) | 1994-06-23 |
DE59307028D1 (de) | 1997-09-04 |
ATE156161T1 (de) | 1997-08-15 |
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