JPH08234764A - Squeaking sound preventive surface treating agent - Google Patents
Squeaking sound preventive surface treating agentInfo
- Publication number
- JPH08234764A JPH08234764A JP7141650A JP14165095A JPH08234764A JP H08234764 A JPH08234764 A JP H08234764A JP 7141650 A JP7141650 A JP 7141650A JP 14165095 A JP14165095 A JP 14165095A JP H08234764 A JPH08234764 A JP H08234764A
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、インストルメントパネ
ル、ドアトリム及びサンバイザー等の自動車の内装部品
に用いられる軋み音防止表面処理剤に関し、特に自動車
の走行時の振動により内装部品が擦れ合って発生する軋
み音を防止するための軋み音防止表面処理剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a squeaking noise preventing surface treatment agent used for automobile interior parts such as instrument panels, door trims and sun visors, and in particular, the interior parts are rubbed against each other due to vibration during running of the car. The present invention relates to a squeaking noise preventing surface treatment agent for preventing squeaking noise generated.
【０００２】[0002]
【従来の技術】従来、自動車の内装部品であるインスト
ルメントパネル、ピラーガーニッシュ、ドアトリム及び
サンバイザー等の表面は、塩化ビニル（ＰＶＣ）等の表
皮材で覆われており、更にその表層には耐候性を付与し
たり、低光沢化等をする目的でアクリル−塩化ビニル系
塗料又はウレタン系塗料を厚さ１０〜３０μｍの範囲で
塗布することによって表面処理が施されている。2. Description of the Related Art Conventionally, the surfaces of automobile interior parts such as instrument panels, pillar garnishes, door trims and sun visors are covered with a skin material such as vinyl chloride (PVC), and the surface layer thereof is also weather-resistant. The surface treatment is performed by applying an acrylic-vinyl chloride paint or a urethane paint in a thickness range of 10 to 30 μm for the purpose of imparting properties and lowering gloss.
【０００３】これらを含む自動車内装品が相互に接触す
る部分では、自動車走行時の振動により内装品同士が擦
れ合い軋み音が発生する。従来、この軋み音対策として
は、接触部に不織布を貼る手段が取られており、この不
織布を接触する二部品間に介在させることにより、音の
発生を抑制させるようにしていた。At a portion where automobile interior parts including these are in contact with each other, the interior parts rub against each other due to vibration during traveling of the automobile, and a squeaking noise is generated. Conventionally, as a countermeasure against this squeaking noise, a means for pasting a non-woven fabric on the contact portion has been adopted, and the non-woven fabric is interposed between two parts in contact with each other to suppress the generation of sound.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、従来の
内装部品表面の接触部に不織布を貼る対策では、細かい
作業のため機械化が困難であり、人手に頼るため作業工
数が多大となり、コスト高となるという欠点があった。
また、ドアトリム端部とインストサイド又はシートサイ
ドとの接触部分では、ドアが閉じた状態では人目につか
ないため、外観品質上問題とならないが、ドアを開けた
状態では人目につくため、不織布を貼ると外観品質が劣
るという欠点があった。However, in the conventional measures for sticking a non-woven fabric to the contact portion on the surface of the interior part, it is difficult to mechanize because of the fine work, and the manpower is large and the cost is high. There was a drawback.
Also, at the contact part of the door trim end and the instrument side or seat side, it is not visible when the door is closed, so there is no problem in appearance quality, but it is visible when the door is open, so apply non-woven fabric. There was a drawback that the appearance quality was inferior.
【０００５】一方、特開平３−１４３７４５号公報、特
開平３−１４３７４６号公報及び特開平３−２１７４２
５号公報には、自動車の内装部品表面の接触部におい
て、音の発生する部分に不織布の代替として弾性塗膜や
異音防止塗料を塗布した軋み音防止剤を塗布する技術が
開示されている。On the other hand, JP-A-3-143745, JP-A-3-143746 and JP-A-3-21742.
Japanese Patent Publication No. 5 discloses a technique of applying an anti-squealing agent, which is an elastic coating or an abnormal noise preventing coating applied as a substitute for a non-woven fabric, to a portion where noise is generated in a contact portion on the surface of an automobile interior part. .
【０００６】しかしながら、これらの方法は音が発生す
る部分に部品を成形した後、後処理として内装部品表面
の接触部分に防止剤を塗布する方法であるため、自動化
は可能であるが、新たに塗布工程が必要となるという欠
点があった。また、これらの方法は軋み音のみを防止す
ることを目的としているので、外観品質を低下させ、人
目につく部分には適用することができないという欠点が
あった。[0006] However, these methods are methods in which a part is molded in a part where a sound is generated and then an inhibitor is applied to a contact part on the surface of the interior part as a post-treatment, so that automation is possible, but newly. There is a drawback that a coating process is required. Further, since these methods are intended to prevent only the squeaking noise, they have a drawback that they deteriorate the appearance quality and cannot be applied to a noticeable part.
【０００７】また、特開平５−１５６２０６号公報に
は、ウレタン樹脂中にウレタンの微粒子を含有したコー
ティング剤が開示されている。しかしながら、このウレ
タン系塗料はアクリル系塗料に比べてコストが高く、更
に接触している部品が滑り出す時に発生する単発音に対
しては、アクリル系塗料に比べ劣るという欠点があっ
た。Further, Japanese Patent Laid-Open No. 5-156206 discloses a coating agent containing urethane fine particles in a urethane resin. However, this urethane-based paint has a drawback that it is higher in cost than the acrylic-based paint and that it is inferior to the acrylic-based paint in terms of a single sound generated when a contacting component slides out.
【０００８】従って本発明は、このような従来の問題点
に着目してなされたもので、自動車の内装部品表面の接
触部に発生する軋み音を防止すると共に、従来から行わ
れている内装部品表面の接触部に不織布を貼る方法に対
して、工程の簡略化（不織布貼り付け工程の省略）を可
能とする軋み音防止表面処理剤を提供することを目的と
する。Therefore, the present invention has been made by paying attention to such a conventional problem, and prevents the squeaking noise generated at the contact portion on the surface of the interior parts of the automobile, and at the same time, the interior parts that have been conventionally used. It is an object of the present invention to provide a squeaking noise preventing surface treatment agent that enables simplification of the process (omission of the non-woven fabric attaching process) as compared with the method of attaching the non-woven fabric to the contact portion of the surface.
【０００９】[0009]
【課題を解決するための手段】本発明者らは、上記課題
を解決すべく鋭意研究した結果、アクリル−塩化ビニル
系塗料用樹脂に、所定のウレタン粒子を所定量含有させ
た場合には、自動車の走行時の振動による内装部品が擦
れ合って発生する軋み音を有効に防止することができる
ことを見い出し、本発明に到達した。Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors have found that when a predetermined amount of urethane particles is contained in a resin for acrylic-vinyl chloride type coating, The inventors have found that it is possible to effectively prevent the squeaking noise generated by the rubbing of the interior parts due to the vibration during the traveling of the automobile, and the present invention has been accomplished.
【００１０】本発明の上記の目的は、アクリル−塩化ビ
ニル系塗料用樹脂に、平均粒径が１〜５０μｍの範囲に
ある球状及び／又は塊状のウレタン粒子を固形分として
２〜６０重量％の範囲で含有させてなることを特徴とす
る軋み音防止表面処理剤により達成された。The above object of the present invention is to provide acrylic-vinyl chloride type coating resin with spherical and / or lumpy urethane particles having an average particle size in the range of 1 to 50 μm in a solid content of 2 to 60% by weight. This has been achieved by a squeaking noise-preventing surface treatment agent characterized by being contained in a range.
【００１１】また、本発明の上記の目的は、アクリル−
塩化ビニル系塗料用樹脂に、（ａ）平均粒径が５〜５０
μｍの範囲にある球状のウレタン粒子５〜６０重量％、
（ｂ）平均粒径が１〜８μｍの範囲にある樹脂及び／又
はゴム系微粒子１〜５０重量％、（ａ）及び（ｂ）を合
計で５〜７０重量％含有させてなることを特徴とする軋
み音防止表面処理剤により達成された。Further, the above object of the present invention is to provide an acrylic resin
(A) average particle size of 5 to 50 for vinyl chloride paint resins
5-60 wt% of spherical urethane particles in the range of μm,
(B) 1 to 50% by weight of resin and / or rubber fine particles having an average particle size in the range of 1 to 8 μm, and (a) and (b) in a total amount of 5 to 70% by weight. Achieved with a squeaking noise-preventing surface treatment agent.
【００１２】まず、本発明における軋み音を低減させる
ための考え方を以下に説明する。自動車車室内において
発生する音は二種類に大別することができる。一つは部
品が滑りだす時に発生する単発音であり、もう一つは自
動車走行時の定常的な振動によって発生する連続音であ
る。前者の単発音は発進時や段差を乗り越えたときなど
に内装部品が衝撃を受けて発生するものであり、後者の
連続音は路面の状況によって車両が走行中、連続的に頻
繁に起こり得るものである。First, the concept for reducing the squeaking noise in the present invention will be described below. The sounds generated in the vehicle interior can be roughly classified into two types. One is a single sound that is generated when the parts start to slide, and the other is a continuous sound that is generated by steady vibration while the vehicle is running. The former single sound is generated when the interior parts are impacted when starting or when climbing over a step, and the latter continuous sound can occur continuously and frequently while the vehicle is running depending on the road surface condition. Is.
【００１３】本発明は、発生頻度及び乗員の感じる不快
度等を考慮し、後者の定常的な振動によって生じる連続
音を低減させることを目的としてなされたものである。
また、前述したように、部品が滑り出す時に生じる単発
音については、ベース塗料をアクリル−塩化ビニル系塗
料とすることで改善される。図１に試験例で用いた往復
運動による摩擦試験の概要を示す。図１に示すように、
被試験体１上で被試験体２を滑らせる試験を行った場合
に、二つの物体間の摩擦係数は一般的に図２に示すよう
に時間の経過と共に変動する。The present invention has been made in view of the frequency of occurrence and the degree of discomfort felt by an occupant, and the object thereof is to reduce the continuous sound generated by the latter steady vibration.
Further, as described above, the single sound generated when the parts start to slide can be improved by using the acrylic-vinyl chloride based paint as the base paint. FIG. 1 shows an outline of the friction test by the reciprocating motion used in the test example. As shown in Figure 1,
When a test of sliding the test object 2 on the test object 1 is performed, the coefficient of friction between two objects generally fluctuates over time as shown in FIG.
【００１４】単発音に対しては静摩擦係数と動摩擦係数
との差を小さくすることが有効となるが、連続的な微振
動によって発生する音を防止するためには、動摩擦係数
（μｄ）の変動幅を小さくするほうが効果的である。It is effective to reduce the difference between the static friction coefficient and the dynamic friction coefficient for a single sound, but in order to prevent the sound generated by the continuous micro vibration, the variation of the dynamic friction coefficient (μd) is required. It is more effective to reduce the width.
【００１５】一方、従来から自動車の内装部品に低光沢
化等をする目的で塗布されているアクリル−塩化ビニル
系塗料について、軋み音の観点から検討した結果、塗料
の艶消し剤として一般的に添加されているシリカ粒子が
摩擦特性を悪化させていることが明らかになった。On the other hand, the acrylic-vinyl chloride type paints which have been conventionally applied to the interior parts of automobiles for the purpose of reducing the gloss etc. were examined from the viewpoint of the squeaking noise. It was revealed that the added silica particles deteriorate the friction characteristics.
【００１６】このため、本発明者らはアクリル−塩化ビ
ニル系塗料中にシリカ以外の種々の微粒子を添加し、動
摩擦係数の幅を測定した結果、平均粒径が１〜５０μｍ
の範囲にある球状及び／又は塊状のウレタン粒子を固形
分として２〜６０重量％の範囲で含有させることによ
り、動摩擦係数の幅を小さくすることが可能となり、そ
の結果、軋み音を防止する効果を見出した。For this reason, the present inventors have added various fine particles other than silica to the acrylic-vinyl chloride-based paint and measured the width of the dynamic friction coefficient. As a result, the average particle diameter is 1 to 50 μm.
By containing spherical and / or lump-shaped urethane particles in the range of 2 to 60% by weight as a solid content, it becomes possible to reduce the width of the dynamic friction coefficient, and as a result, the effect of preventing squeaking noises. Found.
【００１７】本発明において、ウレタン粒子の平均粒径
は１〜５０μｍの範囲、特に５〜３０μｍの範囲である
ことが好ましい。平均粒径が１μｍ未満になると、ウレ
タン粒子が塗膜中に沈降し表面に凹凸が形成されなくな
り、艶消し効果がなくなったり、摩擦特性が低下する。
逆に、５０μｍを超えると、表面処理剤の厚さが３０μ
ｍ程度あるので、耐磨耗性が低下する。In the present invention, the average particle size of the urethane particles is preferably in the range of 1 to 50 μm, particularly 5 to 30 μm. If the average particle size is less than 1 μm, the urethane particles settle in the coating film and the unevenness is not formed on the surface, the matte effect is lost, and the friction characteristics are deteriorated.
On the contrary, when the thickness exceeds 50 μm, the thickness of the surface treatment agent is 30 μm.
Since it is about m, abrasion resistance is reduced.
【００１８】ウレタン粒子の形状は、本発明の効果を出
すため、球状及び／又は塊状であることが必要であり、
特に真球状であることが好ましい。ウレタン粒子の含有
量は固形分として２〜６０重量％の範囲、特に１０〜６
０重量％の範囲であることが好ましい。含有量が２重量
％未満になると、異音防止効果が不十分であり、艶消し
効果も消失する。逆に、６０重量％を超えると、塗膜形
成が不可能になったり、塗膜の耐磨耗性が低下すると共
にコスト高となる。The shape of the urethane particles is required to be spherical and / or massive in order to obtain the effects of the present invention.
It is particularly preferable that the shape is true spherical. The content of urethane particles is in the range of 2 to 60% by weight as a solid content, especially 10 to 6
It is preferably in the range of 0% by weight. If the content is less than 2% by weight, the noise preventing effect is insufficient and the matting effect is also lost. On the other hand, if it exceeds 60% by weight, it becomes impossible to form a coating film, the abrasion resistance of the coating film decreases, and the cost increases.
【００１９】また、本発明の軋み音防止表面処理剤に
は、アクリル−塩化ビニル系塗料用樹脂に、（ａ）平均
粒径が５〜５０μｍの範囲にある球状のウレタン粒子５
〜６０重量％、（ｂ）平均粒径が１〜８μｍの範囲にあ
る樹脂及び／又はゴム系微粒子１〜５０重量％、（ａ）
及び（ｂ）を合計で５〜７０重量％の範囲、特に１０〜
７０重量％含有させることが好ましい。The squeaking noise preventing surface treatment agent of the present invention comprises a resin for acrylic-vinyl chloride paint, (a) spherical urethane particles 5 having an average particle size in the range of 5 to 50 μm.
˜60% by weight, (b) 1 to 50% by weight of resin and / or rubber fine particles having an average particle size in the range of 1 to 8 μm, (a)
And (b) in the range of 5 to 70% by weight, especially 10
It is preferable to contain 70% by weight.
【００２０】含有量が（ａ）及び（ｂ）が合計で５重量
％未満になると、異音防止効果が不十分であり、艶消し
効果も消失する。一方、７０重量％を超えると、塗膜形
成が不可能であったり、塗膜の耐磨耗性が低下すると共
にコスト高となる。この範囲内である限り、軋み音防止
効果が認められるため、艶調整の目的で含有量を調整す
ることができる。When the total content of (a) and (b) is less than 5% by weight, the noise preventing effect is insufficient and the matting effect is also lost. On the other hand, if it exceeds 70% by weight, it becomes impossible to form a coating film, the abrasion resistance of the coating film is lowered, and the cost is increased. As long as it is within this range, the squeaking noise preventing effect is recognized, so that the content can be adjusted for the purpose of adjusting gloss.
【００２１】平均粒径１〜８μｍの範囲にある樹脂及び
／又はゴム系微粒子は、これらを単独で添加しても軋み
音防止効果も艶消し効果も無いが、平均粒径５〜５０μ
ｍの範囲にある球状ウレタン粒子と組み合わせることに
より、艶消し効果を発現させることができる。また、一
般に使用されているシリカなどの艶消し剤と異なり、軋
み音防止特性が悪化することは無い。The resin and / or rubber type fine particles having an average particle size of 1 to 8 μm have neither a squeaking noise preventing effect nor a matting effect even if they are added alone, but the average particle size is 5 to 50 μm.
A matting effect can be exhibited by combining with spherical urethane particles in the range of m. Further, unlike a commonly used matting agent such as silica, the squeaking noise preventing property does not deteriorate.
【００２２】本発明においては、表面の色むらや艶等の
調整が必要な場合には、粒径の異なるウレタン粒子を組
み合わせることが好ましく、またシリカ粒子（平均粒径
１〜８μｍ）を１〜１５重量％の範囲で添加しても良
い。In the present invention, it is preferable to combine urethane particles having different particle diameters when it is necessary to adjust the surface color unevenness and luster, and the silica particles (average particle diameter 1 to 8 μm) are mixed in the range of 1 to 1. You may add in the range of 15 weight%.
【００２３】２種類のウレタン粒子を組み合わせる場合
には、平均粒径が１〜８μｍの球状及び／又は塊状のウ
レタン粒子を固形分として１〜５０重量％と、平均粒径
が５〜５０μｍの範囲にある球状及び／又は塊状のウレ
タン粒子を固形分として１〜４０重量％とを組み合わ
せ、かつ両ウレタンの平均粒径の差が４μｍ以上となる
ように、合計で２〜６０重量％の範囲で含有させること
により、本発明の効果が得られる。When two kinds of urethane particles are combined, spherical and / or lumpy urethane particles having an average particle size of 1 to 8 μm are contained in a solid content of 1 to 50% by weight, and the average particle size is in a range of 5 to 50 μm. In the range of 2 to 60 wt% in total so that the spherical and / or lumpy urethane particles in 1) are combined with 1 to 40 wt% as a solid content and the difference in the average particle size of both urethanes is 4 μm or more. By including it, the effect of the present invention can be obtained.
【００２４】また、主成分であるアクリル−塩化ビニル
系塗料用樹脂としては、現在、車両内装用に使用されて
いる塗料樹脂（例えばクリアコート、カラーコート）を
使用することができ、公知の技術で作製することができ
る。As the acrylic-vinyl chloride-based coating resin, which is the main component, coating resins currently used for vehicle interiors (for example, clear coat and color coat) can be used. Can be made with.
【００２５】本発明の軋み音防止表面処理剤は、アクリ
ル−塩化ビニル系塗料用樹脂に、ウレタン粒子を１〜６
０重量％、又はウレタン粒子を５〜６０重量％、平均粒
径が１〜８μｍの範囲にある樹脂及び／又はゴム系微粒
子１〜５０重量％、合計で５〜７０重量％及び各種添加
剤（安定剤等）を添加し、攪拌した後、三本ロール、ボ
ールミル、ポットミル、スチールミル、ペブルミル、サ
ンドミル及びロールミル等を分散機に投入し、均一に混
合分散させることによって調製することができる。この
際、分散性を高めるため界面活性剤を添加することが好
ましい。次いで、塗布方法に応じて混合分散させた材料
を希釈する。The squeaking noise preventing surface treatment agent of the present invention comprises 1 to 6 urethane particles in a resin for acrylic-vinyl chloride paint.
0% by weight, or 5 to 60% by weight of urethane particles, 1 to 50% by weight of resin and / or rubber fine particles having an average particle size in the range of 1 to 8 μm, 5 to 70% by weight in total and various additives ( It can be prepared by adding a stabilizer, etc.) and stirring, and then introducing into a disperser a three-roll mill, a ball mill, a pot mill, a steel mill, a pebble mill, a sand mill, a roll mill and the like, and uniformly mixing and dispersing them. At this time, it is preferable to add a surfactant in order to enhance the dispersibility. Next, the mixed and dispersed material is diluted according to the coating method.
【００２６】このようにして得られる本発明の軋み音防
止表面処理剤は、表皮材に対しては現状の表面処理剤と
同様の形態で使用することができる。現状の使用形態と
は、内装品の表皮であるＰＶＣシートが製造される工程
において、シート表面にエアスプレー又はエアレススプ
レー或いはグラビアロールにより塗布される。他の部品
及び部位には塗布部の形状や表面形態等により、スプレ
ー塗布、はけ塗り、ローラー塗り及び浸漬塗装をするこ
ともできる。The squeaking noise-preventing surface treating agent of the present invention thus obtained can be used in the same form as the current surface treating agent for the skin material. The current usage pattern is that the surface of the sheet is coated with an air spray, an airless spray, or a gravure roll in the process of manufacturing a PVC sheet that is a skin of an interior product. Spray coating, brush coating, roller coating, and dip coating may be applied to other components and parts depending on the shape and surface form of the coating portion.
【００２７】本発明の軋み音防止表面処理剤の塗布対象
部品としては、インストルメントパネル、ドアトリム、
ピラーガーニッシュ、サンバイザー及びシートレザー等
の表皮の他、メータクラスタやコンソールボックス等の
組付け部品が挙げられる。この塗布対象部品の材質とし
ては、表皮としては特にＰＶＣ表皮やＴＰＯ表皮、他の
部品や部位では各種プラスチック、ゴム、金属及びガラ
ス等が挙げられる。Parts to which the squeaking noise preventing surface treatment agent of the present invention is applied include an instrument panel, a door trim, and
In addition to skins such as pillar garnish, sun visor and seat leather, assembly parts such as meter clusters and console boxes can be mentioned. Examples of the material of the parts to be applied include PVC skins and TPO skins as the skin, and various plastics, rubbers, metals, glass and the like for other parts and parts.
【００２８】[0028]
【作用】次に、本発明の作用を説明する。現状使用され
ている表面処理剤に平均粒径が１〜５０μｍの範囲にあ
る球状及び／又は塊状のウレタン粒子を固形分として２
〜６０重量％の範囲で添加することにより、車両走行時
の定常的な振動により発生する軋み音を防止することが
できる。このことは、球状の軟質粒子を添加することに
より、塗膜表面になだらかな凹凸を形成するため、接触
面での応力集中が起きにくく、相手材表面との引っ掛か
りが発生しにくくなることによると考えられる。Next, the operation of the present invention will be described. Currently used surface-treating agents have spherical and / or lumpy urethane particles having an average particle size in the range of 1 to 50 μm as solid content of 2
By adding in the range of up to 60% by weight, it is possible to prevent the squeaking noise generated by the steady vibration when the vehicle is running. This is because, by adding spherical soft particles, since smooth irregularities are formed on the surface of the coating film, stress concentration is less likely to occur at the contact surface, and it is less likely that a catch with the mating material surface will occur. Conceivable.
【００２９】表面の色むらや艶等の調整が必要な場合に
は、平均粒径が１〜８μｍの範囲にある薄片状フッソ粒
子、不定形ＮＢＲゴム粒子及び不定形ＳＢＲゴム粒子か
ら成る群から選ばれた少なくとも１種を含有させること
が好ましく、また、シリカ粒子（平均粒径１〜８μｍ）
を１〜１５重量％添加しても良い。When it is necessary to adjust the surface color unevenness or luster, the flaky fluorine particles having an average particle size in the range of 1 to 8 μm, amorphous NBR rubber particles and amorphous SBR rubber particles are used. It is preferable to contain at least one selected, and silica particles (average particle size 1 to 8 μm)
1 to 15% by weight may be added.
【００３０】この塗膜層は現在行われているシートの表
面処理工程において形成されるため、新規工程の導入が
不要であり、従来の不織布貼り付け工程を省略すること
ができる。更に、現状使用されている表面処理剤に軋み
音防止機能を付与したことにより外観品質を損なわない
ので、人目に触れる部分にも適用することができる。ま
た、シート全体に塗膜層が形成されることからインスト
ルメントパネル、ドアトリム、ピラーガーニッシュ、サ
ンバイザー及びシートレザー等とそれらに組み付けられ
ている部品、及びそれらと干渉する部品との軋み音も低
減することができる。Since this coating layer is formed in the sheet surface treatment process which is currently performed, it is not necessary to introduce a new process, and the conventional non-woven fabric attaching process can be omitted. Furthermore, since the squeaking noise preventing function is added to the currently used surface treatment agent, the appearance quality is not impaired, so that it can also be applied to a portion that is visible to the human eye. In addition, since a coating layer is formed on the entire seat, squeaking noises of instrument panels, door trims, pillar garnishes, sun visors, seat leathers, etc. and the parts assembled with them, and parts that interfere with them are also reduced. can do.
【００３１】[0031]
【実施例】以下、本発明を実施例によって更に詳細に説
明するが、本発明はこれによって限定されるものではな
い。EXAMPLES The present invention will now be described in more detail by way of examples, which should not be construed as limiting the invention.
【００３２】実施例１ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子（平
均粒径１５μｍ、真球状）を、固形分として４０重量％
添加した後、攪拌した。次いで、サンドグラインドミル
にて混合分散させた後、希釈剤で５０％に希釈し、実施
例１の軋み音防止表面処理剤を調製した。Example 1 Urethane particles (average particle size: 15 μm, true sphere) were added to an acrylic-vinyl chloride coating resin at 40% by weight as a solid content.
After the addition, it was stirred. Then, after mixing and dispersing with a sand grind mill, it was diluted to 50% with a diluent to prepare a squeaking noise preventing surface treatment agent of Example 1.
【００３３】実施例２ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子の他
に、シリカ粒子（平均粒径３μｍ、球状）を３０重量％
添加した他は、実施例１と全く同様にして実施例２の軋
み音防止表面処理剤を調製した。Example 2 In addition to urethane particles, 30% by weight of silica particles (average particle size 3 μm, spherical) was added to the acrylic-vinyl chloride-based coating resin.
The squeaking noise preventing surface treating agent of Example 2 was prepared in exactly the same manner as in Example 1 except that the additives were added.
【００３４】実施例３ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子Ａ
（平均粒径１５μｍ、真球状）を３０重量％、ウレタン
粒子Ｂ（平均粒径５μｍ、球状）を３０重量％添加した
他は、実施例１と全く同様にして実施例３の軋み音防止
表面処理剤を調製した。Example 3 Urethane particles A were added to an acrylic-vinyl chloride paint resin.
30% by weight (average particle size 15 μm, true sphere) and 30% by weight of urethane particles B (average particle size 5 μm, sphere) were added in exactly the same manner as in Example 1, and the squeaking noise prevention surface of Example 3 was added. A treating agent was prepared.
【００３５】実施例４ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子Ａ
（平均粒径１５μｍ、真球状）を２５重量％、ウレタン
粒子Ｂ（平均粒径５μｍ、球状）を２５重量％添加し、
更にシリカ粒子（平均粒径３μｍ）を７重量％添加した
他は、実施例１と全く同様にして実施例４の軋み音防止
表面処理剤を調製した。Example 4 Urethane particles A were added to an acrylic-vinyl chloride paint resin.
25% by weight (average particle size 15 μm, true sphere) and 25% by weight of urethane particles B (average particle size 5 μm, sphere) were added,
Further, a squeaking noise preventing surface treating agent of Example 4 was prepared in exactly the same manner as in Example 1 except that 7% by weight of silica particles (average particle diameter 3 μm) was added.
【００３６】実施例５ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子（平
均粒径１５μｍ、真球状）を４０重量％添加した他は、
実施例１と全く同様にして実施例５の軋み音防止表面処
理剤を調製した。Example 5 40% by weight of urethane particles (average particle size 15 μm, true sphere) were added to the acrylic-vinyl chloride coating resin, except that 40% by weight was added.
The squeaking noise preventing surface treating agent of Example 5 was prepared in exactly the same manner as in Example 1.
【００３７】比較例１ ウレタン粒子を添加しなかった他は、実施例１と全く同
様にして比較例１の軋み音防止表面処理剤を調製した。Comparative Example 1 A squeaking noise preventing surface treating agent of Comparative Example 1 was prepared in exactly the same manner as in Example 1 except that urethane particles were not added.
【００３８】比較例２ ウレタン粒子に代えてシリカ粒子（平均粒径５．０μ
ｍ、真球状）を６０重量％添加した他は、実施例１と全
く同様にして比較例２の軋み音防止表面処理剤を調製し
た。Comparative Example 2 Instead of urethane particles, silica particles (average particle size 5.0 μ
m, true sphere) was added in the same manner as in Example 1 except that 60% by weight was added to prepare a squeaking noise preventing surface treating agent of Comparative Example 2.
【００３９】比較例３ ウレタン粒子に代えてアクリル粒子（平均粒径５．０μ
ｍ、真球状）を６０重量％添加した他は、実施例１と全
く同様にして比較例３の軋み音防止表面処理剤を調製し
た。Comparative Example 3 Instead of urethane particles, acrylic particles (average particle size 5.0 μm
m, true sphere) was added in the same manner as in Example 1 except that 60% by weight was added to prepare the squeaking noise preventing surface treatment agent of Comparative Example 3.
【００４０】比較例４ ウレタン粒子に代えてナイロン粒子（平均粒径１０μ
ｍ、不定形）を６０重量％添加した他は、実施例１と全
く同様にして比較例４の軋み音防止表面処理剤を調製し
た。Comparative Example 4 Nylon particles (average particle size: 10 μm) were used instead of the urethane particles.
m, amorphous) was added in the same manner as in Example 1 except that 60% by weight was added to prepare a squeaking noise preventing surface treatment agent of Comparative Example 4.
【００４１】比較例５ ウレタン粒子に代えてフッ素粒子（平均粒径１０μｍ、
塊状）を６０重量％添加した他は、実施例１と全く同様
にして比較例５の軋み音防止表面処理剤を調製した。Comparative Example 5 Instead of urethane particles, fluorine particles (average particle size 10 μm,
A squeaking noise preventing surface treating agent of Comparative Example 5 was prepared in exactly the same manner as in Example 1 except that 60% by weight of (lumps) was added.
【００４２】比較例６ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子（平
均粒径３μｍ、不定形）を６０重量％添加した他は、実
施例１と全く同様にして比較例６の軋み音防止表面処理
剤を調製した。Comparative Example 6 The squeaking noise of Comparative Example 6 was completely the same as in Example 1 except that 60% by weight of urethane particles (average particle size: 3 μm, amorphous) were added to the acrylic-vinyl chloride coating resin. A surface treatment agent was prepared.
【００４３】比較例７ アクリル−塩化ビニル系塗料用樹脂にウレタン粒子（平
均粒径６０μｍ、球状）を６０重量％添加した他は、実
施例１と全く同様にして比較例７の軋み音防止表面処理
剤を調製した。Comparative Example 7 The squeaking noise preventive surface of Comparative Example 7 was carried out in the same manner as in Example 1 except that 60% by weight of urethane particles (average particle size 60 μm, spherical) were added to the acrylic-vinyl chloride coating resin. A treating agent was prepared.
【００４４】比較例８ 従来から用いている不織布を比較例８とした。Comparative Example 8 A conventionally used nonwoven fabric is referred to as Comparative Example 8.
【００４５】試験結果 実施例１〜５及び比較例１〜８で得られた各表面処理剤
の軋み音防止効果を比較するため、現行の表面未処理Ｐ
ＶＣシートに、各表面処理剤を塗布し塗膜を硬化させて
試験用シートを作製した。このようにして得られたシー
トの相手材として、一般的な自動車内装用ＰＶＣシート
を用い、往復動による摩擦試験を行い、摩擦特性の評価
及び軋み音発生の有無を確認した。また、塗布した後の
６０度表面光沢度をグロスメーターにより測定した。そ
の結果を表１に示す。Test Results In order to compare the squeaking noise preventing effect of each surface treatment agent obtained in Examples 1 to 5 and Comparative Examples 1 to 8, the current surface untreated P
Each surface treatment agent was applied to the VC sheet and the coating film was cured to prepare a test sheet. A general PVC sheet for automobile interiors was used as the mating material of the sheet thus obtained, and a friction test by reciprocating motion was performed to evaluate the friction characteristics and confirm whether or not a squeaking noise was generated. Further, the 60-degree surface glossiness after coating was measured with a gloss meter. Table 1 shows the results.
【００４６】[0046]
【表１】 [Table 1]
【００４７】表１に示すように、実施例で得られた塗料
は音の発生が無く、また動摩擦係数の幅も現在軋み音対
策として用いられている不織布並に小さくなっており、
軋み音防止効果があることが判る。また、艶消し効果も
確認された。これに対し、比較例１で得られた塗料では
軋み音に対しては有効であるが、艶消し効果が無いため
商品性に劣る。比較例２〜４及び６においては、艶消し
効果は付与されているが動摩擦係数の幅が大きくなり軋
み音が発生している。比較例５は艶消し度合いも小さ
い。As shown in Table 1, the paints obtained in the examples did not generate any noise, and the width of the coefficient of dynamic friction was as small as the non-woven fabric currently used as a measure against squeaking noise.
It can be seen that it has a squeaking noise prevention effect. In addition, a matting effect was also confirmed. On the other hand, the paint obtained in Comparative Example 1 is effective against squeaking noises, but lacks in matting effect and is inferior in marketability. In Comparative Examples 2 to 4 and 6, although the matting effect is imparted, the range of the dynamic friction coefficient becomes large and a squeaking noise is generated. Comparative Example 5 also has a small matte degree.
【００４８】実施例６ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として２０重量
％及び市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として４０重量％を添加し、攪拌した。次
いで、サンドグラインドミルにて混合分散させた後、希
釈剤（トルエン、キシレン、ＭＥＫ）にて、１００：２
００に希釈して、実施例６の軋み音防止表面処理剤を調
製した。Example 6 20% by weight of urethane particles (average particle size: 15 μm, true sphere) as solid content with respect to 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65) and commercially available Frozen powder of NBR rubber (average particle size 5μ
40% by weight of m) was added as a solid content and stirred. Then, after mixing and dispersing with a sand grind mill, 100: 2 with a diluent (toluene, xylene, MEK).
It was diluted to 00 to prepare the squeaking noise preventing surface treating agent of Example 6.
【００４９】実施例７ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販のＳＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を用いた他は、実施例６と全く同様にして実施例７
の軋み音防止表面処理剤を調製した。Example 7 Instead of the commercially available freeze-dried particles of NBR rubber (average particle size 5 μm), the freeze-pulverized particles of commercially available SBR rubber (average particle size 5 μm)
Example 7 exactly the same as Example 6 except that m) was used.
A squeaking noise preventing surface treatment agent was prepared.
【００５０】実施例８ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状微粒子（平均粒径５μｍ）を用いた
他は、実施例６と全く同様にして実施例８の軋み音防止
表面処理剤を調製した。Example 8 Example 8 was carried out in the same manner as in Example 6 except that commercially available flaky fine particles (average particle size 5 μm) were used instead of the commercially available frozen NBR rubber particles (average particle size 5 μm). No. 8 squeaking noise surface treatment agent was prepared.
【００５１】実施例９ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として４０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として１０重量％を添加した他は、実施例
６と全く同様にして実施例９の軋み音防止表面処理剤を
調製した。Example 9 40% by weight of urethane particles (average particle size 15 μm, true spherical shape) as solid content based on 100% by weight of acrylic-vinyl chloride type coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
A squeaking noise preventing surface treating agent of Example 9 was prepared in the same manner as in Example 6 except that 10% by weight of m) was added as a solid content.
【００５２】実施例１０ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販のＳＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を用いた他は、実施例９と全く同様にして実施例１
０の軋み音防止表面処理剤を調製した。Example 10 Instead of the commercially available freeze-dried particles of NBR rubber (average particle size 5 μm), freeze-dried particles of commercially available SBR rubber (average particle size 5 μm)
Example 1 exactly the same as Example 9 except that m) was used.
No squeaking noise surface treatment agent was prepared.
【００５３】実施例１１ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状微粒子（平均粒径５μｍ）を用いた
他は、実施例９と全く同様にして実施例１１の軋み音防
止表面処理剤を調製した。Example 11 An example was carried out in the same manner as in Example 9 except that commercially available flaky fine particles (average particle size 5 μm) were used in place of the freeze-ground particles (average particle size 5 μm) of commercially available NBR rubber. Eleven anti-squeaking surface treatment agents were prepared.
【００５４】実施例１２ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として４０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として１０重量％及びダイナミルにより分
散させたシリカ粒子（平均粒径３μｍ、不定形）を固形
分として１１重量％を添加した他は、実施例６と全く同
様にして実施例１２の軋み音防止表面処理剤を調製し
た。Example 12 40% by weight of urethane particles (average particle diameter 15 μm, true sphere) as solid content based on 100% by weight of acrylic-vinyl chloride type coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
Example 12 was carried out in the same manner as in Example 6 except that 10% by weight of m) was added as solid content and 11% by weight of silica particles (average particle size 3 μm, amorphous) dispersed by Dynamill was added as solid content. A squeaking noise preventing surface treatment agent was prepared.
【００５５】実施例１３ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販のＳＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を用いた他は、実施例１２と全く同様にして実施例
１３の軋み音防止表面処理剤を調製した。Example 13 Instead of the commercially available freeze-dried particles of NBR rubber (mean particle size 5 μm), the freeze-milled particles of commercially available SBR rubber (average particle size 5 μm)
The creaking noise preventing surface treating agent of Example 13 was prepared in exactly the same manner as in Example 12 except that m) was used.
【００５６】実施例１４ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状フッソ微粒子（平均粒径５μｍ）を
用いた他は、実施例１２と全く同様にして実施例１４の
軋み音防止表面処理剤を調製した。Example 14 Example 14 was carried out in the same manner as in Example 12 except that commercially available flaky fluorine-containing fine particles (average particle size 5 μm) were used in place of the commercially available freeze-dried particles of NBR rubber (average particle size 5 μm). The anti-squealing surface treatment agent of Example 14 was prepared.
【００５７】実施例１５ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として３０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として１０重量％及び市販のＳＢＲゴムの
凍結粉砕粒子（平均粒径５μｍ）を固形分として１０重
量％を添加した他は、実施例６と全く同様にして実施例
１５の軋み音防止表面処理剤を調製した。Example 15 30% by weight of urethane particles (average particle size 15 μm, true sphere) as solid content based on 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
m) as a solid content and 10% by weight as freeze-dried particles of commercially available SBR rubber (average particle size 5 μm) as a solid content were added in an amount of 10% by weight in the same manner as in Example 15. An anti-sound surface treatment agent was prepared.
【００５８】実施例１６ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状フッソ微粒子（平均粒径５μｍ）を
用いた他は、実施例１５と全く同様にして実施例１６の
軋み音防止表面処理剤を調製した。Example 16 Example 16 was carried out in the same manner as in Example 15, except that commercially available flaky fluorine fine particles (average particle size 5 μm) were used in place of the freeze-ground particles (average particle size 5 μm) of commercially available NBR rubber. The anti-squealing surface treating agent of Example 16 was prepared.
【００５９】実施例１７ 市販のＳＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状フッソ微粒子（平均粒径５μｍ）を
用いた他は、実施例１５と全く同様にして実施例１７の
軋み音防止表面処理剤を調製した。Example 17 The same procedure as in Example 15 was carried out except that commercially available flaky fine particles (average particle size: 5 μm) were used instead of the freeze-ground particles (average particle size: 5 μm) of commercially available SBR rubber. The anti-squealing surface treatment agent of Example 17 was prepared.
【００６０】実施例１８ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として３０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として１０重量％、市販のＳＢＲゴムの凍
結粉砕粒子（平均粒径５μｍ）を固形分として１０重量
％及びダイナミルにより分散させたシリカ粒子（平均粒
径３μｍ、不定形）を固形分として７重量％を添加した
他は、実施例６と全く同様にして実施例１８の軋み音防
止表面処理剤を調製した。Example 18 Urethane particles (average particle size 15 μm, true sphere) as solid content of 30% by weight based on 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
m) as a solid content, 10 wt% of commercially available SBR rubber freeze-pulverized particles (average particle size 5 μm) as a solid content, and silica particles (average particle size 3 μm, amorphous) dispersed by a dynamill are solid. The squeaking noise preventing surface treating agent of Example 18 was prepared in the same manner as in Example 6 except that 7% by weight was added as a component.
【００６１】実施例１９ 市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状フッソ微粒子（平均粒径５μｍ）を
用いた他は、実施例１８と全く同様にして実施例１９の
軋み音防止表面処理剤を調製した。Example 19 Example 19 was carried out in the same manner as in Example 18 except that commercially available flaky fluorine fine particles (average particle size 5 μm) were used instead of the commercially available freeze-dried particles of NBR rubber (average particle size 5 μm). The anti-squealing surface treatment agent of Example 19 was prepared.
【００６２】実施例２０ 市販のＳＢＲゴムの凍結粉砕粒子（平均粒径５μｍ）に
代えて市販の薄片状フッソ微粒子（平均粒径５μｍ）を
用いた他は、実施例１８と全く同様にして実施例２０の
軋み音防止表面処理剤を調製した。Example 20 Example 20 was carried out in the same manner as in Example 18 except that commercially available flaky fluorine fine particles (average particle size 5 μm) were used in place of the commercially available freeze-dried particles of SBR rubber (average particle size 5 μm). The anti-squealing surface treatment agent of Example 20 was prepared.
【００６３】実施例２１ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として２５重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として８重量％、市販のＳＢＲゴムの凍結
粉砕粒子（平均粒径５μｍ）を固形分として８重量％及
び市販の薄片状フッソ微粒子（平均粒径５μｍ）を固形
分として８重量％を添加した他は、実施例６と全く同様
にして実施例２１の軋み音防止表面処理剤を調製した。Example 21 25% by weight of urethane particles (average particle size 15 μm, true sphere) as solid content with respect to 100% by weight of acrylic-vinyl chloride type coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
m) as a solid content, 8% by weight of commercially available SBR rubber freeze-ground particles (average particle size 5 μm) as a solid content, and commercially available flaky fluorine-containing fine particles (average particle size 5 μm) as a solid content of 8% by weight. The squeaking noise preventive surface treating agent of Example 21 was prepared in exactly the same manner as in Example 6 except that the addition of C.
【００６４】実施例２２ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として２５重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として８重量％、市販のＳＢＲゴムの凍結
粉砕粒子（平均粒径５μｍ）を固形分として８重量％、
市販の薄片状フッソ微粒子（平均粒径５μｍ）を固形分
として８重量％及びダイナミルにより分散させたシリカ
粒子（平均粒径３μｍ、不定形）を固形分として７重量
％を添加した他は、実施例６と全く同様にして実施例２
２の軋み音防止表面処理剤を調製した。Example 22 25% by weight of urethane particles (average particle size 15 μm, true spherical shape) as solid content with respect to 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
m) as solid content 8% by weight, commercially available SBR rubber freeze-ground particles (average particle size 5 μm) as solid content 8% by weight,
Other than adding 8% by weight of commercially available flaky fluorine-containing fine particles (average particle size 5 μm) as solid content and 7% by weight of silica particles (average particle size 3 μm, amorphous) dispersed by Dynamill as solid content Example 2 Exactly the same as Example 6
No. 2 squeaking noise surface treatment agent was prepared.
【００６５】比較例９ ウレタン粒子及びＮＢＲゴムの凍結粉砕粒子を添加しな
かった他は、実施例６と全く同様にして比較例９の軋み
音防止表面処理剤を調製した。Comparative Example 9 A creaking noise-preventing surface treating agent of Comparative Example 9 was prepared in exactly the same manner as in Example 6 except that urethane particles and freeze-dried particles of NBR rubber were not added.
【００６６】比較例１０ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ダイナミルに
より分散させたシリカ粒子（平均粒径３μｍ、不定形）
を固形分として２０重量％を添加した他は、実施例６と
全く同様にして比較例１０の軋み音防止表面処理剤を調
製した。Comparative Example 10 Silica particles (average particle size: 3 μm, irregular shape) dispersed by Dynamill with respect to 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65).
A squeaking noise preventing surface treating agent of Comparative Example 10 was prepared in the same manner as in Example 6 except that 20% by weight was added as a solid content.
【００６７】比較例１１ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として７０重量
％を添加した他は、実施例６と全く同様にして比較例１
１の軋み音防止表面処理剤を調製した。Comparative Example 11 Urethane particles (average particle size: 15 μm, true spherical shape) as solid content of 70% by weight were added to 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65). Comparative Example 1 in the same manner as in Example 6 except that
No. 1 squeaking noise surface treatment agent was prepared.
【００６８】得られた表面処理剤について現行の表面未
処理ＰＶＣシートに塗布し試験用シートを作製し、摩擦
試験に供したところ試験中に粉落ちがし、実用に耐える
ものではなかった。The obtained surface treating agent was applied to a current surface-untreated PVC sheet to prepare a test sheet, which was subjected to a friction test. As a result, powder fell off during the test and it was not practical.
【００６９】比較例１２ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径３μｍ、真球状）を固形分として６０重量％
を添加した他は、実施例６と全く同様にして比較例１２
の軋み音防止表面処理剤を調製した。Comparative Example 12 Acrylic-vinyl chloride coating resin 100% by weight (acrylic: 35, vinyl chloride: 65), urethane particles (average particle size 3 μm, true sphere) as solid content of 60% by weight.
Comparative Example 12 in exactly the same manner as in Example 6 except that
A squeaking noise preventing surface treatment agent was prepared.
【００７０】比較例１３ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として３重量％
を添加した他は、実施例６と全く同様にして比較例１３
の軋み音防止表面処理剤を調製した。Comparative Example 13 3% by weight of urethane particles (average particle size 15 μm, true sphere) as solid content based on 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65).
Comparative Example 13 was carried out in the same manner as in Example 6 except that
A squeaking noise preventing surface treatment agent was prepared.
【００７１】比較例１４ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、不定形）を固形分として５０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として８重量％、市販のＳＢＲゴムの凍結
粉砕粒子（平均粒径５μｍ）を固形分として８重量％、
市販の薄片状フッソ微粒子（平均粒径５μｍ）を固形分
として８重量％を添加した他は、実施例６と全く同様に
して比較例１４の軋み音防止表面処理剤を調製した。Comparative Example 14 Acrylic-vinyl chloride coating resin 100% by weight (acrylic: 35, vinyl chloride: 65), urethane particles (average particle size 15 μm, amorphous) as solid content 50% by weight, commercially available Frozen powder of NBR rubber (average particle size 5μ
m) as solid content 8% by weight, commercially available SBR rubber freeze-ground particles (average particle size 5 μm) as solid content 8% by weight,
A squeaking noise preventing surface treating agent of Comparative Example 14 was prepared in exactly the same manner as in Example 6 except that 8% by weight of commercially available flaky fluorine-containing fine particles (average particle diameter 5 μm) was added as a solid content.
【００７２】得られた表面処理剤について現行の表面未
処理ＰＶＣシートに塗布し試験用シートを作製し、摩擦
試験に供したところ試験中に粉落ちがし、実用に耐える
ものではなかった。The obtained surface treating agent was applied to a current surface-untreated PVC sheet to prepare a test sheet, which was then subjected to a friction test. As a result, powder fell off during the test and it was not practical.
【００７３】比較例１５ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として４０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として３０重量％を添加した他は、実施例
６と全く同様にして比較例１５の軋み音防止表面処理剤
を調製した。Comparative Example 15 40% by weight of urethane particles (average particle size 15 μm, true spherical shape) as solid content based on 100% by weight of acrylic-vinyl chloride type coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
A squeaking noise preventing surface treating agent of Comparative Example 15 was prepared in exactly the same manner as in Example 6 except that 30% by weight of m) was added as a solid content.
【００７４】得られた表面処理剤について現行の表面未
処理ＰＶＣシートに塗布し試験用シートを作製し、摩擦
試験に供したところ試験中に粉落ちがし、実用に耐える
ものではなかった。The obtained surface-treating agent was applied to a current surface-untreated PVC sheet to prepare a test sheet, which was subjected to a friction test. As a result, powder fell off during the test and it was not practical.
【００７５】比較例１６ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として４０重量
％及び市販のＳＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として３０重量％を添加した他は、実施例
１と全く同様にして比較例１６の軋み音防止表面処理剤
を調製した。Comparative Example 16 Urethane particles (average particle size 15 μm, true sphere) as solid content of 40% by weight and commercially available with respect to 100% by weight of acrylic-vinyl chloride type coating resin (acrylic: 35, vinyl chloride: 65). SBR rubber frozen pulverized particles (average particle size 5μ
A squeaking noise preventing surface treatment agent of Comparative Example 16 was prepared in exactly the same manner as in Example 1 except that 30% by weight of m) was added as a solid content.
【００７６】得られた表面処理剤について現行の表面未
処理ＰＶＣシートに塗布し試験用シートを作製し、摩擦
試験に供したところ試験中に粉落ちがし、実用に耐える
ものではなかった。The surface treating agent thus obtained was applied to a current surface untreated PVC sheet to prepare a test sheet, which was then subjected to a friction test. As a result, powder fell off during the test and it was not practical.
【００７７】比較例１７ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として４０重量
％及び市販の薄片状フッソ微粒子（平均粒径５μｍ）を
固形分として３０重量％を添加した他は、実施例６と全
く同様にして比較例１７の軋み音防止表面処理剤を調製
した。Comparative Example 17 Urethane particles (average particle size 15 μm, true spherical shape) as solid content of 40% by weight and commercially available with respect to 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65). A creaking noise preventing surface treating agent of Comparative Example 17 was prepared in exactly the same manner as in Example 6 except that 30% by weight of the flaky fluorine-containing fine particles (average particle diameter: 5 μm) as a solid content was added.
【００７８】得られた表面処理剤について現行の表面未
処理ＰＶＣシートに塗布し試験用シートを作製し、摩擦
試験に供したところ試験中に粉落ちがし、実用に耐える
ものではなかった。The obtained surface treatment agent was applied to a current surface-untreated PVC sheet to prepare a test sheet, which was subjected to a friction test. As a result, powder fell off during the test and it was not practical.
【００７９】比較例１８ アクリル−塩化ビニル系塗料用樹脂１００重量％（アク
リル：３５、塩化ビニル：６５）に対し、ウレタン粒子
（平均粒径１５μｍ、真球状）を固形分として３０重量
％、市販のＮＢＲゴムの凍結粉砕粒子（平均粒径５μ
ｍ）を固形分として１０重量％、市販のＳＢＲゴムの凍
結粉砕粒子（平均粒径５μｍ）を固形分として１０重量
％、市販の薄片状フッソ微粒子（平均粒径５μｍ）を固
形分として１０重量％及びダイナミルにより分散させた
シリカ粒子（平均粒径３μｍ、不定形）を固形分として
２０重量％を添加した他は、実施例６と全く同様にして
比較例１８の軋み音防止表面処理剤を調製した。Comparative Example 18 30% by weight of urethane particles (average particle size: 15 μm, true sphere) as solid content based on 100% by weight of acrylic-vinyl chloride coating resin (acrylic: 35, vinyl chloride: 65), commercially available Frozen powder of NBR rubber (average particle size 5μ
m) as a solid content, 10% by weight of commercially available SBR rubber frozen and pulverized particles (average particle size 5 μm) as a solid content, and commercially available flaky fluorine fine particles (average particle size 5 μm) as a solid content of 10% by weight. % And silica particles dispersed by Dynamill (average particle size 3 μm, amorphous) were added in an amount of 20% by weight as a solid content, and the squeaking noise preventing surface treating agent of Comparative Example 18 was prepared in the same manner as in Example 6. Prepared.
【００８０】試験結果 実施例６〜２２及び比較例９〜１８の各表面処理剤の軋
み音防止効果を比較するため、現行の表面未処理ＰＶＣ
シートに、各表面処理剤を塗布し塗膜を硬化させて試験
用シートを作製した。このようにして得られたシートの
相手材として、一般的な自動車内装用ＰＶＣシートを用
い、往復動による摩擦試験を行い、摩擦特性の評価及び
軋み音発生の有無を確認した。また、塗布後の６０度表
面光沢度をグロスメーターにより測定した。その結果を
表２に示す。Test Results In order to compare the squeaking noise preventing effects of the surface treating agents of Examples 6 to 22 and Comparative Examples 9 to 18, the current surface-untreated PVC is used.
Each surface treatment agent was applied to the sheet and the coating film was cured to prepare a test sheet. A general PVC sheet for automobile interiors was used as the mating material of the sheet thus obtained, and a friction test by reciprocating motion was performed to evaluate the friction characteristics and confirm whether or not a squeaking noise was generated. Further, the 60-degree surface glossiness after coating was measured with a gloss meter. The results are shown in Table 2.
【００８１】[0081]
【表２】 [Table 2]
【００８２】表２に示すように、実施例で得られた塗料
は音の発生が無く、また動摩擦係数の幅も現在軋み音対
策に用いている不織布並に小さくなっており、軋み音防
止効果があることが判る。また艶消し効果も確認され
た。これに対し、比較例９及び１２で得られた塗料では
軋み音に対しては有効であるが、艶消し効果が無いため
商品性に劣る。比較例１０及び１８で得られた塗料では
艶消し効果は付与されているが、動摩擦係数の幅が大き
くなり軋み音が発生している。比較例１３は艶消し度合
いが小さい。As shown in Table 2, the paints obtained in the examples did not generate any sound, and the width of the dynamic friction coefficient was as small as that of the non-woven fabric which is currently used for the squeaking noise control. I know that there is. A matting effect was also confirmed. On the other hand, the paints obtained in Comparative Examples 9 and 12 are effective against the squeaking noise, but have no matte effect and are inferior in commercial properties. The paints obtained in Comparative Examples 10 and 18 have a matte effect, but the range of the dynamic friction coefficient is large and a squeaking noise is generated. Comparative Example 13 has a small matte degree.
【００８３】[0083]
【発明の効果】本発明の軋み音防止表面処理剤は、アク
リル−塩化ビニル系塗料用樹脂に球状及び／又は塊状で
平均粒径が１〜５０μｍの範囲にあるウレタン粒子を２
〜６０重量％の範囲で添加することにより得られ、これ
を塗布することにより部品どうしの接触による軋み音を
有効に防止することができるという効果が得られる。EFFECTS OF THE INVENTION The squeaking noise preventing surface treatment agent of the present invention comprises 2 parts of urethane particles having a spherical and / or lump shape and an average particle size in the range of 1 to 50 μm in an acrylic-vinyl chloride coating resin.
It is obtained by adding in an amount of up to 60% by weight, and by applying this, it is possible to effectively prevent the squeaking noise due to the contact between parts.
【００８４】また、本発明の表面処理剤は、現在行われ
ている表面処理工程において原反シート全面に塗布する
ことができるので、新規工程の導入及び不織布の貼り付
けが不要となり、作業工程の簡略化が図られる。更に、
ドアトリムとインスト端部或いはシートサイドといった
人目につく部分にも適用することができるという効果が
得られる。加えて、単発音に対してもアクリル−塩化ビ
ニル系塗料用樹脂がウレタン樹脂より、優れるという特
性はこのようなウレタンビーズを添加しても保持したま
まであった。Further, since the surface treatment agent of the present invention can be applied to the entire surface of the raw sheet in the surface treatment step which is currently performed, the introduction of a new step and the attachment of the non-woven fabric become unnecessary, and Simplification is achieved. Furthermore,
The effect that it can be applied to parts that are noticeable such as the door trim and the instrument end or the seat side is obtained. In addition, the characteristic that the acrylic-vinyl chloride-based coating resin is superior to the urethane resin even in the case of a single tone was maintained even when such urethane beads were added.
【図１】試験例で用いた往復運動による摩擦試験の概要
を示す図である。FIG. 1 is a diagram showing an outline of a friction test by reciprocating motion used in a test example.
【図２】図１に示した摩擦試験により得られた時間に対
する摩擦係数の変化を示す図である。FIG. 2 is a diagram showing a change in a friction coefficient with respect to time obtained by the friction test shown in FIG.
１ 被試験体 ２ 被試験体 1 DUT 2 DUT
───────────────────────────────────────────────────── フロントページの続き (72)発明者 市川 聡 神奈川県横浜市神奈川区宝町２番地 日産 自動車株式会社内 (72)発明者 松谷 久仁子 神奈川県横浜市神奈川区宝町２番地 日産 自動車株式会社内 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Satoshi Ichikawa 2 Takara-cho, Kanagawa-ku, Yokohama, Kanagawa Nissan Motor Co., Ltd. (72) Kuniko Matsutani 2 Takara-cho, Kanagawa-ku, Yokohama, Kanagawa Nissan Motor Co., Ltd.
Claims (5)
平均粒径が１〜５０μｍの範囲にある球状及び／又は塊
状のウレタン粒子を固形分として２〜６０重量％の範囲
で含有させてなることを特徴とする軋み音防止表面処理
剤。1. An acrylic-vinyl chloride coating resin,
A squeaking noise preventing surface treatment agent comprising spherical and / or lumpy urethane particles having an average particle size in the range of 1 to 50 μm in a range of 2 to 60% by weight as a solid content.
（ａ）平均粒径が５〜５０μｍの範囲にある球状のウレ
タン粒子５〜６０重量％、（ｂ）平均粒径が１〜８μｍ
の範囲にある樹脂及び／又はゴム系微粒子１〜５０重量
％、（ａ）及び（ｂ）を合計で５〜７０重量％含有させ
てなることを特徴とする軋み音防止表面処理剤。2. A resin for acrylic-vinyl chloride paint,
(A) 5 to 60% by weight of spherical urethane particles having an average particle size of 5 to 50 μm, (b) an average particle size of 1 to 8 μm
1 to 50% by weight of the resin and / or rubber fine particles in the range of 5 to 70% by weight of (a) and (b) in total, and a squeaking noise preventing surface treatment agent.
及び／又は塊状のウレタン粒子を固形分として１〜５０
重量％と、平均粒径が５〜５０μｍの範囲にある球状及
び／又は塊状のウレタン粒子を固形分として１〜４０重
量％とを組み合わせ、かつ両ウレタン粒子の平均粒径の
差が４μｍ以上となるように、合計で２〜６０重量％含
有させてなることを特徴とする請求項１記載の軋み音防
止表面処理剤。3. Spherical and / or lumpy urethane particles having an average particle size in the range of 1 to 8 μm as a solid content of 1 to 50.
1% to 40% by weight of spherical and / or agglomerated urethane particles having a mean particle size in the range of 5 to 50 μm as a solid content is combined, and the difference in the mean particle size of both urethane particles is 4 μm or more. 2. The squeaking noise preventing surface treatment agent according to claim 1, wherein the surface treatment agent comprises 2 to 60% by weight in total.
範囲にあるシリカ粒子を１〜１５重量％含有させてなる
こと特徴とする請求項１又は２記載の軋み音防止表面処
理剤。4. The squeaking noise-preventing surface-treating agent according to claim 1, which comprises 1 to 15% by weight of silica particles having an average particle diameter in the range of 1 to 8 μm as a matting agent.
ＮＢＲゴム粒子及び不定形ＳＢＲゴム粒子から成る群か
ら選ばれた少なくとも１種であることを特徴とする請求
項２記載の軋み音防止表面処理剤。5. The squeaking sound according to claim 2, wherein the component (b) is at least one selected from the group consisting of flaky fluorine particles, amorphous NBR rubber particles, and amorphous SBR rubber particles. Preventive surface treatment agent.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7141650A JPH08234764A (en) | 1994-12-27 | 1995-06-08 | Squeaking sound preventive surface treating agent |
| US08/928,584 US5770647A (en) | 1994-12-27 | 1997-09-12 | Friction sound-preventing surface-treating agent |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6-325649 | 1994-12-27 | ||
| JP32564994 | 1994-12-27 | ||
| JP7141650A JPH08234764A (en) | 1994-12-27 | 1995-06-08 | Squeaking sound preventive surface treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08234764A true JPH08234764A (en) | 1996-09-13 |
Family
ID=26473842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7141650A Pending JPH08234764A (en) | 1994-12-27 | 1995-06-08 | Squeaking sound preventive surface treating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08234764A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2014168078A1 (en) * | 2013-04-08 | 2017-02-16 | テクノポリマー株式会社 | Contact component and structure including the contact component |
-
1995
- 1995-06-08 JP JP7141650A patent/JPH08234764A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2014168078A1 (en) * | 2013-04-08 | 2017-02-16 | テクノポリマー株式会社 | Contact component and structure including the contact component |
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