JPH08143432A - Shampoo composition - Google Patents
Shampoo compositionInfo
- Publication number
- JPH08143432A JPH08143432A JP30980694A JP30980694A JPH08143432A JP H08143432 A JPH08143432 A JP H08143432A JP 30980694 A JP30980694 A JP 30980694A JP 30980694 A JP30980694 A JP 30980694A JP H08143432 A JPH08143432 A JP H08143432A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- hair
- composition
- washing
- potassium salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、脂肪酸カリウム塩を主
剤としたシヤンプ―組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a shampoo composition containing a fatty acid potassium salt as a main ingredient.
【０００２】[0002]
【従来の技術】脂肪酸カリウム塩を主剤としたシヤンプ
―組成物は、髪や頭皮に温和であり、泡立ちが良く、汚
れ落ちも良いことから、頭髪用として広く利用されてい
るが、難点として、洗髪時に毛髪がからみやすく、きし
み感がある。2. Description of the Related Art A shampoo composition containing a fatty acid potassium salt as a main ingredient is mildly applied to hair and scalp, has a good foaming property, and is excellent in removing stains. Therefore, it is widely used for hair. The hair is easy to get entangled during washing and has a squeaky feeling.
【０００３】この克服のため、両性界面活性剤やカチオ
ン性界面活性剤を添加する試みもあるが、この場合、乳
化安定性が損なわれ、とくに長期保存下で不均一乳化や
沈殿物の生成などの問題を生じやすく、また泡立ちが悪
くなつたり、毛髪がねばついて、さつぱりとした感触が
得られないこともあつた。In order to overcome this, there have been attempts to add an amphoteric surfactant or a cationic surfactant, but in this case, the emulsion stability is impaired, and in particular, the heterogeneous emulsification or the formation of a precipitate during long-term storage. The problem was often caused, and the foaming became poor, and the hair was sticky, and a dry feel could not be obtained.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、このような
事情に鑑み、脂肪酸カリウム塩を主剤としたシヤンプ―
組成物において、保存安定性にすぐれ、泡立ちが良く、
また洗髪時の指滑りが良くて、きしみ感がなく、しかも
洗髪後に毛髪がねばつかず、さつぱりとした感触が得ら
れるシヤンプ―組成物を提供することを目的としてい
る。SUMMARY OF THE INVENTION In view of the above circumstances, the present invention is a sampoo containing a fatty acid potassium salt as a main ingredient.
The composition has excellent storage stability, good foaming,
It is another object of the present invention to provide a shampoo composition which has good finger slip during washing, does not have a squeaky feeling, and does not have sticky hair after washing and has a refreshing feel.
【０００５】[0005]
【課題を解決するための手段】本発明者は、上記の目的
を達成するため、鋭意検討した結果、脂肪酸カリウム塩
を主剤としたシヤンプ―組成物に、特定の両性界面活性
剤およびカチオン性界面活性剤とともに、特定の第３級
アミンを加えることにより、保存安定性にすぐれるとと
もに、泡立ちが良く、また洗髪時の指滑りが良くて、き
しみ感がなく、しかも洗髪後に毛髪がねばつかず、さつ
ぱりとした感触が得られるシヤンプ―組成物が得られる
ことを見い出し、本発明を完成するに至つた。[Means for Solving the Problems] As a result of intensive studies to achieve the above-mentioned object, the present inventor has found that a simpup composition containing a fatty acid potassium salt as a main component has a specific amphoteric surfactant and a cationic surfactant. By adding a specific tertiary amine together with the activator, it has excellent storage stability, good foaming, good finger slip when washing hair, no squeaky feeling, and no sticky hair after washing. It was found that a shampu composition having a refreshing feel can be obtained, and the present invention has been completed.
【０００６】すなわち、本発明は、脂肪酸カリウム塩を
主剤としたシヤンプ―組成物において、上記主剤のほか
に、脂肪酸アミドアルキルベタインおよびカチオン化グ
ア―ガム誘導体とともに、脂肪酸ジアルキルアミノアル
キルアミドを含有させたことを特徴とするシヤンプ―組
成物に係るものである。That is, according to the present invention, in a sham-pump composition containing a fatty acid potassium salt as a main ingredient, in addition to the above-mentioned main ingredient, a fatty acid dialkylaminoalkylamide is contained together with a fatty acid amide alkyl betaine and a cationized guar gum derivative. The present invention relates to a sham-pump composition characterized by the following.
【０００７】[0007]
【発明の構成・作用】本発明においては、既述のとお
り、脂肪酸カリウム塩を主剤とし、これに両性界面活性
剤である脂肪酸アミドアルキルベタインとカチオン性界
面活性剤であるカチオン化グア―ガム誘導体とを加え、
さらに第３級アミンである脂肪酸ジアルキルアミノアル
キルアミドを加えたことにより、これら四成分の相互作
用によつて、上記主剤の利点である良好な泡立ち性を損
なうことなく、また乳化安定性、とくに保存安定性を高
度に維持したまま、その欠点であつた洗髪時の毛髪のか
らみを防いで、きしみ感を回避し、しかも洗髪後には毛
髪がねばつかず、さつぱりとした感触が得られるといつ
た格別の効果を奏し得たものである。In the present invention, as described above, a fatty acid potassium salt is used as a main agent, and a fatty acid amide alkyl betaine which is an amphoteric surfactant and a cationized guar gum derivative which is a cationic surfactant are added to this. And
Furthermore, by adding a fatty acid dialkylaminoalkylamide which is a tertiary amine, the interaction of these four components does not impair the good foaming property, which is an advantage of the above-mentioned main agent, and also the emulsion stability, especially the storage stability. While maintaining a high degree of stability, it prevents the entanglement of the hair when washing it, which is a drawback, avoids the squeaky feeling, and the hair does not become sticky after washing, giving a dry feel. It was possible to achieve a special effect.
【０００８】これに対し、たとえば、上記四成分のうち
のいずれか一成分でも欠如すると、また主剤として脂肪
酸カリウム塩以外の他のアニオン性界面活性剤を用いた
り、脂肪酸アミドアルキルベタイン以外の他の両性界面
活性剤やカチオン化グア―ガム誘導体以外の他のカチオ
ン性界面活性剤を加えたり、また第３級アミンである脂
肪酸ジアルキルアミノアルキルアミドに代えて他の界面
活性剤を加えるなどすると、上記したような効果は得ら
れにくく、通常では、乳化安定性や泡立ち性が悪くなつ
たり、洗髪時のからみ、きしみ感、洗髪後のさつぱり感
などのいずれかの特性が大きく損なわれるおそれがあ
る。On the other hand, for example, if any one of the above-mentioned four components is lacking, an anionic surfactant other than the fatty acid potassium salt is used as the main ingredient, or other than the fatty acid amide alkyl betaine. When other cationic surfactants other than the amphoteric surfactant or the cationized guar gum derivative are added, or other surfactants are added instead of the fatty acid dialkylaminoalkylamide which is a tertiary amine, It is difficult to obtain such effects, and usually, there is a possibility that emulsion stability and foamability may deteriorate, or any of the properties such as entanglement during hair washing, squeaky feeling, and crisp feeling after washing may be greatly impaired. is there.
【０００９】本発明において主剤として用いる脂肪酸カ
リウム塩としては、炭素数が１０〜１６の脂肪酸のカリ
ウム塩が好ましく、脂肪酸は炭素数の異なる２種以上の
混合脂肪酸であつてもよく、また飽和脂肪酸、不飽和脂
肪酸またはこれらの混合脂肪酸のいずれであつてもよ
い。使用量としては、シヤンプ―組成物中、３〜１５重
量％、好ましくは５〜１３重量％であるのがよい。３重
量％未満では洗髪時の泡立ちが悪く、１５重量％より多
いときしみ感が強くなる。The potassium salt of fatty acid used as the main ingredient in the present invention is preferably a potassium salt of a fatty acid having 10 to 16 carbon atoms, and the fatty acid may be a mixed fatty acid of two or more kinds having different carbon numbers, or a saturated fatty acid. , Unsaturated fatty acids or mixed fatty acids thereof. The amount used is 3 to 15% by weight, preferably 5 to 13% by weight in the shampoo composition. If it is less than 3% by weight, foaming during washing is poor, and if it is more than 15% by weight, the blemishes are strong.
【００１０】この主剤に加える脂肪酸アミドアルキルベ
タインは、下記の一般式； （Ｒ1 は炭素数７〜１５の脂肪酸残基、Ｙは炭素数２〜
４のアルキレン基である）で表わされものであり、代表
的なものとして、脂肪酸アミドプロピルジメチルアミノ
酢酸ベタインが挙げられる。使用量は、シヤンプ―組成
物中、１〜９重量％、好ましくは３〜８重量％であるの
がよい。１重量％未満では洗髪時のきしみ感が強く、９
重量％より多いと泡立ちや安定性などが悪くなる。The fatty acid amide alkyl betaine added to this base compound has the following general formula: (R 1 is a fatty acid residue having 7 to 15 carbon atoms, and Y is 2 to 2 carbon atoms.
4 is an alkylene group of 4), and a typical example thereof is fatty acid amidopropyldimethylaminoacetic acid betaine. The amount used is 1 to 9% by weight, preferably 3 to 8% by weight in the shampoo composition. If the amount is less than 1% by weight, the squeaky feeling upon washing the hair is strong and 9
If it exceeds 5% by weight, foaming and stability deteriorate.
【００１１】主剤に加えるもうひとつの成分であるカチ
オン化グア―ガム誘導体には、代表的なものとして、グ
ア―ヒドロキシプロピルトリメチルアンモニウムクロリ
ドがある。これは、豆科作物グア―の胚芽区分より粉砕
製造されるセルロ―ス同様の多糖類グア―ガムに、３−
クロロ−２−ヒドロキシプロピルトリメチルアンモニウ
ムクロライド、２，３−エポキシプロピルトリメチルア
ンモニウムクロライドなどのカチオン化試剤を、アルカ
リの存在下で反応させることにより得られる。使用量
は、シヤンプ―組成物中、０．１〜１重量％、好ましく
は０．２〜０．８重量％であるのがよい。０．１重量％
未満では洗髪時の指通りが悪く、１重量％より多いと泡
立ちや安定性が悪く、また毛髪がねばつきやすい。Another representative component added to the main agent, a cationized guar gum derivative, is guar-hydroxypropyltrimethylammonium chloride. This is a polysaccharide guar gum similar to cellulose produced by crushing from the germ division of legume crop guar.
It can be obtained by reacting a cationizing agent such as chloro-2-hydroxypropyltrimethylammonium chloride or 2,3-epoxypropyltrimethylammonium chloride in the presence of an alkali. The amount used is 0.1 to 1% by weight, preferably 0.2 to 0.8% by weight in the shampoo composition. 0.1% by weight
When the amount is less than the above, the fingers do not pass easily when washing the hair, and when it exceeds 1% by weight, foaming and stability are poor, and the hair tends to stick.
【００１２】本発明において、主剤に上記の脂肪酸アミ
ドアルキルベタインおよびカチオン化グア―ガム誘導体
とともに加える脂肪酸ジアルキルアミノアルキルアミド
は、下記の一般式； （Ｒ2 は炭素数１１〜１９の脂肪酸残基、Ｚは炭素数２
〜４のアルキレン基基、Ｒ3 ，Ｒ4 は炭素数１〜４のア
ルキル基である）で表わされるものであり、代表的なも
のとして、脂肪酸ジエチルアミノエチルアミドが挙げら
れる。使用量は、シヤンプ―組成物中、０．２〜２重量
％、好ましくは０．５〜１．８重量％であるのがよい。
０．２重量％未満では洗髪時のきしみ感が強く、２重量
％より多いと泡立ちや安定性などが悪くなる。In the present invention, the above-mentioned fatty acid amine is used as the main ingredient.
Dealkylbetaine and cationized guar gum derivatives
Fatty acid dialkylaminoalkylamide added with
Is the following general formula; (R2Is a fatty acid residue having 11 to 19 carbon atoms, Z is 2 carbon atoms
~ 4 alkylene group, R3, RFourIs a carbon number of 1 to 4
It is represented by a rukyll group)
Examples include fatty acid diethylaminoethylamide
Be done. The amount used is 0.2 to 2% by weight in the shampoo composition.
%, Preferably 0.5 to 1.8% by weight.
If it is less than 0.2% by weight, the squeaky feeling when washing the hair is strong and 2% by weight.
When it is more than%, foaming and stability are deteriorated.
【００１３】本発明のシヤンプ―組成物は、上記の主
剤、脂肪酸アミドアルキルベタイン、カチオン化グア―
ガム誘導体および脂肪酸ジアルキルアミノアルキルアミ
ドを、水に溶解、乳化させてなるものであり、これに
は、化粧品用汎用組成物として、香料、防腐剤、色素、
親水性乳化剤、親油性乳化剤、グリセリン、プロピレン
グリコ―ル、油性物質などの公知の添加剤を加えてもよ
い。The shampu composition of the present invention comprises the above-mentioned main ingredient, fatty acid amide alkyl betaine, and cationized guar.
A gum derivative and a fatty acid dialkylaminoalkylamide are dissolved in water and emulsified, and as a general-purpose composition for cosmetics, a perfume, a preservative, a pigment,
Known additives such as hydrophilic emulsifiers, lipophilic emulsifiers, glycerin, propylene glycol and oily substances may be added.
【００１４】このように構成される本発明のシヤンプ―
組成物は、乳液状の外観を呈し、長期保存しても極めて
安定であつて、適度な粘稠性を保持し、使用時濡れた頭
髪に対しその適量を手に取り、頭髪を洗えば良く泡立
ち、お湯でゆすぐと毛髪のきしみ感がなく、洗髪後には
毛髪がねばつかず、さつぱりとした感触が得られる。ま
た、洗髪後の乾きがはやく、くし通りも良く、さらに毛
髪につやを与え、また毛髪の強度とくに引張強度が増
し、動摩擦係数も小さく、すべすべとした感触を与え、
リンス効果とトリ―トメント効果をあらわすものであ
る。The jump of the present invention configured as described above
The composition has the appearance of a milky liquid, is extremely stable even after long-term storage, retains an appropriate consistency, and an appropriate amount of wet hair can be picked up by hand and washed. Foaming and rinsing with hot water do not cause the hair to squeak, and after washing, the hair does not become sticky and a dry feel is obtained. In addition, after washing hair, it dries quickly, combs well, gives hair gloss, increases the strength of hair, especially tensile strength, has a small dynamic friction coefficient, and gives a smooth feel.
It shows the rinse effect and the treatment effect.
【００１５】[0015]
【実施例】つぎに、本発明の実施例を記載して、より具
体的に説明する。なお、以下、部とあるのは重量部を、
％とあるのは重量％を、それぞれ意味する。EXAMPLES Next, examples of the present invention will be described to more specifically describe. In the following, parts are parts by weight,
"%" Means "% by weight", respectively.
【００１６】実施例１ やし油脂肪酸カリウム塩 ９部 やし油脂肪酸アミドプロピルベタイン ５部 カチオン化グア―ガム誘導体 ０．３部 〔セラニ―ズ社製の「ジヤガ―Ｃ−１３Ｓ」； グア―ヒドロキシプロピルトリメチルアンモニウムクロリド〕 ステアリン酸ジエチルアミノエチルアミド １部 ジステアリン酸エチレングリコ―ル ２部 香料 適量 防腐剤としてメチルパラベン 適量 水 全量が１００部となる量Example 1 Palm oil fatty acid potassium salt 9 parts Palm oil fatty acid amide propyl betaine 5 parts Cationized guar gum derivative 0.3 parts ["Jiaga C-13S" manufactured by Cellanies; guar Hydroxypropyltrimethylammonium chloride] Stearic acid Diethylaminoethylamide 1 part Ethylene glycol distearate 2 parts Perfume Appropriate amount Methylparaben as preservative Appropriate amount of water 100 parts
【００１７】上記の各成分のうち、水にステアリン酸ジ
エチルアミノエチルアミド１部を７５〜８０℃で均一混
合して第１液とした。また、やし油脂肪酸アミドプロピ
ルベタイン５部とカチオン化グア―ガム誘導体０．３部
を室温で均一混合して第２液とした。つぎに、上記の第
１液に上記の第２液を８０℃で均一混合し、これにやし
油脂肪酸カリウム塩９部、ジステアリン酸エチレングリ
コ―ル２部、防腐剤としてメチルパラベン適量を加えて
均一混合し、さらに室温で香料を適量加えて均一混合
し、シヤンプ―組成物を調製した。Of the above components, 1 part of stearic acid diethylaminoethylamide was uniformly mixed with water at 75 to 80 ° C. to obtain a first liquid. Further, 5 parts of coconut oil fatty acid amide propyl betaine and 0.3 part of cationized guar gum derivative were uniformly mixed at room temperature to obtain a second liquid. Next, the above second liquid was uniformly mixed with the above first liquid at 80 ° C., and 9 parts of coconut oil fatty acid potassium salt, 2 parts of ethylene glycol distearate and an appropriate amount of methylparaben as a preservative were added. After uniform mixing, a proper amount of perfume was added at room temperature and uniformly mixed to prepare a shampu-composition.
【００１８】比較例１ やし油脂肪カリウム塩９部に代えて、ポリオキシエチレ
ンラウリルエ―テル硫酸ナトリウム塩９部を用いた以外
は、実施例１と同様にして、シヤンプ―組成物を調製し
た。Comparative Example 1 A shampoo composition was prepared in the same manner as in Example 1 except that 9 parts of polyoxyethylene lauryl ether sulfate sodium salt was used in place of 9 parts of coconut oil fat potassium salt. did.
【００１９】比較例２ やし油脂肪酸アミドプロピルベタイン５部に代えて、他
の両性界面活性剤であるＮ−ラウリルイミノジ酢酸ナト
リウム塩５部を用いた以外は、実施例１と同様にして、
シヤンプ―組成物を調製した。Comparative Example 2 In the same manner as in Example 1 except that 5 parts of another amphoteric surfactant, N-lauryliminodiacetic acid sodium salt, was used instead of 5 parts of coconut oil fatty acid amide propyl betaine. ,
A shampu-composition was prepared.
【００２０】比較例３ カチオン化グア―ガム誘導体０．３部に代えて、カチオ
ン化セルロ―ズ０．３部を用いた以外は、実施例１と同
様にして、シヤンプ―組成物を調製した。Comparative Example 3 A shampu composition was prepared in the same manner as in Example 1 except that 0.3 part of cationized cellulose was used in place of 0.3 part of the cationized guar gum derivative. .
【００２１】比較例４ ステアリン酸ジエチルアミノエチルアミド１部に代え
て、塩化ステアリルトリメチルアンモニウム塩１部を用
いた以外は、実施例１と同様にして、シヤンプ―組成物
を調製した。Comparative Example 4 A shampu composition was prepared in the same manner as in Example 1 except that 1 part of stearyl trimethyl ammonium chloride was used in place of 1 part of diethylaminoethylamide stearate.
【００２２】上記の実施例１および比較例１〜４の各シ
ヤンプ―組成物について、外観およびｐＨを調べるとと
もに、下記の要領により、粘度および保存安定性を調
べ、また下記の要領により、ロスマイルス起泡力テス
ト、毛髪動摩擦係数および毛髪強度の測定、実際に洗髪
用に使用した官能テストを行つた。これらの結果は、後
記の表１および表２に示されるとおりであつた。The appearance and pH of each of the shampoo compositions of Example 1 and Comparative Examples 1 to 4 described above were examined, and the viscosity and the storage stability were examined according to the following procedures, and the loss milestones were examined according to the following procedures. A foaming power test, a dynamic friction coefficient of hair and a hair strength measurement, and a sensory test actually used for washing hair were performed. These results were as shown in Tables 1 and 2 below.
【００２３】＜粘度＞ブルツクフイ―ルド回転粘度計
（Ｂ型）を用いて、シヤンプ―組成物の２５℃での粘度
〔センチポイズ（ｃｐｓ）〕を測定した。<Viscosity> The viscosity (centipoise (cps)) at 25 ° C. of the sham-pump composition was measured by using a Bruck Field rotational viscometer (B type).
【００２４】＜保存安定性＞シヤンプ―組成物を−１０
℃で２週間，４７℃で２週間のサイクルで、６ケ月間恒
温室で保存し、この保存後の状態で、沈殿物がなく均一
乳化の場合を安定、不均一乳化または沈殿物がある場合
を不安定、と評価した。<Storage stability> Shampu-composition
2 weeks at ℃, 2 weeks at 47 ℃, stored in a constant temperature room for 6 months, and after this storage, if there is no precipitate and uniform emulsion, stable, heterogeneous emulsion or precipitate Was evaluated as unstable.
【００２５】＜ロスマイルス起泡力テスト＞４０℃でシ
ヤンプ―組成物をイオン交換水にて１％に希釈したもの
５０mlを、約１ｍの円筒中に入れ、さらに２００mlを９
０cmの高さより落下させて、１５秒経過したのちの泡高
（mm）を測定した。この測定を２回行い、平均の泡高
（mm）により、シヤンプ―組成物の気泡力を評価した。<Losmiles Foaming Power Test> At 40 ° C., 50 ml of the shampoo composition diluted with ion-exchanged water to 1% was put into a cylinder of about 1 m, and 200 ml was further added to 9 ml.
The bubble height (mm) was measured after dropping for 15 seconds from the height of 0 cm. This measurement was performed twice, and the foam strength of the sham-pump composition was evaluated by the average foam height (mm).
【００２６】＜毛髪動摩擦係数の測定＞３０℃でシヤン
プ―組成物をイオン交換水にて１％に希釈した水溶液を
試料とし、これに人毛を３分間浸漬後、水中で水洗して
乾燥する。この毛髪を２０℃，６５％ＲＨの条件下で２
４時間放置後、レ―タ―法により、摩擦速度２ｍ／分，
荷重０．５ｇの条件で、毛髪の動摩擦係数を測定した。<Measurement of Dynamic Friction Coefficient of Hair> An aqueous solution prepared by diluting the shampoo composition with ion-exchanged water to 1% at 30 ° C. was used as a sample. Human hair was immersed in this for 3 minutes, washed with water and dried. . 2 this hair under the conditions of 20 ° C and 65% RH
After left for 4 hours, the friction method was 2m / min.
The dynamic friction coefficient of hair was measured under the condition of a load of 0.5 g.
【００２７】＜毛髪強度の測定＞３０℃でシヤンプ―組
成物をイオン交換水にて１％に希釈した水溶液を試料と
し、これに人毛を３分間浸漬後、よく人毛をかき混ぜた
のち、水中で水洗して乾燥する。この毛髪を２０℃，６
５％ＲＨの条件下に２４時間放置後、テンシヨンメ―タ
で人毛１本あたりの引張強度（ｇ／cm・秒）を測定し
た。<Measurement of Hair Strength> An aqueous solution prepared by diluting the shampoo composition with ion-exchanged water to 1% at 30 ° C. was used as a sample. After immersing the human hair in this for 3 minutes, the human hair was thoroughly stirred, Wash in water and dry. This hair at 20 ℃, 6
After being left for 24 hours under the condition of 5% RH, the tensile strength (g / cm · sec) per human hair was measured with a tension meter.
【００２８】＜官能テスト＞シヤンプ―組成物の約１０
ｇを頭髪に塗布し、温水または水で毛髪を手でよくもん
だのち、洗い流して、乾燥する。その際の泡立ち、毛髪
のきしみ感（や指滑り）、乾き具合、洗髪後のさつぱり
感、しなやかさ、くし通りについて、女性２０名をパネ
ラ―として調べた。数字は良いと答えた人の人数であ
る。<Sensory Test> Shamp-about 10% of composition
g is applied to hair, and the hair is brushed with warm water or water by hand, then rinsed and dried. Twenty women were examined as panelers for foaming, squeaking of hair (slip on fingers), dryness, dryness after washing, suppleness, and combing. The number is the number of people who answered that it is good.
【００２９】[0029]
【表１】 [Table 1]
【００３０】[0030]
【表２】 [Table 2]
【００３１】上記の表１および表２の結果から明らかな
ように、本発明の実施例１のシヤンプ―組成物は、比較
例１〜４のシヤンプ―組成物に比べ、適度な粘度（粘稠
性）を有してかつ保存安定性が良好であり、またロスマ
イルス起泡力テスト、毛髪動摩擦係数および毛髪強度に
すぐれており、さらに官能テストでも泡立ち、毛髪のき
しみ感、乾き具合、洗髪後のさつぱり感、しなやかさ、
くし通りのすべての特性において格段にすぐれているこ
とがわかる。As is clear from the results shown in Tables 1 and 2, the shampu composition of Example 1 of the present invention has an appropriate viscosity (viscosity) as compared with the shampa compositions of Comparative Examples 1 to 4. Properties, and has good storage stability, and also has excellent loss-mileage foaming power test, dynamic friction coefficient of hair and hair strength. Further, sensory test gives foam, squeaky feeling of hair, dryness, after washing hair. The crispness, suppleness,
It can be seen that all the characteristics of the comb street are excellent.
【００３２】実施例２ ラウリン酸カリウム塩 ９部 ラウリン酸アミドプロピルベタイン ６部 カチオン化グア―ガム誘導体（実施例１と同じもの） ０．４部 パルミチン酸ジエチルアミノエチルアミド ０．８部 ジステアリン酸エチレングリコ―ル １．８部 香料 適量 防腐剤としてメチルパラベン 適量 水 全量が１００部となる量 上記の成分を用い、実施例１と同様にして、シヤンプ―
組成物を調製した。Example 2 Potassium lauric acid salt 9 parts Lauric acid amidopropyl betaine 6 parts Cationized guar gum derivative (the same as in Example 1) 0.4 parts Palmitic acid diethylaminoethylamide 0.8 parts Ethylene glycol distearate -1.8 parts Fragrance Suitable amount Methylparaben as preservative Suitable amount Water that makes 100 parts total amount Using the above components, in the same manner as in Example 1-
A composition was prepared.
【００３３】比較例５ ラウリン酸カリウム塩９部を用いなかつた以外は、実施
例２と同様にして、シヤンプ―組成物を調製した。Comparative Example 5 A shampu composition was prepared in the same manner as in Example 2 except that 9 parts of potassium lauric acid salt was not used.
【００３４】比較例６ ラウリン酸アミドプロピルベタイン６部を用いなかつた
以外は、実施例２と同様にして、シヤンプ―組成物を調
製した。Comparative Example 6 A shampoo composition was prepared in the same manner as in Example 2 except that 6 parts of lauric acid amidopropyl betaine was not used.
【００３５】比較例７ カチオン化グア―ガム誘導体０．４部を用いなかつた以
外は、実施例２と同様にして、シヤンプ―組成物を調製
した。Comparative Example 7 A shampu composition was prepared in the same manner as in Example 2 except that 0.4 part of the cationized guar gum derivative was not used.
【００３６】比較例８ パルミチン酸ジエチルアミノエチルアミド０．８部を用
いなかつた以外は、実施例２と同様にして、シヤンプ―
組成物を調製した。Comparative Example 8 A sample was prepared in the same manner as in Example 2 except that 0.8 part of palmitic acid diethylaminoethylamide was not used.
A composition was prepared.
【００３７】上記の実施例２および比較例５〜８の各シ
ヤンプ―組成物について、外観およびｐＨを調べるとと
もに、前記と同様にして、粘度および保存安定性を調べ
た。また、前記と同様にして、ロスマイルス起泡力テス
ト、毛髪動摩擦係数および毛髪強度の測定、実際に洗髪
用に使用した官能テストを行つた。これらの結果は、下
記の表３および表４に示されるとおりであつた。The appearance and pH of each of the shampoo compositions of Example 2 and Comparative Examples 5 to 8 were examined, and the viscosity and the storage stability were examined in the same manner as above. Also, in the same manner as described above, a loss-mileage foaming force test, measurement of dynamic friction coefficient of hair and hair strength, and sensory test actually used for washing hair were performed. These results were as shown in Tables 3 and 4 below.
【００３８】[0038]
【表３】 [Table 3]
【００３９】[0039]
【表４】 [Table 4]
【００４０】上記の表３および表４の結果から明らかな
ように、本発明の実施例２のシヤンプ―組成物は、前記
の実施例１の場合と同様に、適度な粘度（粘稠性）を有
してかつ保存安定性が良好であり、またロスマイルス起
泡力テスト、毛髪動摩擦係数および毛髪強度にすぐれて
おり、さらに官能テストでも泡立ち、毛髪のきしみ感、
乾き具合、洗髪後のさつぱり感、しなやかさ、くし通り
のすべての特性においてすぐれていることがわかる。こ
れに対して、ラウリン酸カリウム塩、ラウリン酸アミド
プロピルベタイン、カチオン化グア―ガム誘導体または
パルミチン酸ジエチルアミノエチルアミドのうちのいず
れかひとつの成分が欠如する比較例５〜８のシヤンプ―
組成物では、上記の各特性にすべて劣つており、とくに
官能テストではほとんど満足できる結果が得られない。As is clear from the results of Tables 3 and 4, the shampu composition of Example 2 of the present invention has an appropriate viscosity (viscosity) as in Example 1 above. It also has good storage stability, is excellent in loss-mileage foaming power test, hair dynamic friction coefficient and hair strength, and also has foaming in the sensory test, squeaky feeling of hair,
It can be seen that the dryness, the feeling of dryness after washing the hair, the suppleness, and the comb-like characteristics are all excellent. On the other hand, the shampu of Comparative Examples 5 to 8 lacking any one of potassium lauric acid salt, lauric acid amide propyl betaine, cationized guar gum derivative or palmitic acid diethylaminoethylamide.
The composition is inferior in all of the above-mentioned properties, and almost no satisfactory results can be obtained especially in the sensory test.
【００４１】実施例３ 実施例１のシヤンプ―組成物において、やし油脂肪酸カ
リウム塩の使用量を、３部および１５部に変更したとこ
ろ、たとえば、官能テストで「泡立ち良い人」が３部の
場合で１５人、１５部の場合で１４人、「洗髪後のしな
やかさ良い人」が３部の場合で１２人、１５部の場合で
１４人となるなどの多少の低下傾向はみられたが、全体
の特性としてはなお十分に満足できる結果であつた。こ
の結果からも、やし油脂肪酸カリウム塩の使用量として
は、シヤンプ―組成物中、３〜１５％の範囲とするのが
好ましいことがわかつた。Example 3 In the shampoo composition of Example 1, the amount of coconut oil fatty acid potassium salt used was changed to 3 parts and 15 parts. There was a slight decrease in the number of cases, such as 15 people in the case of 15, 14 people in the case of 15 parts, 12 people in the case of “the person who was supple after washing hair” in the case of 3 parts, and 14 people in the case of 15 parts. However, the overall characteristics were still satisfactory. From these results, it was found that the amount of coconut oil fatty acid potassium salt to be used is preferably in the range of 3 to 15% in the shampu composition.
【００４２】実施例４ 実施例１のシヤンプ―組成物において、やし油脂肪酸ア
ミドプロピルベタインの使用量を、１部および９部に変
更したところ、たとえば、官能テストにおいて「泡立ち
良い人」が１部の場合で１４人、９部の場合で１６人、
「洗髪後のしなやかさ良い人」が１部の場合で１５人、
９部の場合で１７人となるなどの多少の低下傾向はみら
れ、またとくに１部の場合、外観が半透明乳化となるな
どの変化はみられたが、全体の特性としてはなお十分に
満足できる結果であつた。この結果からも、やし油アミ
ドプロピルベタインの使用量としては、シヤンプ―組成
物中、１〜９％の範囲とするのが好ましいことがわかつ
た。Example 4 In the shampoo composition of Example 1, the amount of coconut oil fatty acid amide propyl betaine used was changed to 1 part and 9 parts. 14 people in the case of copies, 16 people in the case of 9 copies,
15 people in the case of "the person who is supple after washing hair" is 1 part,
In the case of 9 parts, there was a slight tendency such as 17 people, and especially in the case of 1 part, there were changes such as the appearance becoming a translucent emulsion, but the overall characteristics were still sufficient. The result was satisfactory. From these results, it was found that the amount of coconut oil amidopropyl betaine used is preferably in the range of 1 to 9% in the shampa composition.
【００４３】実施例５ 実施例１のシヤンプ―組成物において、カチオン化グア
―ガム誘導体の使用量を、０．１部および１部に変更し
たところ、たとえば、官能テストにおいて「泡立ち良い
人」が０．１部の場合で１２人、１部の場合で１５人、
「洗髪後のしなやかさ良い人」が０．１部の場合で１５
人、１部の場合で１６人となるなどの多少の低下傾向は
みられたが、全体の特性としてはなお十分に満足できる
結果であつた。この結果からも、カチオン化グア―ガム
誘導体の使用量としては、シヤンプ―組成物中、０．１
〜１％の範囲とするのが好ましいことがわかつた。Example 5 In the shampoo composition of Example 1, the amount of the cationized guar gum derivative used was changed to 0.1 part and 1 part. If 0.1 copy is 12 people, if 1 copy is 15 people,
15 when "People who are supple after washing hair" is 0.1 part
Although there was a slight tendency for the number of people to decrease to 16 for one copy, the overall characteristics were still sufficiently satisfactory. From these results, the amount of the cationized guar gum derivative used was 0.1% in the shampu composition.
It has been found that a preferable range is ˜1%.
【００４４】実施例６ 実施例１のシヤンプ―組成物において、ステアリン酸ジ
エチルアミノエチルアミドの使用量を、０．２部および
２部に変更したところ、たとえば、官能テストにおいて
「泡立ち良い人」が０．２部の場合で１２人、２部の場
合で１７人、「洗髪後のしなやかさ良い人」が０．２部
の場合で１３人、２部の場合で１７人となるなどの多少
の低下傾向はみられたが、全体の特性としてはなお十分
に満足できる結果であつた。この結果からも、ステアリ
ン酸ジエチルアミノエチルアミドの使用量としては、シ
ヤンプ―組成物中、０．２〜２％の範囲とするのが好ま
しいことがわかつた。Example 6 In the shampoo composition of Example 1, the amount of stearic acid diethylaminoethylamide used was changed to 0.2 parts and 2 parts. There are 12 people in the case of 2 parts, 17 people in the case of 2 parts, 13 people in the case of 0.2 parts of "the person who is supple after washing hair", and 17 people in the case of 2 parts. Although there was a tendency to decrease, the results were still satisfactory as a whole. From this result, it was found that the amount of stearic acid diethylaminoethylamide used is preferably in the range of 0.2 to 2% in the shampa composition.
【００４５】[0045]
【発明の効果】本発明のシヤンプ―組性物は、脂肪酸カ
リウムを主剤とし、これに脂肪酸アミドアルキルベタイ
ンおよびカチオン化グア―ガム誘導体とともに、脂肪酸
ジアルキルアミノアルキルアミドを加えたことにより、
適度な粘稠性を有し、安定性とくに保存安定性にすぐ
れ、泡立ちが良く、また洗髪時の指滑りが良くて、きし
み感がなく、しかも洗髪後に毛髪がねばつかず、さつぱ
りとした感触が得られる。また、洗髪後の乾きがはや
く、くし通りも良く、毛髪につやを与え、さらに毛髪の
強度が増し、動摩擦係数も小さく、すべすべとした感触
を与え、とくに風合いが良く髪の重みを感じさせないと
いつたすぐれた性能を発揮する。EFFECTS OF THE INVENTION The shampoo composition of the present invention comprises a fatty acid potassium as a main agent, and a fatty acid dialkylaminoalkylamide together with a fatty acid amide alkylbetaine and a cationized guar gum derivative.
It has moderate viscosity, excellent stability, especially storage stability, good foaming, good finger slip when washing hair, no squeaky feeling, and no sticky hair after washing, and crispness. You can feel it. Also, after washing hair, it dries quickly, combs well, gives hair gloss, further increases hair strength, has a low dynamic friction coefficient, gives a smooth feel, and feels particularly good texture and weight of hair. Demonstrate superior performance.
Claims (4)
―組成物において、上記主剤のほかに、脂肪酸アミドア
ルキルベタインおよびカチオン化グア―ガム誘導体とと
もに、脂肪酸ジアルキルアミノアルキルアミドを含有さ
せたことを特徴とするシヤンプ―組成物。1. A shampoo composition containing a fatty acid potassium salt as a main ingredient, wherein, in addition to the above main ingredient, a fatty acid dialkylaminoalkylamide is contained together with a fatty acid amide alkyl betaine and a cationized guar gum derivative. Shampoo-composition.
アミドプロピルベタインである請求項１に記載のシヤン
プ―組成物。2. A shampu composition according to claim 1, wherein the fatty acid amidoalkyl betaine is fatty acid amidopropyl betaine.
が脂肪酸ジエチルアミノエチルアミドである請求項１に
記載のシヤンプ―組成物。3. The jump composition of claim 1, wherein the fatty acid dialkylaminoalkylamide is fatty acid diethylaminoethylamide.
酸アミドアルキルベタイン１〜９重量％、カチオン化グ
ア―ガム誘導体０．１〜１重量％、脂肪酸ジアルキルア
ミノアルキルアミド０．２〜２重量％を含有してなる請
求項１〜３のいずれかに記載のシヤンプ―組成物。4. Fatty acid potassium salt 3 to 15% by weight, fatty acid amide alkylbetaine 1 to 9% by weight, cationized guar gum derivative 0.1 to 1% by weight, fatty acid dialkylaminoalkylamide 0.2 to 2% by weight. The jump composition according to any one of claims 1 to 3, which comprises:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30980694A JPH08143432A (en) | 1994-11-18 | 1994-11-18 | Shampoo composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30980694A JPH08143432A (en) | 1994-11-18 | 1994-11-18 | Shampoo composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08143432A true JPH08143432A (en) | 1996-06-04 |
Family
ID=17997477
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30980694A Withdrawn JPH08143432A (en) | 1994-11-18 | 1994-11-18 | Shampoo composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08143432A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007009818A1 (en) * | 2005-07-22 | 2007-01-25 | Rhodia Recherches Et Technologies | Polysaccharide-based products with improved easiness of use, process to make the same, and applications of the same |
| US7282520B2 (en) | 2001-09-19 | 2007-10-16 | Lion Corporation | External preparation |
-
1994
- 1994-11-18 JP JP30980694A patent/JPH08143432A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7282520B2 (en) | 2001-09-19 | 2007-10-16 | Lion Corporation | External preparation |
| WO2007009818A1 (en) * | 2005-07-22 | 2007-01-25 | Rhodia Recherches Et Technologies | Polysaccharide-based products with improved easiness of use, process to make the same, and applications of the same |
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