JPH0810789A - Water purifying device - Google Patents

Water purifying device

Info

Publication number
JPH0810789A
JPH0810789A JP18423194A JP18423194A JPH0810789A JP H0810789 A JPH0810789 A JP H0810789A JP 18423194 A JP18423194 A JP 18423194A JP 18423194 A JP18423194 A JP 18423194A JP H0810789 A JPH0810789 A JP H0810789A
Authority
JP
Japan
Prior art keywords
water
active oxygen
microorganisms
tank
bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18423194A
Other languages
Japanese (ja)
Inventor
Masayuki Kobayashi
真之 小林
Masumi Mizutani
増美 水谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHOWA AUTO ENG
Showa Corp
Original Assignee
SHOWA AUTO ENG
Showa Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHOWA AUTO ENG, Showa Corp filed Critical SHOWA AUTO ENG
Priority to JP18423194A priority Critical patent/JPH0810789A/en
Publication of JPH0810789A publication Critical patent/JPH0810789A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Farming Of Fish And Shellfish (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)

Abstract

PURPOSE:To provide a water purifying device for household or business use which purifies bath water, water of water tanks for fish breeding, used brines, antifreezing fluid, etc., which is improved in decomposability of org. matter by microorganisms by using particularly an active oxygen generator and is usable stably over a long period of time, and further, to obtain water which is gentle to a living body. CONSTITUTION:This water purifying device 1 is formed of an electrolyzing device 5 or the active oxygen generating means using hydrogen peroxide water and catalysts and a septic tank 23 packed with propagating materials consisting of ceramics essentially consisting of basic materials. This electrolyzing device 5 applies voltage by inverting polarities at every specified time to anode 7 and cathode 8 and is, therefore, capable of automatically removing the scale stuck thereon. Further, the septic tank 23 has a large active oxygen quantity and dissolved oxygen quantity and is capable of preventing the degradation in pH and, therefore, the high characteristic to decompose the org. matter by the microorganisms is obtd. Since the active oxygen diminishes the clusters of water and, therefore, the water liable to be utilized for the living body is obtd.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は風呂水、プール用水、鑑
賞魚用水槽の水、使用済みブライン・不凍液などを浄化
する家庭用もしくは業務用の水浄化装置に関するもので
ある。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a domestic or commercial water purifying device for purifying bath water, pool water, water for ornamental fish tanks, used brine, antifreeze and the like.

【0002】[0002]

【従来の技術】従来の風呂水、鑑賞魚用水槽の水、使用
済みブライン・不凍液などの浄化装置を図12、図1
3、図14にもとずいて説明する。図12は従来の風呂
水浄化装置付き風呂システムで、風呂水浄化装置70は
浴槽50の往路51a,復路51bの間に配置してあ
る。浴槽50の水は流入口52より往路51aを経由し
ポンプ53により濾過槽54に入り、髪の毛などがフィ
ルターにより除去された後、ヒーター55で加熱され、
さらにケイ酸や酸化アルミニウムを主成分とする火成岩
の粒子が充填してある水浄化槽56に入る。この火成岩
粒子の表面には風呂水中の有機物を分解する微生物が付
着しており、この微生物で有機物が除去された水は、水
流復路51bを経由して流出口57から浴槽50へ戻
る。一方、流出口57には噴流器58が設置されてお
り、空気を吸い込みながら浄化された風呂水を浴槽50
に吐出する。また、流通管59を経由してオゾン発生器
60で発生したオゾンが、前記噴流器58のエゼクター
効果により吸い込まれ、浴槽50の中に放出されるので
風呂水は殺菌される。
2. Description of the Related Art A conventional device for purifying bath water, water for aquarium fish, used brine, antifreeze liquid, etc. is shown in FIGS.
3 and FIG. 14 will be described. FIG. 12 shows a conventional bath system with a bath water purifying device, in which a bath water purifying device 70 is arranged between a forward path 51a and a return path 51b of a bath 50. The water in the bathtub 50 enters the filtration tank 54 from the inflow port 52 via the outward path 51a by the pump 53, is heated by the heater 55 after hair and the like are removed by the filter,
Further, it enters a water purification tank 56 filled with particles of igneous rock whose main component is silicic acid or aluminum oxide. Microorganisms that decompose organic matter in bath water adhere to the surface of the igneous rock particles, and the water from which organic matter has been removed by the microorganisms returns from the outlet 57 to the bath 50 via the water return path 51b. On the other hand, a jet 58 is installed at the outlet 57, so that the bath water purified while sucking in air
To discharge. Further, the ozone generated by the ozone generator 60 via the flow pipe 59 is sucked by the ejector effect of the jet device 58 and discharged into the bath 50, so that the bath water is sterilized.

【0003】図13は従来の鑑賞魚用水槽で、透明な水
槽61の内部には酸素を補給するために磁器製の散気管
62入れ、エアーポンプ63で常にエアーレーションを
行っていた。更に鑑賞魚64と共に見て楽しむために水
草65と水槽61の底部には砂66などが配置されてい
る。図14は従来の使用済みブライン・不凍液を分解す
る水浄化装置で、ブライン・不凍液の入った水槽67の
中には酸素を補給するために磁器製の散気管62を入
れ、エアーポンプ63で常にエアーレーションを行って
いた。更に、ポンプ68で火成岩粒子69を内蔵した水
浄化槽56に使用済みのブライン・不凍液を供給し浄化
していた。
FIG. 13 shows a conventional aquarium for appreciating fish, in which a porcelain diffuser tube 62 is placed in a transparent water tank 61 to supplement oxygen, and aeration is always performed by an air pump 63. In addition, sand 66 and the like are arranged at the bottom of the aquatic plant 65 and the aquarium 61 for viewing and enjoying together with the viewing fish 64. FIG. 14 shows a conventional water purifying device for decomposing used brine / antifreeze liquid. A porcelain diffuser tube 62 is placed in the water tank 67 containing the brine / antifreeze liquid to supply oxygen, and an air pump 63 is used to constantly I was doing aeration. Further, the used brine / antifreeze liquid was supplied to the water purification tank 56 containing the igneous rock particles 69 by the pump 68 for purification.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、このよ
うな従来の風呂水浄化装置や鑑賞魚用水槽や使用済みの
ブライン・不凍液の浄化装置では、酸素の補給をエアー
レーションで行っているために酸素を水に多く溶かすこ
とができなかった。従来方式の水に対する酸素の溶存飽
和点はPH.水温などにより異なるが、例えば水温10
℃では10.6〜11.3PPm、15℃で9.8〜1
0.2PPm、20℃で8.8〜9.2PPmとなり、
あまり溶かすことが出来なかった。
However, in such a conventional bath water purifying apparatus, an aquarium for appreciating fish, and a used brine / antifreeze purifying apparatus, oxygen is supplied by aeration. Couldn't dissolve much in water. In the conventional method, the dissolved saturation point of oxygen in water is PH. It depends on the water temperature, but the water temperature is 10
10.6-11.3PPm at ℃, 9.8-1 at 15 ℃
0.2PPm, 8.8 ~ 9.2PPm at 20 ℃,
I couldn't melt much.

【0005】その結果、従来の風呂水浄化装置では (1)溶存酸素量が少なく有機物を分解する好気性微生
物の繁殖が遅いので、水浄化装置を設置してから風呂水
の浄化が始まるまでの期間が非常に長い。 (2)溶存酸素量が少ないため風呂水の汚れの主成分で
あるステアリン酸や窒素化合物などを分解する好気性微
生物が働きにくいので、風呂水がきれいになりにくい。 (3)従来のケイ酸や酸化アルミニウムを主成分とする
火成岩の粒子を充填している水浄化槽56は、風呂水の
汚れである尿素などの窒素化合物を微生物が酸化分解し
て硝酸が生成すると風呂水のPHが低下する欠点があ
る。このようにPHが低くなると有機物を分解する微生
物の活性が図7に示すように低くなり、風呂水がきれい
にならない。 (4)オゾンを浴槽の中に入れて風呂水の雑菌を殺菌す
る方式を採用しているので、残ったオゾンが空気中に出
ると人体に害を及ぼす危険性がある。 (5)水のクラスターが大きいので水が人体に吸収され
にくい。 などの欠点がある。
As a result, in the conventional bath water purifying apparatus, (1) the amount of dissolved oxygen is small, and the propagation of aerobic microorganisms that decompose organic matter is slow, so that the bath water purification starts after the water purifying apparatus is installed. The period is very long. (2) Since the amount of dissolved oxygen is small, aerobic microorganisms that decompose stearic acid, nitrogen compounds, etc., which are the main components of stains in bath water, do not work easily, so that bath water is difficult to clean. (3) In the conventional water purification tank 56 filled with particles of igneous rock whose main component is silicic acid or aluminum oxide, when microorganisms oxidize and decompose nitrogen compounds such as urea, which is stains in bath water, to generate nitric acid. There is a drawback that the pH of bath water decreases. As shown in FIG. 7, when the pH is low, the activity of the microorganisms that decompose organic matter is low, and the bath water is not clean. (4) Since ozone is put in the bathtub to sterilize the bacteria in the bath water, there is a risk of harming the human body if the remaining ozone is released into the air. (5) Since the water cluster is large, it is difficult for water to be absorbed by the human body. There are drawbacks such as.

【0006】また、鑑賞魚用水槽でも (1)溶存酸素量が少なく水槽の水を浄化する好気性微
生物の繁殖が遅いので、設置してから水槽の水の浄化が
始まるまでの期間が長い。 (2)溶存酸素量が少ないため残餌や鑑賞魚の***物な
どを分解する好気性微生物が働きにくいので、すぐ水槽
の水が汚くなる。 (3)鑑賞魚や水草などの育成が悪い。 (4)水槽や水に藻類が繁殖し汚くなる。 (5)水のクラスターが大きいので水が魚や水草に吸収
されにくい。 などの欠点がある。
[0006] Also in the aquarium for appreciation fish, (1) the amount of dissolved oxygen is small and the aerobic microorganisms for purifying the water in the aquarium propagate slowly, so that the period from installation to the purification of the aquarium water is long. (2) Since the amount of dissolved oxygen is small, aerobic microorganisms that decompose leftover food and excrement of ornamental fish are difficult to work, and the water in the aquarium becomes dirty immediately. (3) The training of appreciation fish and aquatic plants is poor. (4) Algae grow in the aquarium and water and become dirty. (5) Since water clusters are large, it is difficult for water to be absorbed by fish and aquatic plants. There are drawbacks such as.

【0007】更に、使用済みブライン・不凍液の浄化装
置では、有機物であるエチレングリコールやプロピレン
グリコールが主原料となっており、通常ブライン・不凍
液が使用される場合の濃度は30〜50%である。例え
ば濃度50%のブライン・不凍液を1l排出すると、B
OD,CODとも約50万PPmという大変な数字にな
る。このようにBOD,CODの高い水は、従来のエア
ーレーション方式では酸素が不足し好気性微生物が死滅
してしまうので分解が出来なかった。このような欠点に
より水の浄化上非常に不都合を感じていた。
Further, in the used brine / antifreeze purification device, ethylene glycol and propylene glycol, which are organic substances, are the main raw materials, and the concentration when the brine / antifreeze is usually used is 30 to 50%. For example, if 1 liter of brine / antifreeze with a concentration of 50% is discharged, B
Both OD and COD will be a huge number of about 500,000 PPm. As described above, water having high BOD and COD could not be decomposed by the conventional aeration method because oxygen was insufficient and aerobic microorganisms were killed. Due to such drawbacks, it was very inconvenient for water purification.

【0008】[0008]

【課題を解決するための手段】本発明はこのような不都
合を解消し、活性酸素と溶存酸素を多くして水を浄化す
る好気性微生物の繁殖を早め、水浄化手段を設置後、す
ぐ浄化ができるようにすると共に、水を浄化する微生物
の活性を高めて浄化性能を大きくし、従来分解できなか
ったブライン・不凍液やステアリン酸なども分解出来る
ようにし、且つ人や魚や水草などにやさしい殺菌、殺
藻、水質を得ることが出来る水浄化装置を提供せんとす
るものである。
The present invention eliminates such inconveniences, accelerates the propagation of aerobic microorganisms that purify water by increasing active oxygen and dissolved oxygen, and immediately purifies them after the water purifying means is installed. In addition to increasing the activity of microorganisms that purify water, the purification performance is increased and the brine, antifreeze and stearic acid that could not be decomposed in the past can be decomposed, and the sterilization is gentle on people, fish and aquatic plants. The purpose is to provide a water purification device that can obtain algae killing and water quality.

【0009】 生した活性酸素が殺菌作用及び水のクラスターを小さく
する活性酸素発生手段と、水中の有機物を分解する微生
物を繁殖材(バイオキャリア)で繁殖させる微生物繁殖
手段とを備え、活性酸素発生手段として、陽極と陰極に
直流電圧を印加する回路に極性反転用リレーを作動する
よう設置した制御回路を設けてなる水の電気分解装置、
或は、過酸化水素水と、二酸化マンガンを主成分とした
材料による触媒を用いるようにし、微生物繁殖手段とし
て、カルシウム若しくはマグネシウムの酸化物、ケイ酸
塩、アルミ酸塩、炭酸塩より選択した少なくとも一種を
含む塩基性物質が主成分であるセラミックで構成した繁
殖材を用いるようにしたものである。
[0009] The active oxygen produced has a bactericidal action and an active oxygen generating means for reducing water clusters, and a microbial breeding means for breeding a microorganism that decomposes organic matter in water with a breeding material (biocarrier). A water electrolyzer comprising a control circuit installed to operate a polarity reversing relay in a circuit for applying a DC voltage to the anode and the cathode,
Alternatively, a hydrogen peroxide solution and a catalyst containing a material containing manganese dioxide as a main component are used, and at least one selected from oxides of calcium or magnesium, silicates, aluminates, and carbonates is used as a means for microbial propagation. A breeding material composed of a ceramic whose main component is a basic substance containing one kind is used.

【0010】[0010]

【作用】活性酸素発生手段により水中に発生させた活性
酸素は、水中において酸素イオンの状態で発生するの
で、溶存酸素量が従来のエアーレーション方式に比べて
多くなるので、水中の有機物を分解する好気性微生物の
繁殖が早くなり、水浄化手段を設置してから水浄化が始
まるまでの時間が非常に早くなる。又、溶存酸素量が多
いので、前記微生物が働きやすくなり、水中の有機物や
従来分解できなかったプライン・不凍液、ステアリン酸
なども素早く分解出来る。そして前記活性酸素は純粋酸
素に変化する過程で、水槽の汚れの原因となる藻類や風
呂水中に発生したバクテリアなどと素早く接触反応し、
これらを破壊しながら純粋酸素に変化するので、それら
の繁殖を防ぐ事ができると共に、藻類やバクテリアなど
と接触反応して素早く純粋酸素になるため、生態系を壊
すことなく安全である。
The active oxygen generated in the water by the active oxygen generating means is generated in the state of oxygen ions in the water, so that the dissolved oxygen amount becomes larger than that in the conventional aeration method, and thus the organic matter in the water is decomposed. The aerobic microorganisms propagate faster, and the time from the installation of water purification means to the start of water purification becomes very fast. In addition, since the amount of dissolved oxygen is large, the above-mentioned microorganisms can easily work, and organic matter in water, plume / antifreeze solution, stearic acid, etc., which could not be decomposed conventionally, can be decomposed quickly. And in the process in which the active oxygen is changed to pure oxygen, it reacts quickly with algae that cause dirt in the aquarium and bacteria generated in the bath water.
Since it changes into pure oxygen while destroying them, it is possible to prevent their reproduction, and to react with algae, bacteria, etc. to quickly become pure oxygen, which is safe without destroying the ecosystem.

【0011】一般に水は、水分子が単独で構成する集合
体ではなく、水分子が水素結合により、(HO)nで
表せるクラスターを形成しているが、水中に活性酸素を
発生させると、活性酸素が水のクラスターを分解し、水
分子集団を小さくすることができる。このクラクスター
の小さい水は、生体への浸透がよくなり、老化や身体の
不調を解消できる。また、魚の色をより美しく際立たせ
ると共に成長も早くなる。更に、水草などの植物の世界
においても土壌への浸透がよくなり、植物への栄養が吸
収しやすく、組織への浸透もスムースになるので、生育
がよくなるなど生物にとって利用しやすい水と言える。
そして、繁殖材を少なくとも塩基性物質を含むセラミッ
クで構成したので、水中の有機物を分解する微生物の活
性が大きくなり、さらに水中の窒素酸化物を分解して硝
酸ができても、水のPHの低下が生じない。
Generally, water is not an aggregate composed of water molecules alone, but water molecules form clusters represented by (H 2 O) n by hydrogen bonds. However, when active oxygen is generated in water. , Active oxygen can decompose water clusters and reduce the water molecule population. The small water of this claxter improves its penetration into the living body, eliminating aging and physical problems. In addition, the color of the fish will be more beautifully highlighted and the growth will be faster. Further, even in the world of plants such as aquatic plants, the water penetrates well into the soil, the nutrients in the plants are easily absorbed, and the penetration into tissues is smooth, so it can be said that the water is easy to use for living organisms because it grows well.
And since the breeding material is composed of a ceramic containing at least a basic substance, the activity of microorganisms that decompose organic matter in water is increased, and even if nitric oxide is decomposed to form nitric acid, the pH of water No decrease occurs.

【0012】[0012]

【実施例】以下本発明の実施例を図面にもとずいて説明
する。 (実施例1)本実施例は家庭用風呂水の浄化に用いた場
合である。図中1は風呂水浄化装置全体であって、フイ
ルター3を濾過槽4内に設けた濾過装置2と、活性酸素
発生手段としての電気分解装置5と、微生物繁殖手段と
しての繁殖装置6とを設けている。5は陽極7と陰極8
を設け直流電源9を通電可能とした電気分解装置であっ
て、入口10を濾過槽4に出口11を繁殖装置6に接続
している。
Embodiments of the present invention will be described below with reference to the drawings. (Embodiment 1) This embodiment is a case where it is used for purifying domestic bath water. In the figure, 1 is a bath water purifying apparatus as a whole, which comprises a filtering device 2 having a filter 3 provided in a filtering tank 4, an electrolyzing device 5 as active oxygen generating means, and a breeding device 6 as microbial breeding means. It is provided. 5 is an anode 7 and a cathode 8
Is an electrolyzer capable of energizing the DC power supply 9, and the inlet 10 is connected to the filtration tank 4 and the outlet 11 is connected to the breeding device 6.

【0013】直流電圧を印加する電気制御系について
は、交流電源12をON或はOFFされる電源スイッチ
13とヒューズ14を介してトランス15の1次側に接
続し、トランス15の2次側が整流回路16に接続して
いる。整流回路16の直流電圧出力側の正極16aと負
極16bは平滑コンデンサ17を介して極性反転用リレ
ー18の2箇の可動接点19a,20aに接続してい
る。正極16aの可動接点19aに対応する2箇の固定
接点19b,19cのうち一方の固定接点19bは陽極
7に、他方の固定接点19cは陰極8に接続すると共
に、負極16bの可動接点20aに対応する2箇の固定
接点20b,20cのうち固定接点20bは陰極8に、
他方の固定接点20cは陽極7に接続している。これら
2箇の可動接点20a,20aは通常はスプリングの力
で図2に示す如く固定接点19b,20bに接する正接
続位置にあり、制御回路21からの一定時間毎に反転信
号により他方の固定接点19c,20cに逆接続位置に
て接するより切り変わるようになっている。
Regarding an electric control system for applying a DC voltage, an AC power supply 12 is connected to a primary side of a transformer 15 via a power switch 13 which is turned on or off and a fuse 14, and a secondary side of the transformer 15 is rectified. It is connected to the circuit 16. The positive electrode 16a and the negative electrode 16b on the DC voltage output side of the rectifier circuit 16 are connected via a smoothing capacitor 17 to two movable contacts 19a and 20a of a polarity reversing relay 18. Of the two fixed contacts 19b and 19c corresponding to the movable contact 19a of the positive electrode 16a, one fixed contact 19b is connected to the anode 7 and the other fixed contact 19c is connected to the cathode 8 and corresponds to the movable contact 20a of the negative electrode 16b. Of the two fixed contacts 20b and 20c, the fixed contact 20b is the cathode 8.
The other fixed contact 20c is connected to the anode 7. These two movable contacts 20a, 20a are normally in a positive connection position in contact with the fixed contacts 19b, 20b as shown in FIG. 2 by the force of a spring, and the other fixed contact is given by an inversion signal from the control circuit 21 at regular intervals. It is designed such that it switches from contacting 19c and 20c at the reverse connection position.

【0014】6は微生物繁殖装置であって、カルシウム
若しくはマグネシウムの酸化物、ケイ酸塩、アルミ酸
塩、炭酸塩より少なくとも一種類を選択して含む塩基性
物質を主成分とするセラミックからなる繁殖材22を設
けた浄化槽23からなり、入口24と出口25を設け電
気分解装置5に隣接して設け、前記出口11と該入口2
4を接続している。26は浴槽であって、流入口27と
流出口28を設け、強制循環流路29の往路29aを流
入口27に、復路29bを流出口28に接続し、往路2
9a他端を濾過槽4に、復路29b他端を浄化槽23の
出口25に接続し、浴槽26内の水の循環を可能として
いる。30は噴流器具であって、前記流出口28に設け
流通管31を経由して空気がエジェクター効果により吸
い込まれて気泡が浴槽26中に発生するようにしてい
る。
Reference numeral 6 is a microbial breeding apparatus, which is a breeding machine composed of a ceramic containing as a main component a basic substance containing at least one selected from oxides of calcium or magnesium, silicates, aluminates and carbonates. A septic tank 23 provided with a material 22 is provided, an inlet 24 and an outlet 25 are provided adjacent to the electrolyzer 5, and the outlet 11 and the inlet 2 are provided.
4 are connected. Reference numeral 26 denotes a bathtub, which is provided with an inflow port 27 and an outflow port 28, and connects the outward route 29a of the forced circulation flow channel 29 to the inflow port 27 and the return route 29b to the outflow port 28, and the outward route 2
The other end of 9a is connected to the filtration tank 4, and the other end of the return path 29b is connected to the outlet 25 of the septic tank 23 to enable circulation of water in the bath 26. Reference numeral 30 denotes a jetting device, which is provided at the outlet 28 so that air is sucked by the ejector effect via the flow pipe 31 and bubbles are generated in the bath 26.

【0015】[0015]

【作用】浴槽26の風呂水は流入口27より往路29a
を通って濾過装置2の濾過槽4に入りフイルター3にて
髪の毛や糸くずなどを除去した後、入口10より電気分
解装置5に入り、こゝで活性酸素が付加される。この時
電気分解装置5内では、水の電気分解の際に特に水中に
含まれるマグネシウムやカルシウムなどの陽イオンの不
純物が陰極8側に析出、付着してスケールを生成する。
このスケールの量は通電時間が長くなるほど増大し、或
る程度の量になると極度に電解能力が低下し、電極自体
も腐食するようになる。このようなスケールを除去する
ために、スケールの付着している陰極8を陽極7に制御
回路21からの一定時間毎の反転信号により極性逆転し
た電圧を印加し、スケールを水中に溶出して洗浄するた
め定期的に極性を逆転して自動的にスケールを除去し、
連続的に電気分解を可能にした。
[Function] The bath water in the bathtub 26 is forwarded from the inflow port 27 to the outward route 29a.
After entering the filtration tank 4 of the filtration device 2 through the filter 3 to remove hair, lint, etc., it enters the electrolysis device 5 through the inlet 10, and active oxygen is added thereto. At this time, in the electrolyzer 5, when the water is electrolyzed, impurities of cations such as magnesium and calcium contained in the water are particularly deposited and adhered to the cathode 8 side to form a scale.
The amount of this scale increases as the energization time becomes longer, and when it reaches a certain amount, the electrolytic ability is extremely lowered and the electrode itself is corroded. In order to remove such scales, a voltage having polarity reversed by a reversal signal from the control circuit 21 is applied to the cathode 8 with the scale attached to the anode 7 to elute the scale into water and wash it. Therefore, the polarity is periodically reversed to automatically remove the scale,
It enabled electrolysis continuously.

【0016】そして濾過され更に活性酸素が加えられた
風呂水は塩基性物質を主成分とする繁殖材22からなる
浄化槽23に入り、繁殖材22の表面に繁殖させた好気
性微生物により湯垢などの脂肪酸化合物は炭酸ガスと水
に分解され、さらに尿素やアンモニアなどの窒素化合物
は化1の式により硝酸塩に分解され、きれいな水になっ
て復路29bを経由して流出口28から浴槽26へ戻
る。
The bath water filtered and further added with active oxygen enters a septic tank 23 composed of a breeding material 22 containing a basic substance as a main component, and aerobic microorganisms propagated on the surface of the breeding material 22 cause scales such as scales. The fatty acid compound is decomposed into carbon dioxide gas and water, and the nitrogen compound such as urea and ammonia is decomposed into nitrate according to the formula (1), becomes clean water, and returns from the outlet 28 to the bath 26 through the return path 29b.

【0017】[0017]

【化1】 Embedded image

【0018】浴槽26へ戻る風呂水は噴流器30によっ
て、流通管31を経由して空気がエジェクター効果によ
り吸い込まれ気泡となって浴槽26に噴流される。なお
繁殖材22は図3に示すように断面トユ状としていると
共に弓状に湾曲させている。従って繁殖材22が重なり
合い水に接触しない部分が生じる事がなく、浄化槽23
内での水との接触面積も最も広くできる。また好気性微
生物の培養できる面積も最も広くできる。前記繁殖材2
2は高炉水砕を原料として用いた。この高炉水砕は製鉄
所の溶鉱炉から溶鉄1トン当たり0.5トン発生するス
ラグを急冷して製造され、主にセメントの原料や土壌改
良材として使用されているものである。高炉水砕は多孔
質のセセラミックに焼成され、表1に示すようにCa
O,MgOなどの塩基性物質が主成分である。
The bath water returning to the bathtub 26 is jetted into the bathtub 26 by the jet device 30 through the flow pipe 31, air is sucked by the ejector effect to form bubbles. As shown in FIG. 3, the breeding material 22 has a cross section of a towed shape and is curved in an arc shape. Therefore, there is no part where the propagation material 22 overlaps and does not come into contact with water, and the septic tank 23
The area of contact with water inside can be maximized. In addition, the area where aerobic microorganisms can be cultured can be maximized. The breeding material 2
No. 2 used granulated blast furnace as a raw material. This granulated blast furnace is produced by rapidly cooling slag generated in a blast furnace of an iron mill at a rate of 0.5 ton per 1 ton of molten iron, and is mainly used as a raw material for cement and a soil conditioner. Granulated blast furnace is fired into porous ce-ceramic, and as shown in Table 1, Ca
A basic substance such as O or MgO is the main component.

【0019】[0019]

【表1】 [Table 1]

【0020】このようにCaOが主成分であるので、前
述の化1の式でNOが生成してもPHの低下がおこら
ない。また、各地のPHの低い水を使用しても前述のC
aOで中和できるので、水を浄化する微生物の活性を向
上させることができる。さらに、CaOなどが主成分で
ある繁殖材22の表面には、水の中でカルシウムなどの
2価のプラスイオンが沢山存在する。一方、微生物は通
常マイナスに荷電されているので、水を浄化する微生物
は繁殖材22に付着し繁殖しやすい。
Since CaO is the main component as described above, even if NO 3 is produced by the above formula 1, the PH does not decrease. Also, even if water with low pH is used in various places, the above-mentioned C
Since it can be neutralized with aO, the activity of microorganisms that purify water can be improved. Further, on the surface of the breeding material 22 containing CaO or the like as the main component, many divalent positive ions such as calcium exist in water. On the other hand, since the microorganisms are usually negatively charged, the water-purifying microorganisms easily adhere to the breeding material 22 and propagate.

【0021】次に、本実施例における水の電気分解装置
5を図1のように200lの浴槽26に取りつけ、陽極
7と陰極8に12Vの直流電圧を印加した時に発生する
活性 アーレーション方式と比較した。その結果を表2に示
す。
Next, as shown in FIG. 1, the water electrolyzer 5 in this embodiment is attached to a 200 l bath 26, and the activity generated when a DC voltage of 12 V is applied to the anode 7 and the cathode 8 is generated. Compared with the aeration method. The results are shown in Table 2.

【0022】[0022]

【表2】 [Table 2]

【0023】表2から本実施例は従来のエアーレーショ
ン方式に比べ活性酸素量と溶存酸素量が非常に多いこと
がわかる。
It can be seen from Table 2 that the present embodiment has a much larger amount of active oxygen and dissolved oxygen than the conventional aeration system.

【0024】さらに、本実施例の活性酸素発生方式と従
来のエアーレーション方式とによる殺菌効果試験と水の
クラスターすなわち水分子集団の大きさの測定を行っ
た。殺菌効果試験は前述の活性酸素を2.0PPm含ん
だイオン交換水と、従来のエアーレーションを行ったイ
オン交換水に大腸菌液を入れ撹拌し、直後に大腸菌数の
測定を行った。その後室温に静置し、この2つの試験水
の大腸菌数を経時的に測定した。その結果を表3に示
す。
Further, the sterilization effect test and the size of water clusters, that is, water molecule populations were measured by the active oxygen generation method of this example and the conventional aeration method. In the bactericidal effect test, the Escherichia coli solution was placed in ion-exchanged water containing 2.0 PPm of active oxygen and ion-exchanged water that had been aerated in the conventional manner, and the mixture was stirred, and immediately after that, the number of E. coli was measured. Then, the mixture was allowed to stand at room temperature, and the E. coli counts of these two test waters were measured over time. Table 3 shows the results.

【0025】[0025]

【表3】 [Table 3]

【0026】表3から活性酸素2.0PPmで大腸菌は
7時間後に0になり、殺菌効果があることがわかった。
From Table 3, it was found that with 2.0 ppm of active oxygen, Escherichia coli became 0 after 7 hours and had a bactericidal effect.

【0027】また、水中に発生させた活性酸素が水の物
性に対する影響を調べるため活性酸素を500PPmま
で溶存させた水と、前記のエアーレーションを行った水
をNMR(核磁気共鳴分光法)を使用して核スペクトル
の測定および半値幅の算出を行った。その結果を図4、
図5に示す。図4より水中に活性酸素を発生させると半
値幅が小さくなり、水のクラスターが小さく変化してい
る事が確認された。この現象は水中に発生させた高い活
性を 子に直接働きかけ、その高い電気陰性度により水分子自
体の結合電子対を壊し、別の結合電子対を構成する段階
で弱い水素結合によって構成されている水分子集団(H
O)nに強い影響を与えているのではないかと推測さ
れる。このクラスターの小さい水は水中に生息する魚や
水草などの生育によい影響を与えるだけでなく、生体組
織の細胞への浸透もスムースになり、生物にとって利用
しやすいやさしい水である。なお、前記の活性酸素は過
酸化水素水に触媒として二酸化マンガンを用いて化2の
通り発生させた活性酸素でも水のクラスターを小さくす
る効果が得られた。
Further, in order to investigate the influence of active oxygen generated in water on the physical properties of water, water in which active oxygen is dissolved up to 500 PPm and water subjected to the aeration are subjected to NMR (nuclear magnetic resonance spectroscopy). It was used to measure the nuclear spectrum and calculate the full width at half maximum. The result is shown in Figure 4.
As shown in FIG. From FIG. 4, it was confirmed that when active oxygen was generated in water, the full width at half maximum became smaller and the water clusters changed smaller. This phenomenon is due to the high activity generated in water Water molecules that directly act on the child, destroy the bond electron pair of the water molecule itself due to its high electronegativity, and form a weak hydrogen bond at the stage of forming another bond electron pair (H
It is presumed that it has a strong influence on 2 O) n. The small water in this cluster not only has a positive effect on the growth of fish and aquatic plants that live in the water, but also allows smooth penetration of cells into living tissues, making it easy to use for living organisms. The active oxygen generated by using manganese dioxide as a catalyst in hydrogen peroxide solution as shown in Chemical formula 2 had the effect of reducing the water cluster.

【0028】[0028]

【化2】 Embedded image

【0029】そして本実施例で次の実験及び測定を行っ
た。 (1)水浄化装置1を設置してから有機物を分解し始め
るまでの時間 (2)アンモニアを酸化分解する微生物数の計測 (3)ステアリン酸を酸化分解する微生物数の計測 実験に用いた浴槽26は、200lの内容積をもつステ
ンレス製のもで水温は42℃に保持した。浄化槽23は
アクリル樹脂の円筒形のもで前記繁殖材22を6l内蔵
した。濾過槽4に用いたフイルター3は繊維束を円周方
向に規則性をもたせてパイプ状に巻いたもので、その大
きさは内径29mm、外径62mm、長さ252mmで
ある。このフイルター3は孔径2〜40μmで気孔率4
0%のものを4本使用した。さらに活性酸素発生手段で
ある電気分解装置5には12Vの直流を印加し活性酸素
を発生させた。また、噴流器30は30l/minの水
と1l/minの気泡を浴槽26に噴射させた。実験は
上記の条件で運転している浴槽26に風呂水の汚れ成分
であるアンモニアやステアリン酸を添加し、アンモニア
の分解性能、PH、アンモニアを酸化分解する微生物の
数、ステアリン酸を酸化分解する微生物の数などを測定
し、従来品と比較した。その結果を図6と表4、及び表
5に示す。
The following experiments and measurements were carried out in this example. (1) Time from installation of water purification device 1 to start decomposing organic matter (2) Measurement of the number of microorganisms that oxidatively decomposes ammonia (3) Measurement of number of microorganisms that oxidatively decomposes stearic acid Bath used in the experiment 26 is a stainless steel rod having an inner volume of 200 l and the water temperature was kept at 42 ° C. The septic tank 23 was a cylinder of acrylic resin and contained 6 liters of the propagation material 22. The filter 3 used in the filtration tank 4 is a fiber bundle having a regularity in the circumferential direction and wound in a pipe shape, and its size is 29 mm in inner diameter, 62 mm in outer diameter, and 252 mm in length. This filter 3 has a pore diameter of 2 to 40 μm and a porosity of 4
Four 0% ones were used. Further, a direct current of 12 V was applied to the electrolyzer 5 as the active oxygen generating means to generate active oxygen. Further, the jet device 30 jetted 30 l / min of water and 1 l / min of bubbles into the bath 26. In the experiment, ammonia and stearic acid, which are dirty components of bath water, are added to the bath 26 operating under the above conditions, and the decomposition performance of ammonia, PH, the number of microorganisms that oxidatively decompose ammonia, and oxidatively decompose stearic acid. The number of microorganisms was measured and compared with the conventional product. The results are shown in FIG. 6 and Tables 4 and 5.

【0030】[0030]

【表4】 [Table 4]

【0031】[0031]

【表5】 [Table 5]

【0032】図6より本実施例は、設置してからアンモ
ニアの酸化分解を始める迄の時間が従来品に比較して非
常に早いことが判明した。また、表4よりアンモニアを
酸化分解する微生物も従来品に比較して短時間に多く繁
殖していることが確認できた 成しても常に一定で安定しているが、従来品はアンモニ
アの分解が始まるとPHが低下してしまうのでアンモニ
アが完全に分解できなかった。さらに、表5よりステア
リン酸を分解する微生物も従来品に比較して短時間に多
く繁殖させることができる。
From FIG. 6, it was found that the time from the installation to the start of the oxidative decomposition of ammonia is much shorter than that of the conventional product in this embodiment. In addition, it was confirmed from Table 4 that a large number of microorganisms that oxidatively decompose ammonia bred in a shorter time than the conventional products. Even if it is formed, it is always constant and stable, but the conventional product could not completely decompose ammonia because the PH decreases when the decomposition of ammonia starts. Furthermore, from Table 5, it is possible to propagate more microorganisms that decompose stearic acid in a shorter time than the conventional products.

【0033】(実施例2)本実施例は浄化装置を鑑賞魚
水槽に用いた場合である。図中32は直流電源33に陽
極34と陰極35を連結した活性酸素発生手段の電気分
解装置であって、透明な水槽36内に陽極34と陰極3
5を対応設置している。37は塩基性物質を主成分とす
るセラミックからなる繁殖材であって、水槽36底面に
設け水草38を植えている。
(Embodiment 2) In this embodiment, the purifying device is used in an ornamental fish tank. In the figure, reference numeral 32 denotes an electrolyzer of active oxygen generating means in which a DC power source 33 is connected to an anode 34 and a cathode 35, and the anode 34 and the cathode 3 are placed in a transparent water tank 36.
5 is installed correspondingly. 37 is a breeding material composed of a ceramic containing a basic substance as a main component, and is provided on the bottom surface of the water tank 36 to plant aquatic plants 38.

【0034】[0034]

【作用】水槽36内の水は電気分解装置32によって陽
極34から活性酸素を含んだ酸素が発生して供給される
と共に、水中の有機物を分解する好気性微生物を繁殖材
37にて繁殖し、水を浄化している。そして本実施例に
おいて、60lの水槽に大きさ約5cmの鑑賞魚49を
10匹入れ、毎日窒素含有量30mgの餌を与えながら
水温25℃で飼育した。その時の水中に発生するアンモ
ニア量や藻類の繁殖状態、さらに鑑賞魚49や水草38
の育成状態などを従来品と比較した。図9に水中のアン
モニア量の測定結果を示す。
The water in the water tank 36 is supplied with oxygen containing active oxygen generated from the anode 34 by the electrolyzer 32, and at the same time, the aerobic microorganisms that decompose organic matters in the water are propagated by the breeding material 37. Purifying water. In this example, 10 pieces of ornamental fish 49 having a size of about 5 cm were placed in a 60-liter water tank and bred at a water temperature of 25 ° C. while feeding a diet having a nitrogen content of 30 mg every day. The amount of ammonia generated in the water at that time and the breeding state of algae, as well as appreciation fish 49 and aquatic plants 38
The growing condition and the like were compared with the conventional product. FIG. 9 shows the measurement result of the amount of ammonia in water.

【0035】図9より本実施例では残餌や鑑賞魚の***
物からできるアンモニアを分解できるが、従来品はでき
なかった。また、本発明品は藻類の繁殖がなく実験期間
6ケ月間水槽も水もきれいであったので、一度も掃除や
水換えをしなかったが、従来品は水槽に2週間で藻が発
生し水も汚くなるので2週間毎に掃除と水換えを行っ
た。さらに鑑賞魚や水草の生育も本実施例の方がよかっ
た。なお、前記活性酸素は過酸化水素水に触媒として二
酸化マンガンを加えて前述の化2の通り発生させた活性
酸素でも上記と同じ結果が得られた。
As shown in FIG. 9, in the present embodiment, ammonia produced from the leftover food and excrement of ornamental fish can be decomposed, but the conventional product could not. In addition, since the product of the present invention did not reproduce algae and the water tank and water were clean for the experiment period of 6 months, it was never cleaned or changed. However, the conventional product generated algae in the water tank in 2 weeks. The water becomes dirty, so I cleaned and changed the water every two weeks. Furthermore, the growth of the appreciation fish and aquatic plants was also better in this example. As the active oxygen, the same result as above was obtained with active oxygen generated by adding manganese dioxide as a catalyst to hydrogen peroxide solution as shown in Chemical formula 2 above.

【0036】(実施例3)本実施例は浄化装置を使用済
みブライン・不凍液の分解浄化に用いた場合である。図
中39はブライン・不凍液を入れた水槽であって、ポン
プ40を介して塩基性物質を主成分とするセラミックか
らなる繁殖材41を内蔵する分解浄化槽42に配管43
にて連結すると共に、配管44にて分解浄化槽42より
水槽39上方となるよう循環を可能に設けている。活性
酸素発生手段として、45は酸素発生槽であって、二酸
化マンガンを主成分とする触媒46を内蔵し、水槽39
の底部に設け、水槽39外部に設けた過酸化水素水の入
った容器47とチューブ48にて接続している。
(Embodiment 3) In this embodiment, the purifying device is used for decomposing and purifying used brine / antifreeze liquid. In the figure, 39 is a water tank containing brine and antifreeze liquid, and a pipe 43 is provided in a decomposition / purification tank 42 containing a breeding material 41 made of a ceramic containing a basic substance as a main component via a pump 40.
And the pipe 44 is provided so as to be circulated above the water tank 39 above the decomposition and purification tank 42. As an active oxygen generating means, 45 is an oxygen generating tank, which contains a catalyst 46 containing manganese dioxide as a main component, and a water tank 39.
A tube 47 is connected to a container 47, which is provided at the bottom of the tank and contains hydrogen peroxide solution, provided outside the water tank 39.

【0037】[0037]

【作用】使用済みブライン・不凍液は、活性酸素発生手
段の酸素発生槽45から発生した活性酸素を含む溶存酸
素を含みながらポンプ40で前述の繁殖材41を内蔵し
た分解浄化槽42に入り、ここで繁殖材41に繁殖させ
たエチレングリコールやプロピレングリコールの酸化分
解微生物で分解された後、処理槽39に戻る。そして本
実施例において、100lの槽39に500PPmの使
用済みブライン・不凍液を入れ、35%の過酸化水素水
の入った容器47から過酸化水素水を触媒46に供給
し、発生した活性酸素を含んだブライン・不凍液を5l
/minの流量で6lの繁殖材41の入った分解浄化槽
42に供給しながら循環し、水槽39の中のエチレング
リコールやプロピレングリコールの濃度を測定した。又
水槽39の中の温度は35℃に保ちながら従来品と比較
した。その結果を図11に示す。
The used brine / antifreeze liquid enters the decomposition / purification tank 42 containing the above-mentioned breeding material 41 by the pump 40 while containing the dissolved oxygen containing the active oxygen generated from the oxygen generating tank 45 of the active oxygen generating means, and here, After being decomposed by the oxidative decomposition microorganisms of ethylene glycol and propylene glycol propagated in the propagation material 41, the process returns to the treatment tank 39. In this embodiment, 500 PPm of used brine / antifreeze solution is put in a 100-liter tank 39, hydrogen peroxide solution is supplied to a catalyst 46 from a container 47 containing 35% hydrogen peroxide solution, and the generated active oxygen is generated. 5 liters containing brine and antifreeze
The concentration of ethylene glycol and propylene glycol in the water tank 39 was measured while circulating the water while supplying it to the decomposition and purification tank 42 containing 6 l of the propagation material 41 at a flow rate of / min. Further, the temperature in the water tank 39 was kept at 35 ° C. and compared with the conventional product. The result is shown in FIG.

【0038】図11から従来のエアーレーションによる
酸素供給方式では、エチレングリコールやプロピレング
リコールを主成分とするブライン・不凍液は分解できな
かったが、本実施例では分解できることが判明した。本
実験のようにブライン・不凍液は、有機物量が多いので
従来方式では酸素が不足して好気性微生物が死滅してし
まうものと考えられる。これに対して本実施例は、前述
のように活性酸素量と溶存酸素量が多いので好気性微生
物が活発に働き、分解ができるようになったと推定でき
る。なお、本実施例で活性酸素を電気分解装置で発生さ
せても同じ結果が得られた。
From FIG. 11, it was found that the brine / antifreeze solution containing ethylene glycol or propylene glycol as the main component could not be decomposed by the conventional aeration oxygen supply system, but could be decomposed by this embodiment. As in the present experiment, since the brine / antifreeze solution has a large amount of organic matter, it is considered that the conventional method lacks oxygen and kills aerobic microorganisms. On the other hand, in this example, since the amount of active oxygen and the amount of dissolved oxygen are large as described above, it can be presumed that the aerobic microorganisms are actively working and can be decomposed. In addition, the same result was obtained even when active oxygen was generated in the electrolyzer in this example.

【0039】[0039]

【発明の効果】以上のように本発明の水浄化装置によれ
ば次の効果を得る事ができる。 (1)の従来のエアーレーション方式に比較して、活性
酸素量や溶存酸素量がはるかに多いので、水中の有機物
を分解する好気性微生物の繁殖が早くなり、さらに活性
化されるので、設置してから水を浄化するまでの時間が
早くなるとともに有機物を完全に分解できる。 (2)従来分解できなかったエチレングリコールやプロ
ピレングリコールやステアリン酸なども分解できる。 (3)活性酸素が藻類やバクテリアなどと素早く接触反
応し、これらを破壊しながら純粋酸素(O)に変化す
るので、生体に安全に、これらを死滅させることができ
る。 (4)水のクラスターを小さくするので、人体や魚や水
草などに利用しやすいやさしい水にすることができる。 (5)繁殖材を塩基性物質で構成しているので、有機物
を分解して酸が生成しても好気性微生物が繁殖している
繁殖材の周囲はPHの低下がなく、前記微生物の高活性
が維持できる。 (6)活性酸素発生手段として電気分解装置を使用する
場合、陽極と陰極を一定時間毎に極性を逆転して直流電
圧を印加するので、自動的に付着したスケールを除去で
き、長時間連続的に電気分解が可能である。 このように多くの特長を有し産業利用上非常に優れた発
明である。
As described above, according to the water purifying apparatus of the present invention, the following effects can be obtained. Compared with the conventional aeration method of (1), since the amount of active oxygen and dissolved oxygen is much larger, the aerobic microorganisms that decompose organic matter in water grow faster and are further activated. After that, it takes less time to purify water, and organic substances can be completely decomposed. (2) It can decompose ethylene glycol, propylene glycol, stearic acid, etc., which could not be decomposed conventionally. (3) Since active oxygen rapidly reacts with algae, bacteria, etc. and changes them into pure oxygen (O 2 ) while destroying them, these can be safely killed by the living body. (4) Since water clusters are made smaller, it is possible to make water that is easy to use for the human body, fish, water plants, etc. (5) Since the breeding material is composed of a basic substance, even if the organic substance is decomposed to generate an acid, the aerobic microorganisms are propagated. The activity can be maintained. (6) When an electrolyzer is used as the active oxygen generating means, the polarity of the anode and the cathode are reversed at regular time intervals and a DC voltage is applied, so that the scale that has adhered can be removed automatically, and continuous operation is possible for a long time. It can be electrolyzed. As described above, the invention has many features and is a very excellent invention for industrial use.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明実施例1の概略構成図である。FIG. 1 is a schematic configuration diagram of a first embodiment of the present invention.

【図2】本発明実施例1の電気分解装置の概略構成図で
ある。
FIG. 2 is a schematic configuration diagram of an electrolysis device according to a first embodiment of the present invention.

【図3】本発明実施例1の繁殖材の斜視図である。FIG. 3 is a perspective view of a breeding material of Example 1 of the present invention.

【図4】本発明実施例1の電気分解装置による活性酸素
水の核スペクトル測定図である。
FIG. 4 is a nuclear spectrum measurement diagram of active oxygen water by the electrolyzer of Example 1 of the present invention.

【図5】従来のエアーレーションによる溶存酸素水の核
スペクトル測定図である。
FIG. 5 is a nuclear spectrum measurement diagram of dissolved oxygen water by conventional aeration.

【図6】(イ)は本発明実施例1の風呂水のアンモニア
濃度測定図である。(ロ)は本発明実施例1の風呂水の
PH測定図である。
FIG. 6A is an ammonia concentration measurement diagram of bath water of Example 1 of the present invention. (B) is a pH measurement diagram of bath water of Example 1 of the present invention.

【図7】本発明実施例1の水浄化微生物の活性と水のP
Hとの関係図である。
FIG. 7: Activity of water-purifying microorganisms and water P of Example 1 of the present invention
It is a relationship diagram with H.

【図8】本発明実施例2の概略構成図である。FIG. 8 is a schematic configuration diagram of a second embodiment of the present invention.

【図9】本発明実施例2の水槽水のアンモニア濃度測定
図である。
FIG. 9 is a diagram for measuring the ammonia concentration of the aquarium water of Example 2 of the present invention.

【図10】本発明実施例3の概略構成図である。FIG. 10 is a schematic configuration diagram of a third embodiment of the present invention.

【図11】本発明実施例3のブライン・不凍液の分解特
性図である。
FIG. 11 is a decomposition characteristic diagram of the brine / antifreeze liquid of Example 3 of the present invention.

【図12】従来の風呂水浄化装置の概要図である。FIG. 12 is a schematic diagram of a conventional bath water purifying apparatus.

【図13】従来の鑑賞魚用浄化装置の概要図である。FIG. 13 is a schematic diagram of a conventional purification device for ornamental fish.

【図14】従来のブライン・不凍液分解装置の概要図で
ある。
FIG. 14 is a schematic view of a conventional brine / antifreeze liquid decomposition apparatus.

【符号の説明】[Explanation of symbols]

1 風呂水浄化装置 2 濾過装置 3 フイルター 4 濾過槽 5 電気分解装置 6 繁殖装置 7 陽極 8 陰極 9 直流電源 12 交流電源 13 電源スイッチ 14 ヒューズ 15 トランス 16 整流回路 16a 正極 16b 負極 17 平滑コンデンサー 18 極性反転用リレー 19a 可動接点 19b 固定接点 19c 固定接点 20a 可動接点 20b 固定接点 20c 固定接点 21 制御回路 22 繁殖材 23 浄化槽 26 浴槽 27 流入口 28 流出口 29 強制循環流路 29a 往路 29b 復路 30 噴流器 31 流通管 32 電気分解装置 33 直流電源 34 陽極 35 陰極 36 水槽 37 繁殖材 38 水草 39 水槽 40 ポンプ 41 繁殖材 42 分解浄化槽 45 酸素発生槽 46 触媒 47 容器 48 チューブ 49 鑑賞魚 1 Bath water purifying device 2 Filtration device 3 Filter 4 Filter tank 5 Electrolyzer 6 Propagation device 7 Anode 8 Cathode 9 DC power supply 12 AC power supply 13 Power switch 14 Fuse 15 Transformer 16 Rectifier circuit 16a Positive electrode 16b Negative electrode 17 Smoothing capacitor 18 Polarity reversal Relay 19a Movable contact 19b Fixed contact 19c Fixed contact 20a Movable contact 20b Fixed contact 20c Fixed contact 21 Control circuit 22 Breeding material 23 Septic tank 26 Bath tub 27 Inlet 28 Outlet 29 Forced circulation passage 29a Outgoing 29b Return 30 Spout 31 Flow Tube 32 Electrolyzer 33 DC power source 34 Anode 35 Cathode 36 Water tank 37 Breeding material 38 Waterweed 39 Water tank 40 Pump 41 Breeding material 42 Decomposition / purification tank 45 Oxygen generation tank 46 Catalyst 47 Container 48 Tube 49 Watching fish

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 水中に活性酸素(スーパーオキサイドア
ニオンラジカル・O 水中の有機物を分解する微生物を繁殖材(バイオキャリ
ア)で繁殖させる微生物繁殖手段とを備えた水浄化装
置。
1. Active oxygen (superoxide anion radical.O in water) A water purification device equipped with a microorganism breeding means for breeding microorganisms that decompose organic matter in water with a breeding material (biocarrier).
【請求項2】 活性酸素発生手段として水の電気分解装
置を用いた請求項1記載の水浄化装置。
2. The water purifier according to claim 1, wherein an electrolyzer of water is used as the active oxygen generating means.
【請求項3】 陽極と陰極に直流電圧を印加する回路に
設けられる少なくとも極性反転用リレーを作動する制御
回路を備えた請求項2記載の電気分解装置。
3. The electrolyzer according to claim 2, further comprising a control circuit that operates at least a polarity reversing relay provided in a circuit that applies a DC voltage to the anode and the cathode.
【請求項4】 活性酸素発生手段として過酸化水素水と
触媒を用いた請求項1記載の水浄化装置。
4. The water purifying apparatus according to claim 1, wherein hydrogen peroxide solution and a catalyst are used as the active oxygen generating means.
【請求項5】 二酸化マンガンを主成分とした材料を用
いた請求項4記載の触媒。
5. The catalyst according to claim 4, wherein a material containing manganese dioxide as a main component is used.
【請求項6】 繁殖材はカルシウムもしくはマグネシウ
ムの酸化物、ケイ酸塩、アルミン酸塩、炭酸塩より選択
した少なくとも一種を含む塩基性セラミックで構成した
請求項1記載の水浄化装置。
6. The water purifier according to claim 1, wherein the propagation material is composed of a basic ceramic containing at least one selected from oxides of calcium or magnesium, silicates, aluminates and carbonates.
【請求項7】 活性酸素が殺菌作用をする請求項1記載
の水浄化装置。
7. The water purifier according to claim 1, wherein active oxygen has a bactericidal action.
【請求項8】 活性酸素が水のクラスターを小さくする
請求項1記載の水浄化装置。
8. The water purifier according to claim 1, wherein the active oxygen reduces water clusters.
JP18423194A 1994-07-02 1994-07-02 Water purifying device Pending JPH0810789A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18423194A JPH0810789A (en) 1994-07-02 1994-07-02 Water purifying device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18423194A JPH0810789A (en) 1994-07-02 1994-07-02 Water purifying device

Publications (1)

Publication Number Publication Date
JPH0810789A true JPH0810789A (en) 1996-01-16

Family

ID=16149674

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18423194A Pending JPH0810789A (en) 1994-07-02 1994-07-02 Water purifying device

Country Status (1)

Country Link
JP (1) JPH0810789A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0861887A3 (en) * 1997-02-18 1999-08-04 Canon Kabushiki Kaisha Microbial processes using electrolyzed water
KR20010060858A (en) * 1999-12-28 2001-07-07 이양우 Method for manufacturing active oxygen and apparatus thereof
KR20030096534A (en) * 2002-06-12 2003-12-31 정종호 Apparatus for mixing and dissolving oxygen
WO2010049971A1 (en) * 2008-10-29 2010-05-06 Asaoka Keiichiro Apparatus for treating organic wastewater and method of treating organic wastewater
KR20210112927A (en) * 2020-03-06 2021-09-15 조용성 Bathtub with sterilization function for pets
CN113957460A (en) * 2021-10-27 2022-01-21 国红环保科技有限责任公司 Method for synthesizing hydrogen peroxide based on alternating current electrolysis, device and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0861887A3 (en) * 1997-02-18 1999-08-04 Canon Kabushiki Kaisha Microbial processes using electrolyzed water
KR20010060858A (en) * 1999-12-28 2001-07-07 이양우 Method for manufacturing active oxygen and apparatus thereof
KR20030096534A (en) * 2002-06-12 2003-12-31 정종호 Apparatus for mixing and dissolving oxygen
WO2010049971A1 (en) * 2008-10-29 2010-05-06 Asaoka Keiichiro Apparatus for treating organic wastewater and method of treating organic wastewater
KR20210112927A (en) * 2020-03-06 2021-09-15 조용성 Bathtub with sterilization function for pets
CN113957460A (en) * 2021-10-27 2022-01-21 国红环保科技有限责任公司 Method for synthesizing hydrogen peroxide based on alternating current electrolysis, device and application thereof

Similar Documents

Publication Publication Date Title
CN102687699B (en) Seawater cleaning system for aquiculture and seedling raising and use method of same
CN206188442U (en) Circulation mariculture water processing system based on nanometer photoelectrocatalysis technique
JPH0810789A (en) Water purifying device
JP4854623B2 (en) Water treatment system
JPH0615276A (en) Electrolytic disinfection of water and flowing water type water electrolytic disinfector
JPH09187773A (en) Water purifying device
JP3918133B2 (en) Water purification method and purification device
KR101055417B1 (en) Process and treatment system for water for aquatic products
JPH0970586A (en) Water purifying device
US10820579B2 (en) Water quality purification device, water purifier and aquarium using the same
KR100602058B1 (en) Electrolysis and electro-coagulation treatment apparatus of wastewater
JPH04118099A (en) Water purifier
KR0121077Y1 (en) Apparatus for the purification of excretions with electrolysis
KR100579254B1 (en) Electrolytic treatment of wastewater
JPH05131198A (en) Sea water purification device
JPH0377698A (en) Water sterilizing and purifying device
WO2024029555A1 (en) System for denitrification, sterilization, and decoloring treatment of rearing water, and method for denitrification, sterilization, and decoloring treatment of rearing water
JPH07163982A (en) Electrolytic sterilization device for stored water
CN102234149A (en) Method for sterilizing raw water
KR100801493B1 (en) The waste water purifying apparatus of an aquarium
SU1756288A1 (en) Waste water cleaning facility
JP2001314851A (en) Water circulating and sterilizing apparatus
JPH11253958A (en) Apparatus and method for electrolytic sterilization
KR950013318B1 (en) Water purification apparatus
CN109761451A (en) A kind of administering method of petroleum-contaminated water containing algae