JPH0778009B2 - Transparent skin cosmetics - Google Patents
Transparent skin cosmeticsInfo
- Publication number
- JPH0778009B2 JPH0778009B2 JP61301083A JP30108386A JPH0778009B2 JP H0778009 B2 JPH0778009 B2 JP H0778009B2 JP 61301083 A JP61301083 A JP 61301083A JP 30108386 A JP30108386 A JP 30108386A JP H0778009 B2 JPH0778009 B2 JP H0778009B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- water
- transparent
- final composition
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、液状油性物質を多量含有しており、しかも外
観が透明な皮膚化粧料に関する。更に詳しくは、安全性
が高く、保存安定性（経日安定性）に優れ、かつ感触，
外観（透明性），クレンジング効果，水洗性等の良好
な、液状油性物質を多量含有する透明皮膚化粧料に関す
る。TECHNICAL FIELD The present invention relates to a skin cosmetic containing a large amount of a liquid oily substance and having a transparent appearance. More specifically, it is highly safe, has excellent storage stability (day-to-day stability), and feels
The present invention relates to a transparent skin cosmetic containing a large amount of a liquid oily substance, which has good appearance (transparency), cleansing effect, washability, and the like.
（従来技術） 従来、化粧料等に用いられている油性物質を含有する透
明化粧料には、一般にマイクロエマルジョンがあるが、
界面活性剤を多量に使用する為、皮膚に刺激を与えると
いう問題があった。その為、使用する界面活性剤の量を
減少させる研究がなされ、第１段階として親水性非イオ
ン界面活性剤を水溶性溶媒中に添加し、次にこれに油相
を添加して水溶性溶媒中油型エマルジョンを調製し、第
２段として該エマルジョンに水を添加せしめて、親水性
非イオン界面活性剤のみでしかも従来の乳化系に比較し
て半量以下で安定な水中油型エマルジョンを得る方法が
提案された（特公昭57−29213）。(Prior Art) Conventionally, there are microemulsions in transparent cosmetics containing an oily substance that are used in cosmetics, etc.
Since a large amount of a surfactant is used, there is a problem of irritating the skin. Therefore, studies have been conducted to reduce the amount of surfactant used. As a first step, a hydrophilic nonionic surfactant is added to a water-soluble solvent, and then an oil phase is added to this to add a water-soluble solvent. A method of preparing an oil-in-water emulsion and adding water to the emulsion as a second step to obtain an oil-in-water emulsion stable with only a hydrophilic nonionic surfactant and less than half the amount of a conventional emulsification system. Was proposed (JP-B-57-29213).
（発明が解決しようとする問題点） しかしながらこの方法で得られたエマルジョンでは、乳
化安定性が十分とはいえず、また油相／水相比の高いエ
マルジョンが得にくいなどの問題がある。(Problems to be Solved by the Invention) However, the emulsion obtained by this method has problems such as insufficient emulsion stability and difficulty in obtaining an emulsion having a high oil phase / water phase ratio.
（問題点を解決するための手段） 本発明者は、前記従来技術の問題点を改良すべく鋭意研
究を重ねた結果、ジアルキルリン酸エステル系界面活性
剤及び／又はトリアルキルリン酸エステル系界面活性剤
と多量の液状油性物質との混合物を、多価アルコールと
水との混合物に添加混合する場合は、容易に安全性が高
く、保存安定性（経日安定性）に優れ、かつ感触，外観
（透明性），クレンジング効果，水洗性等の良好な透明
皮膚化粧料が得られることを見出し、本発明を完成し
た。(Means for Solving Problems) As a result of earnest studies to improve the problems of the above-mentioned conventional techniques, the present inventor has found that dialkyl phosphate ester-based surfactants and / or trialkyl phosphate ester-based interfaces When a mixture of an active agent and a large amount of liquid oily substance is added and mixed to a mixture of polyhydric alcohol and water, it is easy to have high safety, excellent storage stability (stable stability over time), and feeling, The inventors have found that a transparent skin cosmetic having good appearance (transparency), cleansing effect, and washability can be obtained, and completed the present invention.
すなわち、本発明は、ジアルキルリン酸エステル系界面
活性剤及び／又はトリアルキルリン酸エステル系界面活
性剤と40〜90重量％（重量％は最終組成物の重量基準）
の液状油性物質との混合物を、水の重量に対して４倍量
以上でかつ最終組成物の重量に対して５〜59重量％の多
価アルコールと水との混合物に、添加、混合してなる、
透明皮膚化粧料である。That is, the present invention comprises a dialkyl phosphate ester-based surfactant and / or a trialkyl phosphate ester-based surfactant and 40 to 90% by weight (% by weight is based on the weight of the final composition).
The mixture with the liquid oily substance is added to and mixed with a mixture of polyhydric alcohol and water in an amount of 4 times the amount of water or more and 5 to 59% by weight of the final composition. Become,
It is a transparent skin cosmetic.
本発明で使用される前記のジアルキルリン酸エステル系
界面活性剤及び／又はトリアルキルリン酸エステル系界
面活性剤としては、下記の式（１），（２）で表される
化合物が好ましい。The dialkyl phosphate ester-based surfactant and / or the trialkyl phosphate ester-based surfactant used in the present invention are preferably compounds represented by the following formulas (1) and (2).
（上記の各式中で、R1,R2,R3はエチレン基またはプロピ
レン基を示し、R4,R5,R6は炭素数８〜22の直鎖または分
枝アルキル基またはアルケニル基を示し、l,m,nは０〜3
0の整数を示し、Ｍはカリウムまたはナトリウム、Ｘは
水素原子またはカリウム，ナトリウムである。） ジアルキルリン酸エステル系界面活性剤及び／又はトリ
アルキルリン酸エステル系界面活性剤の使用量（配合
量）は、最終組成物の重量に対して0.5〜10重量％であ
る。0.5重量％よりも少ないと保存安定性が低下する傾
向があり、10重量％よりも多くなると透明度が低下する
傾向がある。 (In the above formulas, R 1 , R 2 and R 3 represent an ethylene group or a propylene group, and R 4 , R 5 and R 6 represent a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms. , L, m, n are 0 to 3
It represents an integer of 0, M is potassium or sodium, and X is a hydrogen atom or potassium or sodium. ) The amount (blending amount) of the dialkyl phosphate ester-based surfactant and / or the trialkyl phosphate ester-based surfactant used is 0.5 to 10% by weight based on the weight of the final composition. If it is less than 0.5% by weight, the storage stability tends to decrease, and if it exceeds 10% by weight, the transparency tends to decrease.
本発明で使用される多価アルコールとしては、例えば、
エチレングリコール，プロピレングリコール,1,3−ブチ
レングリコール，ジプロピレングリコール，グリセリ
ン，ジグリセリン・トリグリセリン・テトラグリセリン
等のポリグリセリン，グルコース，マルトース，マルチ
トール，蔗糖，フラクトース，キシリトール，イノシト
ール，ペンタエリスリトール，ソルビトール，マルトト
リオール，スレイトール，澱粉分解糖，澱粉分解糖還元
アルコール等が挙げられ、これらを一種又は二種以上組
合せて用いるものである。Examples of the polyhydric alcohol used in the present invention include:
Polyglycerin such as ethylene glycol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerin / triglycerin / tetraglycerin, glucose, maltose, maltitol, sucrose, fructose, xylitol, inositol, pentaerythritol, Examples thereof include sorbitol, maltotriol, threitol, starch-decomposing sugar, starch-decomposing sugar reducing alcohol and the like, and these are used alone or in combination of two or more kinds.
多価アルコールの使用量は、水の重量に対して４倍量以
上（好ましくは４〜118倍量）で、かつ最終組成物の重
量に対して５〜59重量％である。多価アルコールの使用
量が水の重量に対して４倍量未満では透明度が不充分で
あり、そして、最終組成物の重量に対して５重量％未満
では保存安定性が低下しやすく、また59重量％よりも多
くなると感触，クレンジング効果が低下しやすい。The amount of polyhydric alcohol used is 4 times or more (preferably 4 to 118 times) the weight of water, and 5 to 59% by weight with respect to the weight of the final composition. If the amount of the polyhydric alcohol used is less than 4 times the weight of water, the transparency is insufficient, and if it is less than 5% by weight with respect to the weight of the final composition, the storage stability tends to decrease. If it is more than wt%, the feel and cleansing effect are likely to deteriorate.
本発明に使用される液状油性物質は、常温下で液状を呈
する公知の化粧料用液状油性物質であって、液状の高級
脂肪族炭化水素類，動植物性油脂類、高級アルコール，
高級脂肪酸，合成エステル油，グリコール高級脂肪酸エ
ステル，シリコン油等である。例えば、流動パラフィ
ン，スクワラン，オリーブ油，ヒマシ油，ホホバ油，オ
クチルドデカノール，オクチルドデシルミリステート，
ジイソプロピルアジペート,2−エチルヘキサン酸トリグ
リセリド，カプリン酸トリグリセリド，オレイルアルコ
ール，オレイン酸等を挙げることができる。これらの液
状油性物質は、一種又は二種以上組合せて用いるもので
ある。液状油性物質の使用量は、最終組成物の重量に対
して40〜90重量％使用される。40重量％より少ない場合
は、感触，クレンジング効果がわるくなりやすく、また
90重量％を超えると保存安定性が低下しやすい。The liquid oily substance used in the present invention is a known liquid oily substance for cosmetics which is in a liquid state at room temperature, and is a liquid higher aliphatic hydrocarbon, animal and vegetable oils and fats, higher alcohols,
Higher fatty acid, synthetic ester oil, glycol higher fatty acid ester, silicone oil and the like. For example, liquid paraffin, squalane, olive oil, castor oil, jojoba oil, octyldodecanol, octyldodecyl myristate,
Examples thereof include diisopropyl adipate, 2-ethylhexanoic acid triglyceride, capric acid triglyceride, oleyl alcohol, and oleic acid. These liquid oily substances are used alone or in combination of two or more. The liquid oily substance is used in an amount of 40 to 90% by weight based on the weight of the final composition. If the amount is less than 40% by weight, the feel and cleansing effect are likely to be poor, and
If it exceeds 90% by weight, the storage stability tends to decrease.
また、水の量は本発明の最終組成物の透明度に応じて適
宜選択しうるが、通常0.5〜15％範囲が好ましい。The amount of water can be appropriately selected depending on the transparency of the final composition of the present invention, but is usually preferably in the range of 0.5 to 15%.
本発明の透明皮膚化粧料には、前記成分の他に必要に応
じて、香料，着色剤，防腐剤，金属イオン封鎖剤，皮膚
栄養剤，感触調整剤,PH調整剤、液状以外の油性物質、
上記以外の非イオン活性剤やアニオン活性剤、両性活性
剤等を上記効果を阻害しない範囲内で配合することがで
きる。In addition to the above-mentioned components, the transparent skin cosmetics of the present invention may optionally contain fragrances, colorants, preservatives, sequestering agents for skin, skin nutritional agents, feel modifiers, pH modifiers, oily substances other than liquid ,
Other nonionic activators, anionic activators, amphoteric activators and the like can be added within the range that does not impair the above effects.
本発明の透明皮膚化粧料は、例えばジアルキルリン酸エ
ステル系界面活性剤及び／又はトリアルキルリン酸エス
テル系界面活性剤と液状油性物質を適温（例えば80℃）
下で混合して均一に溶解した後、この混和物を、多価ア
ルコールと水との混和物（例えば80℃）の中に、適当な
混合機（例えばラボミキサー）で攪拌しながら徐々に添
加して均一に混合すると乳化（または可溶化）して透明
度の極めて高いかつ粘稠液体またはゲル状物のかたちで
生成し、次にこれを適温（約30℃）まで冷却して取得さ
れる。The transparent skin cosmetic of the present invention comprises, for example, a dialkyl phosphate ester surfactant and / or a trialkyl phosphate ester surfactant and a liquid oily substance at an appropriate temperature (for example, 80 ° C.).
After mixing below and dissolving uniformly, this mixture is gradually added to the mixture of polyhydric alcohol and water (eg 80 ° C) while stirring with an appropriate mixer (eg lab mixer). When homogeneously mixed, it is emulsified (or solubilized) to form a highly transparent and viscous liquid or gel, which is then cooled to an appropriate temperature (about 30 ° C.).
本発明の透明皮膚化粧料は、ゲル状又は粘稠液体であっ
て、洗い流し可能な例えば透明ゲル状クレンジング及び
透明マッサージクリーム，透明ナリシングオイル，透明
ナリシングクリーム等として極めて有用である。INDUSTRIAL APPLICABILITY The transparent skin cosmetic of the present invention is a gel-like or viscous liquid and is extremely useful as a washable cleansing gel-like cleansing and transparent massage cream, transparent nourishing oil, transparent nourishing cream and the like.
（実施例） 次に実施例を挙げて本発明を説明するが、本発明はこれ
により限定されるものではない。実施例に示す部とは、
重量部を意味する。(Example) Next, although an Example is given and this invention is demonstrated, this invention is not limited by this. The parts shown in the examples are
Means parts by weight.
実施例１、比較例1,2,3 実施例１は第１表に基づく処方で、，を約80℃にて
均一に溶解する（溶液Ａ）。また，を約80℃にて均
一に溶解する（溶液Ｂ）。次に溶液Ｂに溶液Ａを徐々に
加えラボミキサーで攪拌混合した後、30℃まで冷却して
本発明の透明クレンジングクリームを調製した。Example 1 and Comparative Examples 1, 2 and 3 Example 1 is a formulation based on Table 1, and is uniformly dissolved at about 80 ° C. (Solution A). Also, is uniformly dissolved at about 80 ° C. (Solution B). Next, the solution A was gradually added to the solution B, stirred and mixed with a lab mixer, and then cooled to 30 ° C. to prepare a transparent cleansing cream of the present invention.
比較例１および３は第１表に基づく処方で、の代わり
にそれぞれ、を使用する以外は実施例１と同様の方
法で調製した。Comparative Examples 1 and 3 were prepared in the same manner as in Example 1 except that each of the formulations was based on Table 1 and was used instead of.
比較例２は第１表に基づく処方で、，を約80℃にて
均一に溶解する（溶液Ａ）。溶液Ａに、予め約80℃に加
熱混合したを徐々に加えラボミキサーで攪拌混合した
後、更にを加えラボミキサーで攪拌混合し、これを30
℃まで冷却して調製した。Comparative Example 2 has a formulation based on Table 1, and is uniformly dissolved at about 80 ° C. (Solution A). To the solution A, which was previously mixed by heating to about 80 ° C, was gradually added and mixed by stirring with a lab mixer, and then further added and mixed by stirring with a lab mixer.
It was prepared by cooling to 0 ° C.
皮膚化粧料の保存安定性は40℃の恒温槽内で２ケ月間保
存後の外観状態より判定した。また透明性は肉眼によっ
て判定した。The storage stability of the skin cosmetics was judged from the appearance after storage for 2 months in a constant temperature bath at 40 ° C. The transparency was judged by the naked eye.
実施例１では保存安定性，透明性ともに極めて良好であ
ったが、比較例１、３では透明性はやや良好であったが
保存安定性は不良（分離）であった。In Example 1, both the storage stability and the transparency were extremely good, but in Comparative Examples 1 and 3, the transparency was slightly good but the storage stability was poor (separation).
また、比較例２は調製直後に分離を起した。In Comparative Example 2, separation occurred immediately after preparation.
実施例２〜４、比較例４ 実施例２〜比較例４は第２表に基づく処方で、実施例１
に準じて調製した。表中のクレンジング効果は次の方法
にて調べた。 Examples 2 to 4 and Comparative Example 4 Examples 2 to 4 are formulations based on Table 2, and Example 1
Was prepared according to. The cleansing effect in the table was examined by the following method.
二酸化チタン5.0％，赤色204号0.6％，橙色204号5.0
％，キャンデリラロウ9.3％，赤色223号0.2％，固形パ
ラフィン8.0％，ミツロウ5.0％，カルナウバロウ5.0
％、ラノリン11.0％，ヒマシ油44.8％，イソプロピルミ
リステート10％からなる口紅を油性汚れとして、これを
前腕屈側部に1cm2の広さに塗布した後、試料1gを塗布
し、30秒間マッサージを行なった後、流水で洗い流し、
口紅の取れ易さを調べた。Titanium dioxide 5.0%, Red No. 204 0.6%, Orange No. 204 5.0
%, Candelilla wax 9.3%, Red No. 223 0.2%, Solid paraffin 8.0%, Beeswax 5.0%, Carnauba wax 5.0
%, Lanolin 11.0%, castor oil 44.8%, isopropyl myristate 10% as an oily stain, which was applied to the forearm flexor lateral area 1 cm 2 wide, then 1 g of sample was applied and massaged for 30 seconds. After doing, rinse with running water,
I checked the ease of removing lipstick.
また、水洗性は、試料0.3gを手の甲に塗布し、その部分
に一定水量（100ml/秒）の流水を５秒間あてて、残存し
た試料の量をもって評価した。感触は試料のとれ及び塗
布時の伸びについて評価した。The washability was evaluated by applying 0.3 g of the sample to the back of the hand, applying a constant amount of running water (100 ml / sec) for 5 seconds to the portion, and evaluating the amount of the remaining sample. The touch was evaluated for the breakage of the sample and the elongation during application.
実施例２〜４ではクレンジング効果，水洗性，感触とも
に極めて良好であったが、比較例４では水洗性は良好で
あったものの、クレンジング効果はやや不良、感触は不
良であった。また透明性，保存安定性については、実施
例２〜４では何れも極めて良好であったが、比較例４で
は何れもやや不良であった。 In Examples 2 to 4, the cleansing effect, washability, and feel were extremely good, but in Comparative Example 4, the washability was good, but the cleansing effect was somewhat poor and the feel was poor. Regarding transparency and storage stability, all of Examples 2 to 4 were extremely good, but Comparative Example 4 was somewhat poor.
実施例５（透明ナリシングクリーム） 下記に基づく処方で、実施例１に準じて透明ナリシング
クリームを調製した。Example 5 (Transparent Nourishing Cream) A transparent nourishing cream was prepared according to Example 1 with the following formulation.
ジラウリルリン酸ナトリウム １部 トリラウリルリン酸 １部 ミリスチン酸オクチルドデシル 20部 オリーブ油 35部 スクワラン 20部 純水 ３部 グリセリン 20部 得られたナリシングクリームは透明性も保存安定性も感
触も極めて良好であった。Sodium dilauryl phosphate 1 part Trilauryl phosphate 1 part Octyldodecyl myristate 20 parts Olive oil 35 parts Squalane 20 parts Pure water 3 parts Glycerin 20 parts The obtained nourishing cream has very good transparency, storage stability and feel. It was
実施例６（透明な温感マッサージ化粧料） 下記に基づく処方で、乳化温度を室温とする以外は実施
例１に準じて透明な温感マッサージ化粧料を調製した。Example 6 (Transparent warm-feeling massage cosmetics) A transparent warm-feeling massage cosmetics was prepared according to the procedure described in Example 1 except that the emulsification temperature was room temperature with the following formulation.
トリ（ポリオキシエチレン（8E.O.）オレイルエーテ
ル）リン酸 ３部 カプリン酸トリグリセリド 10部 流動パラフィン 61部 純水 １部 グリセリン 25部 得られた透明な温感マッサージ化粧料は、透明性，保存
安定性，感触，水洗性が何れも極めて良好であり、そし
て適度良好な温感を肌に与えた。Tri (polyoxyethylene (8E.O.) oleyl ether) phosphoric acid 3 parts Capric acid triglyceride 10 parts Liquid paraffin 61 parts Pure water 1 part Glycerin 25 parts The obtained transparent warming massage cosmetic is transparent and preserved. The stability, feel, and washability were all very good, and the skin had a moderately good warm feeling.
実施例７〜9,比較例５〜６ 下記の第３表に基づく処方でかつ実施例１に準じてクレ
ンジングクリームを調製して、その特性をしらべた。そ
の結果を第３表に示した。Examples 7 to 9 and Comparative Examples 5 to 6 Cleansing creams having the formulations shown in Table 3 below and according to Example 1 were prepared and their properties were investigated. The results are shown in Table 3.
実施例10〜13,比較例７〜９ 第４表に基づく処方でかつ実施例１に準じてクレンジン
グクリームを調製した。結果は第４表の通りであった。 Examples 10 to 13 and Comparative Examples 7 to 9 Cleansing creams were prepared according to the formulation shown in Table 4 and according to Example 1. The results are shown in Table 4.
前記の実施例１〜13と比較例１〜９の結果からも明らか
なように、本発明における液状油性物質の配合量は、最
終組成物の重量基準で40〜90重量％であり、そして、多
価アルコールの配合量は水の重量に対して４倍重量以上
でかつ５〜59重量％である。 As is clear from the results of Examples 1 to 13 and Comparative Examples 1 to 9, the blending amount of the liquid oily substance in the present invention is 40 to 90% by weight based on the weight of the final composition, and The content of the polyhydric alcohol is 4 times or more the weight of water and 5 to 59% by weight.
Claims (3)
び／又はトリアルキルリン酸エステル系界面活性剤と40
〜90重量％（重量％は最終組成物の重量基準）の液状油
性物質との混合物を、水の重量に対して４倍量以上でか
つ最終組成物に対して５〜59重量％の多価アルコールと
水との混合物に、添加、混合してなる、透明皮膚化粧
料。1. A dialkyl phosphate-based surfactant and / or a trialkyl phosphate-based surfactant and 40
~ 90% by weight (weight% based on the weight of the final composition) of a liquid oily substance in a polyhydric amount of at least 4 times the weight of water and 5 to 59% by weight of the final composition. A transparent skin cosmetic, which is obtained by adding and mixing it to a mixture of alcohol and water.
重量％配合される、特許請求の範囲（１）項記載の透明
皮膚化粧料。2. Water is 0.5 to 15 relative to the weight of the final composition.
The transparent skin cosmetic according to claim 1, which is blended in a weight percentage.
び／又はトリアルキルリン酸エステル系界面活性剤が、
最終組成物の重量に対して0.5〜10重量％配合される、
特許請求の範囲（１）項記載の透明皮膚化粧料。3. A dialkyl phosphate ester surfactant and / or a trialkyl phosphate ester surfactant,
0.5 to 10% by weight based on the weight of the final composition,
The transparent skin cosmetic according to claim (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61301083A JPH0778009B2 (en) | 1986-12-16 | 1986-12-16 | Transparent skin cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61301083A JPH0778009B2 (en) | 1986-12-16 | 1986-12-16 | Transparent skin cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63154606A JPS63154606A (en) | 1988-06-27 |
| JPH0778009B2 true JPH0778009B2 (en) | 1995-08-23 |
Family
ID=17892659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61301083A Expired - Fee Related JPH0778009B2 (en) | 1986-12-16 | 1986-12-16 | Transparent skin cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0778009B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0696493B2 (en) * | 1987-10-14 | 1994-11-30 | 株式会社資生堂 | Cosmetics |
| US4939179A (en) * | 1989-06-22 | 1990-07-03 | Chesebrough-Pond's Inc. | Cosmetic emulsions with hydrocarbon thickening agents |
| JP3535583B2 (en) * | 1994-09-20 | 2004-06-07 | 株式会社資生堂 | Clear lotion |
| WO1998032419A1 (en) * | 1997-01-29 | 1998-07-30 | Kao Corporation | Cosmetic |
| JP4814745B2 (en) * | 2006-09-27 | 2011-11-16 | 花王株式会社 | Liquid bath agent |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63225312A (en) * | 1986-10-02 | 1988-09-20 | Kao Corp | Transparent or semitransparent jelly-like cosmetic |
| JPS63122775A (en) * | 1986-11-12 | 1988-05-26 | Kao Corp | Oil gelatinizing agent |
-
1986
- 1986-12-16 JP JP61301083A patent/JPH0778009B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63154606A (en) | 1988-06-27 |
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