JPH0752306A - Manufacture of artificial stone laminate - Google Patents

Manufacture of artificial stone laminate

Info

Publication number
JPH0752306A
JPH0752306A JP19976893A JP19976893A JPH0752306A JP H0752306 A JPH0752306 A JP H0752306A JP 19976893 A JP19976893 A JP 19976893A JP 19976893 A JP19976893 A JP 19976893A JP H0752306 A JPH0752306 A JP H0752306A
Authority
JP
Japan
Prior art keywords
artificial stone
stone material
porous material
laminate
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19976893A
Other languages
Japanese (ja)
Inventor
Mitsuru Awata
満 粟田
Atsuhiko Yamamoto
温彦 山本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Priority to JP19976893A priority Critical patent/JPH0752306A/en
Publication of JPH0752306A publication Critical patent/JPH0752306A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To make it possible to manufacture in a short time an artificial stone laminate of which a surface quality is good and excellent in an adhesive property by a method wherein a raw kneaded material of an artificial stone containing hydraulic cement, water, and filler is supplied in an uncured state onto a porous material, formed while being vibrated under less than atmospheric pressure, and thereafter the stone is cured, and the porous material and the stone are integrally laminated. CONSTITUTION:In a manufacturing apparatus for an artificial stone laminate, a porous material 8 being an inner layer material is placed on a rubber packing 3a for lower part sealing, and its periphery is enclosed with a form 3 and fixed. Then, a raw kneaded material of the artificial stone under an uncured state is supplied onto the porous material 8 and if necessary, its surface is leveled. Thereafter, a rubber packing 3b for upper part sealing is placed on the form 3. Then, the whole form 3 is pinched with cover like iron plates 2a, 2b from upper and lower directions, fitted onto a vibrator 1 and fixed with a bolt 5 and a nut 6. An open part 9 is provided to the rubber packing 3b for upper part sealing and the upper part cover like iron plate 2b, and connected to a vacuum system.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、人造石材積層体の製造
法に関する。詳しくは建築物、家具等に広く利用される
石質軽量建材用の人造石材積層体の製造法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an artificial stone material laminate. More specifically, the present invention relates to a method for manufacturing an artificial stone material laminate for lightweight stone building materials widely used in buildings, furniture, and the like.

【0002】[0002]

【従来の技術】石材は太古の昔より重要な建築資材とし
て使用されており、欧米は言うに及ばず我が国でも木材
に比肩しうる地位を得てきた。これは現在も多数残る中
世の城壁に代表される如く、強度及び耐久性が他の素材
に比べて格段に優れていることが大きな要因として挙げ
られる。
2. Description of the Related Art Stone materials have been used as important building materials since ancient times, and have gained a position comparable to wood in Japan, not to mention Europe and America. This is largely due to its outstanding strength and durability compared to other materials, as typified by many medieval castle walls that remain today.

【0003】石材には天然石材と人造石材の2種類があ
り、天然石材は資源の枯渇或いは入手し難くなることが
将来考えられるが、人造石材は殆ど問題を発生せず、地
球に優しいエコロジカルな素材である。近年は建築資材
として人造石材が大量に使用され、強度及び耐久性に加
えて意匠性を改良し、設計者にとって意図を表現し易く
なっており、人造石材はこのニーズにマッチしている。
即ち、天然石材には生成時点における本来の模様が個々
に異なり、意匠上の問題はあるが、人造石材は配合する
充填材を自在に変えることが可能で、同一の意匠を作り
出し易い特徴を持っている。この様に、人造石材はデザ
インの選択性における利点がある反面、物理的性質は天
然石材と同様に硬質であり、重量も大きい。そのため建
築現場での施工、加工が必ずしも容易ではなく、人造石
材の軽量化が求められていた。
There are two types of stone materials, natural stone materials and artificial stone materials. Natural stone materials may be depleted of resources or may become difficult to obtain in the future. It is a material. In recent years, a large amount of artificial stone materials have been used as building materials, and in addition to strength and durability, designability has been improved, making it easier for designers to express their intentions, and artificial stone materials meet this need.
In other words, natural stones have different original patterns at the time of generation and there are problems in design, but artificial stones have the characteristic that the filler to be blended can be changed freely and the same design can be easily created. ing. Thus, while artificial stone has the advantage of design selectivity, it has the same physical properties as natural stone and is heavy. Therefore, construction and processing at the construction site are not always easy, and it has been required to reduce the weight of the artificial stone material.

【0004】軽量材料を内層材として、これにセメント
質人造石材を表層材として組み合わせた人造石材積層体
は、軽量化の一手段であった。そこで、例えば特開昭6
3−261040号公報に見られるように、内層材とし
て軽量な珪酸カルシウムを用い、その表面に表層材とし
て、薄い人工または天然の石材を接着剤で貼着すること
により、軽量性と耐割れ性を改善する貼り合わせ接合法
が知られている。ところが、貼る合わせ接合の場合は接
着強度の信頼性が十分でなく、また、石材板を予め調達
する必要から作業工程数が増していた。更に、通常の石
材板には気泡が混在し易く、緻密性に劣る欠点があっ
た。
An artificial stone material laminate in which a lightweight material is used as an inner layer material and a cementitious artificial stone material is used as a surface layer material has been one means of reducing the weight. Therefore, for example, JP-A-6
As disclosed in JP-A-3-261040, lightweight calcium silicate is used as an inner layer material, and by attaching a thin artificial or natural stone material as an outer layer material to the surface thereof with an adhesive, lightness and crack resistance are obtained. There is known a bonding method that improves the above. However, in the case of pasting and joining, the reliability of the adhesive strength is not sufficient, and the number of working steps is increased because it is necessary to procure a stone board in advance. Further, the ordinary stone plate has a defect that air bubbles are likely to be mixed and the denseness is poor.

【0005】本発明者らは先に型内に内層材として軽量
な珪酸カルシウムを載置し、該内層材上に、種石とバイ
ンダーを含む表層材の原料を、未硬化状態にて供給し、
内層材と表層材をプレス加工機で成形し、その後表層材
を硬化させると同時に、圧着一体化する製造法を特願平
5−90592号として提案した。しかしながら、プレ
ス加工機による成形では、接着強度に信頼性はあるもの
の、圧縮力の微妙な力加減により軽量材料を破損する恐
れがある上、気泡が残存し、緻密性に更なる改良が求め
られた。
The inventors of the present invention first placed a lightweight calcium silicate as an inner layer material in a mold, and supplied a raw material of a surface layer material containing seed stone and a binder in an uncured state on the inner layer material. ,
Japanese Patent Application No. 5-90592 proposes a manufacturing method in which the inner layer material and the surface layer material are molded by a press machine, and then the surface layer material is cured and simultaneously pressure-bonded and integrated. However, in molding with a press machine, although the adhesive strength is reliable, there is a risk of damaging the lightweight material due to the delicate adjustment of the compressive force, bubbles remain, and further improvement in denseness is required. It was

【0006】人造石材の品質としては、気泡が少なく、
且つ含水量の少ないことが緻密性を向上させるうえで必
要である。また、人造石材と多孔質材の接着強度も十分
備わっていなければならない。気泡は人造石材の原料混
練物の流動性が高いと低減されるが、これには水を多量
に配合しなければならない。また、水分が多過ぎると緻
密性に欠けるものと成ってしまう。人造石材の原料混練
物より吸収した水分は多孔質材から空気を追い出し、多
量の気泡を発生させる原因となる。
As for the quality of the artificial stone material, there are few bubbles,
In addition, a low water content is necessary for improving the compactness. Also, the artificial stone material and the porous material must have sufficient adhesive strength. The air bubbles are reduced when the kneaded raw material of the artificial stone material has high fluidity, but a large amount of water must be added to this. Also, if the water content is too high, the resulting product will lack compactness. The water absorbed from the raw material kneaded material of the artificial stone expels air from the porous material and causes a large amount of bubbles.

【0007】更に、人造石材の原料はコンクリートミキ
サーにて混練を行うが、その際に多量の空気を巻き込ん
でしまう。従来までの手法によれば、プレス加工は緻密
性向上のみに使用され、成形、接合を同時に行うプロセ
スは無かった。
Further, the raw material of the artificial stone material is kneaded in a concrete mixer, but a large amount of air is entrained at that time. According to the conventional method, press working is used only for improving the denseness, and there is no process for simultaneously performing molding and joining.

【0008】[0008]

【発明が解決しようとする課題】この為本発明者らは、
セメント質人造石材の緻密化及び多孔質材との積層一体
化について種々検討した結果、多孔質材の上に水硬性セ
メント質の人造石材を供給して、大気圧以下の雰囲気で
振動させることにより、多孔質材から気泡を放出し、続
いて人造石材の原料混練物の中を気泡が浮上し除去され
る。これにより人造石材の原料混練物の脱気泡と多孔質
材の水分吸収が同時に進行する。従って人造石材の原料
混練物の緻密化が可能に成ると共に、多孔質材に深くセ
メントスラリーが浸入することにより、人造石材の原料
混練物が硬化後も完全に接着することを見いだした。
Therefore, the present inventors have
As a result of various studies on densification of cementitious artificial stone material and lamination integration with porous material, as a result of supplying hydraulic cementitious artificial stone material on the porous material and vibrating it in an atmosphere below atmospheric pressure , Air bubbles are released from the porous material, and then the air bubbles float up and are removed in the kneaded material of the artificial stone material. As a result, degassing of the kneaded raw material of the artificial stone and water absorption of the porous material proceed at the same time. Therefore, it has been found that the raw material kneaded product of the artificial stone material can be densified and the raw material kneaded product of the artificial stone material can be completely adhered even after the hardening by the deep penetration of the cement slurry into the porous material.

【0009】水分量が多く、振動による脱気泡効果が発
揮される人造石材の原料混練物を、多孔質材で吸水する
ことにより、適量の水を含んだ人造石材の原料混練物が
多孔質材と共に強固に複合化され、表層体と内層体から
なる積層体を得た。
The kneaded raw material of artificial stone, which has a large amount of water and exhibits a defoaming effect due to vibration, is absorbed by the porous material, so that the kneaded raw material of artificial stone containing an appropriate amount of water is a porous material. A strong composite was obtained, and a laminated body including a surface layer body and an inner layer body was obtained.

【0010】[0010]

【課題を解決するための手段】しかして本発明の目的
は、多孔質材に水硬性セメント質の人造石材を積層して
人造石材積層体を製造する方法において、多孔質材の上
に水硬性セメント、水及び充填材を含有する人造石材の
原料混練物を、未硬化状態にて供給し、大気圧以下の雰
囲気で振動を行いながら所望の形状に成形し、その後人
造石材を硬化させると共に多孔質材と人造石材を積層一
体化することを特徴とする人造石材積層体の製造法によ
り達成される。
SUMMARY OF THE INVENTION An object of the present invention, however, is to provide a method for producing an artificial stone material laminate by laminating a hydraulic cementitious artificial stone material on a porous material. A raw material kneaded product of artificial stone material containing cement, water and a filler is supplied in an uncured state, molded into a desired shape while vibrating in an atmosphere of atmospheric pressure or less, and then the artificial stone material is hardened and porous. This is achieved by a method for manufacturing an artificial stone laminate, which is characterized in that a quality material and an artificial stone material are laminated and integrated.

【0011】以下に本発明をより詳細に説明する。本発
明の人造石材積層体に使用される多孔質材は軽量化する
ことを目的とし、薄板上に積層しても強度を落とすこと
がないものである。本発明製品ではこの多孔質材が内層
材となる。かかる多孔質材の材料としては特に限定され
ないが、軽量であることが好ましく、具体的にはコンク
リートの比重約2.2より軽いものである。更に好まし
くは、人造石材のセメントスラリーが、内層材の深部ま
で浸透することができる空隙が多く、且つ吸水率も高い
内層材であることである。(真比重−見掛け比重)/真
比重×100%により求められる空隙率で表して、空隙
率30〜95%のものが好ましい。内層材中にセメント
スラリーが浸透することにより、内層材と表層材の接着
強度が増すのである。このような材料としては、珪酸カ
ルシウム系、石膏系及び、セメント系等の材料が好まし
い。中でも、珪酸カルシウム系の材料が、軽さ及び強度
の点で最も優れている。内層材は、炭素繊維、ガラス繊
維及び、パルプ、或いはビニロン、アクリル及び、ケプ
ラー等の有機繊維等通常用いられる強化繊維で強化され
るのが好ましい。
The present invention will be described in more detail below. The porous material used in the artificial stone material laminate of the present invention is intended to reduce the weight, and does not lose its strength even when laminated on a thin plate. In the product of the present invention, this porous material serves as the inner layer material. Although the material of the porous material is not particularly limited, it is preferably lightweight, and specifically, it is lighter than the specific gravity of concrete of about 2.2. More preferably, the cement slurry of the artificial stone has many voids that can penetrate deep into the inner layer material and has a high water absorption rate. It is preferable that the porosity is 30 to 95%, which is expressed by (true specific gravity-apparent specific gravity) / true specific gravity x 100%. As the cement slurry permeates into the inner layer material, the adhesive strength between the inner layer material and the surface layer material increases. As such a material, a calcium silicate-based material, a gypsum-based material, a cement-based material or the like is preferable. Among them, the calcium silicate-based material is the most excellent in terms of lightness and strength. The inner layer material is preferably reinforced with commonly used reinforcing fibers such as carbon fibers, glass fibers and pulp, or organic fibers such as vinylon, acryl and Kepler.

【0012】本発明の人造石材積層体に使用される水硬
性セメント質の人造石材の基本組成は、水硬性セメン
ト、水及び充填材の3種を含有するものである。水硬性
セメントには珪酸カルシウム系及びアルミナ系あり、具
体的にはポルトランドセメント、高炉セメント、シリカ
セメント及びフライアッシュセメントから選ばれるもの
を用いる。
The basic composition of the hydraulic cementitious artificial stone material used in the artificial stone material laminate of the present invention contains three kinds of hydraulic cement, water and a filler. The hydraulic cement includes calcium silicate type and alumina type, and specifically, one selected from Portland cement, blast furnace cement, silica cement and fly ash cement is used.

【0013】充填材としては、砕石、砂、硝子片、陶器
片、金属片及び繊維状の金属等が用いられる。夫々の含
有量は、水硬性セメント100重量部に対して水が10
〜200重量部、好ましくは30〜70重量部で、充填
材が100〜1000重量部、好ましくは250〜50
0重量部で、主に出来上がりのデザイン面での意匠性及
び、物理的性質の硬度と磨耗性等の物性を考慮し、目的
とする性能により決められる。
As the filler, crushed stone, sand, glass pieces, pottery pieces, metal pieces and fibrous metal are used. The content of each is 10 parts of water to 100 parts by weight of hydraulic cement.
To 200 parts by weight, preferably 30 to 70 parts by weight, and 100 to 1000 parts by weight, preferably 250 to 50 parts by weight of the filler.
At 0 parts by weight, it is determined mainly by the desired performance in consideration of the designability of the finished design and the physical properties such as hardness and abrasion resistance.

【0014】水の含有量が少ない場合は、気泡の除去が
不十分であり、多い場合は、人造石材のセメントスラリ
ーが多孔質材の深部へ浸透するのに時間を要する。ま
た、人造石材の緻密性を損なうので適当でない。その
他、本発明において人造石材に添加する助剤としては、
未硬化状態の人造石材の流動化を促進する界面活性剤や
増粘剤、気泡を低減する消泡剤、硬質化を促進する改質
剤及び、セメントマトリックス強化剤が存在し、目的に
応じて1〜5種類程度添加することができる。
When the content of water is small, the removal of air bubbles is insufficient, and when it is large, it takes time for the cement slurry of the artificial stone material to penetrate into the deep part of the porous material. Further, it is not suitable because it impairs the compactness of the artificial stone material. In addition, as an auxiliary agent added to the artificial stone material in the present invention,
There are surfactants and thickeners that promote fluidization of uncured artificial stone materials, defoaming agents that reduce air bubbles, modifiers that promote hardening, and cement matrix strengthening agents, depending on the purpose. About 1 to 5 kinds can be added.

【0015】混練は、通常コンクリートミキサーを用い
て1〜90分、好ましくは2〜8分程度混ぜ合わせ、人
造石材の原料混練物とする。例えば、製造工程で板状物
を製作する場合、テーブル型の振動機上にシール用ゴム
パッキンを介して型枠を定着し、その型枠内の底部に多
孔質材を載置する。この上に人造石材の原料混練物を所
定量供給し、大気圧以下の雰囲気で振動を開始する。表
層材及び内層材の厚みは特に限定されるものではない
が、目的とする人造石材積層体の用途により任意に選ぶ
ことが出来る。通常、夫々の厚みは表層材が2〜30m
m、好ましくは3〜8mmで、内層材が6〜80mm、
好ましくは12〜40mmである。
The kneading is usually carried out by using a concrete mixer for about 1 to 90 minutes, preferably about 2 to 8 minutes to obtain a kneaded raw material for an artificial stone material. For example, when a plate-like material is manufactured in the manufacturing process, a mold is fixed on a table-type vibrator via a rubber packing for sealing, and a porous material is placed on the bottom of the mold. A predetermined amount of the kneaded material of the artificial stone material is supplied onto this, and vibration is started in an atmosphere of atmospheric pressure or less. The thickness of the surface layer material and the inner layer material is not particularly limited, but can be arbitrarily selected depending on the intended use of the artificial stone material laminate. Usually, the thickness of each surface layer material is 2 to 30 m
m, preferably 3 to 8 mm, and the inner layer material is 6 to 80 mm,
It is preferably 12 to 40 mm.

【0016】本発明において上記原料混練物を未硬化状
態で供給するとは、混練後速やかに流動性のある状態で
使用することを意味する。水硬性セメント質の種類や水
の量にも影響されるが、混練後通常は10分以内、好ま
しくは5分以内に使用される振動機は加速度が大きく、
振幅は0.2〜10mm、好ましくは0.5〜5mm
で、周波数は40〜180Hz、好ましくは60〜16
0Hzである。
In the present invention, supplying the raw material kneaded product in an uncured state means that it is used in a fluid state immediately after kneading. Although it depends on the type of hydraulic cement and the amount of water, a vibrator used within 10 minutes after kneading, and preferably within 5 minutes, has a large acceleration.
Amplitude is 0.2-10 mm, preferably 0.5-5 mm
And the frequency is 40 to 180 Hz, preferably 60 to 16
It is 0 Hz.

【0017】大気圧以下の雰囲気とは圧力が400mm
Hg以下、好ましくは60mmHg以下であり、処理時
間は1〜100分、好ましくは2〜10分である。ま
た、処理時間が長くなるにつれて、人造石材積層体の緻
密性の向上や、表層材と内層材との接着強度が高くなる
傾向を示した。かくして、大気圧以下の雰囲気での振動
処理直後のものは、人造石材の原料混練物を供給した時
点のものとは変化し、表層体表面の凹凸が均されて平に
なり、板状の積層体として成形される。
Atmospheric pressure or less means a pressure of 400 mm
It is Hg or less, preferably 60 mmHg or less, and the treatment time is 1 to 100 minutes, preferably 2 to 10 minutes. Moreover, as the treatment time became longer, the denseness of the artificial stone material laminate and the adhesive strength between the surface layer material and the inner layer material tended to increase. Thus, the one immediately after the vibration treatment in the atmosphere of atmospheric pressure or less is different from the one at the time when the raw material kneaded product of the artificial stone material is supplied, and the unevenness of the surface layer body is flattened to be a flat plate-shaped laminated body. Molded as a body.

【0018】次に、上記積層体を型枠と共に自然養生或
いは蒸気養生を行い、人造石材を硬化させると共に多孔
質材と人造石材を積層一体化する。そして、適宜研磨、
截断加工後乾燥し製品検査を行い出荷する。次に本発明
の製造法を図面を用いて説明する。図1は本発明に係わ
る人造石材積層体の製造に適した装置の一例である。図
中1は振動機、2a,2bは(下部)(上部)蓋状鉄
板、3は型枠、3a,3bは(下部)(上部)シール用
ゴムパッキン、4は減圧吸引部、5は取り付けボルト、
6は取り付けナット、7は人造石材の原料混練物、8は
多孔質材、9は開放部を示す。
Next, the above laminated body is subjected to natural curing or steam curing together with a mold to harden the artificial stone material and to integrally laminate the porous material and the artificial stone material. And polish appropriately,
After cutting and drying, the product is inspected and shipped. Next, the manufacturing method of the present invention will be described with reference to the drawings. FIG. 1 is an example of an apparatus suitable for manufacturing an artificial stone material laminate according to the present invention. In the figure, 1 is a vibrator, 2a and 2b are (lower) (upper) lid-shaped iron plate, 3 is a form, 3a and 3b are (lower) (upper) sealing rubber packing, 4 is a vacuum suction unit, and 5 is attached. bolt,
6 is a mounting nut, 7 is a kneaded material of artificial stone material, 8 is a porous material, and 9 is an open portion.

【0019】下部シール用ゴムパッキン3a上に内層体
となる多孔質材8を載置し、その周囲を型枠3で包囲
し、定着させる。次いで、未硬化状態の人造石材の原料
混練物7を多孔質材8の上に供給し、要すれば表面を均
した後、上部シール用ゴムパッキン3bを型枠3上に載
置する。上記型枠3の全体を上下方向から蓋状鉄板2
a、2bで挾持し、これを振動機1上に取り付けボルト
5及びナット6で固定する。上部シール用ゴムパッキン
3b及び上部蓋状鉄板2bには開放部9が設けられてお
り、図示していない真空系に接続される。
A porous material 8 to be an inner layer is placed on the lower sealing rubber packing 3a, and the periphery thereof is surrounded by a mold 3 and fixed. Next, the uncured artificial stone material kneaded material 7 is supplied onto the porous material 8, and if necessary the surface is leveled, and then the upper sealing rubber packing 3b is placed on the mold 3. The entire mold 3 is covered with the lid-shaped iron plate 2 from above and below.
It is clamped by a and 2b, and it is fixed on the vibrator 1 by mounting bolts 5 and nuts 6. The upper sealing rubber packing 3b and the upper lid-shaped iron plate 2b are provided with an opening 9 and are connected to a vacuum system (not shown).

【0020】[0020]

【実施例】以下本発明を実施例により更に詳細に説明す
るが、本発明はその要旨を越えない限り、下記実施例に
よって限定されるものではない。 (実施例1)人造石材の原料は下記に示したものを使用
した。
EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to the following examples unless it exceeds the gist. (Example 1) As the raw material of the artificial stone material, the following materials were used.

【0021】[0021]

【表1】 水硬性セメント ;秩父セメント社製白セメント 100重量部 水 ;上水 67重量部 充填材(種石) ;島根産硅砂3号 260重量部 (細骨材);茨城稲田産御影粉 37重量部 増粘材 ;信越化学工業社製 1.0重量部 メトロース90SH−4000 消泡材 ;サンノプコ社製 0.1重量部 SNデフォーマー14HP 以上、6種類を配合し、丸東製作所社製5リットルのモ
ルタルコンクリートミキサーにて3分間混練し、次に述
べる工程に供した。多孔質材として、比重0.4,空隙
率85%の珪酸カルシウム成形体(日本ケイカル社製ケ
イカルタイカ)を25mm×180mm×180mm
(厚み×縦×横)に截断して使用した。
[Table 1] Hydraulic cement; White cement manufactured by Chichibu Cement Co., Ltd. 100 parts by weight Water; Water 67 parts by weight Filler (seed stone); Shimane Silica No. 3 260 parts by weight (fine aggregate); Ibaraki Inada granite 37 parts by weight Thickener; Shin-Etsu Chemical Co., Ltd. 1.0 part by weight Metrose 90SH-4000 Defoamer; San Nopco 0.1 part by weight SN deformer 14HP Above, 6 types are mixed, Maruto Manufacturing Co., Ltd. 5 The mixture was kneaded for 3 minutes in a liter mortar concrete mixer and subjected to the steps described below. As a porous material, a calcium silicate compact having a specific gravity of 0.4 and a porosity of 85% (Keikaru Taika made by Nippon Kaikaru Co., Ltd.) is 25 mm × 180 mm × 180 mm
It was cut into pieces (thickness x length x width) before use.

【0022】図1に示すごとく、ステンレス製の内法寸
法が50mm×185mm×185mm(高さ×縦×
横)の型枠に、で上部が開放された吸引口付蓋状鉄板で
挾持し取り付けボルトで振動機に固定した。振動機とし
ては、丸東製作所社製の電磁バイブレーター式、テーブ
ル型バイブレーター(型式C−10)を用いて、振動数
100Hz、振幅1mmで、垂直方向に加振させた。
As shown in FIG. 1, the internal dimensions of stainless steel are 50 mm × 185 mm × 185 mm (height × length × x).
It was held with a lid-shaped iron plate with a suction port whose upper part was opened and fixed to the vibrator with mounting bolts. As the vibrator, an electromagnetic vibrator type and a table type vibrator (type C-10) manufactured by Maruto Seisakusho Co., Ltd. were used and vibrated in a vertical direction at a frequency of 100 Hz and an amplitude of 1 mm.

【0023】型枠の吸引口に、内容積20リットルの真
空計付トラップを有する真空ポンプを接続した。実施手
順の詳細は次のとうりである。型枠内に多孔質材を載置
し、その上に人造石材の原料混練物を、未硬化状態にて
供給した。型枠上部の開放部をシール用ゴムパッキンを
介して蓋状鉄板で密閉し、型枠をボルト及びナットで固
定した。真空ポンプを作動させ、圧力が60mmHg以
下に達したところで、真空トラップのコックを開け、型
枠内を減圧にした。それと同時に振動機を作動させ垂直
方向に振動を開始した。そして、3分間処理を行った後
振動を停止し、型枠内の減圧をリークさせ、大気圧に戻
した後、成形体を型枠と共に取り出し、10日間の自然
養生を行った。かくして、得られた成形体は上部表面が
平に均されており、研磨が簡単であるばかりでなく緻密
で、表層体と内層体の接着強度も十分満足できる積層成
形体が製作できた。結果を表−1に示した。
A vacuum pump having a trap with a vacuum gauge and an internal volume of 20 liters was connected to the suction port of the mold. The details of the implementation procedure are as follows. A porous material was placed in the mold, and the raw material kneaded material of the artificial stone material was supplied onto the porous material in an uncured state. The open part at the top of the mold was sealed with a lid-shaped iron plate through a rubber packing for sealing, and the mold was fixed with bolts and nuts. The vacuum pump was operated, and when the pressure reached 60 mmHg or less, the cock of the vacuum trap was opened to reduce the pressure inside the mold. At the same time, the vibrator was activated and vibration started in the vertical direction. Then, after performing the treatment for 3 minutes, the vibration was stopped, the reduced pressure in the mold was leaked, and the pressure was returned to the atmospheric pressure. Then, the molded body was taken out together with the mold and subjected to natural curing for 10 days. Thus, the obtained molded product had a flat upper surface, was not only easy to polish, but was dense, and it was possible to manufacture a laminated molded product having sufficient adhesive strength between the surface layer and the inner layer. The results are shown in Table-1.

【0024】(比較例1)実施例1において、減圧を行
わず大気圧で処理した以外は、実施例1と同様な方法で
処理した。製作された成形体の研磨後の外観は気泡が表
面に多数発生しており、緻密性に欠けていた。 (比較例2)実施例1において、振動を行わず処理した
以外は、実施例1と同様な方法で処理した。製作された
成形体の研磨後の外観は気泡が表面に極めて多数発生し
ており緻密性に欠けていた。表層体と内層体の接着強度
も不良であった。
(Comparative Example 1) A treatment was carried out in the same manner as in Example 1 except that the treatment was carried out at atmospheric pressure without depressurization. The appearance of the produced molded body after polishing had a large number of bubbles on the surface and lacked compactness. (Comparative Example 2) A treatment was performed in the same manner as in Example 1 except that the treatment was performed in Example 1 without vibration. The appearance of the produced molded body after polishing was very dense and lacked in denseness because a large number of bubbles were generated on the surface. The adhesive strength between the surface layer body and the inner layer body was also poor.

【0025】[0025]

【表2】 [Table 2]

【0026】[0026]

【発明の効果】この様にして、簡素な設備または、工程
で短時間に表面が良好で、接着性に優れた品質の人造石
材積層体を製作することが出来た。この製造法により、
軽量で施工性が良く、加えて各種の充填材を配合するこ
とにより、優れた意匠性を持ち得る人造石材積層体を産
業上有利に提供できる。かかる人造石材積層体は、建築
物、家具等に広く用いられる石質軽量建材として有用で
ある。
As described above, an artificial stone material laminate having a good surface and excellent adhesiveness can be manufactured in a short time with a simple equipment or process. By this manufacturing method,
By adding various fillers in addition to being lightweight and having good workability, it is possible to industrially provide an artificial stone material laminate that can have excellent designability. Such an artificial stone material laminate is useful as a stone-like lightweight building material widely used in buildings, furniture and the like.

【図面の簡単な説明】[Brief description of drawings]

【図1】 人造石材積層体の製造装置の一例である。FIG. 1 is an example of an apparatus for manufacturing an artificial stone material laminate.

【符号の説明】[Explanation of symbols]

1,振動機 2a,2b,(下部)(上部)蓋状鉄板 3,型枠 3a,3b,(下部)(上部)シール用ゴムパッキン 4,減圧吸引部 5,取り付けボルト 6,取り付けナット 7,人造石材の原料混練物 8,多孔質材 9,開放部 1, vibrators 2a, 2b, (lower) (upper) lid-shaped iron plate 3, formwork 3a, 3b, (lower) (upper) rubber seal packing 4, vacuum suction unit 5, mounting bolt 6, mounting nut 7, Kneaded material of artificial stone material 8, Porous material 9, Open part

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】多孔質材に水硬性セメント質の人造石材を
積層して、人造石材積層体を製造する方法において、多
孔質材の上に水硬性セメント、水及び充填材を含有する
人造石材の原料混練物を、未硬化状態にて供給し、大気
圧以下の雰囲気で振動を行いながら所望の形状に成形
し、その後人造石材を硬化させると共に多孔質材と人造
石材を積層一体化することを特徴とする人造石材積層体
の製造法。
1. A method for producing an artificial stone material laminate by laminating a hydraulic cementitious artificial stone material on a porous material, wherein the artificial stone material contains hydraulic cement, water and a filler on the porous material. Supplying the raw material kneaded product in the uncured state, forming it into a desired shape while vibrating in an atmosphere below atmospheric pressure, then hardening the artificial stone material and laminating and integrating the porous material and the artificial stone material A method for manufacturing an artificial stone laminate, which is characterized by:
【請求項2】多孔質材が空隙率30〜95%の珪酸カル
シウムである請求項1記載の人造石材積層体の製造法。
2. The method for producing an artificial stone material laminate according to claim 1, wherein the porous material is calcium silicate having a porosity of 30 to 95%.
【請求項3】垂直方向に振動数40〜180Hz、振幅
0.2〜10mmで振動を行うことを特徴とする請求項
1記載の人造石材積層体の製造法。
3. The method for manufacturing an artificial stone material laminate according to claim 1, wherein vibration is performed in a vertical direction at a frequency of 40 to 180 Hz and an amplitude of 0.2 to 10 mm.
【請求項4】大気圧以下の雰囲気が、1〜400mmH
gの圧力であることを特徴とする請求項1記載の人造石
材積層体の製造法。
4. Atmospheric pressure below 1 to 400 mmH
The method for producing an artificial stone material laminate according to claim 1, wherein the pressure is g.
【請求項5】人造石材の原料が水硬性セメント100重
量部に対して、水10〜200重量部、充填材100〜
1000重量部を含有することを特徴とする請求項1記
載の人造石材積層体の製造法。
5. A synthetic stone material is used in an amount of 10 to 200 parts by weight of water and 100 to 100 parts by weight of a filler, based on 100 parts by weight of hydraulic cement.
The method for producing an artificial stone material laminate according to claim 1, wherein the artificial stone material laminate contains 1000 parts by weight.
JP19976893A 1993-08-11 1993-08-11 Manufacture of artificial stone laminate Pending JPH0752306A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19976893A JPH0752306A (en) 1993-08-11 1993-08-11 Manufacture of artificial stone laminate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19976893A JPH0752306A (en) 1993-08-11 1993-08-11 Manufacture of artificial stone laminate

Publications (1)

Publication Number Publication Date
JPH0752306A true JPH0752306A (en) 1995-02-28

Family

ID=16413298

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19976893A Pending JPH0752306A (en) 1993-08-11 1993-08-11 Manufacture of artificial stone laminate

Country Status (1)

Country Link
JP (1) JPH0752306A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010103535A2 (en) * 2009-02-20 2010-09-16 Gosakan Aravamudan In situ foaming in artificial stone
US8216755B2 (en) 2008-05-30 2012-07-10 Ricoh Company, Limited Toner, developer, toner container, process cartridge, image forming apparatus, and image forming method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8216755B2 (en) 2008-05-30 2012-07-10 Ricoh Company, Limited Toner, developer, toner container, process cartridge, image forming apparatus, and image forming method
WO2010103535A2 (en) * 2009-02-20 2010-09-16 Gosakan Aravamudan In situ foaming in artificial stone
WO2010103535A3 (en) * 2009-02-20 2010-11-04 Gosakan Aravamudan Structure for door or other furniture

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