JPH0737851A - Cleaning device - Google Patents

Cleaning device

Info

Publication number
JPH0737851A
JPH0737851A JP5200234A JP20023493A JPH0737851A JP H0737851 A JPH0737851 A JP H0737851A JP 5200234 A JP5200234 A JP 5200234A JP 20023493 A JP20023493 A JP 20023493A JP H0737851 A JPH0737851 A JP H0737851A
Authority
JP
Japan
Prior art keywords
hydrofluoric acid
pure water
tank
circulating
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP5200234A
Other languages
Japanese (ja)
Inventor
Satoshi Kobayashi
敏 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP5200234A priority Critical patent/JPH0737851A/en
Publication of JPH0737851A publication Critical patent/JPH0737851A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/80Forming a predetermined ratio of the substances to be mixed
    • B01F35/82Forming a predetermined ratio of the substances to be mixed by adding a material to be mixed to a mixture in response to a detected feature, e.g. density, radioactivity, consumed power or colour

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cleaning Or Drying Semiconductors (AREA)

Abstract

PURPOSE:To contrive to increase the reproducibility and uniformity of the mixed compositional ratio of the mixed treating liquid of a hydrofluoric acid and pure water. CONSTITUTION:A cleaning device has a treating tank 1, which involves semiconductor wafers 3 to be cleaned and in which a treating liquid obtainable by diluting a hydrofluoric acid with pure water is put, a circulating system 21 having a circulating pump 7 for circulating the treating liquid so that the pure water and the hydrofluoric acid, which are sent in this tank 1, are evenly mixed with each other, a filter 8 and the like, a fluorine ion densitometer 10, which measures the concentration of the circulating treating liquid and senses variations of the concentration, and a flow rate controller 11, which controls the flow rates of the pure water and the hydrofluoric acid for sending a prescribed amount of the pure water and the hydrofluoric acid in the tank 1 on the basis of the measurement of this densitometer 10.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、半導体装置の製造に使
用される半導体ウエハの洗浄装置に関し、特に、製造工
程において半導体ウエハをフッ酸で洗浄するための洗浄
装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an apparatus for cleaning semiconductor wafers used in the manufacture of semiconductor devices, and more particularly to an apparatus for cleaning semiconductor wafers with hydrofluoric acid in the manufacturing process.

【0002】[0002]

【従来の技術】半導体装置の製造において、半導体ウエ
ハの表面は清浄に保つ必要がある。なぜならば、例え
ば、フォトエッチングの際に半導体ウエハ表面に異物が
付着している等の汚染があると、配線ショートや断線の
原因となり、また、金属を含む異物が半導体ウエハ表面
に付着したまま該半導体ウエハを加熱すると、その部分
が合金化してpn接合をショートさせてしまう等の恐れ
があるからである。
2. Description of the Related Art In the manufacture of semiconductor devices, it is necessary to keep the surface of a semiconductor wafer clean. This is because, for example, contamination such as foreign matter adhering to the surface of the semiconductor wafer during photo-etching may cause a wiring short circuit or disconnection, and the foreign matter containing a metal may remain attached to the surface of the semiconductor wafer. This is because if the semiconductor wafer is heated, that portion may be alloyed and the pn junction may be short-circuited.

【0003】これらを防止するため、酸化膜生成前の前
洗浄、フォトエッチング後の後洗浄等の洗浄が必要であ
るが、従来は、図2に示すように、半導体ウエハ3を載
置したウエハキャリア2を処理槽1中に浸漬し、フッ酸
はバルブ16を開けて薬品タンク4から供給ポンプ5に
より処理槽1へ供給し、一方、純水6はバルブ17を開
けて処理槽1へ供給し、該フッ酸と純水を循環ポンプ7
により循環させながら、フィルター8により濾過し、均
一に混合しながら、半導体ウエハ3を洗浄していた。な
お、12及び14は循環用のバルブ、13及び15は廃
液用のバルブである。
In order to prevent these, cleaning such as pre-cleaning before oxide film formation and post-cleaning after photo-etching is necessary. Conventionally, as shown in FIG. 2, a wafer on which a semiconductor wafer 3 is mounted is mounted. The carrier 2 is immersed in the treatment tank 1, and hydrofluoric acid is supplied from the chemical tank 4 to the treatment tank 1 by the supply pump 5 by opening the valve 16, while pure water 6 is supplied to the treatment tank 1 by opening the valve 17. Then, the hydrofluoric acid and pure water are circulated by a pump 7
The semiconductor wafer 3 was washed while being circulated by, filtered by the filter 8 and uniformly mixed. In addition, 12 and 14 are valves for circulation, and 13 and 15 are valves for waste liquid.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、前記従
来の洗浄装置においては、フッ酸と純水の混合組成比の
再現精度に関して、最小でも2%の誤差が生じ、また、
均一性も比較的低かった。このため、該混合処理液によ
る半導体ウエハのエッチングにおいて、所望のエッチン
グレートが実現しにくいという問題があった。
However, in the above-mentioned conventional cleaning apparatus, an error of at least 2% occurs in the reproducibility of the mixed composition ratio of hydrofluoric acid and pure water, and
The uniformity was also relatively low. Therefore, there is a problem in that it is difficult to achieve a desired etching rate when etching a semiconductor wafer with the mixed treatment liquid.

【0005】そこで本発明は、フッ酸と純水との混合処
理液の混合組成比の再現精度、及び均一性が高く、所望
のエッチング量が実現できるような洗浄装置を提供する
ことを目的とする。
SUMMARY OF THE INVENTION Therefore, an object of the present invention is to provide a cleaning device which has high reproducibility and uniformity of the mixing composition ratio of a mixed treatment liquid of hydrofluoric acid and pure water and can realize a desired etching amount. To do.

【0006】[0006]

【課題を解決するための手段】本発明の洗浄装置は、上
記課題を解決するために、洗浄を施す半導体ウエハを内
包し、フッ酸を純水で希釈した処理液が入れられる処理
槽と、該処理槽に送り込まれた純水とフッ酸が均一に混
合するように、該処理液を循環させるための例えば循環
ポンプ及びフィルター等を有する循環系と、循環中の処
理液の濃度を計測し、また、その変動を感知する、フッ
素イオン濃度計と、該フッ素イオン濃度計の計測に基づ
いて、所定量の純水及びフッ酸を前記処理槽に送り込む
ため、前記純水及びフッ酸の流量を制御する流量制御器
とを有する。
In order to solve the above-mentioned problems, a cleaning apparatus of the present invention includes a processing tank containing a semiconductor wafer to be cleaned and containing a processing solution obtained by diluting hydrofluoric acid with pure water. In order to uniformly mix pure water and hydrofluoric acid fed into the treatment tank, a circulation system having, for example, a circulation pump and a filter for circulating the treatment liquid, and a concentration of the treatment liquid in circulation are measured. Further, the flow rate of the pure water and the hydrofluoric acid is measured in order to feed a predetermined amount of pure water and hydrofluoric acid into the processing tank based on the measurement of the fluorine ion concentration meter and the fluorine ion concentration meter that senses the fluctuation. And a flow rate controller for controlling.

【0007】[0007]

【作用】本発明においては、流量制御器により純水及び
フッ酸の流量を制御しながら、処理槽内へ純水及びフッ
酸を供給し、該処理液中に洗浄を施す半導体ウエハを浸
漬し、該処理液により該半導体ウエハに付着した塵を除
去し、また不要な例えば二酸化シリコン膜等をエッチン
グして除去する。
In the present invention, the flow rate controller controls the flow rates of pure water and hydrofluoric acid, while supplying pure water and hydrofluoric acid into the processing bath and immersing the semiconductor wafer to be cleaned in the processing solution. Dust adhering to the semiconductor wafer is removed by the treatment liquid, and unnecessary silicon dioxide film or the like is removed by etching.

【0008】まず、例えば循環ポンプにより、前記処理
槽に送り込まれた純水とフッ酸とが均一に混合するよう
に該処理液を循環させ、電気的にフッ化物イオンを感知
するフッ素イオン濃度計により、該循環中の処理液の濃
度を計測し、濃度の変動が無くなり一定になった後、前
記流量制御器により、所定のフッ素イオン濃度になるよ
うに調整する。これは例えば、所定のフッ素イオン濃度
以下の場合は、補正量のフッ酸を、該流量制御器により
途中の関連するポンプを開栓する等して、前記処理槽に
供給し、逆に所定のフッ素イオン濃度以上の場合は、補
正量の純水を前記処理槽に供給することにより行なう。
First, for example, by a circulation pump, the treatment liquid is circulated so that the pure water and hydrofluoric acid fed into the treatment tank are uniformly mixed, and a fluoride ion concentration meter for electrically sensing fluoride ions is provided. Thus, the concentration of the processing liquid in the circulation is measured, and after the fluctuation of the concentration becomes constant and becomes constant, the flow rate controller adjusts to a predetermined fluorine ion concentration. For example, when the concentration of fluorine ions is lower than a predetermined value, a correction amount of hydrofluoric acid is supplied to the processing tank by opening the related pump on the way by the flow rate controller, and the like. If the concentration is higher than the fluorine ion concentration, a correction amount of pure water is supplied to the processing tank.

【0009】然る後、前記処理槽内に、キャリア等によ
り半導体ウエハを入れ、前記調整済の処理液を再び循環
させ、例えばフィルターで該処理液を濾過しながら洗浄
を行なう。
After that, the semiconductor wafer is put into the processing tank by a carrier or the like, the adjusted processing liquid is circulated again, and the cleaning is performed while filtering the processing liquid with a filter, for example.

【0010】[0010]

【実施例】以下、図1を用いて、本発明に係る洗浄装置
の一実施例を説明する。図1は、実施例における洗浄装
置のシステム構成を示すブロック図である。
EXAMPLE An example of the cleaning apparatus according to the present invention will be described below with reference to FIG. FIG. 1 is a block diagram showing the system configuration of the cleaning apparatus in the embodiment.

【0011】本実施例の洗浄装置は、処理槽1と、バル
ブ12と、フッ素イオン濃度計10が中に設置されてい
る濃度監視箱9と、循環ポンプ7と、フィルター8と、
バルブ14とが、この順に互いに連結されている状態で
備えられており、洗浄処理液が循環する循環系21と、
開閉動作により純水の放出及び遮断を制御するバルブ1
7と、フッ酸が貯蔵されている薬品タンク4と、開閉動
作によりフッ酸の放出及び遮断を制御するバルブ16
と、薬品タンク4に直結しており、薬品タンク4からフ
ッ酸をバルブ16へと送出する供給ポンプ5と、循環系
21へのフッ酸及び純水の供給量を管理する流量制御器
11と、循環ポンプ7と濃度監視箱9との中間部分と処
理槽1を結ぶ経路途中に位置する廃液用バルブ13と、
循環系21の脇に位置する廃液用バルブ15とを備え
る。処理槽1は、内槽1aと外槽1bとを備えており、
内槽1a中に処理液を流入し、該処理液に半導体ウエハ
3を装填したキャリア2を浸漬して洗浄を行なうが、外
槽1bは内槽1aを内包するように設けられており、洗
浄中、内槽1aから溢れ出た処理液を受け止め、該処理
液を循環系21内へと流入させる。
The cleaning apparatus of this embodiment comprises a treatment tank 1, a valve 12, a concentration monitoring box 9 in which a fluorine ion concentration meter 10 is installed, a circulation pump 7, a filter 8,
A valve 14 is provided in such a state that they are connected to each other in this order, and a circulation system 21 in which the cleaning treatment liquid circulates,
Valve 1 that controls the release and shutoff of pure water by opening and closing operation
7, a chemical tank 4 in which hydrofluoric acid is stored, and a valve 16 for controlling release and shutoff of hydrofluoric acid by opening and closing operations.
And a supply pump 5 that is directly connected to the chemical tank 4 and sends hydrofluoric acid from the chemical tank 4 to the valve 16, and a flow rate controller 11 that controls the supply amount of hydrofluoric acid and pure water to the circulation system 21. A waste liquid valve 13 located in the middle of a path connecting the intermediate portion between the circulation pump 7 and the concentration monitoring box 9 and the processing tank 1,
The waste liquid valve 15 is provided beside the circulation system 21. The processing tank 1 includes an inner tank 1a and an outer tank 1b,
Cleaning is carried out by injecting the processing liquid into the inner tank 1a and immersing the carrier 2 loaded with the semiconductor wafer 3 in the processing liquid, while the outer tank 1b is provided so as to include the inner tank 1a. Inside, the processing liquid overflowing from the inner tank 1a is received, and the processing liquid is caused to flow into the circulation system 21.

【0012】処理液を生成するためには、流量制御器1
1によりバルブ17を開栓して、所定量の純水6を処理
槽1に供給し、次に、流量制御器11によりバルブ16
を開栓して、薬品タンク4から供給ポンプ5により所定
量のフッ酸(HF)を処理槽1に供給する。然る後、廃
液用バルブ13を閉栓した状態で、バルブ12及び14
を開栓し、循環ポンプ7を作動させ、循環系21内に処
理液を循環させながらフッ酸と純水の混合を均一にす
る。
In order to generate the processing liquid, the flow rate controller 1
1, the valve 17 is opened, a predetermined amount of pure water 6 is supplied to the processing tank 1, and then the flow controller 11 is used to open the valve 16.
And a predetermined amount of hydrofluoric acid (HF) is supplied from the chemical tank 4 to the processing tank 1 by the supply pump 5. Then, while the waste liquid valve 13 is closed, the valves 12 and 14 are closed.
And the circulation pump 7 is operated to circulate the treatment liquid in the circulation system 21 to make the mixing of hydrofluoric acid and pure water uniform.

【0013】そして、フッ化物イオンを電気的に感知し
電圧によりその濃度を表示するフッ素イオン濃度計10
により、この循環中処理液のフッ酸濃度を計測し、フッ
素イオン濃度計10からの出力値が一定になれば、処理
液の混合具合が完全に均一になったものとして循環を中
止する。
Then, a fluoride ion concentration meter 10 which electrically senses the fluoride ions and displays the concentration by voltage.
Thus, the concentration of hydrofluoric acid in the circulating treatment liquid is measured, and when the output value from the fluorine ion concentration meter 10 becomes constant, the mixing condition of the treatment liquid is considered to be completely uniform, and the circulation is stopped.

【0014】然る後、流量制御器11により、所定のフ
ッ素イオン濃度になるように調整する。これは例えば、
所定のフッ素イオン濃度以下の場合は、補正量のフッ酸
を、流量制御器11によりバルブ16を開栓し、薬品タ
ンク4から処理槽1へ供給し、逆に所定のフッ素イオン
濃度以上の場合は、バルブ17を開栓し、補正量の純水
6を処理槽1に供給することにより行なう。
After that, the flow rate controller 11 adjusts the concentration of the fluorine ions to a predetermined value. This is for example
When the concentration of the fluorine ion is less than the predetermined value, a correction amount of hydrofluoric acid is supplied from the chemical tank 4 to the processing tank 1 by opening the valve 16 by the flow controller 11, and when the concentration of the fluorine ion is more than the predetermined value. Is performed by opening the valve 17 and supplying a correction amount of pure water 6 to the processing tank 1.

【0015】然る後、キャリア2に搭載した半導体ウエ
ハ3を内槽1a内に入れ、濃度調整済の上記処理液を再
び循環系21に循環させながら洗浄を行なうが、この時
フィルター8により、循環中の処理液を濾過しながら行
なう。
After that, the semiconductor wafer 3 mounted on the carrier 2 is put into the inner tank 1a, and cleaning is performed while circulating the processing solution whose concentration has been adjusted again in the circulation system 21. At this time, the filter 8 is used. The treatment liquid in circulation is filtered.

【0016】このようにして半導体ウエハ3の洗浄が完
了した後、バルブ12及び14を閉栓し、廃液用バルブ
13及び15を開栓して、処理液を廃棄する。
After the cleaning of the semiconductor wafer 3 is completed in this way, the valves 12 and 14 are closed and the waste liquid valves 13 and 15 are opened to discard the processing liquid.

【0017】[0017]

【発明の効果】以上説明したように本発明に係る洗浄装
置においては、処理液を循環させながらフッ酸の濃度を
計測するフッ素イオン濃度計により、フッ酸濃度及びそ
の変動を正確に読み取ってフッ素イオン濃度を所定値に
保つよう制御することにより、フッ酸と純水との混合処
理液の混合組成比の再現精度、及び均一性が高くなり、
その結果、エッチング量のばらつきの少ない洗浄装置が
実現できる。
As described above, in the cleaning apparatus according to the present invention, the concentration of hydrofluoric acid and its fluctuation are accurately read by the fluorine ion concentration meter which measures the concentration of hydrofluoric acid while circulating the treatment liquid. By controlling the ion concentration so as to keep it at a predetermined value, the reproducibility and uniformity of the mixed composition ratio of the mixed treatment liquid of hydrofluoric acid and pure water are increased,
As a result, it is possible to realize a cleaning device with less variation in etching amount.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例に係る洗浄装置のシステム構
成を示すブロック図である。
FIG. 1 is a block diagram showing a system configuration of a cleaning apparatus according to an embodiment of the present invention.

【図2】従来の洗浄装置のシステム構成を示すブロック
図である。
FIG. 2 is a block diagram showing a system configuration of a conventional cleaning device.

【符号の説明】[Explanation of symbols]

1 処理槽 3 半導体ウエハ 4 薬品タンク 5 供給ポンプ 6 純水 7 循環ポンプ 8 フィルター 10 フッ素イオン濃度計 11 流量制御器 12、14 処理液循環系のバルブ 16 フッ酸供給用のバルブ 17 純水供給用のバルブ 1 Processing Tank 3 Semiconductor Wafer 4 Chemical Tank 5 Supply Pump 6 Pure Water 7 Circulation Pump 8 Filter 10 Fluorine Ion Concentration Meter 11 Flow Controllers 12 and 14 Processing Liquid Circulation Valve 16 Hydrofluoric Acid Supply Valve 17 Pure Water Supply Valve

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 フッ酸を純水で希釈した処理液により半
導体ウエハを洗浄する洗浄装置において、 洗浄を施す半導体ウエハを内包し、前記処理液が入れら
れる処理槽と、 該処理槽に送り込まれた前記処理液を循環させるための
循環系と、 該循環系を循環中の前記処理液のフッ素イオン濃度を計
測するフッ素イオン濃度計と、 該フッ素イオン濃度計の計測に従って、前記処理槽に送
り込む前記純水及びフッ酸の流量を制御する流量制御器
と、 を有することを特徴とする洗浄装置。
1. A cleaning apparatus for cleaning a semiconductor wafer with a processing solution obtained by diluting hydrofluoric acid with pure water, the processing tank containing a semiconductor wafer to be cleaned, and a processing tank in which the processing solution is placed, and the processing tank is fed into the processing tank. A circulation system for circulating the treatment liquid, a fluorine ion concentration meter for measuring the fluorine ion concentration of the treatment liquid circulating in the circulation system, and feeding into the treatment tank according to the measurement of the fluorine ion concentration meter And a flow rate controller for controlling the flow rates of the pure water and hydrofluoric acid.
JP5200234A 1993-07-20 1993-07-20 Cleaning device Withdrawn JPH0737851A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5200234A JPH0737851A (en) 1993-07-20 1993-07-20 Cleaning device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5200234A JPH0737851A (en) 1993-07-20 1993-07-20 Cleaning device

Publications (1)

Publication Number Publication Date
JPH0737851A true JPH0737851A (en) 1995-02-07

Family

ID=16421045

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5200234A Withdrawn JPH0737851A (en) 1993-07-20 1993-07-20 Cleaning device

Country Status (1)

Country Link
JP (1) JPH0737851A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH112806A (en) * 1997-03-21 1999-01-06 Lg Electron Inc Etching device
JP2002278473A (en) * 2001-03-21 2002-09-27 Sony Corp Method for manufacturing display panel
KR20030005777A (en) * 2001-07-10 2003-01-23 삼성전자 주식회사 Semiconductor cleaning process using electrolytic ionized water and diluted HF solution at the same time
US6802911B2 (en) * 2001-09-19 2004-10-12 Samsung Electronics Co., Ltd. Method for cleaning damaged layers and polymer residue from semiconductor device
KR100455904B1 (en) * 1997-09-09 2005-01-13 동경 엘렉트론 주식회사 Cleaning process and cleaning plant
US7214537B2 (en) * 2001-10-08 2007-05-08 Advanced Technology Materials, Inc. Real-time component monitoring and replenishment system for multicomponent fluids
CN108834528A (en) * 2018-06-19 2018-11-20 利辛县风雅颂机电科技有限公司 A kind of chemical fertilizer spraying device
CN110241538A (en) * 2019-06-27 2019-09-17 漳州泰里斯生物科技有限公司 A kind of antibacterial processing equipment of fabric and its control method
CN111354637A (en) * 2020-02-28 2020-06-30 通威太阳能(眉山)有限公司 Method for washing graphite boat by cyclic utilization of hydrofluoric acid

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH112806A (en) * 1997-03-21 1999-01-06 Lg Electron Inc Etching device
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