JPH07325307A - Production of liquid crystal display element and liquid crystal display element - Google Patents

Production of liquid crystal display element and liquid crystal display element

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Publication number
JPH07325307A
JPH07325307A JP11793494A JP11793494A JPH07325307A JP H07325307 A JPH07325307 A JP H07325307A JP 11793494 A JP11793494 A JP 11793494A JP 11793494 A JP11793494 A JP 11793494A JP H07325307 A JPH07325307 A JP H07325307A
Authority
JP
Japan
Prior art keywords
liquid crystal
spacers
agent
spraying
crystal display
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11793494A
Other languages
Japanese (ja)
Inventor
Kiyoshi Shobara
潔 庄原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP11793494A priority Critical patent/JPH07325307A/en
Publication of JPH07325307A publication Critical patent/JPH07325307A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To make uniform display with a good contrast ratio, wider visual angle and higher reliability without generating biasing in the spacers by vibrations and inflow of liquid crystals by spraying spacers via a space part by a spraying means and irradiating these spacers with UV rays. CONSTITUTION:The spacers 27 consisting of org. polymer resin spheres are uniformly ejected and sprayed from a nozzle 26 of a spacer spraying device 24 onto a second electrode substrate 11. Two pieces of UV lamps 28 of 100W are disposed on both sides and the spacers 27 to be sprayed are irradiated with UV rays in parallel in the space part where the spacers arrive at the second electrode substrate 11 from the nozzle 26 at the time of this spraying. As a result, an excitation state is induced at the surfaces of the spacers 27, by which the spacer surfaces are activated and made easily chemically reactable. High adhesiveness is eventually imparted to these surfaces. Since the spacers 27 have no adhesiveness at the point of the time when the spacers 27 are sprayed by the spacer spraying device 24 and, therefore, the dispersibility and uniformity of the spraying are maintained without impairment.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、間隙剤を介し所定の間
隔を隔てて対向する電極基板を有する液晶表示素子の製
造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a liquid crystal display device having electrode substrates facing each other with a predetermined gap therebetween via a gap agent.

【0002】[0002]

【従来の技術】近年、OA機器等の表示装置に用いられ
る液晶表示素子にあっては、大型化、カラー化等の高性
能化と共に、高コントラスト化、広視覚化、表示の均一
化等の表示の高品位化が求められている。
2. Description of the Related Art In recent years, liquid crystal display elements used in display devices such as office automation equipment have been improved in performance such as size and color, as well as high contrast, wide visualization, and uniform display. Higher display quality is required.

【0003】この液晶表示素子の高性能化及び、表示の
高品位化に対する要求を満たすためには、位相差フィル
ム、液晶材料、セル構成の最適化や、カラーフィルタの
色純度、表面の平坦性の向上と共に、液晶表示素子の電
極基板の間隔を均一に保持する事が重要な要素となって
いる。
In order to meet the demands for higher performance and higher display quality of this liquid crystal display element, the retardation film, the liquid crystal material, the cell structure are optimized, the color purity of the color filter, and the surface flatness. It is an important factor to keep the distance between the electrode substrates of the liquid crystal display device uniform as well.

【0004】このため液晶表示素子にあっては、通常、
対向する電極基板間に所望の径を有する間隙剤を均一に
散布し、両電極基板間の間隔を均一に保持している。
Therefore, in a liquid crystal display device, normally,
A space agent having a desired diameter is uniformly dispersed between the opposing electrode substrates to maintain a uniform space between both electrode substrates.

【0005】しかしながら、一般に製造過程において、
両電極基板間に間隙剤を均一に散布する事は比較的容易
に出来るものの、その後、液晶表示素子を完成するまで
に行われる液晶セル組み立て工程あるいは液晶組成物注
入工程等において、振動や液晶組成物の流動により間隙
剤が、散布時に配置された位置から動いてしまい、散布
状態が均一にならず片寄ってしまう場合を生じていた。
However, in the manufacturing process,
Although it is relatively easy to evenly disperse the gap agent between the two electrode substrates, vibration or liquid crystal composition may occur in the liquid crystal cell assembling process or the liquid crystal composition injecting process that is performed until the liquid crystal display element is completed. Due to the flow of the substance, the interstitial agent moves from the position where it is disposed at the time of spraying, resulting in a case where the spraying state is not uniform and deviated.

【0006】そして、間隙剤の片寄りによって両電極基
板間の間隔が不均一になると、液晶組成物による電気光
学的特性が不均一となる事から、液晶表示素子による表
示が不均一となり、コントラストにバラツキを生じたり
広視覚化が得られなかったり、という様に表示ムラを生
じ、表示品位が著しく低下するという問題を有してい
た。 更に、液晶セル中で間隙剤に片寄りを生じる際
に、配向膜表面が傷付けられ、配向不良を起こし、これ
によっても表示品位が低下されてしまう恐れが有った。
このため従来は、間隙剤表面に熱硬化型接着剤を付着
し、これを電極基板に均一に散布した後、電極基板を加
熱する事により、電極基板に間隙剤を接着し、間隙剤の
移動を防止したり、あるいは、所定の径のスペーサを接
着剤に混入し、基板全面の所定位置に印刷し固化した
り、又所定の膜厚のレジスト材を基板全面に塗布形成し
た後、パターニング処理を行い、所定の位置にレジスト
柱を形成する等により、所定の高さの間隙剤を電極基板
上に予め固定形成する方法等が検討されていた。
When the gap between the two electrode substrates becomes non-uniform due to the deviation of the gap agent, the electro-optical characteristics of the liquid crystal composition become non-uniform, so that the display by the liquid crystal display element becomes non-uniform, resulting in a contrast. However, there is a problem in that display unevenness occurs, such as variations in image quality and wide visualization cannot be obtained, and display quality is significantly reduced. Further, when the gap agent is offset in the liquid crystal cell, the surface of the alignment film may be damaged, resulting in poor alignment, which may also deteriorate the display quality.
For this reason, conventionally, a thermosetting adhesive is attached to the surface of the interstitial agent, which is evenly dispersed on the electrode substrate, and then the electrode substrate is heated to adhere the interstitial agent to the electrode substrate and move the interstitial agent. Or a spacer with a predetermined diameter is mixed into the adhesive to print and solidify at a predetermined position on the entire surface of the substrate, or a resist material with a predetermined film thickness is applied and formed on the entire surface of the substrate, followed by patterning processing. Then, a method of forming a resist pillar at a predetermined position and fixing a gap agent having a predetermined height on the electrode substrate in advance has been studied.

【0007】[0007]

【発明が解決しようとする課題】従来は、液晶セル内で
間隙剤が片寄るのを防止するため、熱硬化型接着剤を用
いて間隙剤を電極基板に接着したりあるいは所定の高さ
の間隙剤を電極基板上に予め固定形成する等していた。
Conventionally, in order to prevent the gap agent from being unbalanced in the liquid crystal cell, the gap agent is adhered to the electrode substrate using a thermosetting adhesive, or the gap having a predetermined height is used. The agent was previously fixed and formed on the electrode substrate.

【0008】このため、熱硬化型接着剤を使用する場合
にあっては間隙剤の均一な散布が難しく、間隙剤の散布
時に既に片寄りを生じてしまう惧れがあると共に、強力
な接着力を付与する事が出来ず、接着剤を使用するにも
かかわらず、間隙剤が動いてしまい、信頼性に劣るとい
う問題を生じていた。
For this reason, when the thermosetting adhesive is used, it is difficult to evenly disperse the interstitial agent, and there is a risk that deviation will already occur during the dispersal of the interstitial agent and a strong adhesive force. However, despite the use of the adhesive, the interstitial agent moves, resulting in poor reliability.

【0009】又所定高さの間隙剤を固定形成する場合に
あっては、液晶セルを形成する工程に更に間隙剤を形成
する工程が加わり、製造工程が複雑となり、製造に時間
を要すると共に、コストが上昇するという問題を生じて
いた。
In the case of fixedly forming a space agent having a predetermined height, the step of forming the space agent is added to the step of forming the liquid crystal cell, the manufacturing process becomes complicated, and it takes time to manufacture. There was a problem of rising costs.

【0010】そこで本発明は上記課題を除去するもの
で、間隙剤散布時の分散性を損なう事無く、均一な散布
を行えると共に、製造容易であり、コストの上昇を生じ
る事の無い液晶表示素子の製造方法及び液晶表示素子を
提供する事を目的とする。
Therefore, the present invention eliminates the above-mentioned problems. A liquid crystal display device that can be uniformly sprayed without impairing the dispersibility at the time of spraying a space agent, is easy to manufacture, and does not cause an increase in cost. It is an object of the present invention to provide a method for manufacturing the same and a liquid crystal display device.

【0011】[0011]

【課題を解決するための手段】本発明の請求項1は、上
記課題を解決するために、所定の間隔を有して対向する
2枚の電極基板の間隙に、液晶組成物及び前記所定間隔
を保持するための間隙剤を封入して成る液晶表示素子の
製造方法において、散布手段により前記間隙剤を前記電
極基板の少なくともいずれか一方に空間部を経て散布
し、前記散布手段から前記電極基板にいたる前記空間部
にて前記間隙剤に紫外線光を照射するものである。
According to a first aspect of the present invention, in order to solve the above-mentioned problems, a liquid crystal composition and the predetermined gap are provided in a gap between two electrode substrates facing each other with a predetermined gap. In a method of manufacturing a liquid crystal display device, which comprises a space agent for holding the liquid crystal material, the space agent is sprayed by at least one of the electrode substrates by a spraying device through a space portion, and the spraying device causes the electrode substrate to disperse. The space agent is irradiated with ultraviolet light in the space.

【0012】本発明の請求項2は、上記課題を解決する
ために、電極を有し間隙を隔てて互いに対向する2枚の
電極基板と、この電極基板の前記間隙に封入される液晶
組成物とを具備する液晶表示素子において、紫外線光の
照射により表面が活性化され前記間隙に散布される間隙
剤を設けるものである。
According to a second aspect of the present invention, in order to solve the above problems, two electrode substrates having electrodes and facing each other with a gap therebetween, and a liquid crystal composition sealed in the gap of the electrode substrates. In a liquid crystal display device including the above, a surface-activating agent is provided by irradiation with ultraviolet light, and a space agent is dispersed in the space.

【0013】[0013]

【作用】本発明は上記の様に構成され、製造容易であり
ながら、間隙剤はその散布時に外部から力を受ける事が
なく、均一な散布が得られる一方、紫外線光の照射によ
り間隙剤表面を活性化する事により、散布後、電極基板
上に達した後は、間隙剤は強力な付着力を保持する事と
なり、電極基板上に強力に反応付着される。従って、電
極基板上に配置後は、振動や液晶の流入により間隙剤に
片寄りを生じる事がなく、配向膜が傷付く事も無い事か
ら、コントラストが均一であり、均一な広視角化を得ら
れ、画像ムラの無い良好な表示を得られる。
The present invention is configured as described above and is easy to manufacture, but the interstitial agent does not receive a force from the outside during its application and a uniform application can be obtained. On the other hand, the interstitial agent surface is irradiated by the ultraviolet light. By activating, after reaching the electrode substrate after spraying, the interstitial agent retains a strong adhesive force and is strongly reactively attached to the electrode substrate. Therefore, after being placed on the electrode substrate, the gap agent will not be biased due to vibration or liquid crystal inflow, and the alignment film will not be damaged, so that the contrast is uniform and a uniform wide viewing angle is achieved. It is possible to obtain a good display without image unevenness.

【0014】[0014]

【実施例】以下、本発明の一実施例を図1乃至図3を参
照して説明する。図1は液晶表示素子1の断面を模式的
に示し、10、11は第1及び第2の電極基板であり、
酸化シリコン(SiOx )を主成分とした青板ガラス
(ソーダガラス)からなる厚さ1.1mm、外形寸法2
50mm×300mmの第1及び第2の透明基板12、
13の表面に、厚さ3000オングストロームのITO
(Indium Tin Oxide)蒸着膜からなり
ストライプ状にパターン形成される第1及び第2の透明
電極14、16が形成されている。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS. FIG. 1 schematically shows a cross section of a liquid crystal display element 1, and 10 and 11 are first and second electrode substrates,
Made of soda lime glass with silicon oxide (SiO x ) as the main component, thickness 1.1 mm, external dimensions 2
50 mm × 300 mm first and second transparent substrates 12,
3000 Angstrom ITO on the surface of 13
First and second transparent electrodes 14 and 16 formed of (Indium Tin Oxide) vapor-deposited film and formed in a stripe pattern are formed.

【0015】更に各透明電極14、16上に厚さ600
オングストロームのポリイミド(SE−150:日産化
学株式会社製)からなる第1及び第2の配向膜20、2
1を成膜しラビング配向処理を行う。
Further, a thickness of 600 is formed on each transparent electrode 14, 16.
First and second alignment films 20, 2 made of angstrom polyimide (SE-150: manufactured by Nissan Chemical Co., Ltd.)
1 is deposited and rubbing alignment treatment is performed.

【0016】この後第1の電極基板10の第1の配向膜
20の周囲に沿って、注入口(図示せず)を残し、周辺
接着剤として径7μmのガラスファイバを含有したエポ
キシ系接着剤23をシール印刷する。
Thereafter, an epoxy adhesive containing a glass fiber having a diameter of 7 μm is used as a peripheral adhesive, leaving an injection port (not shown) along the periphery of the first alignment film 20 of the first electrode substrate 10. 23 is printed on the sticker.

【0017】次に、散布手段である間隙剤散布装置24
のノズル26より、第2の電極基板11上に径7μmの
有機高分子樹脂球からなる間隙剤27を均一に噴出散布
するが、この散布時、ノズル26から第2の電極基板1
1に達する空間部にて、100wの紫外線ランプ28を
両側に2本設け、散布される間隙剤27に紫外線光を平
行に照射する。
Next, a gap agent spraying device 24 which is a spraying means.
From the nozzle 26, a space agent 27 made of an organic polymer resin sphere having a diameter of 7 μm is uniformly ejected and sprayed onto the second electrode substrate 11, and at the time of this spraying, from the nozzle 26 the second electrode substrate 1
In the space reaching 1, the two 100-w ultraviolet lamps 28 are provided on both sides, and the scattered space agent 27 is irradiated with ultraviolet light in parallel.

【0018】これにより、間隙剤27表面は、励起状態
を引き起こし、活性化され化学反応しやすくなり、強い
付着性を有するものとなる。
As a result, the surface of the interstitial agent 27 causes an excited state, is easily activated and chemically reacts, and has a strong adhesive property.

【0019】次に配向処理された第1及び第2の配向膜
20、21による液晶組成物の捩じれが、240°の左
捩じれになるよう、第1及び第2の電極基板10、11
を対向配置し、更に1kg/cm2 の圧力を印加しなが
ら150℃で3時間加熱し、シール材23を硬化させ液
晶セルを形成する。
Next, the first and second electrode substrates 10 and 11 are arranged so that the twist of the liquid crystal composition by the first and second alignment films 20 and 21 subjected to the alignment treatment becomes a left twist of 240 °.
Are opposed to each other and further heated at 150 ° C. for 3 hours while applying a pressure of 1 kg / cm 2 , and the sealing material 23 is cured to form a liquid crystal cell.

【0020】更にこの液晶セルを真空チャンバーに設置
し、液晶セル内部を減圧した後、液晶セル内外の圧力差
を利用する減圧注入法にて注入口より液晶セルの間隙
に、超ねじれネマティック型であるZLI−2293
(E.メルク社製)にカイラル剤としてS−811を
0.7wt%添加した液晶組成物26を注入し、注入口
を紫外線硬化型樹脂により封止し、第1、第2の位相差
板27、28、第1、第2の偏光板30、31を貼付
し、液晶表示素子1を完成する。
Further, this liquid crystal cell is placed in a vacuum chamber, and after decompressing the inside of the liquid crystal cell, a super twisted nematic type is put in the gap between the liquid crystal cells from the injection port by a reduced pressure injection method utilizing the pressure difference between the inside and outside of the liquid crystal cell. There is ZLI-2293
A liquid crystal composition 26 containing 0.7% by weight of S-811 as a chiral agent was injected into (manufactured by E. Merck), the injection port was sealed with an ultraviolet curable resin, and the first and second retardation plates were formed. The liquid crystal display element 1 is completed by sticking 27, 28 and the first and second polarizing plates 30, 31.

【0021】この様にして形成された液晶表示素子1の
間隙剤27の分布状態を顕微鏡により調べた所、図3に
示す様に注入口付近[A]を含め均一に散布配置されて
おり、0.3mm角の画素部に約10個の間隙剤27が
ほぼ均一に配置されていた。更にこの液晶表示素子によ
り白黒表示し、1/200デューティで駆動点灯した
所、コントラスト比は30:1でしかも全面にわたり非
常に均一な表示が得られた。 又振動試験として、1気
圧で100Hzの振動を20分与えたところ、間隙剤2
7の片寄りは見られず、高品位の表示が得られた。更に
70℃で200時間放置しても、配向性及び表示品位共
良好であった。
When the distribution state of the interstitial agent 27 of the liquid crystal display element 1 thus formed is examined by a microscope, it is found that the interstices 27 are uniformly dispersed in the vicinity of the injection port [A] as shown in FIG. About 10 interstitial agents 27 were arranged almost uniformly in the pixel portion of 0.3 mm square. Further, when this liquid crystal display device was used for black and white display and was driven and lit at 1/200 duty, the contrast ratio was 30: 1 and a very uniform display was obtained over the entire surface. In addition, as a vibration test, when a vibration of 100 Hz was applied at 1 atm for 20 minutes, the gap agent 2
No deviation of 7 was observed, and a high-quality display was obtained. Further, even if it was allowed to stand at 70 ° C. for 200 hours, both the orientation and the display quality were good.

【0022】一方、これに対する比較例として紫外線光
を照射する事なく、単に均一に散布しただけの間隙剤を
有する、従来の電極基板を用いて形成された液晶表示素
子31を形成した所、その間隙剤の分布状態は、注入口
付近[B]を除くほとんどの所は、0.3mm角の画素
部に約10個の間隙剤27がほぼ均一に分散配置されて
いたものの、注入口付近[B]にあっては、0.3mm
角の画素部に約6個の割合で配置されており、他の部分
に比べて少なくなっていた。
On the other hand, as a comparative example, a liquid crystal display element 31 formed by using a conventional electrode substrate having a gap agent merely uniformly dispersed without being irradiated with ultraviolet light was formed. Regarding the distribution of the porosity agent, in most places except for the vicinity of the injection port [B], about 10 porosity agents 27 were dispersed almost uniformly in the pixel portion of 0.3 mm square, but near the injection port [ B], 0.3 mm
About 6 pixels are arranged in the corner pixel portion, which is smaller than other portions.

【0023】このため、従来の液晶表示素子を白黒表示
し1/200デューティで駆動点灯した所、注入口付近
で良好なコントラストが得られず、表示が不均一となっ
た。又振動試験として、1気圧で100Hzの振動を2
0分与えたところ、液晶セル中で間隙剤27が移動した
事、更には移動による配向膜の損傷による配向異常が発
生し、表示品位が低下されてしまった。
For this reason, when the conventional liquid crystal display device was displayed in black and white and driven and lit at 1/200 duty, good contrast was not obtained in the vicinity of the injection port, and the display became non-uniform. In addition, as a vibration test, 2 vibrations of 100 Hz at 1 atmosphere
When 0 minutes was applied, the gap agent 27 moved in the liquid crystal cell, and further, the alignment abnormality occurred due to the damage of the alignment film due to the movement, and the display quality was degraded.

【0024】この様に構成すれば、間隙剤散布装置24
により間隙剤27を散布する時点にあっては、間隙剤2
7は付着性を有していない事から散布の分散性及び均一
性が損なわれる事無く、しかも散布後間隙剤27は、第
2の電極基板11に達する迄の間に紫外線光の照射によ
り表面が活性化される事から、第2の配向膜21表面に
確実に反応付着されるので、間隙剤27の、第2の配向
膜21表面上における散布は均一化されしかも分散配置
後は、液晶表示素子1の製造過程あるいは、表示使用中
における振動等の衝撃によっても液晶セル内で片寄りを
生じる惧れが無くなる。
With this structure, the interstitial agent spraying device 24
At the time of spraying the interstitial agent 27 by the
No. 7 does not have adhesiveness, so the dispersibility and uniformity of spraying are not impaired. Moreover, the interstitial agent 27 after spraying is exposed to ultraviolet light before it reaches the second electrode substrate 11. Is activated, it is surely reactively adhered to the surface of the second alignment film 21. Therefore, the dispersion of the interstitial agent 27 on the surface of the second alignment film 21 is made uniform, and the liquid crystal is dispersed after the disposition. There is no fear of deviation in the liquid crystal cell due to the manufacturing process of the display element 1 or an impact such as vibration during display use.

【0025】又従来、間隙剤が散布位置から動く際に生
じていた配向膜20、21の損傷を生じる事も無く、配
向不良の防止も図れる。
In addition, the alignment films 20 and 21 are not damaged when the interstitial agent moves from the spraying position in the related art, and the alignment failure can be prevented.

【0026】従って、液晶表示素子1の製造工程の複雑
化を招く事無く、液晶表示素子1全面にわたり、均一で
良好なコントラスト比を有し、均一な広視覚化を有する
信頼性の高い表示を得られ、高品位表示を達成可能とな
る。
Therefore, a highly reliable display having a uniform and good contrast ratio over the entire surface of the liquid crystal display element 1 and a uniform wide visualization can be obtained without complicating the manufacturing process of the liquid crystal display element 1. As a result, high quality display can be achieved.

【0027】尚本発明は上記一実施例に限られるもので
なく、その趣旨を変えない範囲での変更は可能であっ
て、例えば間隙剤は有機高分子に限定されず、シリカ球
等の無機系の材質を用いても良い。この無機系の間隙剤
にあっては、紫外線光の照射により、その酸化不活性な
表面が還元される事となり、表面にOH基等を発生さ
せ、活性な表面とする事により、間隙剤に付着性を生じ
させる事となる。
It should be noted that the present invention is not limited to the above-mentioned one embodiment and can be modified within the scope of the invention. For example, the interstitial agent is not limited to an organic polymer, and an inorganic material such as silica sphere is used. A system material may be used. In this inorganic type intercalating agent, the oxidation-inactive surface is reduced by irradiation with ultraviolet light, and OH groups are generated on the surface to make it an active surface. This will cause adhesion.

【0028】又液晶表示素子の製造工程等も任意であ
り、間隙剤の付着性をより強力にするために、間隙剤の
散布時あるいは散布後に電極基板を加熱し配向膜との密
着性を更に向上する等しても良い。
Further, the manufacturing process of the liquid crystal display element and the like are also optional, and in order to further enhance the adhesiveness of the interstitial agent, the electrode substrate is heated during or after the application of the interstitial agent to further improve the adhesion to the alignment film. It may be improved.

【0029】更に配向膜等の材質も有機高分子薄膜に限
定されず無機系薄膜にする等任意である。
Further, the material of the alignment film and the like is not limited to the organic polymer thin film, and may be any inorganic thin film.

【0030】尚、液晶表示素子の駆動手段もアクティブ
マトリクス方式にする等任意である。
The driving means of the liquid crystal display element may be an active matrix type or the like.

【0031】[0031]

【発明の効果】以上説明したように本発明によれば、製
造工程を複雑化する事なく、間隙剤を均一に散布出来、
しかも散布後は振動等により間隙剤が液晶セル内で片寄
りを生じる事が無く、液晶表示素子全面にわたり、コン
トラスト比が良く、広視覚化を有する良好で均一な信頼
性の高い表示を得られ、高品位表示を達成出来、高性能
装置への実装が可能となる。
As described above, according to the present invention, the interstitial agent can be uniformly dispersed without complicating the manufacturing process,
Moreover, after spraying, the gap agent does not become offset in the liquid crystal cell due to vibration or the like, and the contrast ratio is good over the entire liquid crystal display element, and a good, uniform and reliable display with wide visualization can be obtained. , High quality display can be achieved and it can be mounted on high performance devices.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例の液晶表示素子を示す概略断
面図である。
FIG. 1 is a schematic cross-sectional view showing a liquid crystal display element of one embodiment of the present invention.

【図2】本発明の一実施例の間隙剤の散布方法を示す説
明図である。
FIG. 2 is an explanatory view showing a method for spraying a space agent according to an embodiment of the present invention.

【図3】本発明の一実施例の第2の電極基板の注入口付
近における間隙剤の分散配置状態を示す一部平面図であ
る。
FIG. 3 is a partial plan view showing a dispersed arrangement state of a spacing agent in the vicinity of an injection port of a second electrode substrate according to an embodiment of the present invention.

【図4】比較例の電極基板の注入口付近における間隙剤
の分散配置状態を示す一部平面図である。
FIG. 4 is a partial plan view showing a dispersed arrangement state of a space agent near an injection port of an electrode substrate of a comparative example.

【符号の説明】[Explanation of symbols]

1…液晶表示素子 10…第1の電極基板 11…第2の電極基板 24…間隙剤散布装置 26…液晶組成物 27…間隙剤 28…紫外線ランプ DESCRIPTION OF SYMBOLS 1 ... Liquid crystal display element 10 ... 1st electrode substrate 11 ... 2nd electrode substrate 24 ... Pouring agent spraying device 26 ... Liquid crystal composition 27 ... Pouring agent 28 ... Ultraviolet lamp

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 所定の間隔を有して対向する2枚の電極
基板の間隙に、液晶組成物及び前記所定間隔を保持する
ための間隙剤を封入して成る液晶表示素子の製造方法に
おいて、散布手段により前記間隙剤を前記電極基板の少
なくともいずれか一方に空間部を経て散布する工程と、
前記散布手段から前記電極基板にいたる前記空間部にて
前記間隙剤に紫外線光を照射する工程とを具備する事を
特徴とする液晶表示素子の製造方法。
1. A method of manufacturing a liquid crystal display device, comprising a liquid crystal composition and a space agent for holding the predetermined space enclosed in a space between two electrode substrates facing each other with a predetermined space. Spraying the interstitial agent on at least one of the electrode substrates through a space portion by a spraying means;
And a step of irradiating the interstitial agent with ultraviolet light in the space from the spraying means to the electrode substrate.
【請求項2】 電極を有し間隙を隔てて互いに対向する
2枚の電極基板と、この電極基板の前記間隙に封入され
る液晶組成物とを具備する液晶表示素子において、紫外
線光の照射により表面が活性化され前記間隙に散布され
る間隙剤を具備する事を特徴とする液晶表示素子
2. A liquid crystal display device comprising two electrode substrates having electrodes and facing each other with a gap therebetween, and a liquid crystal composition enclosed in the gaps of the electrode substrates, wherein the liquid crystal display device is irradiated with ultraviolet light. A liquid crystal display device characterized by comprising a space agent whose surface is activated and dispersed in the space.
JP11793494A 1994-05-31 1994-05-31 Production of liquid crystal display element and liquid crystal display element Pending JPH07325307A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11793494A JPH07325307A (en) 1994-05-31 1994-05-31 Production of liquid crystal display element and liquid crystal display element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11793494A JPH07325307A (en) 1994-05-31 1994-05-31 Production of liquid crystal display element and liquid crystal display element

Publications (1)

Publication Number Publication Date
JPH07325307A true JPH07325307A (en) 1995-12-12

Family

ID=14723831

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11793494A Pending JPH07325307A (en) 1994-05-31 1994-05-31 Production of liquid crystal display element and liquid crystal display element

Country Status (1)

Country Link
JP (1) JPH07325307A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9488597B2 (en) 2011-11-30 2016-11-08 Corning Incorporated Apparatus and methods for determining surface compliance for a glass surface

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9488597B2 (en) 2011-11-30 2016-11-08 Corning Incorporated Apparatus and methods for determining surface compliance for a glass surface

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