JPH07126113A - Insecticidal composition - Google Patents
Insecticidal compositionInfo
- Publication number
- JPH07126113A JPH07126113A JP5298891A JP29889193A JPH07126113A JP H07126113 A JPH07126113 A JP H07126113A JP 5298891 A JP5298891 A JP 5298891A JP 29889193 A JP29889193 A JP 29889193A JP H07126113 A JPH07126113 A JP H07126113A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- insecticidal composition
- methyl
- cyano
- chloro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は殺虫組成物に関する。FIELD OF THE INVENTION This invention relates to insecticidal compositions.
【０００２】[0002]
【従来の技術】多年にわたる殺虫剤の研究開発によって
多数の防除薬剤が開発、実用化されているが、その効果
が不十分であったり薬剤抵抗性の出現によりその使用が
制限されたり、また植物体に薬害や汚れを生じたり、あ
るいは人畜魚類に対する毒性が強かったりすることから
必ずしも満足すべき防除薬剤とは言い難いものが少なく
ない。従って、かかる欠点の少ない安全に使用できる薬
剤が強く要望されている。2. Description of the Related Art Although many insecticides have been developed and put into practical use through many years of research and development of insecticides, their effects are insufficient and their use is restricted due to the emergence of drug resistance. It is difficult to say that it is a satisfactory control agent because it causes phytotoxicity and stains on the body, or is highly toxic to humans and fishes. Therefore, there is a strong demand for a drug that can be used safely with few such drawbacks.
【０００３】[0003]
【発明が解決しようとする課題】本発明者は、Ｎ 1 −
〔（６−クロロ−３−ピリジル）メチル〕−Ｎ 2 −シア
ノ−Ｎ 1 −メチルアセトアミジンの有効な利用を検討す
る中で、ある種の殺虫剤との組合せにより共力的な殺虫
効果が得られることを見い出した。SUMMARY OF THE INVENTION It is an object of the present invention have, N 1 -
While investigating the effective use of [(6-chloro-3-pyridyl) methyl] -N 2 -cyano- N 1 -methylacetamidine, a synergistic insecticidal effect can be obtained by combining with certain insecticides. I found that I could get it.
【０００４】[0004]
【課題を解決するための手段】本発明は、Ｎ 1 −〔（６
−クロロ−３−ピリジル）メチル〕−Ｎ 2 −シアノ−Ｎ
1 −メチルアセトアミジン（Ｉ）と、チオジカルブ
（Ａ）、トラロメトリン（Ｂ）、テフルベンズロン
（Ｃ）及びジクロルボス（Ｄ）からなる化合物群から選
ばれた少くとも１種とを有効成分として含有する殺虫組
成物である。According to the present invention, N 1 -[(6
- chloro-3-pyridyl) methyl] - N 2 - cyano - N
Insecticidal composition containing 1 -methylacetamidine (I) and at least one selected from the compound group consisting of thiodicarb (A), tralomethrin (B), teflubenzuron (C) and dichlorvos (D) as active ingredients It is a thing.
【０００５】以下、Ｎ 1 −〔（６−クロロ−３−ピリジ
ル）メチル〕−Ｎ 2 −シアノ−Ｎ 1−メチルアセトアミ
ジンを化合物（Ｉ）と略記する。また、チオジカルブ
（Ａ）、トラロメトリン（Ｂ）、テフルベンズロン
（Ｃ）及びジクロルボス（Ｄ）からなる化合物群から選
ばれた化合物を化合物（II）と略記する。Hereinafter, N 1 -[(6-chloro-3-pyridyl) methyl] -N 2 -cyano- N 1 -methylacetamidine is abbreviated as compound (I). A compound selected from the compound group consisting of thiodicarb (A), tralomethrin (B), teflubenzuron (C) and dichlorvos (D) is abbreviated as compound (II).
【０００６】化合物（Ｉ）に化合物（II）を配合した本
発明による殺虫組成物の殺虫効果はそれぞれ単独の活性
化合物の効果より強く優れた共力作用を示した。即ち、
本発明による殺虫組成物を施用することにより例えば、
アブラナ科作物の重要害虫であるコナガ、ハスモンヨト
ウ、アブラムシ、チャノハマキ、チャノホソガ、チャノ
キイロアザミウマ、リンゴのハマキ虫に対して各々単独
の活性化合物の場合より効果が高く共力的な殺虫効果を
示した。The insecticidal effect of the insecticidal composition according to the present invention, in which the compound (II) is mixed with the compound (I), has a stronger synergistic effect than the effect of each active compound. That is,
By applying the insecticidal composition according to the present invention, for example,
It showed a higher and more synergistic insecticidal effect than the active compounds alone against the important pests of cruciferous crops, Plutella xylostella, Spodoptera litura, Aphid, Chanohamaki, Chanohosogha, Anoectus alba, and Apple beetle.
【０００７】本発明の殺虫組成物は、有効成分化合物の
純品のままでも使用できるが通常一般の農薬のとり得る
形態、即ち水和剤、水溶剤、粉剤、乳剤、粒剤、フロア
ブル剤、燻煙剤、燻蒸剤等の形態に同時に混合製剤して
使用しても良いし或いは別々に製剤したものを混合して
使用してもよい。添加剤及び担体としては固型剤を目的
とする場合は大豆粉、小麦粉等の植物性粉末、珪藻土、
燐灰石、石膏、タルク、ベントナイト等の鉱物性微粉
末、安息香酸ソーダ、尿素、芒硝等の有機及び無機化合
物が使用される。液体の剤型を目的とする場合は、植物
油、鉱物油、ケロシン、キシレンおよびソルベントナフ
サ等の石油留分、シクロヘキサン、シクロヘキサノン、
ジメチルホルムアミド、ジメチルスルホキシド、トリク
ロルエチレン、メチルイソブチルケトン、水等を溶剤と
して使用する。これらの製剤において、均一なかつ安定
な形態をとるために必要ならば界面活性剤を添加するこ
ともできる。このようにして得られた水和剤、乳剤、水
溶剤、フロアブル剤は水で所定の濃度に希釈して懸濁
液、溶液あるいは乳濁液として、粉剤、粒剤はそのま
ま、散布する方法で使用される。混合製剤時の化合物
（Ｉ）と化合物（II）の混合比率は４：１から１：１０
０であり望ましくは１：１から１：１０である。The pesticidal composition of the present invention can be used as it is as a pure product of an active ingredient compound, but it is usually in a form which can be taken by general agricultural chemicals, that is, a wettable powder, a water solution, a powder, an emulsion, a granule, a flowable agent, The fumigants, fumigants and the like may be mixed and formulated at the same time, or may be formulated separately and mixed and used. As the additives and carriers, soybean powder when the purpose is a solidifying agent, plant powder such as wheat flour, diatomaceous earth,
Mineral fine powders such as apatite, gypsum, talc and bentonite, and organic and inorganic compounds such as sodium benzoate, urea and mirabilite are used. For the purpose of liquid dosage form, petroleum fractions such as vegetable oil, mineral oil, kerosene, xylene and solvent naphtha, cyclohexane, cyclohexanone,
Dimethylformamide, dimethylsulfoxide, trichloroethylene, methyl isobutyl ketone, water and the like are used as the solvent. Surfactants can also be added to these formulations if necessary to achieve a uniform and stable form. The wettable powder, emulsion, water solvent, and flowable agent thus obtained are diluted with water to a predetermined concentration to give a suspension, solution, or emulsion, and powders and granules are sprayed as they are. used. The mixing ratio of compound (I) and compound (II) in the mixed preparation is from 4: 1 to 1:10.
It is 0, and preferably 1: 1 to 1:10.
【０００８】[0008]
【実施例】次に製剤の実施例を示すが、添加する担体、
界面活性剤等はこれらの実施例に限定されるものではな
い。[Examples] Examples of formulations are shown below.
The surfactant and the like are not limited to these examples.
【０００９】 実施例１ 水和剤 化合物（Ｉ） １０部 化合物（II） １０部 高級アルコール硫酸エステルのＮａ塩 ５部 リグニンスルホン酸のＮａ塩 ５部 珪藻土 ６５部 シリカ ５部 以上を混合して微粉に粉砕し、使用に際し水で希釈して
懸濁液として散布する。Example 1 Wettable powder Compound (I) 10 parts Compound (II) 10 parts Higher alcohol sulfate ester Na salt 5 parts Lignin sulfonic acid Na salt 5 parts Diatomaceous earth 65 parts Silica 5 parts Fine powder by mixing the above It is crushed into water and diluted with water before use and sprayed as a suspension.
【００１０】 実施例２ 水和剤 化合物（Ｉ） ２０部 化合物（II） ３０部 高級アルコール硫酸エステル ５部 クレー ４０部 シリカ ５部 以上を混合して微粉に粉砕し、使用に際し水で希釈して
懸濁液として散布する。Example 2 Wettable powder Compound (I) 20 parts Compound (II) 30 parts Higher alcohol sulfate ester 5 parts Clay 40 parts Silica 5 parts The above components are mixed and ground into fine powder, and diluted with water before use. Spray as a suspension.
【００１１】 実施例３ 乳剤 化合物（Ｉ） １０部 化合物（II） ２０部 アルキルフェニルポリオキシエチレン ５部 ジメチルホルムアミド ４５部 キシレン ２０部 以上を混合溶解し、使用に際し水で希釈して懸濁液とし
て散布する。Example 3 Emulsion Compound (I) 10 parts Compound (II) 20 parts Alkylphenyl polyoxyethylene 5 parts Dimethylformamide 45 parts Xylene 20 parts Mix and dissolve the above, and dilute with water to use as a suspension. Disperse.
【００１２】[0012]
【発明の効果】次に、本発明が殺虫剤として有効である
ことを試験例で示す。以下の表において、Ｉは化合物
（Ｉ）、Ａはチオジカルブ、Ｂはトラロメトリン、Ｃは
テフルベンズロン、Ｄはジクロルボスである。 試験例１ コナガに対する試験 実施例１に示された処方に準じて作成された水和剤を所
定濃度になるように水を加えて薬液を調整し、この薬液
をコナガの寄生したキャベツに散布し７日後に虫数を数
えた。結果を第１表に示す。The effect of the present invention as a pesticide will be shown in the following test examples. In the table below, I is compound (I), A is thiodicarb, B is tralomethrin, C is teflubenzuron, and D is dichlorvos. Test Example 1 Test against diamondback moth The water-dispersible powder prepared according to the formulation shown in Example 1 was added with water to a predetermined concentration to prepare a drug solution, and this drug solution was sprayed on cabbage infested with diamondback moth. After 7 days, the number of insects was counted. The results are shown in Table 1.
【００１３】[0013]
【表１】 [Table 1]
【００１４】試験例２ モモアカアブラムシに対する試
験 実施例１に示された処方に準じて作成された水和剤を所
定濃度になるように水を加えて薬液を調整し、この薬液
をモモアカアブラムシの寄生したキャベツに散布し、７
日後に虫数を数えた。結果を第２表に示す。Test Example 2 Test for green peach aphid A wettable powder prepared according to the formulation shown in Example 1 was adjusted to a predetermined concentration by adding water to prepare a chemical solution, and this chemical solution was used for the green peach aphid. Sprinkle on the parasitic cabbage of 7
The number of insects was counted after the day. The results are shown in Table 2.
【００１５】[0015]
【表２】 [Table 2]
【００１６】試験例３ チャノホソガに対する試験 実施例３に示された処方に準じて作成された乳剤を所定
濃度になるように水を加えて薬液を調整し、この薬液を
茶樹に散布し、３５日後に茶葉数を数え防除率を求め
た。結果を第３表に示す。Test Example 3 Test against Chanophosoga Emulsion prepared according to the formulation shown in Example 3 was adjusted to a predetermined concentration with water to prepare a chemical solution, which was sprayed on tea plants for 35 days. After that, the number of tea leaves was counted and the control rate was calculated. The results are shown in Table 3.
【００１７】[0017]
【表３】 [Table 3]
───────────────────────────────────────────────────── フロントページの続き (72)発明者 武 智宏 静岡県榛原郡榛原町坂部62−１ 日本曹達 株式会社榛原農業研究所内 (72)発明者 高橋 英光 静岡県榛原郡榛原町坂部62−１ 日本曹達 株式会社榛原農業研究所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Tomohiro Take, 62-1 Sakabe, Haibara-cho, Haibara-gun, Shizuoka Prefecture Inside the Haibara Agricultural Research Institute, Nippon Soda Co., Ltd. (72) Hidemitsu Takahashi 62-1 Sakabe, Haibara-cho, Haibara-gun, Shizuoka Japan Soda Co., Ltd. Haibara Agricultural Research Institute
Claims (1)
メチル〕−Ｎ 2 −シアノ−Ｎ 1 −メチルアセトアミジン
と、チオジカルブ、トラロメトリン、テフルベンズロン
及びジクロルボスからなる化合物群から選ばれた少くと
も１種とを有効成分として含有する殺虫組成物。1. N 1 -[(6-chloro-3-pyridyl)
An insecticidal composition comprising, as an active ingredient, methyl] -N 2 -cyano- N 1 -methylacetamidine and at least one selected from the group of compounds consisting of thiodicarb, tralomethrin, teflubenzuron and dichlorvos.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5298891A JPH07126113A (en) | 1993-11-04 | 1993-11-04 | Insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5298891A JPH07126113A (en) | 1993-11-04 | 1993-11-04 | Insecticidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07126113A true JPH07126113A (en) | 1995-05-16 |
Family
ID=17865505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5298891A Pending JPH07126113A (en) | 1993-11-04 | 1993-11-04 | Insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07126113A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996010915A1 (en) * | 1994-10-11 | 1996-04-18 | Bayer Aktiengesellschaft | Insecticides |
| WO2005058039A1 (en) * | 2003-12-12 | 2005-06-30 | Bayer Cropscience Aktiengesellschaft | Synergistic insecticidal mixtures |
| WO2007053613A1 (en) * | 2005-11-01 | 2007-05-10 | Bayer Cropscience Lp | Nematicidal compositions and methods |
| JP2007211015A (en) * | 2005-06-01 | 2007-08-23 | Meiji Seika Kaisha Ltd | Pest-controlling agent |
| JP2012197284A (en) * | 2005-06-01 | 2012-10-18 | Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 | Pest control agent |
| US8367707B2 (en) | 2005-06-01 | 2013-02-05 | Meiji Seika Pharma Co., Ltd. | Pest control agents |
-
1993
- 1993-11-04 JP JP5298891A patent/JPH07126113A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996010915A1 (en) * | 1994-10-11 | 1996-04-18 | Bayer Aktiengesellschaft | Insecticides |
| KR100886846B1 (en) * | 2003-12-12 | 2009-03-04 | 바이엘 크롭사이언스 아게 | Synergistic insecticidal mixtures |
| JP2007513902A (en) * | 2003-12-12 | 2007-05-31 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Synergistic insecticide mixture |
| KR100859547B1 (en) * | 2003-12-12 | 2008-09-22 | 바이엘 크롭사이언스 아게 | Synergistic insecticidal mixtures |
| WO2005058039A1 (en) * | 2003-12-12 | 2005-06-30 | Bayer Cropscience Aktiengesellschaft | Synergistic insecticidal mixtures |
| JP4691042B2 (en) * | 2003-12-12 | 2011-06-01 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Synergistic insecticide mixture |
| AU2004298747B2 (en) * | 2003-12-12 | 2011-06-02 | Bayer Intellectual Property Gmbh | Synergistic insecticidal mixtures |
| US8916613B2 (en) | 2003-12-12 | 2014-12-23 | Bayer Cropscience Ag | Synergistic insecticidal mixtures |
| JP2007211015A (en) * | 2005-06-01 | 2007-08-23 | Meiji Seika Kaisha Ltd | Pest-controlling agent |
| JP2012197284A (en) * | 2005-06-01 | 2012-10-18 | Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 | Pest control agent |
| US8367707B2 (en) | 2005-06-01 | 2013-02-05 | Meiji Seika Pharma Co., Ltd. | Pest control agents |
| US8822501B2 (en) | 2005-06-01 | 2014-09-02 | Meiji Seika Pharma Co., Ltd. | Pest control agents |
| WO2007053613A1 (en) * | 2005-11-01 | 2007-05-10 | Bayer Cropscience Lp | Nematicidal compositions and methods |
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