JPH07126104A - Pest-repelling composition for human body - Google Patents
Pest-repelling composition for human bodyInfo
- Publication number
- JPH07126104A JPH07126104A JP21769594A JP21769594A JPH07126104A JP H07126104 A JPH07126104 A JP H07126104A JP 21769594 A JP21769594 A JP 21769594A JP 21769594 A JP21769594 A JP 21769594A JP H07126104 A JPH07126104 A JP H07126104A
- Authority
- JP
- Japan
- Prior art keywords
- pest repellent
- composition
- human body
- silicic acid
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000443 aerosol Substances 0.000 claims abstract description 19
- -1 silicic acid compound Chemical class 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000003380 propellant Substances 0.000 claims abstract description 6
- 239000005871 repellent Substances 0.000 claims description 62
- 230000002940 repellent Effects 0.000 claims description 62
- 241000607479 Yersinia pestis Species 0.000 claims description 44
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000000077 insect repellent Substances 0.000 claims description 2
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- 239000000377 silicon dioxide Substances 0.000 abstract description 5
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- 230000002459 sustained effect Effects 0.000 abstract 1
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- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- XXUNIGZDNWWYED-UHFFFAOYSA-N 2-methylbenzamide Chemical compound CC1=CC=CC=C1C(N)=O XXUNIGZDNWWYED-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
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- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- 239000006096 absorbing agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
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- 229960000846 camphor Drugs 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- GJWSUKYXUMVMGX-UHFFFAOYSA-N citronellic acid Chemical compound OC(=O)CC(C)CCC=C(C)C GJWSUKYXUMVMGX-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 2
- 229960001826 dimethylphthalate Drugs 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
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- 238000011156 evaluation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
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- 230000002209 hydrophobic effect Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
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- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- VBAYIYXVOOGXEM-UHFFFAOYSA-N methyl 6-pentylcyclohexene-1-carboxylate Chemical compound COC(=O)C1=CCCCC1CCCCC VBAYIYXVOOGXEM-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229940010310 propylene glycol dioleate Drugs 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 206010039766 scrub typhus Diseases 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は人体用害虫忌避組成物に
関し、さらに詳しくはその持続性を、付着性および使用
感とともに改善された人体用害虫忌避用組成物に係る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pest repellent composition for humans, and more particularly to a pest repellent composition for humans, which is improved in durability as well as adhesion and feeling of use.
【０００２】[0002]
【従来の技術】Ｎ，Ｎ−ジエチル−ｍ−トルアミドを含
有した人体用忌避組成物は従来より知られていたが、こ
れらの成分が揮発性の薬剤であることから、その持続性
においては十分でないという問題があった。この揮発性
が高いために持続性が劣るという問題についてそれを解
決するための技術としては、特開昭５９−１９９６１５
号公報や特開平２−２４３８２号公報などでは鉱物粉体
を用い、特開昭５５−１２９２０２号公報などでは有機
粉体を用い、特開昭６３−１９２７０２号公報にはマイ
クロカプセルを用い、特開平１−１７２３０３号公報で
はヒマシ油などを配合し、特開昭６３−１６６８０２号
公報では水性シリコーンを添加することにより、特開平
４−２４４００１号公報には疎水性シリコーンを添加す
ることによりそれぞれ忌避効力を持続させるものが開示
されている。2. Description of the Related Art A human repellent composition containing N, N-diethyl-m-toluamide has been conventionally known. However, since these components are volatile drugs, their durability is not sufficient. There was a problem not. As a technique for solving the problem of poor sustainability due to high volatility, Japanese Patent Laid-Open No. 59-199615 is known.
In Japanese Patent Application Laid-Open No. 2-24382 and Japanese Patent Application Laid-Open No. 2-24382, mineral powder is used, in Japanese Patent Application Laid-Open No. 55-129202, organic powder is used, and Japanese Patent Application Laid-Open No. 63-192702 uses microcapsules. In Kaihei 1-173203, castor oil and the like are compounded, in JP-A-63-166802, an aqueous silicone is added, and in JP-A-4-244001, a hydrophobic silicone is added to repel each. Those that maintain efficacy are disclosed.
【０００３】特に、特開昭５９−１９９６１５号公報に
は鉱物粉体としてタルク、シリカ、カオリン、モンモリ
ロナイト、白土、ベントナイト、珪藻土、炭酸カルシウ
ム、炭酸マグネシウム、リン酸カルシウム、酸化チタン
および硫酸バリリウムを含むことで忌避効力を持続し、
特にこれら鉱物粉末の皮膚表面への付着性を考慮する
と、平均粒径を５０μｍ以下にし、かつ適用時の肌ざわ
りあるいは外観上から配合量を１から２０重量％が好適
であることが記載されている。さらに、皮膚への鉱物粉
末の付着性を増すためにステアリン酸マグネシウム、ス
テアリン酸亜鉛、ミリスチン酸イソプロピルおよびステ
アリン酸ｎ−ブチルなどを添加することが記載されてい
る。In particular, Japanese Patent Laid-Open No. 59-199615 discloses that talc, silica, kaolin, montmorillonite, clay, bentonite, diatomaceous earth, calcium carbonate, magnesium carbonate, calcium phosphate, titanium oxide and barium sulfate are contained as mineral powders. Sustains repellent efficacy,
In particular, considering the adhesiveness of these mineral powders to the skin surface, it is described that the average particle size is 50 μm or less, and the blending amount is preferably 1 to 20% by weight from the feel of the application or the appearance. There is. Further, it is described that magnesium stearate, zinc stearate, isopropyl myristate, n-butyl stearate and the like are added to increase the adhesion of the mineral powder to the skin.
【０００４】[0004]
【発明が解決しようとする課題】しかし、前記の様に持
続性向上のためにヒマシ油や水性シリコーンを用いた際
には、べとつき感がして、使用感が悪くなることや、忌
避組成物を適用した部位に土・砂が付着したり、前記の
鉱物粉体を用いた場合はそれが水や汗に流れ易いこと、
あるいは当該鉱物粉体を適用するには、分散液として吹
きつける関係で、溶液中で分散させるために界面活性剤
を用いなければならないため、その界面活性剤によりべ
とつき感が出て、使用感が著しく低下する。さらに、使
用感の点では、害虫忌避成分のＮ，Ｎ−ジエチル−ｍ−
トルアミドは油状であるため、皮膚に塗布した際にベと
つく感がして、使用感が悪かった。However, as described above, when castor oil or aqueous silicone is used for improving sustainability, a sticky feeling is caused and the usability is deteriorated, and the repellent composition is used. Soil or sand adheres to the area where is applied, or when the above-mentioned mineral powder is used, it easily flows into water or sweat,
Alternatively, in order to apply the mineral powder, a surfactant must be used to disperse in the solution because of spraying as a dispersion liquid, so that the surfactant gives a sticky feeling and a feeling of use. Markedly reduced. Furthermore, in terms of usability, N, N-diethyl-m-, a pest repellent component, is used.
Since toluamide is oily, it feels sticky when applied to the skin, and is uncomfortable to use.
【０００５】さらに、鉱物粉体を用いた忌避組成物を適
用した場合には、その処理した面が乾燥後に当該鉱物粉
体により、白く粉を吹いたようになり、この白い粉が衣
類などに付着して汚れたり、あるいは処理した衣類が白
くなるため、忌避組成物で身体や衣類を処理することが
好まれなかった。しかし、蚊、ハチ、アブ、ブユ、、ダ
ニ、ノミ、ナッキンムシ、ムカデ、ゲジゲジ等による被
害が増しており、特に野外における活動が活発になった
結果、ツツガムシ病、ライム病など、刺咬害虫によって
生命にかかわる場合も増加してきている。このため、持
続効果性があり、先の問題点を解消した使用感の良く、
かつ白化しない人体用害虫忌避剤の開発が望まれている
状況にある。Further, when the repellent composition using a mineral powder is applied, the treated surface becomes dry after the dried surface due to the mineral powder, and the white powder is applied to clothes and the like. It was not preferred to treat the body or clothing with the repellent composition because it adheres and stains or the treated clothing becomes white. However, the damage caused by mosquitoes, bees, flies, gnats, mites, fleas, stickworms, centipedes, and gudgeages has increased, especially as a result of active outdoor activities, such as tsutsugamushi disease and Lyme disease. Life-threatening cases are also increasing. Therefore, it has a long-lasting effect and has a good usability that solves the above problems,
Moreover, there is a demand for the development of a human body harmful insect repellent.
【０００６】[0006]
【課題を解決するための手段】そこで本発明者らは、忌
避効力が長時間持続するようにするために、鉱物粉体配
合の人体用忌避剤を検討し、詳しくは害虫忌避成分、ケ
イ酸化合物、分散剤および溶媒を配合した人体用害虫忌
避組成物を検討した結果、特徴あるケイ酸化合物を用い
ることで使用感が良く、白化せずかつ忌避効力を有する
時間も十分に長い害虫忌避組成物を調製し、本発明を完
成した。すなわち、本発明は次の手段により前記の目的
を達成した。 （１）害虫忌避成分、ケイ酸化合物および溶媒を含有す
る人体用害虫忌避剤において、該ケイ酸化合物が比表面
積が５００ｍ2 ／ｇ以上の無水ケイ酸であることを特徴
とする人体用害虫忌避組成物。 （２）害虫忌避成分がＮ，Ｎ−ジエチル−ｍ−トルアミ
ドであることを特徴とする前記（１）記載の人体用害虫
忌避組成物。 （３）溶媒がエタノールであることを特徴とする前記
（１）又は（２）記載の人体用害虫忌避組成物。 （４）害虫忌避成分、比表面積が５００ｍ2 ／ｇ以上の
無水ケイ酸および溶媒を含有する人体用害虫忌避剤を噴
射剤とともに配合したことを特徴とする人体用害虫忌避
エアゾール。[Means for Solving the Problems] Therefore, in order to make the repellent effect last for a long time, the present inventors have investigated a repellent for human body containing a mineral powder, and more specifically, a pest repellent component, silicic acid. As a result of examining a human body pest repellent composition containing a compound, a dispersant and a solvent, a pest repellent composition having a good feeling in use by using a characteristic silicic acid compound, which does not whiten and has a long repellent effect time The product was prepared and the present invention was completed. That is, the present invention has achieved the above object by the following means. (1) A human pest repellent containing a pest repellent component, a silicic acid compound and a solvent, wherein the silicic acid compound is silicic anhydride having a specific surface area of 500 m 2 / g or more. Composition. (2) The pest repellent composition for human body according to (1) above, wherein the pest repellent component is N, N-diethyl-m-toluamide. (3) The pest repellent composition for human body according to the above (1) or (2), wherein the solvent is ethanol. (4) A pest repellent aerosol for a human body, comprising a pest repellent for the human body containing a pest repellent component, silicic acid anhydride having a specific surface area of 500 m 2 / g or more, and a solvent together with a propellant.
【０００７】本発明において用いる害虫忌避成分として
は、害虫に対して忌避作用あるいは吸血阻害作用を有す
る合成あるいは天然の各種の化合物が挙げられる。例え
ば、ユーカリプトール、α−ピネン、ゲラニオール、シ
トロネラール、カンファー、リナロール、ｐ−メンテン
−３，８−ジオール、テルペノール、フタル酸ジオクチ
ル、フタル酸ジブチル、Ｎ，Ｎ−ジエチル−ｍ−トルア
ミド、２−エチル−１，３−ヘキサジオール、インダロ
ン（ブチル ３，４−ジヒドロ−２，２−ジメチル−４
−オキソ−２Ｈ−ピラン−６−カルボキシレート）、Ｓ
ＲＩ−Ｃ（ｎ−ヘキシルトリエチレングリコールモノエ
ーテル）、２５０４−５（メチル ６−ｎ−ペンチル−
シクロヘキセン−１−カルボキシレート）、ＤＭＰ（ジ
メチルフタレート）、シトロネラル（３，７−ジメチル
−６−オクテナル）、ナフタレン、シトロネール酸、２
−エチル−２−ブチル−１，３−プロパンジオール、
２，３，４，５−ビス（Δ2 −ブチレン）テトラハイド
ロフルフラール、ジ−ｍ−プロピルイソシンコメロネー
ト、２−（４−エトキシフェニル）−２メチルプロピル
−３−フェキシベンジルエーテル、１−エチニル−２−
メチル−２−ペンテニル−２，２，３，３−テトラメチ
ルシクロプロパンカルボキシレート、１−エチニル−２
−メチル−２−ペンテニル−２，２−ジメチル−３−
（２′−メチル−１′−プロペニル）シクロプロパンカ
ルボキシレートなどが例示できる。Examples of the pest repellent component used in the present invention include various synthetic or natural compounds having a repellent action or blood-feeding inhibitory action against pests. For example, eucalyptol, α-pinene, geraniol, citronellal, camphor, linalool, p-menthene-3,8-diol, terpenol, dioctyl phthalate, dibutyl phthalate, N, N-diethyl-m-toluamide, 2- Ethyl-1,3-hexadiol, indarone (butyl 3,4-dihydro-2,2-dimethyl-4
-Oxo-2H-pyran-6-carboxylate), S
RI-C (n-hexyl triethylene glycol monoether), 2504-5 (methyl 6-n-pentyl-
Cyclohexene-1-carboxylate), DMP (dimethylphthalate), citronellal (3,7-dimethyl-6-octenal), naphthalene, citronellic acid, 2
-Ethyl-2-butyl-1,3-propanediol,
2,3,4,5-bis (Δ 2 -butylene) tetrahydrofurfural, di-m-propylisocinchomeronate, 2- (4-ethoxyphenyl) -2methylpropyl-3-foxybenzyl ether, 1 -Ethynyl-2-
Methyl-2-pentenyl-2,2,3,3-tetramethylcyclopropanecarboxylate, 1-ethynyl-2
-Methyl-2-pentenyl-2,2-dimethyl-3-
Examples include (2'-methyl-1'-propenyl) cyclopropanecarboxylate.
【０００８】さらに天然物としては、桂皮、樟脳、シト
ロネラ、レモングラス、クローバ、タチジャコウソウ、
ジェラニウム、ベルガモント、月桂樹、松、アカモモ、
ペニーロイアル、ユーカリおよびインドセンダンなどか
ら取れる精油、抽出液などが例示でき、これらの１種ま
たは２種以上を選択して用いることができる。上記化合
物、天然物の中、特にＮ，Ｎ−ジエチル−ｍ−トルアミ
ドが好ましい。そして、その配合量としては各薬剤の忌
避効力により異なるが、例えば、Ｎ，Ｎ−ジエチル−ｍ
−トルアミドであれば２〜２５ｗ／ｖ％、好ましくは５
〜１５ｗ／ｖ％の範囲が良い。さらに好ましくは液剤で
は５〜１０ｗ／ｖ％、エアゾール剤では２〜５％が良
い。そしてこの範囲を外れて用量が２ｗ／ｖ％より少な
いと忌避効力が弱く、２５ｗ／ｖ％より多過ぎるとべと
つき感を感じる。Further, as natural products, cinnamon, camphor, citronella, lemongrass, clover, red musk,
Geranium, bergamont, laurel, pine, redberry,
Examples thereof include essential oils and extracts obtained from penny royal, eucalyptus, neem, and the like, and one or more of these can be selected and used. Among the above compounds and natural products, N, N-diethyl-m-toluamide is particularly preferable. The amount of the compound varies depending on the repellent efficacy of each drug, but is, for example, N, N-diethyl-m.
2-25 w / v% for toluamide, preferably 5
A range of up to 15 w / v% is preferable. More preferably, it is 5 to 10 w / v% for a liquid agent and 2 to 5% for an aerosol agent. If the dose is out of this range and the dose is less than 2 w / v%, the repellent effect is weak, and if the dose is more than 25 w / v%, a sticky feeling is felt.
【０００９】本発明においては、前記害虫忌避成分等を
溶媒中に均一に分散させるために、分散剤を一緒に用い
ることが好ましい。ただ、長期間保存することを要しな
いような場合には、この分散剤をかならずしも使用しな
くてもよい。このような分散剤としては、各種の界面活
性剤が用いられ、例えばソルビタントリオレエート、ポ
リオキシエチレンモノオレエート、ポリオキシエチレン
ノニルフェニルエーテル、ポリオキシエチレン（１０モ
ルから４０モル）硬化ヒマシ油、トリポリオキシエチレ
ンアルキルエーテル、１，３−ブチレングリコール、デ
カグリセリンモノオレエート、ジオレイン酸プロピレン
グリコール、ポリオキシエチレン（１６モルから２０モ
ル）ステアリル酸アミド、ポリオキシエチレンポリオキ
シプロピレングリコール、ポリオキシエチレンラウリル
エーテルリン酸が例示でき、その他にもステアリルアル
コール、ポリビニルピロリドン、ラノリン脂肪酸が例示
できる。これらの分散剤の１種または２種以上を配合す
ることでケイ酸化合物を組成物中に分散することがで
き、その配合量としては０．２〜５ｗ／ｖ％であり、好
ましくは０．５〜２ｗ／ｖ％で、特に好ましいのは０．
５〜１ｗ／ｖ％である。そして分散剤の配合量が０．２
ｗ／ｖ％以下であればケイ酸化合物が十分に分散せず、
５ｗ／ｖ％以上であればべとつき感を生じる。In the present invention, it is preferable to use a dispersant together in order to uniformly disperse the pest repellent component and the like in the solvent. However, when it is not necessary to store for a long period of time, this dispersant may not always be used. As such a dispersant, various surfactants are used, for example, sorbitan trioleate, polyoxyethylene monooleate, polyoxyethylene nonylphenyl ether, polyoxyethylene (10 to 40 mol) hydrogenated castor oil, Tripolyoxyethylene alkyl ether, 1,3-butylene glycol, decaglycerin monooleate, propylene glycol dioleate, polyoxyethylene (16 to 20 mol) stearyl amide, polyoxyethylene polyoxypropylene glycol, polyoxyethylene lauryl Examples thereof include ether phosphoric acid, and stearyl alcohol, polyvinylpyrrolidone, and lanolin fatty acid. The silicic acid compound can be dispersed in the composition by blending one or more of these dispersants, and the blending amount is 0.2 to 5 w / v%, and preferably 0.1. 5 to 2 w / v%, and particularly preferably 0.
It is 5 to 1 w / v%. And the compounding amount of the dispersant is 0.2
If w / v% or less, the silicic acid compound is not sufficiently dispersed,
If it is 5 w / v% or more, a sticky feeling occurs.
【００１０】本発明において用いる溶媒としては、化粧
料に用いれるものであればなんら限定されない。例えば
水：例えばエチルアルコール、イソプロピルアルコール
など低級アルコール、またこれらの低級アルコールに香
料などで変性した変性アルコールなどから選ばれる１種
または２種以上が例示できるが、そしてこれらの配合量
は各々性状により異なるが、例えばエタノールを例に取
ると、その配合量としては２０〜９５ｖ／ｖ％であり、
好ましくは５０〜９０ｖ／ｖ％で、さらに好ましくは６
０〜８５ｖ／ｖ％ある。そして、エタノールの配合量が
２０ｖ／ｖ％以下であれば清涼感が不十分で、９５ｖ／
ｖ％以上であれば他の成分をを添加することができなく
なる。The solvent used in the present invention is not limited as long as it is used in cosmetics. For example, water: for example, one or more selected from lower alcohols such as ethyl alcohol and isopropyl alcohol, and denatured alcohols obtained by modifying these lower alcohols with perfumes, etc., and the blending amount thereof depends on the properties. Although different, for example, in the case of ethanol, the compounding amount is 20 to 95 v / v%,
It is preferably 50 to 90 v / v%, more preferably 6
There is 0-85 v / v%. And, if the blending amount of ethanol is 20 v / v% or less, the refreshing feeling is insufficient, and 95 v /
If it is v% or more, other components cannot be added.
【００１１】本発明においては、ケイ酸化合物として比
表面積が５００ｍ2 ／ｇ以上の無水ケイ酸を使用するも
のである。これは、使用するケイ酸化合物として、各種
ケイ酸化合物、例えば疎水性シリカ、ケイ酸カルシウ
ム、ケイソウ土、高純度シリカおよび無水ケイ酸を比較
した結果、比表面積が５００ｍ2 ／ｇ以上の無水ケイ酸
が好ましいことが判明したためである。この場合の比表
面積は普通吸着量を実験的に求め、これをＢ．Ｅ．Ｔ．
の式を適用して算出したもの（一般に云うＢＥＴ法）
で、そしてその比表面積が５００ｍ2 ／ｇ未満であると
分散性が悪く、保存時にケイ酸化合物が凝集して使用時
にザラザラした感じになったり、白化したりする。人体
用害虫忌避エアゾールに用いた場合は目づまりを生じ
る。このような比表面積を有する無水ケイ酸は、市販さ
れており、容易に入手することができる。その比表面積
の上限については特に限定する技術的理由もないが、実
際上は比表面積が５００ｍ2 ／ｇよりもかなり大きいも
のを製造することは困難なことであって、実用上の制約
がある。なお、本発明において「無水ケイ酸」とは、
「二酸化ケイ素を高純度で含有するケイ酸化合物」を意
味するものである。In the present invention, silicic acid anhydride having a specific surface area of 500 m 2 / g or more is used as the silicic acid compound. As a result of comparing various silicic acid compounds, for example, hydrophobic silica, calcium silicate, diatomaceous earth, high-purity silica and silicic acid as silicic acid compounds to be used, anhydrous silicic acid having a specific surface area of 500 m 2 / g or more is obtained. This is because it has been found that an acid is preferable. For the specific surface area in this case, the amount of adsorption is usually obtained experimentally, and this is calculated by E. T.
Calculated by applying the formula of (BET method generally called)
When the specific surface area is less than 500 m 2 / g, the dispersibility is poor, and the silicic acid compound aggregates during storage, resulting in a rough feeling or whitening during use. If it is used as a pest repellent aerosol for humans, it may cause clogging. Silicic anhydride having such a specific surface area is commercially available and can be easily obtained. There is no particular technical reason for limiting the upper limit of the specific surface area, but it is actually difficult to produce a material having a specific surface area much larger than 500 m 2 / g, and there is a practical limitation. . In the present invention, "silicic anhydride" means
It means a "silicic acid compound containing silicon dioxide in high purity".
【００１２】本発明の人体用害虫忌避エアゾールは、前
記した人体用害虫忌避組成物に噴射剤を添加してエアゾ
ール容器に充填することでできる。噴射剤としては液化
石油ガス、プロパン、プロピレン、ｎ−ブタン、イソブ
タン、ｎ−ブチレン、イソブチレン、ブタジエン、ｎ−
ペンタン、イソペンタン、ｎ−ヘキサン、イソヘキサ
ン、ジメチルエーテル、炭酸ガス、窒素ガスおよびフロ
ンガス（ＨＣＦＣ２２、１２３、１２４、１４１ｂ、１
４２ｂ、２２５、ＨＦＣ１２５、１３４ａ、１４３ａ、
１５２ａ、３２、２２７など）などが挙げられ、これら
から選ばれた１種または２種以上の物を用いることがで
きる。そして、その配合量は人体用害虫忌避組成物：噴
射剤が１０：９０〜７０：３０の割合で、特に２０：８
０〜５０：５０の範囲が好ましい。また、１０：９０〜
７０：３０の範囲を外れると、噴射粒子が大きくべとつ
き感を感じたりあるいは付着率が悪くなり充分な効力を
発揮することができなくなる。The pest repellent aerosol for human body of the present invention can be prepared by adding a propellant to the above-mentioned human pest repellent composition and filling the aerosol container. As the propellant, liquefied petroleum gas, propane, propylene, n-butane, isobutane, n-butylene, isobutylene, butadiene, n-
Pentane, isopentane, n-hexane, isohexane, dimethyl ether, carbon dioxide gas, nitrogen gas and CFC gas (HCFC22, 123, 124, 141b, 1
42b, 225, HFC125, 134a, 143a,
152a, 32, 227, etc.) and the like, and one or more kinds selected from these can be used. The blending amount of the pest repellent composition for human body: propellant is 10:90 to 70:30, especially 20: 8.
The range of 0 to 50:50 is preferable. Also, from 10:90
If the ratio is out of the range of 70:30, the ejected particles are large and have a sticky feeling, or the adherence rate is poor, and it becomes impossible to exert sufficient effect.
【００１３】さらに、本発明の人体用害虫忌避エアゾー
ルに用いるエアゾール容器としては、押しボタンの噴射
口径０．３から０．５ｍｍ、ステムの内径０．３から
０．６ｍｍ、アンダータップの内径０．３から２．２ｍ
ｍ、ディップチューブの内径が０．５から４ｍｍを具備
する容器が好ましい。さらに、構造的には浮遊粒子を液
中に含むため噴射量を増やすためステムの穴が２個以上
であったたり、粉末の蓄積によるステムラバーの復元阻
害を防止する突起あるいはケイ酸化合物の凝集した場合
に備えて、金属の球を耐圧容器内に入れるなど各種の工
夫を凝らしたものが好ましい。Further, as the aerosol container used for the pest repellent aerosol for human body of the present invention, the injection port diameter of the push button is 0.3 to 0.5 mm, the inner diameter of the stem is 0.3 to 0.6 mm, and the inner diameter of the undertap is 0. 3 to 2.2m
m, the dip tube having an inner diameter of 0.5 to 4 mm is preferable. Further, structurally, since the suspended particles are contained in the liquid, the number of stem holes was two or more in order to increase the injection amount, and the protrusions or aggregation of silicic acid compounds that prevent the stem rubber from being hindered by powder accumulation are restored. In case of doing so, it is preferable to make various efforts such as putting a metal ball in a pressure resistant container.
【００１４】そして、このようなエアゾール容器に充填
することで調製された人体用害虫忌避エアゾールを使用
する場合は、当該エアゾール容器を振とうし、人体用害
虫忌避組成物中のケイ酸化合物を液中に分散させた後
は、通常の人体用害虫忌避エアゾールと同様の使用方法
で用いることができる。本発明の人体用害虫忌避組成物
または人体用害虫忌避エアゾールに、その他の成分とし
て香料、潤滑剤、殺菌剤、色素、保湿剤、紫外線吸収
剤、紫外線遮断剤などの添加剤および溶媒以外の溶剤を
含有させることができる。本明細書において「白化」と
は、本発明の人体用害虫忌避組成物あるいは人体用害虫
忌避エアゾールにより処理した面が、製剤中の溶媒が処
理面から揮散などして当初の皮膚の感触に戻ったとき
に、白色の微粉末がある様に見える状態を言う。When a human body pest repellent aerosol prepared by filling such an aerosol container is used, the aerosol container is shaken to remove the silicic acid compound in the human body pest repellent composition. After being dispersed in it, it can be used in the same manner as in the case of using a normal human insect pest repellent aerosol. Human pest repellent composition or human pest repellent aerosol of the present invention, as a component other than perfume, lubricants, bactericides, dyes, humectants, ultraviolet absorbers, ultraviolet absorbers and other solvents other than solvents Can be included. In the present specification, the term "whitening" means that the surface treated with the human body pest repellent composition or the human body pest repellent aerosol of the present invention returns to the initial skin feel by volatilizing the solvent in the preparation from the treated surface. When it is turned on, it means that it looks like there is a white fine powder.
【００１５】[0015]
【作用】本発明においては、無水ケイ酸が油成分である
ＤＥＥＴなどの害虫忌避成分と共に腕などに塗布された
場合、広い表面積にこれらを付着し、直接これらの化合
物が皮膚と接触しないために良好な使用感が得られる。
また、作用は不明であるがケイ酸化合物が配合されてい
るにもかかわらず、塗布面が白化しない。さらに、害虫
忌避成分を直接皮膚に塗布するのに比して汗あるいは体
温などの影響を受けにくくできたことから従来のものよ
り忌避効果を持続できるような組成物が調製できる。In the present invention, when the silicic acid anhydride is applied to the arm or the like together with the pest repellent component such as DEET which is an oil component, they adhere to a large surface area and the compounds do not come into direct contact with the skin. A good usability is obtained.
Further, although the action is unknown, the coated surface does not whiten even though the silicic acid compound is incorporated. Furthermore, as compared with the case where the pest repellent component is directly applied to the skin, the composition is less susceptible to the influence of sweat or body temperature, so that a composition having a longer repellent effect than the conventional one can be prepared.
【００１６】[0016]
【実施例】以下の示す使用試験および製剤例により、本
発明の人体用害虫忌避剤をより詳細に説明する。但し、
本発明は以下の実施例に限定されるものではない。 試験例 使用試験 実使用の際に気になる点、すなわちベトツキ感、白化、
刺激（スプレー時の噴射物の吸引による刺激）および分
散性（ガラスビン内での粉体のケーキングの状態）につ
いて使用感を調査した。EXAMPLES The human pest repellent of the present invention will be described in more detail by the following use tests and formulation examples. However,
The present invention is not limited to the examples below. Test example Usage test Points to be worried about during actual use, namely stickiness, whitening,
The feeling of use was investigated with respect to irritation (irritation due to suction of a sprayed product during spraying) and dispersibility (state of powder caking in a glass bottle).
【００１７】１．試験試料 試料は、（忌避成分）ＤＥＥＴ５．１６ｇ、（分散剤）
１，３−ブチレングリコール１ｇ、香料０．０５ｇおよ
び（無水ケイ酸）パウダー２．５ｇを（溶媒）変性アル
コールにて５０ｍｌにまでフィルアップし、そして耐圧
性容器に入れ、さらにＬＰＧ５０ｍｌを添加してエアゾ
ール組成物を調製した。そして、配合したパウダーは次
に記載したものを用いた （無水ケイ酸パウダー） サイロイド ５５ （富士シリシア化学（株）社製：「化合物Ａ」という） 〃 ５７ （ 〃 ：「化合物Ｂ」という） 〃 ６５ （ 〃 ：「化合物Ｃ」という） 〃 ６６ （ 〃 ：「化合物Ｄ」という） 〃 ７２ （ 〃 ：「化合物Ｅ」という） 〃 ７４ （ 〃 ：「化合物Ｆ」という） 〃 ４０４（ 〃 ：「化合物Ｇ」という） 〃 ８００（ 〃 ：「化合物Ｈ」という） 〃 １５０（ 〃 ：「化合物Ｉ」という） 〃 ２４４（ 〃 ：「化合物Ｊ」という）1. Test sample The sample is (repellent component) DEET 5.16g, (dispersant)
1 g of 1,3-butylene glycol, 0.05 g of fragrance and 2.5 g of (silicic acid) powder were filled up to 50 ml with (solvent) denatured alcohol, put in a pressure resistant container, and further added with 50 ml of LPG. An aerosol composition was prepared. Then, the following powders were used (silicic acid powder) Syloid 55 (manufactured by Fuji Silysia Chemical Ltd .: “Compound A”) 〃 57 (〃: “Compound B”) 〃 65 (〃: "Compound C") 〃 66 (〃: called "Compound D") 〃 72 (〃: called "Compound E") 〃 74 (〃: called "Compound F") 404 (〃: "Compound G)) 800 (〃: "Compound H") 〃 150 (〃: "Compound I") 244 (〃: "Compound J")
【００１８】 シルデックスＨ−３１ （旭硝子（株）製 ：「化合物Ｋ」という） 〃 Ｈ−５１ （ 〃 ：「化合物Ｌ」という） ゴットボールＢ−６Ｃ （鈴木油脂工業（株）製 ：「化合物Ｍ」という） 〃 Ｅ−６Ｃ （ 〃 ：「化合物Ｎ」という） 〃 Ｄ−１１Ｃ（ 〃 ：「化合物Ｏ」という） アエロジェル ２００ （日本アエロジル（株）製：「化合物Ｐ」という） 〃 ３００ （ 〃 ：「化合物Ｑ」という） 〃 Ｒ９７２Ｄ（ 〃 ：「化合物Ｒ」という） フローライト Ｒ （徳山曹達（株）製 ：「化合物Ｓ」という） トクシール Ｎ （ 〃 ：「化合物Ｔ」という） ファインシールＦ−８０ （ 〃 ：「化合物Ｕ」という） 〃 Ｔ−３２５（ 〃 ：「化合物Ｖ」という）Sildex H-31 (manufactured by Asahi Glass Co., Ltd .: “Compound K”) 〃 H-51 (〃: referred to as “Compound L”) Gottball B-6C (manufactured by Suzuki Yushi Kogyo Co., Ltd.): “Compound” M-6) E-6C (〃: "Compound N") D-11C (〃: "Compound O") Aerogel 200 (Nippon Aerosil Co., Ltd .: "Compound P") 300 (〃 : "Compound Q") 〃 R972D (〃: "Compound R") Fluorite R (Made by Tokuyama Soda Co., Ltd .: "Compound S") Tokseal N (〃: "Compound T") Fineseal F- 80 (〃: "Compound U") T-325 (〃: "Compound V")
【００１９】２．ベトツキ感の確認 試験試料を耐圧噴射用容器（１００ｍｌ東洋製罐社製）
内に充填した。そして、直接手の甲に各試料約０．８５
ｍｌ（約２秒）を噴射した後に、手の甲上の噴射で付着
した物を手の甲全体に反対の手にて伸ばし、その感触を
対照（試験試料よりパウダーを除いた組成物のエアゾー
ルを耐圧噴射用容器内に充填したもの）と毎回比較し
た。比較に際して、始めに対照を左手の甲に噴射・塗布
し感触を確かめた後に、石ケンにて良く洗いタオルで水
分を充分に拭いて、約５分経過後、再度右手の甲に同様
に用いて対照と比較して評価した。評価は対照に比べて
良い方を○、悪いを×で示した。2. Checking for stickiness A test sample container for pressure-resistant injection (100 ml manufactured by Toyo Seikan Co., Ltd.)
Filled inside. And about 0.85 of each sample directly on the back of the hand
After spraying ml (approx. 2 seconds), the object adhered by the spray on the back of the hand is extended to the entire back of the hand with the opposite hand, and the feel is controlled (the aerosol of the composition obtained by removing the powder from the test sample is used for pressure-resistant injection). (Filled in the container) each time. For comparison, first inject and apply the control to the back of the left hand, check the feel, wash well with a soap ball and wipe off the water thoroughly with a towel, and after about 5 minutes, use it again on the back of the right hand as a control. It was evaluated in comparison with. As for the evaluation, the better one and the worse one were shown by x and x, respectively, as compared with the control.
【００２０】３．白化 試験試料を耐圧容器内に充填した。そして前記のベトツ
キ感の確認と同様に、直接手の甲に各試料約０．８５ｍ
ｌ（約２秒）を噴射し、約３０分間放置して風乾後噴射
面が白化するか否かを観察した。観察の結果処理面が白
化していないものを○、白化したものを×で示した。 ４．刺激 試験試料を耐圧容器内に充填した。そして、中空円筒
（内径２０×高さ４０ｃｍ）内に試験試料又は対照（ベ
トツキ感の確認で用いたものと同じ資料）を約３秒間噴
霧し、噴射後約１０秒以内に円筒上面に顔を近づけて鼻
から大きく深呼吸を行いその刺激の感触を確かめた。順
序は毎回先に対照を行いその後約５分以内に試験試料の
刺激の感触を確かめた。評価は対照に比べて同じ程度の
ものを○、刺激が強いものを×で示した。3. The whitening test sample was filled in a pressure resistant container. Then, in the same way as the above-mentioned confirmation of stickiness, about 0.85 m
1 (about 2 seconds) was sprayed and left for about 30 minutes to observe whether the sprayed surface was whitened after air drying. As a result of the observation, ◯ indicates that the treated surface was not whitened, and x indicates that the treated surface was whitened. 4. The stimulation test sample was filled in a pressure resistant container. Then, a test sample or a control (the same material as used for confirmation of stickiness) was sprayed for about 3 seconds into a hollow cylinder (inner diameter 20 × height 40 cm), and the face was placed on the upper surface of the cylinder within about 10 seconds after the injection. We approached the subject and took a deep breath through the nose to confirm the feeling of the stimulus. Each sequence was preceded by a control and within about 5 minutes thereafter the feel of the stimulus of the test sample was confirmed. In the evaluation, those having the same degree as that of the control are indicated by ◯, and those having strong irritation are indicated by x.
【００２１】５．分散性 試験試料５０ｍｌを耐圧ガラス噴射用容器（１００ｍｌ
日本高分子社製）内に充填し、手で約１０回程度激しく
振とうして、まず液中にパウダーが分散しているか確認
した。さらに、約１分程度静置後再度振とうして液中に
パウダーが分散するか否かを観察した。２回の振とうと
もパウダーが液中に分散したものを○、底部で凝固した
り、沈殿物が生成したりあるいは一部が凝固したりした
物を×で示した。また、分散性において“−”の記号は
「測定せず」を示す。 ６．試験結果 前記のベトツキ感の確認、白化、刺激および分散性の４
項目の試験結果を第１表ないし第２表に記載し、同時に
前記の試験試料に用いた各パウダーの表面積（ｍ2 ／
ｇ）を示す。5. Dispersibility 50 ml of the test sample was put in a container for pressure-resistant glass injection (100 ml
(Manufactured by Nippon Kobunshi Co., Ltd.) and vigorously shaken by hand for about 10 times to first confirm whether or not the powder is dispersed in the liquid. Furthermore, after standing for about 1 minute, it was shaken again and whether or not the powder was dispersed in the liquid was observed. The thing which the powder disperse | distributed in the liquid even if it shakes twice is shown by (circle), and the thing which solidified at the bottom part, produced | generated the precipitate, or partially solidified was shown by x. The symbol "-" in dispersibility means "not measured". 6. Test results 4 of the above-mentioned confirmation of stickiness, whitening, irritation and dispersibility
The test results for the items are shown in Tables 1 and 2, and at the same time, the surface area (m 2 / m 2
g) is shown.
【００２２】[0022]
【表１】 [Table 1]
【００２３】[0023]
【表２】 [Table 2]
【００２４】第１〜２表の結果からも明らかなように、
比表面積５００ｍ2 ／ｇ以上の無水ケイ酸である化合物
Ａ〜Ｄ、Ｋ〜Ｏを用いたもののみが４項目すべてについ
て満足できる組成物であった。忌避試験As is clear from the results shown in Tables 1 and 2,
Only the compositions using silicic acid compounds A to D and K to O having a specific surface area of 500 m 2 / g or more were satisfactory compositions for all four items. Repellent test
【００２５】１．試験方法 マウスの背中（２×３ｃｍ2 ）に．本発明、比較例及び
対照の各試料を約１０ｃｍの距離から約０．５秒噴射し
た。本発明の試料は、ＤＥＥＴ５ｇ、１，３−ブチレン
グリコール１ｇ、化合物Ｃ２．５ｇ、エタノールで５０
ｍｌまでフィルアップして耐圧容器に入れてＬＰＧ５０
ｍｌで充填したものである。比較例は本発明の試料の
中、化合物Ｃを配合しなかったものであり、そして対照
は忌避剤のＤＥＥＴを用いなかったものである。そし
て、各々のヒトスジシマカメス成虫（羽化後２から７
日）を約２０頭いれた試験ケージ（２５ｃｍ×２５ｃｍ
×２５ｃｍ）の中に、試料処理マウス１頭を身動きがで
きないように荒い目（蚊の通過が可能）の金網製の容器
に入れ、入れてから１、３、５、７および１０分毎にヒ
トスジシマカの試料処理面への飛来率（％：飛来数／約
２０頭×１００）およびマウスを入れてから１０分後に
マウスを取りだし供試虫全部を潰して吸血しているヒト
スジスマカを数えて吸血成虫率（％：吸血数／約２０頭
×１００）を測定した。1. Test method On the back (2 × 3 cm 2 ) of the mouse. Each sample of the present invention, the comparative example and the control was jetted from a distance of about 10 cm for about 0.5 seconds. The sample of the present invention comprises 5 g of DEET, 1 g of 1,3-butylene glycol, 2.5 g of compound C and 50 g of ethanol.
Fill up to ml and put in a pressure resistant container LPG50
It is filled with ml. The comparative example is the sample of the present invention without compound C, and the control is without the repellent DEET. And each adult Aedes albopictus (2 to 7 after emergence)
A test cage (25 cm x 25 cm) containing about 20
X 25 cm), place one sample-treated mouse in a wire mesh container with rough eyes (mosquitoes can pass) so that it cannot move, and every 1, 3, 5, 7 and 10 minutes after putting it. Flying rate of the Aedes albopictus to the sample-treated surface (%: number of flying / approx. 20 heads x 100) and 10 minutes after inserting the mouse, the mouse was taken out and all the tested insects were crushed to count the sucked Aedes albopictus The rate (%: blood sucking number / about 20 horses × 100) was measured.
【００２６】また測定時間は、試料処理後４、６および
１０時間目に測定した。その間は前記と同様に金網製の
容器に入れたままで通常の飼育状態においた。さらに飼
育ゲージ中のヒトスジシマカは各測定時間の３０分〜１
時間前に試験ゲージに放し慣化した。表中の吸血率およ
び飛来率は２回の平均値を示す。 ２．測定結果 前記の忌避試験の結果を第３表に示した。表中において
横の欄の項目には、マウスを金網製容器に収容した際に
おける経時的吸血飛来率を示した。この表に示す結果か
らもわかるように本発明の人体用忌避組成物は、無水ケ
イ酸パウダーのない比較例の試料あるいは忌避剤を含有
しない対照に比して大きく効力持続時間を伸ばす事がで
きた。The measurement time was measured at 4, 6 and 10 hours after the sample treatment. In the meantime, as in the above, the animals were kept in a normal breeding state while being kept in a metal mesh container. Furthermore, for Aedes albopictus in the breeding gauge, 30 minutes to 1 of each measurement time
It was acclimated to the test gauge a few hours before. The blood-sucking rate and the flying rate in the table are average values of two times. 2. Results of measurement The results of the repellent test are shown in Table 3. In the horizontal column in the table, the time-dependent blood-sucking flight rate when the mouse was housed in a wire mesh container was shown. As can be seen from the results shown in this table, the repellent composition for human body of the present invention can greatly extend the duration of efficacy as compared with the sample of Comparative Example without the anhydrous silicic acid powder or the control containing no repellent. It was
【００２７】[0027]
【表３】 [Table 3]
【００２８】[0028]
【発明の効果】本発明により、忌避効力の持続性に優
れ、べとつき感がなく使用感が良くてかつ、組成物の塗
布面が白化しない人体用害虫忌避組成物および人体用害
虫忌避エアゾールの提供が可能になった。さらに、本発
明の人体用害虫忌避組成物および人体用害虫忌避エアゾ
ールは、刺激がないため人体に影響を与えることがな
く、また分散性がよいため、保存性がよく、長期にわた
って同じ性質をもつことができる。The present invention provides a pest repellent composition for human body and a pest repellent aerosol for human body which is excellent in persistence of repellent efficacy, has no sticky feeling, has a good feeling in use, and does not whiten the coated surface of the composition. Became possible. Furthermore, the human pest repellent composition and the human pest repellent aerosol of the present invention do not affect the human body due to no irritation and have good dispersibility, and thus have good storage stability and have the same properties over a long period of time. be able to.
Claims (4)
を含有する人体用害虫忌避剤において、該ケイ酸化合物
が比表面積が５００ｍ2 ／ｇ以上の無水ケイ酸であるこ
とを特徴とする人体用害虫忌避組成物。1. A human pest repellent containing a harmful insect repellent component, a silicic acid compound and a solvent, wherein the silicic acid compound is anhydrous silicic acid having a specific surface area of 500 m 2 / g or more. Pest repellent composition.
トルアミドであることを特徴とする請求項１記載の人体
用害虫忌避組成物。2. The pest repellent component is N, N-diethyl-m-
The pest repellent composition for human body according to claim 1, which is tolamide.
る請求項１又は請求項２記載の人体用害虫忌避組成物。3. The pest repellent composition for human body according to claim 1 or 2, wherein the solvent is ethanol.
ｇ以上の無水ケイ酸および溶媒を含有する人体用害虫忌
避組成物を噴射剤とともに配合したことを特徴とする人
体用害虫忌避エアゾール。4. A pest repellent component having a specific surface area of 500 m 2 /
A pest repellent aerosol for a human body, comprising a pest repellent composition for a human body containing g or more of anhydrous silicic acid and a solvent together with a propellant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21769594A JP3405833B2 (en) | 1993-09-13 | 1994-09-12 | Pest repellent composition for human body |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24969893 | 1993-09-13 | ||
| JP5-249698 | 1993-09-13 | ||
| JP21769594A JP3405833B2 (en) | 1993-09-13 | 1994-09-12 | Pest repellent composition for human body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07126104A true JPH07126104A (en) | 1995-05-16 |
| JP3405833B2 JP3405833B2 (en) | 2003-05-12 |
Family
ID=26522166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21769594A Expired - Fee Related JP3405833B2 (en) | 1993-09-13 | 1994-09-12 | Pest repellent composition for human body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3405833B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007022920A (en) * | 2005-07-12 | 2007-02-01 | Suzuki Yushi Kogyo Kk | Insect pest repellent composition |
| JP2008169248A (en) * | 2007-01-09 | 2008-07-24 | Earth Chem Corp Ltd | Aerosol composition |
| JP2008195707A (en) * | 2007-01-17 | 2008-08-28 | Earth Chem Corp Ltd | Vermin controlling agent and vermin controlling method |
| CN106420510A (en) * | 2016-12-06 | 2017-02-22 | 广州睿森生物科技有限公司 | Mosquito-repelling liquid and preparation method thereof |
| CN106473990A (en) * | 2016-12-06 | 2017-03-08 | 广州睿森生物科技有限公司 | A kind of mosquito-driving liquid and preparation method thereof |
-
1994
- 1994-09-12 JP JP21769594A patent/JP3405833B2/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007022920A (en) * | 2005-07-12 | 2007-02-01 | Suzuki Yushi Kogyo Kk | Insect pest repellent composition |
| JP2008169248A (en) * | 2007-01-09 | 2008-07-24 | Earth Chem Corp Ltd | Aerosol composition |
| JP2008195707A (en) * | 2007-01-17 | 2008-08-28 | Earth Chem Corp Ltd | Vermin controlling agent and vermin controlling method |
| CN106420510A (en) * | 2016-12-06 | 2017-02-22 | 广州睿森生物科技有限公司 | Mosquito-repelling liquid and preparation method thereof |
| CN106473990A (en) * | 2016-12-06 | 2017-03-08 | 广州睿森生物科技有限公司 | A kind of mosquito-driving liquid and preparation method thereof |
| CN106473990B (en) * | 2016-12-06 | 2019-04-12 | 广州睿森生物科技有限公司 | A kind of mosquito repellent liquid and preparation method thereof |
| CN106420510B (en) * | 2016-12-06 | 2019-04-12 | 广州睿森生物科技有限公司 | A kind of mosquito repellent liquid and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3405833B2 (en) | 2003-05-12 |
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