JPH07118558A - Reactive dye composition and dyeing therewith - Google Patents
Reactive dye composition and dyeing therewithInfo
- Publication number
- JPH07118558A JPH07118558A JP5288671A JP28867193A JPH07118558A JP H07118558 A JPH07118558 A JP H07118558A JP 5288671 A JP5288671 A JP 5288671A JP 28867193 A JP28867193 A JP 28867193A JP H07118558 A JPH07118558 A JP H07118558A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- salt
- dyeing
- composition
- represented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Coloring (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はヒドロキシル基及び／又
はアミド基を含有する材料、例えばセルロース繊維、天
然又は合成ポリアミド繊維、ポリウレタン繊維或いは皮
革等、更にはそれらの混合繊維を染色及び捺染するに適
し、とりわけセルロース繊維を耐光堅牢且つ汗耐光堅牢
な染色可能な優れた水溶性モノアゾ反応染料組成物並び
にそれを用いる染色法に関する。FIELD OF THE INVENTION The present invention is for dyeing and printing materials containing hydroxyl groups and / or amide groups, such as cellulose fibers, natural or synthetic polyamide fibers, polyurethane fibers or leather, as well as mixed fibers thereof. The present invention relates to an excellent water-soluble monoazo reactive dye composition which is suitable for dyeing cellulose fibers, which is fast and fast to light and sweat, and a dyeing method using the same.
【０００２】[0002]
【従来の技術】下記構造式2. Description of the Related Art The following structural formula
【０００３】[0003]
【化３】 [Chemical 3]
【０００４】で示される染料を用い、これを第２リン酸
ナトリウムの存在下に８０℃の水に溶解し、酢酸酸性と
した染浴で羊毛を染色する方法は知られている。（例え
ば特公昭３１−１６４３号公報参照のこと。）A method is known in which a dye represented by the formula (1) is dissolved in water at 80.degree. C. in the presence of dibasic sodium phosphate, and the wool is dyed in a dye bath acidified with acetic acid. (See, for example, Japanese Examined Patent Publication No. 31-1643.)
【０００５】[0005]
【発明が解決しようとする課題】この染料をセルロース
繊維に適用するには溶解性、均染性及びビルドアップ性
を改良する必要がある。本発明者等は、上述の問題点を
改良するよう研究を重ねた結果本発明に到達した。In order to apply this dye to cellulosic fibers, it is necessary to improve solubility, leveling property and build-up property. The present inventors arrived at the present invention as a result of repeated research to improve the above-mentioned problems.
【０００６】[0006]
【課題を解決するための手段】本発明は、遊離酸の形で
下記一般式（Ｉ）The present invention provides a compound of the following general formula (I) in the form of a free acid.
【０００７】[0007]
【化４】 [Chemical 4]
【０００８】で示される染料及び遊離酸の形で下記一般
式（II）The following general formula (II) in the form of a dye and a free acid represented by
【０００９】[0009]
【化５】 [Chemical 5]
【００１０】で示される染料を含有する反応染料組成物
及びこれを用いる繊維材料の染色または捺染法を要旨と
する。以下、本発明を詳細に説明する。The gist of the present invention is a reactive dye composition containing a dye represented by and a method for dyeing or printing a fiber material using the same. Hereinafter, the present invention will be described in detail.
【００１１】前記一般式（Ｉ）中、Ｘは−ＣＨ＝ＣＨ2
基または−ＣＨ2 ＣＨ2 Ｗ基を表わし、Ｗはアルカリの
作用により脱離する基を表わすが、−ＣＨ2 ＣＨ2 Ｗ基
はＷが脱離すると−ＣＨ＝ＣＨ2 基となる。Ｗで表わさ
れるアルカリの作用により脱離する基としては、通常、
硫酸エステル基、チオ硫酸エステル基、リン酸エステル
基、酢酸エステル基またはハロゲン原子などが挙げら
れ、特に硫酸エステルが好ましい。In the general formula (I), X is -CH = CH 2
Represents a group or -CH 2 CH 2 W groups, W is represents a group capable of leaving by the action of an alkali, -CH 2 CH 2 W group W is -CH = CH 2 group when leaving. The group that is eliminated by the action of an alkali represented by W is usually
Examples thereof include a sulfuric acid ester group, a thiosulfuric acid ester group, a phosphoric acid ester group, an acetic acid ester group and a halogen atom, and a sulfuric acid ester is particularly preferable.
【００１２】本発明の組成物における一般式（Ｉ）及び
（II）で示される反応染料は、それぞれ遊離酸の形また
はその塩の形で用いられ、特にアルカリ金属塩およびア
ルカリ土類金属塩、中でもナトリウム塩、カリウム塩、
リチウム塩が好ましい。液状の組成物を得るには特にリ
チウム塩が好ましい。The reactive dyes represented by the general formulas (I) and (II) in the composition of the present invention are used in the form of a free acid or a salt thereof, and in particular, an alkali metal salt and an alkaline earth metal salt, Among them, sodium salt, potassium salt,
Lithium salts are preferred. A lithium salt is particularly preferable for obtaining a liquid composition.
【００１３】本発明の染料組成物は、前記一般式（Ｉ）
および（II）で示される反応染料を混合することによっ
て得られるが、一般式（Ｉ）及び（II）で示される反応
染料の混合割合は、一般式（Ｉ）で示される反応染料１
重量部に対し、一般式（II）で示される染料０．１〜２
重量部、好ましくは０．２〜１．５重量部、更に好まし
くは０．３〜１．０重量部である。本発明においては、
前記一般式（Ｉ）および（II）で示される反応染料は、
それぞれの合成時において同時に合成することで混合さ
れていてもよく、又別々に合成した後、混合してもよ
い。更には、染色時に混合されても差支えない。The dye composition of the present invention has the general formula (I)
The reactive dyes represented by the general formulas (I) and (II) can be obtained by mixing the reactive dyes represented by the general formulas (I) and (II).
0.1 to 2 of the dye represented by the general formula (II) per part by weight.
Parts by weight, preferably 0.2 to 1.5 parts by weight, more preferably 0.3 to 1.0 parts by weight. In the present invention,
The reactive dyes represented by the general formulas (I) and (II) are
They may be mixed by simultaneously synthesizing each of them, or may be separately synthesized and then mixed. Furthermore, it does not matter if they are mixed at the time of dyeing.
【００１４】本発明の染料組成物は、木綿、ビスコース
レーヨン、キュプラアンモニウムレーヨン、麻等のセル
ロース系繊維、さらにポリアミド、羊毛、絹等の含窒素
繊維の染色に適するが、特にセルロース系繊維の染色に
優れた効果を発揮する。また、これらの繊維は、例え
ば、ポリエステル、セルローストリアセテート、ポリア
クリロニトリル等との混合繊維であっても差し支えな
い。The dye composition of the present invention is suitable for dyeing cellulosic fibers such as cotton, viscose rayon, cupra ammonium rayon and hemp, and also nitrogen-containing fibers such as polyamide, wool and silk. It has an excellent effect on dyeing. Further, these fibers may be mixed fibers with polyester, cellulose triacetate, polyacrylonitrile, etc., for example.
【００１５】本発明の染料組成物を用いてセルロース系
繊維を吸尽染色する際には、通常、重炭酸ソーダ、炭酸
ソーダ等の無機アルカリ、またはトリエチルアミン等の
有機塩基よりなる酸結合剤を用い、中性塩、例えば芒硝
又は食塩を加えて染色する。この際加える中性塩の量は
２０〜５０ｇ／リットルであり、又染色温度は５０〜６
０℃が好ましい。When exhaust dyeing a cellulosic fiber using the dye composition of the present invention, an acid binder comprising an inorganic alkali such as sodium bicarbonate and sodium carbonate or an organic base such as triethylamine is usually used. Dyeing is performed by adding a neutral salt such as Glauber's salt or salt. The amount of neutral salt added at this time is 20 to 50 g / liter, and the dyeing temperature is 50 to 6
0 ° C is preferred.
【００１６】合成及び天然のポリアミド及びポリウレタ
ン繊維の染色は、まず酸性ないし弱酸性の染浴からｐＨ
値の制御下に吸尽させ、次に固着させるため中性、場合
によりアルカリ性のｐＨ値に変化させることによって行
われる。染色は通常６０〜１２０℃の温度で行われる。
パジング法に従ってセルロース繊維を染色する場合、室
温又は高められた温度で染液をパッドし、乾燥後、スチ
ーミング又は乾熱によって固着する。The dyeing of synthetic and natural polyamide and polyurethane fibers is carried out by first applying a pH from an acidic to slightly acidic dyeing bath.
It is carried out by exhausting it under controlled value and then changing it to a neutral and possibly alkaline pH value for fixing. Dyeing is usually performed at a temperature of 60 to 120 ° C.
When dyeing cellulose fibers according to the padding method, the dyeing solution is padded at room temperature or at an elevated temperature, and after drying, fixed by steaming or dry heat.
【００１７】セルロース繊維に対して捺染を行う場合、
一相で、例えば重曹又はその他の酸結合剤を含有する捺
染ペーストを印捺し、次いで１００〜１６０℃でスチー
ミングすることによって、あるいは二相で、例えば中性
又は弱酸性捺染ペーストを印捺し、これを熱い電解質含
有アルカリ性浴に通過させ、又はアルカリ性電解質含有
パジング液をオーバーパジングし、スチーミング又は乾
熱処理して実施する。When performing printing on cellulose fibers,
In one phase, for example by printing a printing paste containing baking soda or other acid binder, then steaming at 100-160 ° C. or in two phases, for example printing a neutral or weakly acidic printing paste, This is carried out by passing it through a hot electrolyte-containing alkaline bath or over-padging with an alkaline electrolyte-containing padding solution and steaming or dry heat treatment.
【００１８】捺染ペーストには、糊剤として例えばアル
ギン酸ソーダ又は澱粉エーテル、その他乳化剤、必要に
応じて更に、例えば尿素のような通常の捺染助剤や分散
剤が用いられる。本発明の染料組成物は前記した通り、
特にセルロース繊維材料の染色に好適である。特に良好
な耐光性と耐汗日光性を具えた染色物を提供することが
できる。In the printing paste, as a sizing agent, for example, sodium alginate or starch ether, other emulsifiers, and if necessary, a usual printing aid or dispersant such as urea is used. The dye composition of the present invention, as described above,
It is particularly suitable for dyeing cellulose fiber materials. It is possible to provide a dyed product having particularly good light resistance and sweat and sun resistance.
【００１９】[0019]
【実施例】以下実施例により本発明を具体的に説明す
る。 実施例１ 下記構造式（Ａ）The present invention will be described in detail with reference to the following examples. Example 1 The following structural formula (A)
【００２０】[0020]
【化６】 [Chemical 6]
【００２１】で示されるモノアゾ反応染料１００ｇと下
記構造式（Ｂ）100 g of a monoazo reactive dye represented by the following structural formula (B)
【００２２】[0022]
【化７】 [Chemical 7]
【００２３】で示されるモノアゾ反応染料８０ｇを配合
して染料組成物を得た。この組成物０．１ｇ、０．２
ｇ、０．４ｇを各々水２００ｍｌに溶解し、芒硝１０ｇ
を加えて染液を調製した。未シルケット処理綿布１０ｇ
を浸漬し、３０分かけて６０℃まで昇温した。次いで炭
酸ソーダ４ｇを添加し、６０℃で１時間染色した。次い
で水洗、ソーピング、水洗そして乾燥を行ない良好なビ
ルドアップ性を有する均染性の良好な赤色の染色物を得
た。A dye composition was obtained by mixing 80 g of the monoazo reactive dye represented by: 0.1 g of this composition, 0.2
g and 0.4 g are each dissolved in 200 ml of water, and 10 g of Glauber's salt
Was added to prepare a dye liquor. Un-mercerized cotton cloth 10g
Was immersed and the temperature was raised to 60 ° C. over 30 minutes. Next, 4 g of sodium carbonate was added and dyeing was carried out at 60 ° C. for 1 hour. Next, washing with water, soaping, washing with water and drying were carried out to obtain a red dyed product having good build-up properties and good levelness.
【００２４】尚、組成物０．２ｇを用いて染色した染布
の耐光堅牢度は５級、汗耐光堅牢度は４−５級と優れて
いた。尚、耐光堅牢度はＪＩＳ Ｌ−０８４２により、
また汗耐光堅牢度はＪＩＳＬ−０８８８Ａ法アルカリの
方法に依り評価した。The dyed fabric dyed with 0.2 g of the composition was excellent in light fastness of grade 5 and sweat light fastness of grade 4-5. The light fastness is according to JIS L-0842.
The sweat light fastness was evaluated by the JISL-0888A method alkali method.
【００２５】実施例２ 実施例１において用いた構造式（Ａ）で示される反応染
料１００ｇと実施例１において用いた構造式（Ｂ）で示
される反応染料３０ｇとを配合して染料組成物を得て、
これを０．１ｇ、０．２ｇ、０．４ｇを用いて実施例１
の記載に準じて染色した。その結果良好な均染性とビル
ドアップ性を有する染色物が得られた。Example 2 A dye composition was prepared by mixing 100 g of the reactive dye represented by the structural formula (A) used in Example 1 and 30 g of the reactive dye represented by the structural formula (B) used in Example 1. Get,
Example 1 using 0.1g, 0.2g, 0.4g of this
Staining was carried out according to the description. As a result, a dyed product having good levelness and build-up was obtained.
【００２６】実施例３ 実施例１において用いた構造式（Ａ）で示される反応染
料１００ｇと実施例１において用いた構造式（Ｂ）で示
される反応染料７０ｇとを配合して染料組成物を得て、
これを０．１ｇ、０．２ｇ、０．４ｇを用いて実施例１
の記載に準じて染色した。その結果良好な均染性とビル
ドアップ性を有する染色物が得られる。Example 3 100 g of the reactive dye represented by the structural formula (A) used in Example 1 and 70 g of the reactive dye represented by the structural formula (B) used in Example 1 were blended to form a dye composition. Get,
Example 1 using 0.1g, 0.2g, 0.4g of this
Staining was carried out according to the description. As a result, a dyed product having good levelness and build-up can be obtained.
【００２７】比較例１ 実施例１において用いた構造式（Ａ）で示される反応染
料を０．１ｇ、０．２ｇ、０．４ｇを用い実施例１の記
載に準じて染色したその結果、実施例１に比べビルドア
ップ性が著しく劣り、均染性も劣っていた。Comparative Example 1 The reactive dye represented by the structural formula (A) used in Example 1 was dyed in an amount of 0.1 g, 0.2 g and 0.4 g according to the description of Example 1, and the result was obtained. The build-up property was remarkably inferior to that of Example 1, and the level dyeing property was also inferior.
【００２８】比較例２ 実施例１において用いた構造式（Ｂ）で示される反応染
料を０．１ｇ、０．２ｇ、０．４ｇを用い実施例１の記
載に準じて染色したその結果、均染性は良好であるがビ
ルドアップ性が著しく劣っていた。 実施例４Comparative Example 2 The reactive dye represented by the structural formula (B) used in Example 1 was dyed in accordance with the description of Example 1 using 0.1 g, 0.2 g and 0.4 g. The dyeability was good, but the build-up property was extremely poor. Example 4
【００２９】[0029]
【化８】 [Chemical 8]
【００３０】で示されるモノアゾ反応染料１００ｇと下
記構造式100 g of a monoazo reactive dye represented by the following structural formula
【００３１】[0031]
【化９】 [Chemical 9]
【００３２】で示されるモノアゾ反応染料２００ｇを配
合して染料組成物を得た。この組成物０．１ｇ、０．２
ｇ、０．４ｇを用いて実施例１に準じて染色を実施し、
比較的良好なビルドアップ性を有する均染性の良好な赤
色の染色物を得た。 実施例５A dye composition was obtained by mixing 200 g of the monoazo reactive dye represented by: 0.1 g of this composition, 0.2
dyeing was carried out according to Example 1 using g and 0.4 g,
A red dyed product having relatively good build-up properties and good levelness was obtained. Example 5
【００３３】[0033]
【化１０】 [Chemical 10]
【００３４】で示されるモノアゾ反応染料１００ｇと下
記構造式100 g of monoazo reactive dye represented by the following structural formula
【００３５】[0035]
【化１１】 [Chemical 11]
【００３６】で示されるモノアゾ反応染料１００ｇを配
合して染料組成物を得た。この組成物０．１ｇ、０．２
ｇ、０．４ｇを用いて実施例１に準じて染色を実施し良
好なビルドアップ性を有する均染性の良好な赤色の染色
物を得た。A dye composition was obtained by mixing 100 g of the monoazo reactive dye represented by: 0.1 g of this composition, 0.2
g and 0.4 g were dyed according to Example 1 to obtain a red dyed product having good build-up properties and good levelness.
【００３７】[0037]
【発明の効果】本発明の染料組成物によれば、特にセル
ロース繊維に諸堅牢度の優れた染色を施すことができ
る。特に、耐光堅牢度、耐汗日光性に優れた染色が可能
である。又、本発明の染色組成物は溶解性に富み、均染
性、ビルドアップ性にも優れている。Industrial Applicability According to the dye composition of the present invention, it is possible to dye cellulose fibers, in particular, with excellent fastness. In particular, dyeing with excellent light fastness and sweat / sunlight resistance is possible. Further, the dyeing composition of the present invention has high solubility, and is excellent in level dyeing property and build-up property.
Claims (3)
染料の組成割合が前記一般式（Ｉ）で示される染料１重
量部に対し一般式（II）で示される染料０．１〜２重量
部である請求項（Ｉ）記載の反応染料組成物。2. The composition ratio of the dye represented by the general formula (I) or (II) is 0.1 part by weight of the dye represented by the general formula (II) to 1 part by weight of the dye represented by the general formula (I). The reactive dye composition according to claim 1, wherein the reactive dye composition is about 2 parts by weight.
用いることを特徴とする繊維材料の染色又は捺染法。3. A method for dyeing or printing a fiber material, which comprises using the reactive dye composition according to claim 1 or 2.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28867193A JP3260522B2 (en) | 1993-10-25 | 1993-10-25 | Reactive dye composition and dyeing method |
| TW83106376A TW418239B (en) | 1993-08-02 | 1994-07-13 | Red reactive dyes, their composition and dyeing method empolying them |
| DE69418264T DE69418264T2 (en) | 1993-08-02 | 1994-07-29 | Red reactive dyes, their mixtures and the dyeing method using them |
| EP94111903A EP0637615B1 (en) | 1993-08-02 | 1994-07-29 | Red reactive dyes, their compositions and dyeing method employing them |
| ES94111903T ES2134884T3 (en) | 1993-08-02 | 1994-07-29 | RED REACTIVE DYES, THEIR COMPOSITIONS AND DYING PROCEDURE USING THEM. |
| KR1019940019129A KR100320639B1 (en) | 1993-08-02 | 1994-08-02 | Red reactive dyes, compositions thereof and staining methods using the same |
| US08/400,934 US5545236A (en) | 1993-08-02 | 1995-03-09 | Red reactive dyes, their compositions and dyeing method employing them |
| US08/639,332 US5756690A (en) | 1919-08-23 | 1996-04-25 | Red reactive dyes, their compositions and dyeing method employing them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28867193A JP3260522B2 (en) | 1993-10-25 | 1993-10-25 | Reactive dye composition and dyeing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07118558A true JPH07118558A (en) | 1995-05-09 |
| JP3260522B2 JP3260522B2 (en) | 2002-02-25 |
Family
ID=17733179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28867193A Expired - Fee Related JP3260522B2 (en) | 1919-08-23 | 1993-10-25 | Reactive dye composition and dyeing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3260522B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425760C (en) * | 2006-07-13 | 2008-10-15 | 吴江德伊时装面料有限公司 | Dyeing method of copper ammonia fiber cloth |
-
1993
- 1993-10-25 JP JP28867193A patent/JP3260522B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425760C (en) * | 2006-07-13 | 2008-10-15 | 吴江德伊时装面料有限公司 | Dyeing method of copper ammonia fiber cloth |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3260522B2 (en) | 2002-02-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR950009540B1 (en) | Fiber reactive red dye composition | |
| KR960002227B1 (en) | Dioxazine compound, the process for producing it and the process | |
| JPH07118558A (en) | Reactive dye composition and dyeing therewith | |
| JPH0619046B2 (en) | Disazo compound and dye composition containing the same | |
| JPH07118557A (en) | Reactive dy e composition and dyeing therewith | |
| JPH0655905B2 (en) | Disazo compound and dye composition containing the same | |
| JPH0662873B2 (en) | Triazine compounds | |
| JP3293969B2 (en) | Water-soluble monoazo dye composition and dyeing method using the same | |
| JP2982300B2 (en) | Reactive dye composition and method for dyeing or printing fiber material using the same | |
| JP2548945B2 (en) | Reactive dye composition and dyeing method | |
| JPS63101458A (en) | Water-soluble monoazo compound and method of dyeing and printing fibrous material by using the same | |
| JPH0635556B2 (en) | Formazan compounds | |
| JPH0619043B2 (en) | Disazo compound and dyeing method using the same | |
| JP2881917B2 (en) | Reactive dye composition and method for dyeing or printing fiber material using the same | |
| JP2949834B2 (en) | Reactive dye composition and method for dyeing or printing fiber material using the same | |
| JP2881916B2 (en) | Reactive dye composition and method for dyeing or printing fiber material using the same | |
| JPH0751676B2 (en) | Water-soluble formazan dye | |
| JP3221792B2 (en) | Dyeing method for textile materials | |
| JPH059396A (en) | Reactive dye composition and dyeing or printing method for textile material or leather using the same | |
| JPH07207180A (en) | Dye composition and dyeing method using the same | |
| JP2001348503A (en) | Reactive dye composition and method for dyeing or printing textile using the same | |
| JPH04314762A (en) | Reactive dye composition and dyeing or printing of fibrous material therewith | |
| JPH01289867A (en) | Water-soluble dioxazine coloring matter | |
| JPS63168465A (en) | Water-soluble formazan dye and dyeing method using the same | |
| JPH04261471A (en) | Reactive dye composition and method for dyeing or printing textile material using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |