JPH066936Y2 - Color-sensitive picture book - Google Patents
Color-sensitive picture bookInfo
- Publication number
- JPH066936Y2 JPH066936Y2 JP1987195119U JP19511987U JPH066936Y2 JP H066936 Y2 JPH066936 Y2 JP H066936Y2 JP 1987195119 U JP1987195119 U JP 1987195119U JP 19511987 U JP19511987 U JP 19511987U JP H066936 Y2 JPH066936 Y2 JP H066936Y2
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- Prior art keywords
- temperature
- color
- quasi
- range
- reversible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Description
【考案の詳細な説明】 産業上の利用分野 本考案は感温変色性絵本に関する。更に詳細には非変色
像に熱変色性図柄を重ね刷りしてなり、熱又は冷熱の適
用により前記熱変色性図柄と非変色像を互変的に常温域
で記憶保持させて視覚させる二面性を備えた感温変色性
絵本に関する。TECHNICAL FIELD The present invention relates to a thermosensitive color-changing picture book. More specifically, a thermochromic pattern is overprinted on the non-color-changing image, and the two sides are made to alternately retain and visualize the thermochromic pattern and the non-color-changing image at room temperature by applying heat or cold heat. The present invention relates to a thermosensitive color change picture book having a property.
従来の技術 従来、広く一般に出回っている絵本は、図柄の色彩、模
様等は不変であるが、近時幼児向けの風呂本として、湯
温で図柄が可逆的に変色するタイプの絵本がみられる。Conventional technology Conventionally, the picture books that are widely available in general do not change the color and pattern of the design, but recently, as a bath book for infants, there is a type of picture book in which the design changes color reversibly with hot water temperature. .
前記風呂絵本は、所定の温度を境としてその前後で表面
の色が異なるよう彩色されたものであって、変化前後の
両状態のうち常温域では特定の一方の状態しか存在しえ
ない。即ち、もう一方の状態は、その状態が発現するの
に要する熱または冷熱が適用されている間は維持される
が、前記熱または冷熱の適用がなくなれば常温域で呈す
る状態に戻ってしまうタイプのものである。The bath picture book is colored such that the surface color is different before and after a predetermined temperature as a boundary, and only one specific state can exist in the normal temperature region of both states before and after the change. That is, the other state is maintained while the heat or cold heat required to develop that state is applied, but returns to the state exhibited at room temperature when the heat or cold heat is no longer applied. belongs to.
考案が解決しようとする問題点 本考案は熱又は冷熱の適用により熱変色性図柄層を変色
させて、下層の非変色ぞを隠顕させるだけでなく、熱変
色性図柄と非変色像のいずれかを自由に選択して常温域
でその様相を維持させることができる二面性を備え、変
化の妙味に加えて多様な様相の図柄が楽しめる絵本を提
供しようとするものである。The problem to be solved by the invention The present invention not only causes the thermochromic pattern layer to be discolored by application of heat or cold heat to hide the non-color-changing grooves of the lower layer, but also the thermochromic pattern and the non-color-changing image. It aims to provide a picture book that has the duality of being able to freely select and maintain that aspect at room temperature, and in addition to the subtleties of change, you can enjoy various aspects of the design.
問題点を解決するための手段 本考案の感温変色性絵本は、支持体表面に形成した非変
色像に着色時の視覚濃度が前記非変色像より濃い熱変色
性図柄が重ね刷りされてなり、熱又は冷熱の適用により
前記非変色像と熱変色性図柄を互変的に常温域で記憶保
持されて視覚させる二面性を備えた絵本であって、前記
熱変色性図柄は温度−色濃度の関係において大きなヒス
テリシス特性を呈して変色する準可逆感温色素を含む色
材で彩色されてなり、前記準可逆感温色素は該感温色素
が第1色相状態にあって温度が上昇する過程では、第2
の温度t3に達すると第1色相は変色し始め、第2の温
度t3より高い温度t4以上の温度域で完全に第2色相
となり、前記感温色素が第2色相状態にあって温度が下
降する過程では、前記第2の温度t3より低い第1の温
度t2に達すると、第2色相は変色し始め、第1の温度
t2より低い温度t1以下の温度域で完全に第1色相と
なり、前記第1の温度t2と第2の温度t3の温度の間
の温度域内で第1色相と第2色相の両相が共存可能であ
るヒステリシス特性を示す感温色素であり、ここで前記
温度t1は0℃乃至15℃の間の温度であり、温度t4
は27℃乃至90℃の間の温度であり、第1の温度t2
と第2の温度t3の間の温度域は10℃乃至35℃の範
囲内の温度域であり、着色時の視覚濃度が非変色像のそ
れを越える準可逆感温色素が選択されてなることを要件
とする。Means for Solving Problems The thermosensitive color-changing picture book of the present invention comprises a non-color-changing image formed on the surface of a support, and a thermochromic pattern whose visual density when coloring is darker than that of the non-color-changing image is overprinted. A picture book having a two-sided property that allows the non-color-changing image and the thermo-color-changing pattern to be alternately retained and stored in the normal temperature range by application of heat or cold heat, and the thermo-color-changing pattern is temperature-color. Colored with a coloring material containing a quasi-reversible temperature-sensitive dye that exhibits a large hysteresis characteristic in terms of density and changes color, and the temperature of the quasi-reversible temperature-sensitive dye rises when the temperature-sensitive dye is in the first hue state. In the process, the second
Upon reaching the temperature t 3 the first color begins to discolor, become completely second color at a second higher temperature t 4 above temperature range than the temperature t 3, the temperature sensitive dye is in the second color state In the process of lowering the temperature, when the first temperature t 2 lower than the second temperature t 3 is reached, the second hue starts to change color, and in the temperature range lower than the temperature t 1 lower than the first temperature t 2. A temperature-sensing temperature that exhibits a hysteresis characteristic such that the hue becomes completely the first hue and both the first hue and the second hue can coexist within a temperature range between the first temperature t 2 and the second temperature t 3. A dye, wherein the temperature t 1 is a temperature between 0 ° C. and 15 ° C., and the temperature t 4
Is a temperature between 27 ° C. and 90 ° C., the first temperature t 2
The temperature range between the second temperature t 3 and the second temperature t 3 is within the range of 10 ° C. to 35 ° C., and a quasi-reversible temperature-sensitive dye whose visual density during coloring exceeds that of a non-color-change image is selected. It is a requirement.
前記準可逆感温色素を含む色材として、本出願人が先に
提案(特開昭60−264285号公報)した可逆感熱
記録組成物が好適に適用できる。As the coloring material containing the quasi-reversible temperature-sensitive dye, the reversible thermosensitive recording composition previously proposed by the present applicant (JP-A-60-264285) can be preferably applied.
前記準可逆感温色素は、温度変化により温度−色濃度に
ついてヒステリシス特性を示して変色する、すなわち変
色温度域より低温側から温度を上昇させていく場合と逆
に変色温度域より高温側から温度を下降させていく場合
とでは異なる経路をたどって変色する現像を呈するもの
である。The quasi-reversible temperature-sensitive dye exhibits a hysteresis characteristic with respect to temperature-color density due to temperature change and changes color, that is, the temperature is increased from a temperature side higher than the color change temperature range, contrary to the case where the temperature is increased from a temperature lower side than the color change temperature range. The development is such that the color changes by following a different path from the case where the color is lowered.
このことを図面について説明する 第3図は準可逆感温色素を含む色材の温度変化による色
濃度の変化を示したグラフであり、縦軸に色濃度、横軸
に温度が表されている。This will be described with reference to the drawings. FIG. 3 is a graph showing a change in color density due to a temperature change in a color material containing a quasi-reversible thermosensitive dye, in which the vertical axis represents color density and the horizontal axis represents temperature. .
温度変化による色濃度の変化は矢印に沿って進行する。
グラフ中のA点(温度t1)はこれ以下の温度では前記
色材が完全に呈色している状態になる点であり、B点
(温度t3)は温度が上昇する過程で実質的な変色(消
色)が始まる点であり、C点(温度t4)はこれ以上の
温度では完全に消色している状態になる点であり、変色
温度域とは前記t1とt4の間の温度域であり、特に着
色状態と無色状態の両相又は有色〔I〕と有色〔II〕の
両相が共存でき、色濃度の差の大きい領域であるt2と
t3の間の温度域を実質変色温度域(2色保持温度域)
と表記する。The change in color density due to the temperature change progresses along the arrow.
The point A (temperature t 1 ) in the graph is the point where the color material is completely colored at a temperature below this point, and the point B (temperature t 3 ) is the point when the temperature rises substantially. The color change (decoloration) starts, the point C (temperature t 4 ) is a point where the color is completely decolored at a temperature higher than this, and the color change temperature range is the above t 1 and t 4. Between t 2 and t 3 , which is a temperature range between the two, in which both the colored and colorless phases or both the colored [I] and colored [II] phases can coexist and the difference in color density is large. Temperature range is the actual color change temperature range (2-color holding temperature range)
It is written as.
前記において、t1は氷や水から得られる温度、即ち0
℃乃至15℃程度の温度であり、t4は体温、風呂の湯
温又はヘアドライヤー等身近なものから得られる温度、
即ち凡そ27℃乃至90℃の温度を示すものであり、実
質変色温度域が数℃乃至三十数℃、より好ましは10℃
乃至35℃の範囲内の温度にあるものが好適に選択され
る。In the above, t 1 is the temperature obtained from ice or water, that is, 0
Is a temperature of about 15 ° C to 15 ° C, and t 4 is a body temperature, a bath water temperature, or a temperature obtained from familiar things such as a hair dryer,
That is, it shows a temperature of about 27 ° C. to 90 ° C., and a substantial discoloration temperature range is several ° C. to thirty-several ° C., more preferably 10 ° C.
Those having a temperature within the range of 35 to 35 ° C. are preferably selected.
準可逆感温色素について、色の異なるもの、前記2色保
持温度域が共に常温域であるが互いに異なるもの、前記
の特殊な例として一方の準可逆感温色素の2色保持域が
他方の準可逆感温色素のそれより且つそれを包含してい
る関係にある組合せ等、異種の組合せが同一表面部分に
適用されたり、異なる表面部分にそれぞれ適用されるこ
とにより多種多様の様相の様相間の互変的を備えた絵本
を構成することができる。Regarding the quasi-reversible thermosensitive dyes, those having different colors, those in which the two color holding temperature regions are both normal temperature regions but different from each other, and as a special example of the above, one quasi-reversible temperature dye has two color holding regions in the other Different types of combinations, such as a combination of quasi-reversible temperature-sensitive dyes and a relationship that includes them, are applied to the same surface portion or to different surface portions, so that a variety of appearances It is possible to compose a picture book with the alternation of.
準可逆感温色素は、適宜のビヒクル中に分散されて印刷
インキの形態の色材として用いられ、支持体2の表面に
熱変色性図柄層31を形成して絵本1を構成する。The quasi-reversible temperature-sensitive dye is dispersed in an appropriate vehicle and used as a coloring material in the form of printing ink, and the thermochromic pattern layer 31 is formed on the surface of the support 2 to form the picture book 1.
支持体2は、従来より汎用の紙質、プラスチックシー
ト、合成紙、その他印刷適正を備えた材料であればよ
い。The support 2 may be made of any conventional paper material, plastic sheet, synthetic paper, or any other material that is suitable for printing.
作用 前記熱変色性図柄層31が無色の状態(下地の非変色像
が現れている様相)にある絵本は該表面を一旦前記t1
温度以下に冷却して着色状態にし、常温に戻せば、前記
着色状態の熱変色性図柄は非変色像を隠蔽して常温域で
保持される。Action The picture book in which the thermochromic pattern layer 31 is in a colorless state (a state in which the non-color-changing image of the base appears) has the surface once t 1
When cooled to a temperature or lower to be in a colored state and returned to room temperature, the thermochromic pattern in the colored state conceals the non-color-changing image and is retained in the room temperature range.
また、着色状態にある前記表面部分を一旦前記t4程度
以上に加温して無色状態にしてから常温域に戻せば前記
無色状態の様相は常温域で保持され非変色像を視覚させ
る。Further, if the surface portion in the colored state is once heated to about t 4 or more to be in the colorless state and then returned to the normal temperature range, the appearance in the colorless state is maintained in the normal temperature range and the non-color-change image is visualized.
このように本考案の絵本1は、2種の様相、即ち着色状
態の熱変色性図柄と非変色像から、使用者が所望に応じ
て一つの様相を選択して、それを保持できる機能を発揮
する。この場合、前記熱変色性図柄層31の一部だけに
熱又は冷熱を適用すれば、その部分のみが変化した様相
となる。また、図柄3の部分毎に異種の準可逆感温色素
による熱変色性図柄層31が配設されていると、各部分
が変化する毎に全体の模様または構図が変わるという機
能も示される。In this way, the picture book 1 of the present invention has a function of allowing the user to select one aspect from two types of aspects, that is, the thermochromic pattern in the colored state and the non-discolored image, and hold it. Demonstrate. In this case, if heat or cold is applied to only a part of the thermochromic pattern layer 31, only that part will be changed. Further, when the thermochromic pattern layer 31 made of different types of quasi-reversible temperature-sensitive dyes is provided for each part of the pattern 3, a function of changing the whole pattern or composition every time each part changes is also shown.
前記機能の応用としては、人物像を描いた絵本では、素
顔の様相と化粧した顔、普通の化粧をした顔と濃厚な化
粧をした顔の各2相間の変化、馬と縞馬、白熊とパンダ
等の各両相間の互変性を呈しそれぞれの様相が常温域で
保持されるものである。As an application of the above function, in a picture book depicting a human figure, the appearance of a bare face and a face with makeup, a change between two phases of a face with normal makeup and a face with heavy makeup, horse and stripe horse, white bear and panda And the like, which exhibit tautomerism between the two phases, and each aspect is maintained in the normal temperature range.
実施例 実施例1(第1図、第2図参照) 紙面の左半部に桃の輪郭、該輪郭内に桃太郎(淡肌
色)、桃を切ろうとする包丁、文章を非変色性インキに
より印刷すると共に、前記桃太郎を隠蔽する桃を温度変
化により、淡紅色←→無色(A点8℃、C点32℃)に
変化する準可逆感温色素を含むインキで印刷した。右半
部には、左半部と関連する絵物語が非変色性インキによ
り印刷されてなる。Example Example 1 (see FIGS. 1 and 2) A peach outline on the left half of the paper, Momotaro (light skin color) within the outline, a knife for cutting peach, and a sentence printed with a non-color-changing ink At the same time, the peach hiding Momotaro was printed with an ink containing a quasi-reversible thermosensitive dye that changes from light pink to colorless (A point 8 ° C., C point 32 ° C.) due to temperature change. In the right half, the story of the story related to the left half is printed with non-discoloring ink.
前記に準じて印刷した他の内容の絵柄シートを綴じて絵
本を構成した。紙質の替わりに白色の塩化ビニルシート
の表面に前記同様の図柄を印刷して製本化することによ
り同様に絵本を構成した。A picture book was constructed by binding picture sheets of other contents printed according to the above. A picture book was constructed in the same manner by printing a pattern similar to the above on the surface of a white vinyl chloride sheet instead of the paper quality and binding it.
前記図柄は、常温では桃太郎は淡紅色に着色した桃によ
り隠蔽されており、32℃以上の加熱(手触、呼気の吹
きつけ、擦過、ヘアドライヤー、湯温を毛筆等に含ませ
て筆記)により、淡紅色が消色し、淡肌色の桃太郎が視
覚された。At room temperature, Momotaro is concealed by peach colored in pink, and the pattern is heated to 32 ° C or higher (handwriting, exhalation of air, rubbing, hair dryer, hot water temperature included in a writing brush etc.) Caused the pale red color to disappear and a pale skin-colored Momotaro was visualized.
前記の様相は常温で安定に保持された。次に8℃以下に
全体を冷やしたところ、再び桃は、淡紅色に着色して、
桃太郎を隠蔽した状態となり、常温域でこの様相に維持
される。The aspect described above was kept stable at room temperature. Next, when the whole was cooled to 8 ° C or lower, the peach was colored pink again,
It becomes a state where Momotaro is hidden, and this aspect is maintained at room temperature.
この操作の繰り返し毎に桃太郎が隠蔽状態と現出状態の
互変性を示し、何回も繰り返して遊ぶことができた。Every time this operation was repeated, Momotaro showed an alternation between the hidden state and the exposed state, and he could play it many times.
実施例2 顔面が通常の化粧をした様相、即ち唇が淡いピンク色、
頬が淡い朱色、瞼が淡い紫色に着色されている人形の絵
について、温度変化により青色←→無色(A点10℃、
C点32℃)、紫色←→無色(A点10℃、C点32
℃)、及びピンク色←→無色(A点10℃、C点32
℃)にそれぞれ変化する準可逆感温色素をそれぞれ含む
インキを用いて、それぞれ前記唇、頬及び瞼に重ね刷
り、乾燥して顔面が二面性を示す色彩の人形の絵を得
た。(支持体は実施例1と同様であり、同様にして製本
化した。) 前記絵本の顔面を手で温めて普通の化粧をした顔の様相
にした後、約25℃に室温下、約10℃の冷水で冷やし
たところ唇が青色、頬が紫色、瞼がピンク色にそれぞれ
変化してサイケデリックな様相を呈し、この様相は14
℃乃至29℃の温度域で安定に保持された。Example 2 A face has a normal makeup appearance, that is, the lips have a pale pink color,
About the picture of the doll whose cheeks are pale vermilion and whose eyelids are pale purple, blue ← → colorless due to temperature change (point A 10 ℃,
C point 32 ° C), purple ← → colorless (A point 10 ° C, C point 32)
℃) and pink ← → colorless (A point 10 ℃, C point 32)
Each of the inks containing a quasi-reversible temperature-sensitive dye that changes in temperature (.degree. C.) was overprinted on the lips, cheeks, and eyelids, respectively, and dried to obtain a picture of a doll with a two-faced face. (The support was the same as in Example 1 and was bound in the same manner.) After warming the face of the picture book by hand to make it look like a face with normal makeup, it was heated to about 25 ° C. at room temperature for about 10 minutes. When cooled with cold water at ℃, the lips changed to blue, the cheeks changed to purple, and the eyelids changed to pink, giving a psychedelic appearance.
It was kept stable in the temperature range of ℃ to 29 ℃.
次に再度顔面を手で温めたところ、サイケデリックな化
粧の様相が消え、普通の化粧をした顔の様相に変化し
た。この操作の繰り返し毎にサイケデリック化粧相と普
通の化粧相の互変性を示し、何回も繰り返して遊ぶこと
ができた。また、唇、頬又は瞼の何れかの部分だけにつ
いても前記の変化をさせることができた。Next, when I warmed my face again with my hands, the appearance of psychedelic makeup disappeared and the appearance of ordinary makeup changed. Each time this operation was repeated, the psychedelic makeup phase and the ordinary makeup phase showed alternation, and they could be played many times. Further, it was possible to make the above change only on any part of the lips, cheeks or eyelids.
考案の効果 本考案絵本は、日常の生活範囲の熱源または冷熱源で熱
変色性図柄を変色させて、非変色像を現出させて楽しむ
ことができると同時に、常温域で着色状態の熱変色性図
柄と非変色像をユーザーが自由に選択して保持でき、変
化の妙味に加えて、一つの絵本で多様な様相を楽しむこ
とができ、物語絵本、学習絵本、ガイドブック、カタロ
グ、ゲーム絵本、囲碁、将棋、ゴルフ、テニス等の趣
味、スポーツの指導、教習絵本、漫画、内部構成の説明
絵本、マップその他レジャー関連の各種絵本等として付
加価値の高い絵本を提供できる。The effect of the invention The picture book of the invention can be enjoyed by changing the color of the thermochromic pattern with a heat source or a cold heat source in the range of everyday life to reveal a non-color-changing image, and at the same time, it can be colored in the normal temperature range. Users can freely select and hold sex patterns and non-color-change images, and in addition to the wonderfulness of change, you can enjoy various aspects with one picture book, story picture book, learning picture book, guide book, catalog, game picture book , High-value-added picture books such as hobbies such as Go, shogi, golf, tennis, instruction of sports, picture books for learning, cartoons, picture books explaining the internal structure, maps, and various other picture books related to leisure can be provided.
第1図は本考案絵本の一実施例の状態図、第2図は前記
の一部を省略した変色後の状態図、第3図は本考案に用
いられる準可逆感温色素を含む色材の温度変化による変
色状態を示すグラフである。 1……感温変色性絵本、2……支持体 3……図柄、31……熱変色性図柄層 32……非変色像FIG. 1 is a state diagram of an embodiment of a picture book of the present invention, FIG. 2 is a state diagram after discoloration with some of the above parts omitted, and FIG. 3 is a coloring material containing a quasi-reversible thermosensitive dye used in the present invention. 5 is a graph showing a discolored state due to a temperature change of FIG. 1 ... Thermosensitive color-changing picture book, 2 ... Support 3 ... Design, 31 ... Thermo-color-changing pattern layer 32 ... Non-color-changing image
Claims (1)
の視覚濃度が前記非変色像より濃い熱変色性図柄が重ね
刷りされてなり、熱又は冷熱の適用により前記非変色像
と熱変色性図柄を互変的に常温域で記憶保持させて視覚
させる二面性を備えた絵本であって、前記熱変色性図柄
は温度−色濃度の関係において大きなヒステリシス特性
を呈して変色する準可逆感温色素を含む色材で彩色され
てなり、前記準可逆感温色素は該感温色素が第1色相状
態にあって温度が上昇する過程では、第2の温度t3に
達すると、第1色相は変色し始め、第2の温度t3より
高い温度t4以上の温度域で完全に第2色相となり、前
記感温色素が第2色相状態にあって温度が下降する過程
では、前記第2の温度t3より低い第1の温度t2に達
すると、第2色相は変色し始め、第1の温度t2より低
い温度t1以下の温度域で完全に第1色相となり、前記
第1の温度t2と第2の温度t3の温度の間の温度域内
で第1色相と第2色相の両相が共存可能であるヒステリ
シス特性を示す感温色素であり、ここで前記温度t1は
0℃乃至15℃の間の温度であり、温度t4は27℃乃
至90℃の間の温度であり、第1の温度t2と第2の温
度t3の間の温度域は10℃乃至35℃の範囲内の温度
域であり、着色時の視覚濃度が非変色像のそれを越える
準可逆感温色素が選択されてなることを特徴とする感温
変色性絵本。1. A non-color-changing image formed on a surface of a support is overprinted with a thermochromic pattern whose visual density at the time of coloring is higher than that of the non-color-changing image, and by applying heat or cold heat to the non-color-changing image. It is a picture book having a two-sided property in which the thermochromic pattern is alternately stored in the normal temperature range and stored for visualization, and the thermochromic pattern exhibits a large hysteresis characteristic in the relation of temperature-color density and discolors. The quasi-reversible temperature-sensitive dye is colored with a coloring material containing the quasi-reversible temperature-sensitive dye, and when the temperature of the quasi-reversible temperature-sensitive dye is in the first hue state and the temperature rises, the second temperature t 3 is reached. , the first color begins to discolor, become completely second color at a second higher temperature t 4 above temperature range than the temperature t 3, the temperature sensitive dye is in the process of temperature in the second color state is lowered the the second reaching the first temperature t 2 less than the temperature t 3, the second Phase begins to change color, become completely the first color at a first temperature range lower temperatures t 1 less than the temperature t 2, the temperature range between the temperature of the first temperature t 2 and the second temperature t 3 Is a temperature-sensitive dye exhibiting a hysteresis characteristic that both the first hue and the second hue can coexist, wherein the temperature t 1 is a temperature between 0 ° C. and 15 ° C., and the temperature t 4 is 27. ° C. to a temperature of between 90 ° C., a temperature range between the first temperature t 2 and the second temperature t 3 is the temperature range within the range of 10 ° C. to 35 ° C., the visual density on coloration A thermochromic picture book, characterized in that a quasi-reversible thermosensitive dye that exceeds that of a non-color-change image is selected.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1987195119U JPH066936Y2 (en) | 1987-12-23 | 1987-12-23 | Color-sensitive picture book |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1987195119U JPH066936Y2 (en) | 1987-12-23 | 1987-12-23 | Color-sensitive picture book |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0197962U JPH0197962U (en) | 1989-06-29 |
JPH066936Y2 true JPH066936Y2 (en) | 1994-02-23 |
Family
ID=31485812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1987195119U Expired - Lifetime JPH066936Y2 (en) | 1987-12-23 | 1987-12-23 | Color-sensitive picture book |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH066936Y2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2524886Y2 (en) * | 1991-03-18 | 1997-02-05 | 榮一 太田 | Map |
JP2012183779A (en) * | 2011-02-14 | 2012-09-27 | Pilot Ink Co Ltd | Picture book set for drawing |
JP2015208376A (en) * | 2014-04-24 | 2015-11-24 | フジモリ産業株式会社 | Paper for folding |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60264285A (en) * | 1984-06-13 | 1985-12-27 | Pilot Ink Co Ltd | Reversible thermal recording composition |
JPS6343094Y2 (en) * | 1985-06-18 | 1988-11-10 |
-
1987
- 1987-12-23 JP JP1987195119U patent/JPH066936Y2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH0197962U (en) | 1989-06-29 |
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